Académique Documents
Professionnel Documents
Culture Documents
w
= Enthalpy at 100C (Saturated vapour)
Q
8
= 4800 x 2676 = 12.84 GJ
54
Q
7
= Q6 Q8 = 13.646 -12.84 = 0.806GJ
Component Enthalpy(GJ) Enthalpy(GJ)
Slurry 13.65
Water 12.84
Wet SSP 0.81
TOTAL 13.65 13.65
4. SCRUBBER
0MJ
Water 25C
Q
8
100C Q
10
HF = 1.2 t Solution
Water = 4.8t
As obtained earlier, Q
8
= 12.84GJ
Q
10
= Q
8
+
Q9
= 12.84 + 0
= 12.84GJ
Component Enthalpy(GJ) Enthalpy(GJ)
Gases 12.84
Water 0
Solution 12.84
TOTAL 12.84 12.84
5. DRYER
Hot dry air
T = 120C
M = 250.093 tons
54 tons 52.365 tons
49.5 tons SSP SSP = 49.365 tons
4.5 tons H
2
O H
2
O 3.0 tons
100C Hot air
Vapour = 1.5 tons
Q = 4.014GJ T = 105C
Solids = 0.135 tons
Heat energy = Mass * Enthalpy
55
Mass of evaporated vapour (Mv) = 1.5tons
Enthalpy of steam at 100C () = 2676KJ/kg
Q (M
V
) = 1.5 * 10
3
* 2676 = 4014000KJ
Heat of Drying = 4.014GJ
M
V
= M
air
Cp T
M
air
= Mass of hot dry air
Cp of hot dry air at 100C = 1.07KJ/Kg
Change in temperature (T) = 120C 105C = 15C
1.5 * 1000 * 2676 = M
air
* 1.07 * 15
M
air
= [1.5*1000*2676]/[1.07*15] = 250.093 tons
Moisture Enthalpy at 25C = 1.5 1000 335.474 = 503211KJ = 0.503GJ
Since at 25C the enthalpy was taken to be 0, enthalpy of moisture at 105C is obtained
by deducting that of 25C from 105C i.e.
(440.274 104.8KJ/Kg) = 335.474KJ/Kg
Enthalpy of wet TSP = 0.806GJ
After drying
Enthalpy of moisture content after drying = 3 335.474 1000 = 1006422KJ = 1.01GJ
Total Enthalpy after drying = Enthalpy of dry SSP + Enthalpy of moisture it contains
= 0.806 + 1.01 = 1.816 GJ
Component Enthalpy(GJ) Enthalpy(GJ)
Wet SSP 0.81
Heat for Drying 4.01
Dried SSP 1.82
Cooled Stream 3.00
TOTAL 4.82 4.82
56
CHAPTER FIVE
5.0 EQUIPMENT SPECIFICATION
1. Conveyor Belt
This design requires six conveyor belts
BC1 BC2 BC3 BC4 BC5 BC6
Diameter(m) 1 1 1 1 1 1
Length 46 49 47 45 48 50
Material Flexible
rubber
Flexible
rubber
Flexible
rubber
Flexible
rubber
Flexible
rubber
Flexible
rubber
2. Ball Mill
Length - 4.25m
Diameter - 9.84ft
Power - 10kwh/ton
Balls diameter 25 -125mm
Material - Carbon Steel
3. Cyclone
Diameter - 1.1m
Length of cylinder - 2.2m
Length of cone - 2.2m
Height of entrance - 0.55m
Width of entrance - 0.275m
Diameter of exit cylinder - 0.55m
Diameter of dust exit - 0.275m
Number of revolutions - 6
Flow rate - 649.35 tons/hr
Material - Carbon Steel
4. Scrubber 1
Type Circular spray tower
Gas flow rate 365 399ft
3
/min
Water flow rate 15792.5ft
3
/min
Material for construction Carbon Steel & API
57
Pressure Atmospheric pressure
Volume - 452m
3
Diameter 4m
Height 36m
Mist eliminator 33m height
5. Scrubber 2
Type Circular spray tower
Gas flow rate 5907.51ft
3
/min
Water flow rate 7166.84ft
3
/min
Material for construction Carbon Steel & API
Pressure Atmospheric pressure
Volume 204m
3
Diameter 3m
Height 29m
Mist eliminator 27m height
6. Leaching tank
Flow rate 52540kg/hr
Diameter 3m
Height 4m
Volume 57m
3
Material Carbon Steel & API
Type - Vertical, cone roof and flat bottom
7. Agitator for leaching tank
Type Paddle with 4 arms
Power 4.9Kw
Diameter 1m
Rotation- 2.2rev/s
8. Storage tank
Flow rate 50170kg/hr
Diameter 3m
58
Height 6.83m
Volume 48.30m
3
Material Carbon Steel & API
Type - Vertical, cone roof and flat bottom
9. Mixer 1
Flow rate 30000kg/hr
Diameter 3m
Height 2.93m
Volume 20.7m
3
Material Carbon Steel
Type - Jacketed and Non-agitated
10. Mixer 2
Flow rate 60000kg/hr
Diameter 3m
Height 8.1m
Volume 55.27m
3
Material Carbon Steel
Type - Mixer & Settler
11. Cone Mixer
Flow rate 30000kg/hr
Diameter 3m
Height 7m
Volume 49.41m
3
Material Carbon Steel
Type - Mixer & Settler
12. Reactor
Flow rate 23000kg/hr
Diameter 3m
Height 4.5m
Volume 32.20m
3
59
Material Carbon Steel
Type - Jacketed & Agitated
13. Agitator for Reactor
Type Paddle with 4 arms
Power 6.3 Kw
Diameter 1m
Rotation- 2.2rev/s
14. Continuous Den
Flow rate 60000kg/hr
Width 3m
Length 4m
Volume 65m
3
Material Carbon Steel
Type - Mixer & Settler with screw conveyor
15. Vibrating screen
Vibrations 3600 vibrations/min
Screen diameter- 1.2m
Size of openings- 4mm
Feed rate 50300kg/hr
Type 1-deck
Deck area - 742ft
2
Material - Carbon steel with light carbon steel wire
16. Coating drum
Flow rate 50000kg/hr
Diameter 3m
Height 8.3m
Volume 59m
3
Material Carbon Steel
Type - Horizontal & round
17. Pump
60
Centrifugal pump
Type - Vertical turbine, 1-stage
Diameter - 6inches
Height - 22m
Length - 30m
Efficiency - 40%
Flow rate - 68.22m
3
/hr
Material - Cast Iron & API
Power - 20hp
18. Rotary Drier
Design feed capacity 60700kg/hr
Volume flow rate of air 639M
3
/s
Slope of the shell 1in/ft
Diameter 3m
Length 6m
Type Rotary, direct, Gas-fired with flights
Area 55.65m
2
19. Plate and Frame filter
Plates Rectangular and vertical
Plate area - 40cm x 40cm
Filter medium- Carbon Steel
Frame thickness 5cm
Material Cast Iron
Number of plates 70
Area of filter 121.25ft
2
20. Precipitator
Diameter 3m
Area 28.27m
2
Height 0.22m
Material Carbon Steel
61
21. Agitator for Precipitator
Type Paddle with 4 arms
Power 5.77Kw
Diameter 1m
Rotation- 2.2rev/s
22. Rortification tank
Flow rate 20kg/hr
Diameter 3m
Height 3m
Volume 57m
3
Material Carbon Steel & API
Type - Vertical, cone roof and flat bottom
23. Clarifier
Flow rate 12.3kg/s
Height 0.49m
Area 266.5m
2
Material Carbon Steel & API
Type - Vertical, cone roof and flat bottom
24. Agitator for clarifier
Type Paddle with 4 arms
Power 5.3Kw
Diameter 1m
Rotation- 2.2rev/s
25. Crusher
Size range - 20 -200
26. Bag House
Type Fabric filter dust collector
Flow rate 2ft/min
Particle size range 74 1micrometer
27. Granulator
Motor 300hp
Feed 57.2 tons
62
CHAPTER SIX
6.0 EQUIPMENT DESIGN
6.1 CYCLONE DESIGN
6.0 INTRODUCTION................................................................................................... 62
6.1 CYCLONE DESIGN.................................................................................................. 62
6.2 CYCLONE LAYOUT ................................................................................................. 64
6.3 MECHANICAL DESIGN............................................................................................ 65
BY JOY BUSOLO CPE/21/99
63
6.1.1 INTRODUCTION
A significant challenge in many fertilizer processing plants is to minimize air pollution
caused by dust fertilizer particles that could be carried in air. Dust separation mechanism
that offers effective pollution control is thus needed.
