Vous êtes sur la page 1sur 6

MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA SHEET MATERIAL SAFETY DATA

SHEET
1 11 1. . . . Product and Company Identification Product and Company Identification Product and Company Identification Product and Company Identification
Material name Material name Material name Material name AMMONIUM CHLORIDE AMMONIUM CHLORIDE AMMONIUM CHLORIDE AMMONIUM CHLORIDE
Version # Version # Version # Version # 01
Revision date Revision date Revision date Revision date 09-28-2011
CAS # CAS # CAS # CAS # 12125-02-9
Product Codes Product Codes Product Codes Product Codes J.T.Baker: 0660, 0661 J.T.Baker: 0660, 0661 J.T.Baker: 0660, 0661 J.T.Baker: 0660, 0661
Macron: 3364, 3384 Macron: 3364, 3384 Macron: 3364, 3384 Macron: 3364, 3384
Synonym(s) Synonym(s) Synonym(s) Synonym(s) Sal ammoniac; Ammonium muriate
Customer Service Customer Service Customer Service Customer Service 855-282-6867
24 Hour Emergency 24 Hour Emergency 24 Hour Emergency 24 Hour Emergency 908-859-2151
Chemtrec Chemtrec Chemtrec Chemtrec 800-424-9300
Manufacturer Manufacturer Manufacturer Manufacturer
Address Address Address Address
Avantor Performance Materials, Inc.
3477 Corporate Parkway
Center Valley, PA 18034
US
Suite #200
2 22 2. . . . Hazards Identification Hazards Identification Hazards Identification Hazards Identification
Emergency overview Emergency overview Emergency overview Emergency overview WARNING
May be harmful if swallowed. Irritating to eyes, respiratory system and skin.
OSHA regulatory status OSHA regulatory status OSHA regulatory status OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects Potential health effects Potential health effects Potential health effects
Routes of exposure Routes of exposure Routes of exposure Routes of exposure Inhalation. Skin contact. Eye contact. Ingestion.
Eyes Eyes Eyes Eyes Irritating to eyes. Eye may become red, tear, and become painful.
Skin Skin Skin Skin Dust or powder may irritate the skin.
Inhalation Inhalation Inhalation Inhalation Inhalation of dusts may cause respiratory irritation.
Ingestion Ingestion Ingestion Ingestion May cause irritation of the gastrointestinal tract. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhea.
Target organs Target organs Target organs Target organs Eyes. Skin. Respiratory system.
Potential environmental effects Potential environmental effects Potential environmental effects Potential environmental effects Toxic to aquatic organisms.
Components Components Components Components CAS # CAS # CAS # CAS # Percent Percent Percent Percent
3 33 3. . . . Composition Composition Composition Composition / / / / Information on Ingredients Information on Ingredients Information on Ingredients Information on Ingredients
12125-02-9 99 - 100 AMMONIUM CHLORIDE
4 44 4. . . . First Aid Measures First Aid Measures First Aid Measures First Aid Measures
First aid procedures First aid procedures First aid procedures First aid procedures
Eye contact Eye contact Eye contact Eye contact Any material that contacts the eye should be washed out immediately with water. If easy to do,
remove contact lenses. Get medical attention if irritation develops and persists.
Skin contact Skin contact Skin contact Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Inhalation Inhalation Inhalation Inhalation Move to fresh air. Treat symptomatically. Get medical attention if symptoms persist.
Ingestion Ingestion Ingestion Ingestion Call a physician or poison control center immediately. Only induce vomiting at the instruction of
medical personnel. Never give anything by mouth to an unconscious person.
Notes to physician Notes to physician Notes to physician Notes to physician Treat symptomatically.
Material name: AMMONIUM CHLORIDE
MSDS ID: A5724 Version #: 01 Revision date: 09-28-2011
MSDS US COV
1 / 6
General advice General advice General advice General advice Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance.
5 55 5. . . . Fire Fighting Measures Fire Fighting Measures Fire Fighting Measures Fire Fighting Measures
Flammable properties Flammable properties Flammable properties Flammable properties This product is not flammable. Exposure to fire can generate toxic fumes.
