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DOI/10.1007/s12257-008-0144-y
Estimating and Improving Cold Filter
Plugging Points by Blending Biodiesels with
Different Fatty Acid Contents
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1
School of Biological Sciences and Technology, Chonnam National University, Gwangju 500-757, Korea
2
Engineering Research Institute, Chonnam National University, Gwangju 500-757, Korea
3
Interdisciplinary Program of Graduate School for Bioenergy and Biomaterials, Chonnam National University,
Gwangju 500-757, Korea
4
Biotechnology Research Institute, Chonnam National University, Gwangju 500-757, Korea
5
Institute of Bioindustrial Technology, Chonnam National University, Gwangju 500-757, Korea
6
Research Institute for Catalysis, Chonnam National University, Gwangju 500-757, Korea
7
Functional Food Research Center, Chonnam National University, Gwangju 500-757, Korea
Abstract Biodiesels are alkyl esters produced by transesterification of higher fatty acids (aliphatic chains composed of 14 to 22
carbon units) from animal fats and/or vegetable oils. The cold filter plugging points (CFPP) of biodiesels are not only
higher than that of petro-diesel, but they also differ from the melting point of the raw (unesterified) materials. In this
study, we empirically derived equations that estimated the CFPP of a biodiesel based on its fatty acid content, using
various biodiesel blends containing four methyl esters with different fatty acid compositions: soybean (SME), palm
(PME), rapeseed (RME), and lard (LME). These blending ratio experiments yielded three equations that described the
correlation between CFPP and fatty acid content: Y (CFPP, C) = 3.1X (blending ratio) 12.7 (PME/SME); Y = 2.2X
10.7 (LME/SME); and Y = 4.0X 13.0 (PME/RME). We also obtained the correlation between CFPP and total
saturated fatty acid methyl ester content in the biodiesels: Y (CFPP, C) = 0.449X (total saturated fatty acid methyl es-
ter content, wt%) 9.198. These empirical equations accurately predicted CFPP values of biodiesel compounds with
known fatty acid compositions, facilitating the use of diverse biodiesels in industrial fields. KSBB
Keywords: biodiesel, transesterification, cold filter plugging point, prediction
INTRODUCTION
Over the past three decades, a substantial quantity of re-
search has focused on developing a novel renewable and
sustainable energy resource, in order to reduce greenhouse
gas emissions and substitute for non-renewable resources [1-
3]. Since biodiesels exhibit several properties that are com-
parable to those of petro-diesel, most notably cetane number,
flash point, and volumetric heating value, they may eventu-
ally be applicable as a petro-diesel and chemical substitute
[4-6]. Biodiesel is generally manufactured by acid-, alkali-,
and enzyme-catalyzed, or supercritical non-catalyzed, trans-
*Corresponding author
Tel: +82-62-530-1841 Fax: +82-62-530-1910
e-mail: dhpark@chonnam.ac.kr