The available particulate control equipment available includes:
6.1.2 Gravity settling chambers
Gravitational force is employed to remove particulate in settling chambers. Gravity
collectors are generally built in the form of long, empty, horizontal, rectangular chambers
with an inlet at one end and an outlet at the side or top of the other end. The difference
in densities between the solid particles and the transport gas acts as the driving force.
6.1.3 Wet collectors
In a wet collector, a liquid, usually water is used to capture particulate dust or to increase
the size of aerosols. In either case the resulting increased size facilitates the removal of
the contaminant from the gas stream. Fine particulate, both liquid and solid ranging from
0.1 to 20 micrometers can be effectively removed from a gas stream by wet collectors.
6.1.4 Electrostatic precipitators
When particles suspended in a gas are exposed to gas ions in an electrostatic field, they
will become charged and migrate under the action of the field. The functional
mechanisms of electrical precipitation may be listed as follows:
1. Gas ionization
2. Particle collection
a. Production of electrostatic field to cause charging and migration of dust
particles
b. Gas retention to permit particle migration to a collection surface
c. Prevention of re-entrainment of collected particles
d. Removal of collected particles from the equipment
There are two general classes of electrical precipitators:
(1) Single stage, in which ionization and collection are combined
(2) two-stage, in which ionization is achieved in one portion of the equipment, followed
by collection in another.
64
6.1.5 Impingement/Inertial separators
Impingement separators are a class of inertial separators in which particles are
separated from the gas by inertial impingement on collecting bodies arrayed across the
path of the gas stream. Fibrous-pad inertial impingement separators for the collection of
wet particles are the main application in current technology. With the growing need for
very high performance dust collectors, there is little application anymore for impingement
collectors that catch large amounts of dry dust.
6.1.6 Centrifugal separators
6.2 CYCLONE DESIGN
Cyclone separators are gas cleaning devices that employ a centrifugal force generated
by a spinning gas stream to separate the particulate matter from the carrier gas. In this
case air is used to separate TSP solid particles from the cooled stream from the dryer.
The solid particles are taken back to the process for recycle while the gas goes to the
scrubber for further cleaning.
There are two types of cyclones
The cyclone in question is a 2D2D single chamber rectangular inlet involute type.
6.2.1 Operation principle
Once the gas is introduced into the cyclone through the rectangular inlet, the circular
motion of the gas is attained as a result of the tangential gas inlet. The rectangular
involute inlet passage has its inner wall tangent to the cylinder and the inlet blends
gradually with the cylinder over a 180 involute. The operation depends on the tendency
of the particles to move in a straight line when the direction of the gas stream is
changed. The particles then slide down the walls and into the storage hopper. The
gradually cleaned gas reverses its downward spiral motion and forms a smaller
ascending spiral.
6.2.2 Flow pattern
In a cyclone the gas path involves a double vortex with the gas spiraling downward at
the outside and upward at the inside. When the gas enters the cyclone, its velocity
undergoes redistribution so that the tangential component of velocity increases with
decreasing radius. Tangential velocity approaches zero at the walls while radial velocity
65
is directed toward the center throughout most of the cyclone, except at the center, where
it is directed outward.
[v
1
/v
2
] = [r1/r
2
]
0.7
The performance of a cyclone can be measured in terms of efficiency using
6.3 MECHANICAL DESIGN
1. Diameter of cyclone (D
c
)
2
1
8
|
.
|
=
in
C
V
Q
D
Where
Q = volumetric flow rate of gas into the cyclone
V
in
= velocity of inlet gas
Q = 639000 kg/hr
639000 / 4 = 159750 kg/hr
159750/1.149 = 139033.9 m
3
/hr
139033.9/3600 = 38.62 m
3
/s
V
in
= Q/A
Where A = inlet area
= 38.62/0.15125
= 255.34 m/s
D
c
= [(8 * 38.62)/255.34]
1/2
= 1.1m
This diameter is used to determine several design parameters for the cyclone
according to the following correlations
66
Diameter - 1.1m
Length of cylinder, L
c
- 2.2m
Length of cone, Z
c
- 2.2m
Height of entrance, H
c
- 0.55m
Width of entrance, B
c
- 0.275m
Diameter of exit cylinder, D
e
- 0.55m
Diameter of dust exit, J
c
- 0.275m
2. Number of revolutions (N
e
)
| | 2 /
1
C C e
Z L
H
N + =
= 1/0.55 [ 2.2 + 2.2/2]
= 6
3. Particle diameter (d
p
)
( ) ( ) | |
g p
in
e p
V N W d = / 9
67
where
= viscosity of air at 86c = 0.0002 Pa
B
c
= inlet width = 0.275
p
= density of particles = 1100kg/m
3
g
= density of air at 86C = 1.149kg/m
3
d
p
= [9*0.00002*0.275/(3.142*6*255.34(1100 1.149))]
= 2.163 * 10
-6
m
4. Radial velocity of air
R V d V in p
P r
18 /
2 2
=
= (1100*(2.163 * 10
-6
)
2
*(255.34)
2
)/(18*0.0002*0.55)
= 1.7m/s
5. Efficiency of a cyclone
= [1 (Amount of dust in the outlet stream/Amount of dust in the inlet stream)] * 100
= [ 1 (18/152) ] * 100
= 88%
6. Pressure drop
( ) | | { } Ve r r K V P
e t
in
g
2 1 / 2 2 1 203 /
2
2
+ + =
Where
K = function constant
r
t
= radius of which the centerline is tangential
r
e
= radius of exit pipe
V
e
= velocity of exit dust
To obtain K,
( )
t s C
A A F / =
F
c
= friction factor which is taken as 0.005 for gases
A
s
= surface area of cyclone exposed to the surface area of a cylinder with the
same diameter as the cyclone and length equal to the total height of the
cyclone (barrel and cone)
2r (Z
c
+ L
c
)
= 2 * * 0.55 (2.2 + 2.2)
= 15.20m
2
A
1
= area of inlet duct
= 0.55 * 0.275
68
= 0.15125m
2
= 0.005 * (15.20/0.15125)
= 0.5
r
t
/r
e
= 0.275/0.1375
= 2
From tables, we obtain the cyclone pressure drop factor (K) using r
t
/r
e
as 2 and
as 0.5.