Extinguishing media Extinguishing media Extinguishing media Extinguishing media
Suitable extinguishing Suitable extinguishing Suitable extinguishing Suitable extinguishing
media media media media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Unsuitable extinguishing Unsuitable extinguishing Unsuitable extinguishing Unsuitable extinguishing
media media media media
None known.
Protection of firefighters Protection of firefighters Protection of firefighters Protection of firefighters
Protective equipment and Protective equipment and Protective equipment and Protective equipment and
precautions for firefighters precautions for firefighters precautions for firefighters precautions for firefighters
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask. Wear self-contained breathing
apparatus with a full facepiece operated in the positive pressure demand mode when fighting
fires.
Specific methods Specific methods Specific methods Specific methods In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened
containers.
Hazardous combustion products Hazardous combustion products Hazardous combustion products Hazardous combustion products Combustion generates toxic fumes of ammonia. Hydrogen Chloride (HCl). Nitrogen Oxides (NOx).
6 66 6. . . . Accidental Release Measures Accidental Release Measures Accidental Release Measures Accidental Release Measures
Personal precautions Personal precautions Personal precautions Personal precautions Keep unnecessary personnel away. Keep upwind. Ventilate the area. Avoid inhalation of dust
from the spilled material. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing.
Environmental precautions Environmental precautions Environmental precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not discharge into drains, water courses or
onto the ground.
Methods for containment Methods for containment Methods for containment Methods for containment If sweeping of a contaminated area is necessary use a dust suppressant agent which does not
react with the product. Prevent entry into waterways, sewer, basements or confined areas.
Methods for cleaning up Methods for cleaning up Methods for cleaning up Methods for cleaning up Avoid dust formation.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal.
Large Spills: Collect dust or particulates using a vacuum cleaner with a HEPA filter. Reduce
airborne dust and prevent scattering by moistening with water.
Never return spills in original containers for re-use. Clean contaminated surface thoroughly. Clean
up in accordance with all applicable regulations.
7 77 7. . . . Handling and Storage Handling and Storage Handling and Storage Handling and Storage
Handling Handling Handling Handling Keep formation of airborne dusts to a minimum. Avoid breathing dust. Avoid contact with eyes,
skin, and clothing. Do not taste or swallow. Do not eat, drink or smoke when using the product.
Use only with adequate ventilation. Wash thoroughly after handling. See Section 8 of the MSDS
for Personal Protective Equipment.
Storage Storage Storage Storage Keep container tightly closed. Store in a well-ventilated place.
ACGIH ACGIH ACGIH ACGIH
8 88 8. . . . Exposure Controls Exposure Controls Exposure Controls Exposure Controls / / / / Personal Protection Personal Protection Personal Protection Personal Protection
Material Material Material Material Type Type Type Type Value Value Value Value Form Form Form Form
AMMONIUM CHLORIDE (12125-02-9) 20.0000 mg/m3 Fume. STEL
10.0000 mg/m3 Fume. TWA

Engineering controls Engineering controls Engineering controls Engineering controls Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes
that may be generated during handling or thermal processing. If engineering measures are not
sufficient to maintain concentrations of dust particulates below the OEL, suitable respiratory
protection must be worn.
Material name: AMMONIUM CHLORIDE
MSDS ID: A5724 Version #: 01 Revision date: 09-28-2011
MSDS US COV
2 / 6
Personal protective equipment Personal protective equipment Personal protective equipment Personal protective equipment
Eye / face protection Eye / face protection Eye / face protection Eye / face protection Use tight fitting goggles if dust is generated.
Skin protection Skin protection Skin protection Skin protection Wear appropriate chemical resistant clothing.
Respiratory protection Respiratory protection Respiratory protection Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Respirator type: High-efficiency
particulate respirator with full facepiece.
General hygeine General hygeine General hygeine General hygeine
considerations considerations considerations considerations
Provide eyewash station and safety shower. Always observe good personal hygiene measures,
such as washing after handling the material and before eating, drinking, and/or smoking.
Routinely wash work clothing and protective equipment to remove contaminants.