K = 1
P = 1.149/203 {255.34
2
[1 + 2(1)
2
(2*2) 1] + 2 * 1.7
2
}
= 10.14 millibars
= 1014Pa
7. Cyclone thickness
( ) C P SE PD t
Y O m
+ + = 2 / where
P = Pressure
Do = Diameter of cyclone
C = corrosion allowance
E = Joint quality factor
S = maximum tensile strength
Y = coefficient having value in for ductile ferrous materials
= {(14.7 * 43.30) / 2[(60 000 * 0.85) + (14.7*0.6)]} + 0.1
= (636.6129/102017.64) + 0.1
= 0.10627inches
= 2.7mm
69
6.4 ROTARY DRYER DESIGN
BY NYONJE ISAAC ODHIAMBO CPE/10/99
TABLE OF CONTENTS
6.4 ROTARY DRYER DESIGN................................................................................... 69
6.4.1 INTRODUCTION................................................................................................ 70
6.4.2 DYER CONSTRUCTION.................................................................................... 70
6.6 MECHANICAL DESIGN........................................................................................ 73
70
6.4.1 INTRODUCTION
Drying theory
When a surface is completely covered with water, the drying is fairly constant, and this
period is called the constant-rate period. The dry-bulb temperature minus the wet-bulb
temperature is the potential for heat transfer. The pressure at the wet bulb temperature
minus the pressure at the dew point is the potential for mass transfer.
The higher the temperature of the inlet gas stream, the higher the efficiency of the dryer
in general.
The equilibrium moisture content of any substance will depend upon temperature and
humidity of the surrounding and will vary according to the material. The temperature of
the material remains at the wet bulb temperature for as long as the moisture is being
removed, by which time the dry bulb temperature will have fallen to a point at which it
has no harmful effect on the product.
Types of Rotary Dryers
The following are the types of dryers:
Drum dryers, Rotary dryers, Tunnel dryers, Spray dryer, Pneumatic dryers, Fluidized-
bed dryers, Turbo-shelf, Tray dryers -shelf, Disc dryers and Tumble Dryers.
Choice of Dryer
More material is dried in rotary dryers than any other type of dryer. Lasts for years
without maintenance problems and their efficiency is also high.
Rotary Drying
It is mounted at a modest angle with the horizontal so that any feed material introduced
at the upper end will travel to the lower or discharge end. The ratio of length to diameter
of the shell may vary widely from as high as 10 or 12 to 1 or as low as 2 to1.Most dryers
have flights or lifters placed spirally or parallel along the length of the shell. Heat is
usually supplied through the introduction of hot air. About 50-70% of he volume is filled
with the material to be dried and the internal pressure is between 1 -10Kpa.
6.4.2 DYER CONSTRUCTION
Fabrication is done by carbon, stainless or other alloy with reinforced bands for fitting
and drive rings. Flight or lifters are welded or bolted internally to provide the required
degree of contact between the material and the drying air.
71
The drum rotates on cast iron or steel tyres, supported on forged or cast steel supported
rollers with shaft mounted. All rollers assemblies are fitted with safety guards and
lubrication where appropriate.
The dryer drum is rotated by an electric motor through V-belts, gear box pinion and
either heavy duty chain to a chain wheel. Integral low speed auxiliary drives can be
supplied for emergency or maintenance purposes.
6.4.3 Process Control
Product moisture content can be controlled through control of exhaust air temperature.
This control is achieved by regulating the flow of fuel to the burner by means of a
temperature controller with a thermocouple located in the exhausted air duct.
The evaporation load may be controlled by measurement of inlet air temperature using a
second controller with temperature probe located in the inlet air duct and output signal to
a variable rate feeder.
6.4.5 Dryer Design
6.4.5.1 Design Consideration
The general procedure for design of the rotary dryer is as outlined below.
1. Calculating the amount of heat required to achieve the desired reduction of moisture
at the design throughput.
2. The diameter of the dryer drum is therefore related to the quantity of air required for
drying.
3. The length of the dryer is related to the time required to the effect the transfer of heat
from the drying air stream to the material being processed and the time required to effect
the transfer of the masses of water evaporated from the material to the drying air stream.
4. Mechanical specifications (dryer drum plate thickness, tyre dimensions, support roller
loadings, shaft and bearing capacities as drive power requirements).
6.4.5.2 Heat Load
Moisture content of fertilizer is reduced from 21.7 -6%.At T= 86.3C,heat of evaporation,
= 2279KJ/Kg, it is assumed that this heat is used only for evaporation. The total
amount of moisture to evaporated is, m = 10.2 tons,
Thus Q
D
= m = 102000kg 2279KJ/Kg = 23.3GJ/hr
Where Q
D
is the amount of heat energy required to vaporize the water.
72
6.4.5.3 Amount Air required for Drying.
Hot dry air enters at T
1
= 120C
Air leaves at T2 = 87C
Hence T = (T
1
-T
2
) = 33C
Heat given out by dry air is given by
T C M Q
P air AIR
=
Where C
P
specific heat capacity of air = 1.07KJ/KgK
but Q
D =
Q
AIR
= 23.2GJ/hr = 22002880Btu/hr
thus M
air
= G = (Q
AIR
/C
p
T) = (102002279)/(107033) = 658 ton /hr = 182.8 Kg/s
6.4.5.4 Diameter of the Dryer Drum
Estimated diameter of the dryer is
D = 3.0m = 9.8424 ft, but ( )
5 . 0
/ 4
S
G G D = where
G gas flow rate Kg/s
G
S
gas flow rate Kg/sm
2
Thus G
S
= (4182.8)/(9) = 25.85Kg/sm
2
= 0.0235m
3
/sm
2
= 19027 lb/hft
2
Number of transfer units N
t
is given by
( ) ( ) Perry tm T T N
t
= /
2 1
tm = logarithimic- mean temperature difference = (34 1.7)/(ln34/1.7) = 10.8K
t
1
= 120 86 = 34K
t
2
= 88 -86.3 = 1.7K
Hence N
t
= (120-88)/10.8 = 2.96
The rate of heat transfer is given as
( ) Perry tm LDG tm V G Q q S
D t
= = =
67 . 0 67 . 0
125 . 0 5 . 0
where D diameter of dryer(ft), L dryer length(ft),V- dryer volume(ft
3
)
L = 22002880 /(0.1259.842419027
0.67
10.8) = 715ft = 218m
But universally, 4< L/D <12 , hence 218/3 = 72
This requires more than i dryer to bring the ratio to acceptable level,
using 4 dryers instead of1, we get G
S
= (19027 / 4) = 4756.75 lb/hft
2
q
t
= (22002880 / 4) = 5500720Btu/hr
hence L = 452.9ft = 138m , now L/D = 138/3 = 46 > 12, still more
for 5 dryers,
L = 420.8ft = 128m, L/D = 42.8 >12
73
For 6 dryers,
L = 396ft =120m, L/D = 40
Taking 6 dryers with L = 40m, D = 3m
The hold up which is given as percentage of dryer volume is obtained as
\
|
|
.
|
= D SN
F
X
9 . 0
7 . 25
Where D Diameter,m 3.0m
F - Feed rate m
3
/sm
2
(0.0235 / 6 = 0.0039m
3
/sm
2
)
S slope of the dryer (m/m length = 0.083)
N is the rate of rotation(HZ)
X is the hold up, (50 -70%), taking 50%
)
9 . 0
1
7 . 25 F
XSD
N
\
|
=
= (0.5 0.083 9.8424 /25.7 0.0039)
1/0.9
= 0.246HZ = 12.6rpm
Which is within the acceptable value i.e 5 -35rpm
Summary of Chemical Dryer Design
Dryer type : Rotary drum dryer
Diameter: 3m (9.8424ft)
Length : 40m (131.2ft)
Speed : 12.6 rpm
Operating Pressure: 11KN/m
2
Material of Construction: Low Carbon steel
Flight: Radial with 90 lip
Inlet air temp. : 120C
Hold up: 50%
Number of transfer units: 2.96
6.6 MECHANICAL DESIGN
Material of construction is low carbon(mild) steel whose typical mechanical and physical
properties are given below(Lloyd,1986)
E Youngs modulus of elasticity = 207 GN/m
2
G Shear modulus = 80GN/m
2
y
Elastic limit = 280MN/m
2
y
- Shear yield strength =175MN/m
2
74
Tensile strength =480MN/m
2
Ultimate strength in shear = 350MN/m
2
Percentage elongation = 25%
Density = 7800Kg/m
3
Linear coefficient of thermal expansion = 11.710
-6
Design stress (f) at 100C = 125N/mm
2
6.6.1 Thickness of the Drum
If D
i
is the internal diameter, the minimum thickness, then, the mean diameter will be
(D
i
+ t ).