9 99 9. . . . Physical & Chemical Properties Physical & Chemical Properties Physical & Chemical Properties Physical & Chemical Properties
Appearance Appearance Appearance Appearance Powder.
Color Color Color Color White.
Odor Odor Odor Odor Odorless.
Odor threshold Odor threshold Odor threshold Odor threshold Not available.
Physical state Physical state Physical state Physical state Solid.
Form Form Form Form Powder.
pH pH pH pH 5 - 5.5 Aqueous solution
Melting point Melting point Melting point Melting point 640.4 F (338 C)
Freezing point Freezing point Freezing point Freezing point 640.4 F (338 C)
Boiling point Boiling point Boiling point Boiling point 968 F (520 C)
Flash point Flash point Flash point Flash point Not available.
Evaporation rate Evaporation rate Evaporation rate Evaporation rate Not available.
Flammability limits in air, upper, Flammability limits in air, upper, Flammability limits in air, upper, Flammability limits in air, upper,
% by volume % by volume % by volume % by volume
Not available.
Flammability limits in air, lower, Flammability limits in air, lower, Flammability limits in air, lower, Flammability limits in air, lower,
% by volume % by volume % by volume % by volume
Not available.
Specific gravity Specific gravity Specific gravity Specific gravity 1.5274
Relative density Relative density Relative density Relative density Not available.
Solubility (water) Solubility (water) Solubility (water) Solubility (water) 370 g/l
Partition coefficient Partition coefficient Partition coefficient Partition coefficient
(n-octanol/water) (n-octanol/water) (n-octanol/water) (n-octanol/water)
Not available
Auto-ignition temperature Auto-ignition temperature Auto-ignition temperature Auto-ignition temperature Not available.
Decomposition temperature Decomposition temperature Decomposition temperature Decomposition temperature 640.4 F (338 C)
Molecular weight Molecular weight Molecular weight Molecular weight 53.5 g/mol
Molecular formula Molecular formula Molecular formula Molecular formula Cl-H4-N
10 10 10 10. . . . Chemical Stability & Reactivity Information Chemical Stability & Reactivity Information Chemical Stability & Reactivity Information Chemical Stability & Reactivity Information
Chemical stability Chemical stability Chemical stability Chemical stability Stable under normal temperature conditions. The substance is hygroscopic and will absorb water
by contact with the moisture in the air.
Conditions to avoid Conditions to avoid Conditions to avoid Conditions to avoid Excessive heat. Moisture.
Incompatible materials Incompatible materials Incompatible materials Incompatible materials Strong oxidizing agents. Strong acids. Potassium. Nitrates. Copper. Halogens.
Hazardous decomposition Hazardous decomposition Hazardous decomposition Hazardous decomposition
products products products products
Ammonia. Nitrogen oxides (NOx). Hydrogen chloride.
Possibility of hazardous Possibility of hazardous Possibility of hazardous Possibility of hazardous
reactions reactions reactions reactions
Hazardous polymerization does not occur.
Material name: AMMONIUM CHLORIDE
MSDS ID: A5724 Version #: 01 Revision date: 09-28-2011
MSDS US COV
3 / 6
Toxicological data Toxicological data Toxicological data Toxicological data
11 11 11 11. . . . Toxicological Information Toxicological Information Toxicological Information Toxicological Information
Product Product Product Product Test Results Test Results Test Results Test Results
Acute Oral LD50 Rat: 1650 mg/kg AMMONIUM CHLORIDE (12125-02-9)
Sensitization Sensitization Sensitization Sensitization Not a skin sensitizer.
Acute effects Acute effects Acute effects Acute effects May be harmful if swallowed.
Local effects Local effects Local effects Local effects Irritating to eyes, respiratory system and skin.
Chronic effects Chronic effects Chronic effects Chronic effects None known.
Carcinogenicity Carcinogenicity Carcinogenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Skin corrosion/irritation Skin corrosion/irritation Skin corrosion/irritation Skin corrosion/irritation May irritate and cause redness and pain.
Epidemiology Epidemiology Epidemiology Epidemiology No epidemiological data is available for this product.
Mutagenicity Mutagenicity Mutagenicity Mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Neurological effects Neurological effects Neurological effects Neurological effects None known.
Reproductive effects Reproductive effects Reproductive effects Reproductive effects Contains no ingredient listed as toxic to reproduction
Teratogenicity Teratogenicity Teratogenicity Teratogenicity No data available to indicate product or any components present at greater than 0.1% may cause
birth defects.
Symptoms and target Symptoms and target Symptoms and target Symptoms and target
organs organs organs organs
Irritant effects. Shortness of breath.
Ecotoxicological data Ecotoxicological data Ecotoxicological data Ecotoxicological data
12 12 12 12. . . . Ecological Information Ecological Information Ecological Information Ecological Information
Product Product Product Product Test Results Test Results Test Results Test Results
EC50 American lobster (Homarus americanus): 0.237 mg/l
48.00 hours
AMMONIUM CHLORIDE (12125-02-9)
Ecotoxicity Ecotoxicity Ecotoxicity Ecotoxicity Toxic to aquatic life.
Persistence and Persistence and Persistence and Persistence and
degradability degradability degradability degradability
Expected to be readily biodegradable.
Partition coefficient Partition coefficient Partition coefficient Partition coefficient
(n-octanol/water) (n-octanol/water) (n-octanol/water) (n-octanol/water)
Not available
13 13 13 13. . . . Disposal Considerations Disposal Considerations Disposal Considerations Disposal Considerations
Disposal instructions Disposal instructions Disposal instructions Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.
Incinerate the material under controlled conditions in an approved incinerator.
Contaminated packaging Contaminated packaging Contaminated packaging Contaminated packaging Offer rinsed packaging material to local recycling facilities. Since emptied containers retain
product residue, follow label warnings even after container is emptied.
14 14 14 14. . . . Transport Information Transport Information Transport Information Transport Information
DOT DOT DOT DOT
Not regulated as dangerous goods.
IATA IATA IATA IATA
Not regulated as dangerous goods.
IMDG IMDG IMDG IMDG
Not regulated as dangerous goods.
15 15 15 15. . . . Regulatory Information Regulatory Information Regulatory Information Regulatory Information
US federal regulations US federal regulations US federal regulations US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Material name: AMMONIUM CHLORIDE
MSDS ID: A5724 Version #: 01 Revision date: 09-28-2011
MSDS US COV
4 / 6
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
AMMONIUM CHLORIDE (CAS 12125-02-9) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
AMMONIUM CHLORIDE (CAS 12125-02-9) Listed.
CERCLA (Superfund) reportable quantity CERCLA (Superfund) reportable quantity CERCLA (Superfund) reportable quantity CERCLA (Superfund) reportable quantity
AMMONIUM CHLORIDE: 5000.0000
Superfund Amendments and Reauthorization Act of 1986 (SARA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Hazard categories Hazard categories Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Section 311 hazardous Section 311 hazardous Section 311 hazardous Section 311 hazardous
chemical chemical chemical chemical
Yes
Clean Water Act (CWA) Clean Water Act (CWA) Clean Water Act (CWA) Clean Water Act (CWA) Hazardous substance
Food and Drug Administration Food and Drug Administration Food and Drug Administration Food and Drug Administration
(FDA) (FDA) (FDA) (FDA)
Total food additive
Direct food additive
GRAS food additive
Inventory status Inventory status Inventory status Inventory status
Country Country Country Country( (( (s ss s) ) ) ) or region or region or region or region Inventory name Inventory name Inventory name Inventory name On inventory On inventory On inventory On inventory ( (( (yes yes yes yes/ // /no no no no)* )* )* )*
Yes Australia Australian Inventory of Chemical Substances (AICS)
Yes Canada Domestic Substances List (DSL)
No Canada Non-Domestic Substances List (NDSL)
Yes China Inventory of Existing Chemical Substances in China (IECSC)
Yes Europe European Inventory of Existing Commercial Chemical
Substances (EINECS)
No Europe European List of Notified Chemical Substances (ELINCS)
Yes Japan Inventory of Existing and New Chemical Substances (ENCS)
Yes Korea Existing Chemicals List (ECL)
Yes New Zealand New Zealand Inventory
Yes Philippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations State regulations State regulations State regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US - Pennsylvania RTK - Hazardous Substances: Listed substance US - Pennsylvania RTK - Hazardous Substances: Listed substance US - Pennsylvania RTK - Hazardous Substances: Listed substance US - Pennsylvania RTK - Hazardous Substances: Listed substance
AMMONIUM CHLORIDE (CAS 12125-02-9) Listed.