Thickness, is given as (Coulson,1996)
(
) )
\
|
=
i
i i
P f
D P
t
2
where P
i
(11KN/m
2
)
internal pressure , f(125N/mm
2
) the design stress
= (0.0113000) /(2125 0.011)
= 0.132mm
A much thicker wall will be required at the column base to withstand dead weight loads.
The nominal thicker for a 3m diameter is 10mm (Coulson,1996).
Hence taking t = 10mm,
6.6.2 Dead weight of the vessel
Coulson (1996) gives the formula
( )
3
10 8 . 0 (
+ = t D H g D C W
M V M M V V
where W
v
total weight of the drum excluding the flights. C
V
(1.15) - a factor to account
for the weight flights and internal supports. H
V
Length of dryer = 40m
t wall thickness,
m
density of material (7800Kg/m
3
) , D
m
mean diameter of
vessel(3 + 1010
-3
) = 3.01m
W
v
= 78009.8110
-3
1.153.01(40 + 0.83.01)10 = 352 KN
6.6.3 Analysis of stress (Hearn,1997)
6.6.3.1 Hoop or Circumferential stress,
H
t PD
H
2 / = where P internal pressure, t- thickness, D- internal diameter
= (113000) / (210) = 1650 KN/m
2
For a thin rotating cylinder,
H
=
2
r
2
= 78001.54
2
1.5
2
= 27952N/m
2
Since f = 2 = 1.54 rads/s
6.6.3.2 Longitudinal Stress
L
75
2
/ 825 4 / m KN t PD
L
= =
6.7 Design of Flat ends
The minimum thickness required is given by
( ) f p D C e
e
P
/ = = 0.553000(0.011/125) = 1.54mm
where
e P
D C 55 . 0 = ,De = D (nominal plate diameter)
6.8 Saddle Supports
A vessel supported on two saddles, maximum stress occurs at the supports and at the
mid-span. The saddles supports will be located near the ends.
6.8.1 Stress in the vessel wall,
b1
( ) t D
L b
2 / 4
1
= = (4 825) /(91010
-3
) = 11671KN/m
2
76
CHAPTER SEVEN
7.0 PROCESS CONTROL AND INSTRUMENTATION
7.1 PROCESS CONTROL
A process forms a set of production or processing functions executed in and by means
of process hardware such as tanks, pipes, fittings, motors, shafts, couplings, measuring
devices etc.
The performance of an industrial process is influenced by internal and external
conditions called process variables which include:
Energy variables temperature, pressure, electricity, sound and radiation.
Quantity and rate variables fluid flow, liquid level, weight, thickness and speed.
Chemical and physical characteristics density, humidity, moisture content, viscosity,
calorific value, colour, electrical and thermal conductivity, chemical absorption, refractive
index, x-ray diffraction, polarity, PH, oxidation-reduction potential.
7.1.1 CHARACTERISTICS OF INSTRUMENTATION SYSTEM.
Measurement systems are designed to accurately detect changes in parameters
encountered in industrial process such as pressure, fluid flow, motion resistance,
voltage, current and power.
The information they generate facilitate the manual or automated control.
7.1.2 PROCESS CONTROL.
In a processing plant, the above listed variables need to be controlled. One of the first
consideration is to categorize all the system inputs and outputs into those which can be
controlled, those which may be adjusted to achieve this control, and those which are
beyond the control of the designer.
The control of the process variables is achieved by the control instrument e.g.
electromagnetic valves, transformer trap positions etc. The process control is, therefore,
an engineering science of measuring one or more of these process variables and
automatically controlling them to the desired level called set points or reference points
in spite of disturbance.
77
7.1.3 CLASSIFICATION OF CONTROLLERS
The three types of controllers depending on the actuating medium are described below;
1. Pneumatic controllers i. Displacement sensing devices (pneumatic nozzle-
flapper); ii. Pneumatic relays
2. Hydraulic controllers.
3. Electrical controller.
7.1.4 MODES OF CONTROL ACTIONS
A controller is used to eliminate or reduce error (difference between set point and the
measured output) by generating a correction signal to the final control element. Modern
industrial controllers are usually made to produce one or a combination of six basic
control actions i.e.
1. On off or two position action
2. Proportional control action
3. Integral control action
4. Derivative control action
5. Proportional plus Integral (PI) control action
6. Proportional plus Integral plus Derivative (PID) control action
For this project, the system employed to control the process are;
Automatic control which are electrically operated
Direct digital (electronic) control which uses the PID.
7.1.5 CONTROL SEQUENCES
The integrated system control will involve such operations as interlocking, timing and
recording. These are particularly important during such operation times such as start up,
shut down and change of operating capacity. Timers and relays should be used in these
operations.
Typical Control Of Unit Operation
In all the unit operations to be performed, it requires the control of parameters such as;
Pressure
The pressure measurement method used in this project will be Electrical pressure
transducers which uses elastic primary sensing elements such as the Bourdon tube,
Bellows and Diaphragm
78
These are mostly used pressure gauge because of their simplicity and rugged
construction. Covers ranges from 0-15psig to 0-100 000psig,as well as vacuum from 0 to
30 inches of mercury,
Temperature
Temperature controllers used for this project is thermostat and the instrument for
measuring the temperature would be thermocouple due their sensitivity.
Flow rates concentrations of streams
A number of measurements are used for determining the chemical composition. The
measurement of these variables is based on; Electromagnetic radiation, chemical
reactions, current, voltage or flux changes produced in energized electric and magnetic
circuits and the result of applying thermal or mechanical energy to a system.
Level of liquids
For the project, sight-glass and electrical method of measurement will be used.
Alarms
Alarms will be used to draw the attention of the operator to the process whenever
there is any disturbance /deviations caused by the change in one of the parameters to
be monitored in the equipment.
7.2 CONFIGURATION OF THE PROCESS CONTROLS
7.2.1 CONTROLS
The main control parameters to be monitored in the plant would be pressure,
temperature,
composition, level and feed flows. Major equipment in the plant will be used to discuss
the controls.
1. Ball Mill
It is used to grind the phosphate rock. There are a number of variables that can change
causing the operation to deviate from its desired value. Therefore, action must be taken
to control any deviation so as to maintain the outlet flow rate at its desired value F (t).
An automatic control can be achieved by measuring the flow rate using a flow sensor
comparing the value with the set point and the deviation corrected.
79
Flow Control in Ball Mill
2. Mixing Tank
This tank mixes the controlled flow of Sulphuric and water to produce dilute acid. A
desired flow rate of concentrated acid and diluting water is to be maintained. An
automatic control is achieved by measuring the flow rates using a flow sensor,
comparing the value with the set point and any deviation is corrected.
80
Control of the Mixer
3. Dryer
The dryer receives granulated wet grains mixture from granulator and by hot gas, the
water content is lowered to an amount maintained at some desired level. This is
achieved automatically through utilization of a feed flow sensor to measure the flow rate.
Deviations are corrected by adjusting the inlet and outlet valves appropriately.
Control for Dryer
81
4. Reactor
A desired flow rate of phosphoric acid rock products is to be maintained by opening or
closing the outlet valve. The automatic control is achieved by measuring the flow rate
using a flow sensor, comparing the value with the set point value and by deviation
adjusts the flow tare appropriately. A sight glass, pressure and temperature indicators,
lump are also fitted to enhance control.
Control for Reactor
6. Scrubber
A desired concentration of exit gas is to be maintained. The automatic control can be a
achieved by measuring the concentration using a concentration sensor, comparing the
value with the desired (set point) value and adjusting the water inlet flow accordingly.
82
7. Leaching Tank
A desired flow rate of hydrochloric acid, flocculant and the dry fertilizer is to be
maintained by opening or closing the inlet valve. When a disturbance such as change in
feed flow of inlets and concentration of acid occur, the automatic control can be
achieved by measuring the flow and concentration sensors, comparing the values with
the set points and adjusting the values appropriately.
FC
FC
Control for Leaching Tank
8. Pumps
A desired flow rate is to be maintained by opening or closing the outlet valve. The
disturbance may occur include flow changes. The automatic control may be achieved by
measuring the flow rate using a flow sensor, comparing the value with the set point
and adjusting the fluid outlet appropriately.
83
9. Plate and Filter Frame
This is used to dewater the wet fertilizer. This is achieved by controlling feed flow of
fertilizer and the filter aid. The disturbance may include changes in flow .The automatic
control can be achieved by measuring the inlet flow rate. By putting a flow sensor and
comparing the value with the set points, adjustment of the values can be done
appropriately.
PF1
Control for Plate and Frame Filter
CC
84
CHAPTER EIGHT
8.0 ECONOMIC ANALYSIS
8.1 INTRODUCTION
A design engineer, by analysis of costs and profits attempts to predict whether capital
should be invested in a particular project. This is done with the assumption that the
original cost predictions will agree with the facts obtained during implementation.
This chapter looks into the economic aspects of the plant. The viability of the project
would be tested by doing the profitability analysis. The equipment cost used is obtained
from www.matche.com giving costs as per year 2003 in relation to their physical
dimension.
8.2 PLANT SPECIFICATION
Start of construction 2006
Completion is end of 2007
Commencement of operation 2008
Expected plant life is 15 years
Operation conditions are as follows:
The plant operates in a 24 hour basis with 3 shifts of 8 hours each, 300 days a
year at 100 % capacity
Production costs will increase at a rate of 4% per annum and selling price will
increase by 11% by the end of the 15
th
year.
Salvage value is 12% of fixed capital investment
Sum of- the years digit method will be applied to calculate the depreciation
An operation running at 100% capacity is equal to 50tons per hour and 1200 tons
per day.
The cost index for 1990 is 356 while that for 2003 is 405.
8.3 ECONOMIC EVALUATION
Consideration is given to the following factors while carrying out the economic
evaluation.
1. FIXED CAPITAL INVESTMENT [FCI]
This is the capital needed to supply the necessary manufacturing and plant facilities.
Manufacturing FCI includes equipment with all auxiliary, piping, instrumentation,
85
insulation, foundation and site preparation. While the non-manufacturing FCI consists of
land, processing buildings, administrative offices, warehouse, laboratories,
transportation, shipping and receiving facilities.
2. WORKING CAPITAL [WC]
This is the amount of money used to operate the plant. It consists of costs of raw
materials, finished products in stock , semi-finished products, accounts receivable, cash
kept at hand for salaries and wages, accounts and taxes payable.
3. TOTAL CAPITAL INVESTMENT [TCI]
This is the sum value of working capital and fixed capital investment.
TCI = FCI + WC
Total product cost [TPC]
It consists of the following cost
i) Manufacturing cost
Direct production costs
Fixed charges
Plant overhead costs
ii) General expenses
Administrative expenses
Distribution and marketing expenses
86
1. DELIVERED EQUIPMENT COST
EQUIPMENT NUMBER COST (2003)
US $
TOTAL US $
(2003)
Conveyor belt 6 90 800 544 800
Ball Mill 1 807 000 807 000
Cyclone 4 319 600 1 278 400
Scrubber 4 646 600 2 586 400
Scrubber 1 18 800 18 800
Agitator for scrubber 1 5 800 5 800
Leaching tank 2 19 900 39 800
Agitator for leaching tank
1 5 800 5 800
Storage tank 2 17 900 35 800
Mixer 1 1 21 000 21 000
Mixer 2 1 322 100 322 100
Cone mixer 1 306 400 306 400
Reactor 1 83 400 83 400
Agitator 1 5 600 5 600
Continuous den 1 9 900 9 900
Vibrating screen 2 125 000 250 000
Coating drum 1 25 300 25 300
Pump 8 3 100 24 800
Rotary drier 4 209 900 839 600
Plate & frame filter 4 47 700 190 800
Precipitator 1 123 900 123 900
Agitator for precipitator
1 6 200 6 200
Rortification tank 1 26 700 26 700
Clarifier 2 473 000 946 000
Agitator for Clarifier 2 6000 12 000
Crusher 1 792.8 793
Bag house 1 400
1990
455
Granulator 1 792.8 793
Mortar (300hp) 1 18 000
1990
20 478
TOTAL
3 747 385.6 8 538 819
87
2. FIXED CAPITAL INVESTMENT [FCI]
FCI is based on percentage delivered equipment cost
ITEM % ON PURCHASED
EQUIPMENT
COST (US $)
DIRECT COSTS
1. Purchased equipment 100 8 538 819
2. Equipment installation 36 3 073 975
3. Instrumentation and
controls
28 2 390 869
4. Piping 32 2 732 422
5. Electrical installation 20 1 707 763
6. Buildings 20 1 707 763
7. Yard improvement 8 683 106
8. Service facilities 60 5 123 291
9. Land 4 341 553
TOTAL DIRECT COSTS 308 26 299 563
INDIRECT COSTS
1. Engineering and
supervision
40 3 415 528
2. Construction expense 48 4 098 633
3. Contractors fee 8 683 106
4. Contingency 32 2 732 422
TOTAL INDIRECT COSTS 128 10 929 689
FCI (Indirect and direct) 436 37 229 252
3. TOTAL CAPITAL INVESTMENT [TCI]
TCI = FCI + WC
Taking WC = 15% TCI
TCI = FCI + 0.15 TCI
TCI = FCI/0.85 = (37 229 252/ 0.85)
TCI = 43 799 120
WC = 6 569 868
88
4. LABOUR COSTS
Department Title Number Unit Salary
Sh/Month
Total Amount US $
Per year
Administration
Chief Executive Officer 1 600000
94711.91792
Managing Directors 2 480000
151539.0687
General Managers 2 350000
110497.2376
Purchasing Agents 2 250000
78926.59826
Company Secretary 1 100000
15785.31965
Clerks 3 30000
14206.78769
Receptionists 2 25000
7892.659826
Messenger 2 25000
7892.659826
Accounting Finance Manager 1 160000
25256.51144
Accountant 3 150000
71033.93844
Secretary 1 30000
4735.595896
Sales Manager 1 190000
29992.10734
Sales men 4 100000
63141.27861
Secretary 1 20000
3157.063931
Maintenance Superintendent 12 90000
170481.4522
Supervisors 12 80000
151539.0687
Technicians 12 45000
85240.72612
Engineering Production Manager 1 350000
55248.61878
Mechanical Engineers
8 250000
315706.3931
Chemical Engineers 9 250000
355169.6922
Electrical Engineers 5 200000
197316.4957
Civil Engineers 2 200000
63141.27861
Draftsmen 6 40000
37884.76717
Laboratory QC Manager 1 150000
23677.97948
Chief Chemist 1 70000
11049.72376
Chemists 6 30000
28413.57537
Operation Supervisors 12 90000
170481.4522
Operators 50 60000
473559.5896
Security Guards 15 12000
28413.57537
Support Staff Drivers 7 19000
20994.47514
Cleaners 6 15000
14206.78769
89
Kitchen staff 6 15000
14206.78769
TOTAL 197
2895501.18
5. TOTAL PRODUCTION COST ESTIMATION
a) DIRECT PRODUCTION COSTS
ITEM % COST
Raw materials 40% TPC 5 791 218
Operating labour 20% TPC 2 895 609
Operating supervision 25% OL(5%TPC) 723 902
Utilities 15% TPC 2 171 707
Maintenance and repair 6% FCI 2 233 755
Operating supplies 1% FCI 372 293
Laboratory charges 10% OL(2%TPC) 289 561
TOTAL TPC 14 478 044
b) FIXED CHARGES
ITEM % COST
Property taxes 4% FCI 1 489 170
Insurance 1% FCI 372 293
Depreciation 2 503 713
TOTAL FIXED CHARGES 4 365 176
c) PLANT OVERHEAD COST
60% of OL, supervision and maintenance 3 511 960
TOTAL MANUFACTURING COST 22 355 180
d) GENERAL EXPENSES
ITEM % COST
Administrative 15% OL, supervision and
maintenance
877 990
Distribution and marketing 11% TPC 1 592 585
Research and development 5% TPC 723 902
TOTAL GENERAL EXPENSES 3 194 477
90
TOTAL PRODUCTION COST 25 549 657
6. TOTAL SALES
PRODUCT
(SSP/TSP)
ANNUAL
PRODUCTION BAGS
(Million)
COST PER BAG
(KSH)
TOTAL SALES
US $ (Million)
1 4.32 900 51.14
2 4.68 900 55.14
3 5.04 920 61.00
4 5.04 920 61.00
5 5.18 940 64.05
6 5.18 940 64.05
7 5.40 950 67.48
8 5.40 960 68.19
9 5.76 960 72.74
10 5.76 970 73.50
11 6.12 970 78.09
12 6.12 980 78.09
13 6.48 980 83.34
14 6.84 1000 89.98
15 7.20 1000 94.71
1 bag = 50kg
The firm starts to operate at 60% maximum capacity and reaches 100% in the 15
th
year.