Saf-T-Data Saf-T-Data Saf-T-Data Saf-T-Data Health: 2 - Moderate
Flammability: 0 - None
Reactivity: 1 - Slight
Contact: 2 - Moderate
Lab Protective Equip: B - GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: G - Green (General Storage)
16 16 16 16. . . . Labeling Info Labeling Info Labeling Info Labeling Info
Label Hazard Warning Label Hazard Warning Label Hazard Warning Label Hazard Warning WARNING
May be harmful if swallowed. Irritating to eyes, respiratory system and skin.
Label Precautions Label Precautions Label Precautions Label Precautions Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Use
only with adequate ventilation. Wash thoroughly after handling. Keep container closed.
Material name: AMMONIUM CHLORIDE
MSDS ID: A5724 Version #: 01 Revision date: 09-28-2011
MSDS US COV
5 / 6
Label First Aid Label First Aid Label First Aid Label First Aid Immediately flush eyes with plenty of water for at least 15 minutes. Flush skin thoroughly with
water. If gas/fume/vapor/dust/mist from the material is inhaled, remove the affected person
immediately to fresh air. Get medical attention if symptoms persist. IF SWALLOWED:
Immediately call a POISON CENTER or doctor/physician.
17 17 17 17. . . . Other Information Other Information Other Information Other Information
NFPA ratings NFPA ratings NFPA ratings NFPA ratings Health: 2
Flammability: 0
Instability: 0
Disclaimer Disclaimer Disclaimer Disclaimer THE INFORMATION PRESENTED IN THIS MATERIAL SAFETY DATA SHEET (MSDS/SDS)
WAS PREPARED BY TECHNICAL PERSONNEL BASED ON DATA THAT THEY BELIEVE IN
THEIR GOOD FAITH JUDGMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED
HEREIN IS PROVIDED AS IS, AND AVANTOR PERFORMANCE MATERIALS MAKES AND
GIVES NO REPRESENTATIONS OR WARRANTIES WHATSOEVER, AND EXPRESSLY
DISCLAIMS ALL WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT TO
WHICH IT RELATES, WHETHER EXPRESS, IMPLIED, OR STATUTORY, INCLUDING
WITHOUT LIMITATION, WARRANTIES OF ACCURACY, COMPLETENESS,
MERCHANTABILITY, NON-INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY,
STABILITY, AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES ARISING
FROM COURSE OF DEALING, COURSE OF PERFORMANCE, OR USAGE OF TRADE. THIS
MSDS/SDS IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY
HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT,
AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER AND CONDITIONS
OF USE, HANDLING, STORAGE, OR DISPOSAL OF THE PRODUCT. INDIVIDUALS
RECEIVING THIS MSDS/SDS MUST ALWAYS EXERCISE THEIR OWN INDEPENDENT
JUDGMENT IN DETERMINING THE APPROPRIATENESS OF SUCH ISSUES. ACCORDINGLY,
AVANTOR PERFORMANCE MATERIALS ASSUMES NO LIABILITY WHATSOEVER FOR THE
USE OF OR RELIANCE UPON THIS INFORMATION. NO SUGGESTIONS FOR USE ARE
INTENDED AS, AND NOTHING HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION
TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL, STATE, LOCAL, OR
FOREIGN LAWS. AVANTOR PERFORMANCE MATERIALS REMINDS YOU THAT IT IS YOUR
LEGAL DUTY TO MAKE ALL INFORMATION IN THIS MSDS/SDS AVAILABLE TO YOUR
EMPLOYEES.
Issue date Issue date Issue date Issue date 09-28-2011
Material name: AMMONIUM CHLORIDE
MSDS ID: A5724 Version #: 01 Revision date: 09-28-2011
MSDS US COV
6 / 6