91
7. DEPRECIATION
Salvage value (V
s
) = 12 % of FCI
= US$ 2 731 323
Depreciation by sum of - the years method
V = US $ 22 761 028
Depreciation = 20 029 705
Income tax is charged at 34% Gross profit
YEAR Depreciation YEAR Depreciation
1 2 503 713 8 1 335 314
2 2 336 799 9 1 168 399
3 2 169 885 10 1 001 485
4 2 002 971 11 834 571
5 1 836 056 12 667 657
6 1 669 142 13 500 743
7 1 502 228 14 333 828
15 166 914
92
8. ANNUAL CASH FLOW
The year to year analysis will be based on the assumption that the plant starts operation at 60% capacity and projects to full
capacity in the subsequent years. (Values * 10
6
)
ITEM 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
FCI 22.76
WC 4.02
TCI
-43.80
Sales 51.14 55.41 59.67 61.00 64.05 64.05 67.48 68.19 72.74 73.50 78.09 78.90 83.54 89.98 94.71
TPC 25.55 26.57 27.63 28.74 29.88 31.08 32.32 33.62 34.96 36.36 37.81 39.33 40.90 42.54 44.24
Annual
operating
income
25.59 28.84 32.04 32.26 34.17 32.97 35.16 34.57 37.78 37.14 40.28 39.57 42.64 47.44 50.47
Depreciation
2.50 2.34 2.17 2.02 1.84 1.67 1.50 1.34 1.17 1.01 0.84 0.67 0.50 0.33 0.17
Profit before
tax
23.09 26.50 29.87 30.24 32.33 31.30 23.66 33.23 36.61 36.13 39.44 38.90 42.14 47.11 50.30
Tax paid
7.85 9.01 10.16 10.28 10.99 10.64 11.44 11.30 12.45 12.28 13.41 13.23 14.33 16.02 17.01
Profit after
tax
15.24 17.49 19.71 19.96 21.34 20.66 22.22 21.93 24.16 23.85 26.03 25.67 27.81 31.09 33.20
Annual cash
income
17.74 19.83 21.88 21.98 23.18 22.33 23.72 23.27 25.33 24.86 26.87 26.34 28.31 31.42 33.37
Annual cash
flow
-26.06
-6.23 15.65 37.63 60.81 83.14 106.86 130.13 155.46 180.32 207.19 233.53 261.84 293.26 326.63
9. GRAPH OF CUMULATIVE CASH FLOW
CUMULATIVE CASH FLOW
-50
0
50
100
150
200
250
300
350
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Years
C
a
s
h
F
l
o
w
94
8.4 PROFITABILITY ANALYSIS
1. DISCOUNTED CASH FLOW ON RETURN
DCFROR is the minimum rate of return by which the capital investment is received at the
end of service life. It is equivalent to maximum interest rate at which money could be
borrowed to finance the project where the net cash flow of the project would be just
sufficient to pay the entire principle amount plus the interest.
i.e.
Initial TCI = net present worth of cash flow for year 1 to 15 (US $)
= - 43 799 120
Year 1 = US $ 17 740 000
Year 2 = US $ 19 830 000
Year 3 = US $ 21 880 000
Hence
43 799 120 = {17 740 000/(1+i)} + {19 830 000/(1+i)
2
} + {21 880 000/(1+i)
3
}+
{21 980 000/(1+i)
4
}+ {23 180 000/(1+i)
5
}+ {23 330 000/(1+i)
6
}+
{23 720 000/(1+i)
7
}+ {23 270 000/(1+i)
8
}+ {23 330 000/(1+i)
9
}+
{24 860 000/(1+i)
10
}+ {26 870 000/(1+i)
11
}+ {26 340 000/(1+i)
12
}+
{28 310 000/(1+i)
13
}+ {31 420 000/(1+i)
14
}+ {33 370 000/(1+i)
15
}
i = 47%
2. PAY BACK PERIOD
This is the period required after the start of the project to pay off the initial investment
from the income. From the graph showing the cumulative cash flow, it is the point where
the curve crosses the x axis i.e. the pay back period is 2 years.
3. RATE OF RETURN
R.O.R = {Average Net profit/ Total Capital Investment} * 100
Average net profit = US $ 24 695 333
R.O.R = {24 695 333/ 43 799 120} * 100
= 56%
95
CHAPTER NINE
9.0 SAFETY AND ENVIRONMENTAL IMPACT
9.1 SAFETY
Any chemical industry has legal and moral obligation to safeguard the health and welfare
of its employees and the general public. The magnitude of safety factors are dictated by
the economic or market considerations, the accuracy of the design data and
calculations, potential changes in the operating performance and the background
information available. On the overall, process safety of the industry is considered under
the following titles:
Identification and assessment of the hazards
Control of the hazards
Control of the process
Limitation of any loss
The potential health hazard to an individual by material used in any chemical process is
a function of the inherent toxicity of the material and the frequency and duration of
exposure. The designer must therefore be aware of these hazards and ensure through
the application of sound engineering practice that the risks are reduced to acceptable
levels. The necessity to anticipate potential problems so as to avoid them or to reduce
their effect requires thorough appraisal of an environmentally significant action before it
is taken. The formalization of this concept is embodied in the environmental impact
assessment.
The main areas that involve safety considerations in this plant include:
Vibration problems
Spillage of acids and their effects
Noise
Corrosion
Accidents
Pressure buildup in continuous den, scrubbers and mixers
Exposure to fumes and vapour and hydrogen fluoride
There are two ways of controlling such problems
Engineering controls
Administrative controls
96
9.1.2 ENGINEERING SAFETY CONTROLS
Involves technical solutions within the design process to deal with the identified problem
1. ISOLATION
Control by isolation or containment is used for highly volatile or toxic material. This will
apply to acids, alkalines and hydrogen fluoride.
2. VENTILATION
Both forced and natural convection ventilation process will be required within the factory.
This will eliminate or reduce to minimal level exposure to fumes and dust
3. CONTROL VALVES
There should be remote control valves to isolate equipment and areas of the plant in an
emergency.
4. ALARMS, SAFETY TRIPS AND INTERLOCKS
Alarms are used to alert operations of the hazardous deviations in process conditions.
Key instruments are fitted with switches and relays to operate audible and visual alarms
on the control and communication panels.
Safety trips should be fitted in equipment where delay in action would cause serious
hazard e.g. the reactors, mixers
5. SPACING
There should be a minimum distance between vessels (5m) between vessels and
buildings.
6. VENT
For all pressure vessels including tanks and columns, a vent system must be installed to
protect the vessel from rupturing.
7. DETECTORS
Detectors of fire should be placed all over the plant
8. MATERIALS
Raw materials such as acids, rock, base and flocculant should be handled with care to
avoid spillage and its effect.
9. SPILLAGE
Spillage should be avoided and whenever it happens, water system should be readily
available to wash out the spillage.
97
9.1.3 ADMINISTRATIVE CONTROLS
1. TECHNICAL FACILITIES
It is required that all personnel working with technical facilities undergo introductory
training of all facilities as indicated below
45 hours initial instruction of site
Days instruction on site
An hours annual refresher training course
2. OPERATING PRACTISES
Adequate training of personnel
Provision of protective clothing
Good house keeping and personnel hygiene
Regular medical check-up of the employers
Ensuring that all safety regulations are adhered to
Conducting HAZOPS study
9.1.4 NOISE CONTROL
Excessive noise is a hazard to health and safety. Long exposure to high noise levels
can cause permanent damage to hearing. At lower levels, noise is a distraction and
causes fatigue. In the plant, noise could be generated by vibration, ball mill and crusher.
To attain efficient, effective and practical noise control, it is necessary to understand the
individual equipment or process noise sources, their acoustic properties and
characteristics and how they interact to create the overall noise situation. Possible noise
control treatments may include acoustically lined fan covers, acoustic plenums, inline
silencers, vibration isolation and lagging.
98
9.2 ENVIRONMENTAL IMPACT
The concept of ecological sustainable industrial development motivates producers and
consumers to use products and operate industry using the best technologies to minimize
adverse environmental impact.
Fertilizer producers and users are faced with a number of potential points where adverse
impacts on the environment may occur. Fertilizer production processes may release
emissions containing potential pollutants that may have local environmental impact and
theoretically may contribute to global environmental problems.
The environmental issues related to use of fertilizer include:
9.2.1 ATMOSPHERIC EMISSIONS [SSP/TSP]
Phosphate rock usually contains 3% to 4.5% of fluorine by weight. During the
acidulation of phosphate rock Hydrogen fluoride is released and converted into fluosilic
acid by silica in the rock most of which is retained in the TSP process but 25% is
released in the SSP process. Wet scrubbers are used in the production of SSP to trap
the 25% that is released to the atmosphere. Efficient scrubber designs allow recovering
of the H
2
SiF
6
as a concentrated solution which could be processed to synthetic cryolite,
aluminium fluoride and various fluorosilicates. If there is no market for the acid or fluoride
derivatives, the fluosilic acid can be neutralized by liming. In addition, fluoride emission
continues during the curing process. Feedstock handling bins for phosphate rock must
be equipped with individual bag filters from which recovered dust is recycled.
9.2.2 PARTICULATE EMISSION
Sources of particulate emissions include the reactor, granulator, dryer, screens, cooler,
mills and transfer conveyors. Additional emissions of particulate result from the
unloading, grinding, storage and transfer of ground phosphate rock. One facility uses
limestone, which is received in granulated form and does not require additional milling.
9.2.3 SOLID WASTE
Solid wastes are not generally produced in finished fertilizer production process because
of the size of the required particles. Oversized particles are recycled to the process.
99
9.2.4 HAZARDOUS WASTE
There are no hazardous wastes in fertilizer production other than the Cadnium contained
in fertilizer. The level of Cadnium content in fertilizer is limited to 50 mg Cd/kg of P
2
O
5
.
This level is increasingly causing concern. Fertilizer organic matter increases the
retention of Cadnium in the fertilizer.
Fluoride emissions cause damage to vegetation and are harmful to livestock that
consume that vegetation.
Phosphorus also contributes to the eutrophication process of the surface waters. Plant
residues contribute to the high phosphorus content of surface waters.
9.2.5 POLLUTION CONTROL
At a typical plant, bag houses are used to control the fine rock particles generated by the
rock grinding and handling activities. These bag house - cloth filters have reported
efficiencies of over 99 percent.
Emissions from the reactor, den, and granulator are controlled by scrubbing the effluent
gas with recycled gypsum pond water in scrubbers.
Emissions from the dryer, cooler, screens, mills, product transfer systems, and storage
building are sent to a cyclone separator for removal of a portion of the dust before going
to wet scrubbers to remove fluorides. Collected solids are recycled to the process.
Emissions of SiF4, HF, and particulate from the production area and curing building
(storage vessel) are controlled by scrubbing the off-gases with recycled water. Gaseous
SiF4 in the presence of moisture reacts to form gelatinous silica, which has the tendency
to plug scrubber packings. Therefore, the use of conventional packed countercurrent
scrubbers and other contacting devices with small gas passages for emissions control is
not feasible. Most emissions of Fluoride into the atmosphere can be reduced by
selecting efficient absorption equipment.
Exhausts from the dryer, screens, mills, and curing building are sent first to a cyclone
separator and then to a wet scrubber. Wet scrubbers perform final cleanup of the plant
offgases.
100
Recycling and by-product recovery of all materials resulting from fertilizer production can
be recycled.
Use of acid leaching process is essential to curb the fatal effects of lead contained in
phosphate rock if exposed to human beings thorough the fertilizer. Acid leaching
process provides long term effectiveness by recovering much of the lead and
reforming to commercial use; this also eliminates the effects of lead associated with the
production and use of fertilizer.
101
CHAPTER TEN
10.0 PLANT LOCATION
The following factors are to be put into consideration when determining the plant
location.
Low nutrient containing fertilizers should be produced near the users area (e.g.
SSP, (NH
4
)CO
3
, (NH
4
)
2
SO
4
).
High nutrient fertilizers, in particular phosphate fertilizers should be produced as
near as possible to the raw material source to minimize transportation costs.
The availability of utilities such as water, steam and electricity near the selected
location presents an advantage.
The establishment of the fertilizer complex near existing electricity power station
provides a better opportunity for process selection.
Environmental protection units are cheaper when joint (industrial or communal)
water treatment stations are constructed or utilized. Waste from fertilizer provides
the feed for active bacteria in the treatment plant.
25 60 hectares of land surface are required.
The soils characteristics and the underground water level are important factors.
Existing transport infrastructure such as road, water, railway line is a necessity.
Availability of both skilled and non skilled labour is a requirement.
With these factors in mind, the proposed plant location site is Migori District in South
Nyanza, Nyanza Province of Kenya. This is because of
Availability of labour
Infrastructure, the roads are well established
Other neighbouring industries such as Sony Sugar
Proximity of the major raw material being phosphate rock i.e. Homabay and
Minjingu in Tanzania
Permanent river water i.e. River Kuja and River Migori
Immediate market from the sugar cane, maize and tobacco farmers
Power (Electricity) generated at Oyani power station.
102
CONCLUSION AND RECOMMENDATION
The ever existing negative balance of trade is contributed by the importation of fertilizer.
The analysis carried out in this project establishes that by its implementation, this
negative balance of trade will reduce plus other benefits such as creation of
employment, reduction of poverty and elimination of diseases related to lead metal.
In the economic analysis, the cost index of 2003 was used and it is thus recommended
that during implementation, the cost of equipment to be adjusted appropriately.
It is our hope that this project or a similar one will be put into operation in the near future.
103
APPENDIX
DETAILED CALCULATION FOR MASS AND HEAT BALANCE FOR REACTOR
Mass Balance
Mass of input material = Mass of output material (in tons)
Mass of Rock +Mass of Phosphoric acid =Mass of the product(TSP)
23 + 31 = 54
Component
Inlet(tons) Outlet(tons)
Phosphate Rock 23
Phosphoric acid 31
Slurry 1 54
Total 54 54
Phosphoric acid
Cp = 2952.6J/KgK
= 0.703Kcal/KgK
Mp = 31 tons
T = 25C
H
3
=0MJ
Rock
Cp = 751.86J/degmol
M = 23 tons
H
2
= 68.4MJ
T = 26.8C
M` = 54 tons
T = 57.6C
H
4
= 70.9MJ
Q = 2475KJ
= 2.5MJ
REACTOR
104
Heat Balance
From the reaction equation in the reactor, it is seen that the heat of reaction is
172.58Kcal i.e.
Ca
3
(PO
4
)
2
+ 4H
3
PO
4
+ H
2
O 3Ca(H
2
PO
4
)
2
.H
2
O + 172.58 Kcal
And using the most appropriate reaction equation,
Ca
10
(PO
4
)
6
F
2
+ 14H
3
PO
4
+10H
2
O 10CaH
4
P
2
O
8
.H
2
O + 2HF
Heat formation (HF) of the reaction components(UNIDO).
Ca
10
(PO
4
)
6
F
2
= 3267.2Kcal/gmol = 13.83GJ
H
3
PO
4
= 308.25Kcal/gmol
,
hence 14H
3
PO
4
=1.78GJ
H
2
O = 68.317 Kcal/gmol, hence 10H
2
O = 0.052GJ
10CaH
4
P
2
O
8
.H
2
O = 4.504GJ
HF= 75.56Kcal/gmol 2HF = 0.013GJ
Thus the heat of reaction is obtained as
13.83+ 1.78+ 0.052 - 4.504 0.013 = 11.14GJ
Component Inlet(GJ) Outlet(GJ)
Rock 0.684
Heat of reaction 11.14
Phosphoric acid 0.0
TSP 11.824
TOTAL 11.824 11.824
Phosphoric acid
Cp = 2952.6J/KgK
= 0.703Kcal/KgK
Mp = 31 tons
T = 25C
H
3
=0MJ
Rock
Cp = 751.86J/degmol
M = 23 tons
H
2
= 68.4MJ
T = 26.8C
TSP
M` = 54 tons
T = 57.6C
H
4
= 11.824GJ
Q = 11.14GJ
REACTOR
105
DETAILED CALCULATION FOR MASS AND HEAT BALANCE FOR CONE MIXER
Mass Balance
0.6 tons of ground rock is required per ton of SSP. For 50 tons/hr we require 30 tons
of ground rock mixing it with the 30 tons of Sulphuric acid (75%).
22.5 tons H
2
SO
4
7.5 tons H
2
O
30 tons 60 tons
28.2 tons Rock 50.7 tons slurry
1.8 tons H
2
O 9.3 tons H
2
O
The rock contains 6% moisture and hence this accounts for the 1.8 tons of water in
the in feed to the cone mixer:
6 % (30) = 1.8 tons
Mass in = Mass out
(29.2 + 1.8 + 22.5 + 7.5) = (50.7 + 9.3)
60 tons = 60 tons
Component Inlet(tons) Outlet(tons)
Ground Rock 30
Sulphuric acid 30
Slurry 60
Total 60 60
Heat Balance
| ( ) | ) ( | | 4 7 2 . 2 4 4 3 2 3 4 2 7 2 3 2 4 3 CaSO O H PO CaH O H SO H CaF PO Ca + + +
Heat formation (HF) of the reaction components(UNIDO).
Ca
10
(PO
4
)
6
F
2
= 3267.2Kcal/gmol = 13.83GJ
H
2
SO4 = 193.91Kcal/gmol hence 7H
2
SO4 = 0.558GJ
CaSO
4
= 483.06 Kcal/gmol hence 7CaSO
4
= 1.93GJ
H
2
O = 68.317 Kcal/gmol, hence 3H
2
O = 0.0152GJ
106
3CaH
4
P
2
O
8
.H
2
O = 1.3512GJ
HF= 75.56Kcal/gmol 2HF = 0.013GJ
Heat of reaction is thus obtained,
13.83 + 0.559 + 0.0156 1.3512 1.93 0.013 = 11.11GJ
H
2
SO
4
70C
Q
5
= 2.482GJ
Rock Slurry 100C
Q
6
= 13.646GJ
Q
3
=54 MJ
Q
R
Working backwards,
Enthalpy of the slurry at 100C is obtaining by using the enthalpy of water at 100C
Q
R
= Heat of reaction
Q
R
= 11.11GJ
Q
6
= Q
3
+ Q
5
+ Q
R
therefore
= 0.054 + 2.482 + 11.11 = 13.646GJ
Component Enthalpy(GJ) Enthalpy(GJ)
Rock 0.05
Enthalpy of Solution 2.48
Slurry 13.65
Heat of reaction 11.11
TOTAL 13.65 13.65
107
BIBLIOGRAPHY
1. Austin T. G, 1984, 5
th
edition Shreve's Chemical Process Industries. McGraw-Hill
book company, New York.
2. Battelle. 1997 a Technology Evaluation Report. Physical separation and acid
leaching. A demonstration of small arms range remediation at Fort Polk, Lovsian.
Report prepared by Battelle Columbus, Ohio operations for the naval facilities
engineering service center and the U.S. Army environmental center.
3. Hearn, E. J. 3
rd
Ed. 1997, Mechanics of Materials, Linacre House, Jordan Hill,
Oxford, Boston.
4. Lloyd E. & Young E., 1986, Process Equipment Design, Mohinder Singh
Publishers, New Delhi, India.
5. http:// www.matche.com
6. Nriagu J. O and More P. B.(eds), 1984, Phosphate Minerals, Springer-verlag
Berline Heidberg, Germany
7. Othmer Kirk, 1980, 3
rd
edition, vol 10, Encyclopedia of Chemical Technology, John
Wiley & Sons, Incl, New York.
8. Perry, R. H. 6
th
edition 1984, Perry's handbook for chemical engineers McGraw Hill
book company, New York.
9. Shuka, S.D. Pandey G.N, 3
rd
edition, 1987, chemical Technology, Jughu offset,
shahdara, Delhi (India).
10. Sinnort,R.K, 1996, Chemical Engineering Design, Butterworth, Heinemann,
Oxford
11.TVA and US Department of Agriculture, 1964,Super phosphate: Its Chemistry and
Manufacture, Washington DC.
TVA Tennessee Development Authority.
12.UNIDO and IFDC, 1998, Fertilizer manual, Kluwer Academics
Publishers, Netherlands.
UNIDO United Industrial Development Organization Viena, Austria
IFDC International Fertilizer Development centre, Alabama USA
13. US Environmental Protection Agency, office of pollution Prevention and Toxics
(US EPA) 1999. Background Report on Fertilizer use, contaminants and
regulation. Http://www.epa.gov/oppt/fertilizer.