Biogas Energy Instead of Waste Nikola Rajakovi 1 , Milomir Kneevi 1
Abstract In the last century technical progress was dominantly based on two energy sources, coal and oil. These sources are limited and due to very intensive usage, reserve of these sources are significantly reduced. Experts predict that with current consumption these fuels will last between 80 and 100 years. This is why the renewable technology started to improve so fast. One of the most important resources among renewables is biomass. Biomass also include all organic residues as waste from wood industry, agriculture, food industry etc. We can treat this fuel in different ways. Today the most popular is the combustion process, but pyrolyses and gasification during last years have been getting more and more popular. Besides that thermochemical utilization of biomass, biological and biochemical conversion is of growing importance. This is the point where biogas comes in. Biogas is produced during anaerobic decomposition of biomass by different groups of micro-organisms in a four step fermentation process. The resulting product gas consist of methane (around 60%) and carbon dioxide (around 40 vol%). Serbia is country of agriculture and there are a lot of farms and the installation of biogas power plants has the big potential. One of problems for start-up biogas projects is of financial nature and some subsidies are needed in the beginning. Keywords biogas, organic waste, and biogas power plant, subsidies I. INTRODUCTION Biogas technology is very promising for farmers because of improved effectiveness. Waste material which previously was unused now becomes an energy source. Biogas is produced in anaerobic process by micro-organisms and this process is called anaerobic digestion. In principle the substrate such as animal manure, industrial waste or grass is mixed by a stirring system and then brought into the fermenter. In fermenter, without oxygen, bacteria start to raze organic material. This is the process which consists of several phases. In the beginning organic materials reduce in volume, then become acids and at the end is methanogenisation where methanogenic bacteria produce methane from substance from previous phases. Besides methane, product of this process is also carbon dioxide and also traces of nitrogen, oxygen and hydrogen sulphide. Those are main components of biogas (see Table 1). ----------- 1 Nikola Rajakovi and Milomir Kneevi
are with the Faculty of Electrical Engineering, Bulevar kralja Aleksandra 73, 11000 Belgrade, Serbia, E-mail: rajakovic@etf.bg.ac.yu In process of getting biogas, we should take care about C:N ratio. The optimal one is between 20 and 30. If there is more C then N then bacteria spend all nitrogen and can not convert all carbon to the methane. Also if ratio is lower, after bacteria consume all carbon, it will start to produce ammoniac, which kills bacteria. The process of biogas production take place in a specially designed unit, digestor. Usually the temperature of this process is 35C and decomposition of organic material is finished after 20 days. This retention time is lower if temperature is higher. In Table 1 the overview of potential for producing biogas, from different sources, is shown.
Table I. Average composition of biogas
Substance Percentage CH 4 60 to 80% CO 2 25 to 38% H 2 S 0.05 to 0.5% H 2 0 to 1% N 2 0 to 7% O 2 0 to 2%
Table II. Biogas produced from different sources
Input material Biogas produced per tone of dry substance Rest of kitchen oil 1038 m 3 Grass 520 700 m 3 Sugarcane 550 m 3 Pig manure 370 480 m 3
Vegetable waste 450 m 3
Chicken manure 450 m 3
Cattle manure 250 m 3
Calorific value of biogas is higher if percentage of methane is higher. Biogas is quite similar with natural gas that is extracted from the wells, but natural gas has higher calorific value because contains various hydrocarbons such as ethane, propane and butane. When gas is produced it can be treated in several ways in order to convert into thermal or electric energy. The very effective is the Combine Heat and Power unit which will be described in the next chapter. II. BIOGAS FOR ENERGY PURPOSES
As we mentioned before, biogas is produced from organic materials which are treated in anaerobic condition. This biogas later can be used for producing heat or electricity in gas engine or gas turbine, depending of amount of biogas per day. Either we convert biogas in gas engine or gas turbine, process of producing biogas which we used for fuel in both solutions is the same. First of all we mixed organic material with water in ratio which depends of how substance is dry. This liquid substance is going to the digestor. This is part of biogas plant where process of digestion is done. The main function of this part is to provide anaerobic conditions. (Bio)material feeds in the digestor daily in some amount. This material is mixed and process of anaerobic digestion is under way in the next 15 days. This period is called the retention time. During this period temperature in digestor should be around 35 degrees C. If temperature is lower, retention time is longer. When biogas is produced it is exported by pipe to the storage, where process of desulphurization continues. After this process, gas is prepared for the gas machine (engine or turbine). Residue of inputs that comes out from the outlet after the substrate is acted upon (slurry) can be in different forms (solid fraction, fibrous material, and viscous fraction, liquid and heavy solids). Slurry is pathogen free stabilized manure that can be used to maintain soil fertility and enhance crop production. Produced biogas now can be burned in the gas engine or turbine. Which unit will be used depends of plant size. For smaller units the gas engine is recommended. In the gas engine biogas is burned and pistons are driving the synchronous generator which is connected with the engine. This is the classical principle the same as drive with inside burning (OTO motor). Heat which is produced after burning is used for thermal power in industry or district heating system. The efficiency is between 85% and 95% (32-42% electric efficiency). In this moment this technology is very practical and popular in the world. Gas turbines are well known machines which are commonly used in the industry. The smallest, on the market available, gas turbine has an electrical power output of about 1 MWel. By this fact the use is acceptable only at the central units. Advantage of gas turbine is that the exhausted gas results in a higher temperature range then in the engine and enables the production of high grade steam for industrial use. Efficiency of gas turbine is around 82% (28-36% electrical efficiency). In Figure 1 the scheme of a farm biogas plant is shown. Produced electricity is partially used for running the biogas plant and partially to be delivered to the grid. One part of thermal power is used in process of digestion for providing continues temperature level in the digestor and rest can be used in district heating system or for some industrial consumers. It is very important that consumers which use heat have to be close to the plant because hot water or low pressure steam cannot be transported over longer distances.
Figure 1: Scheme of a farm biogas plant
III. BIOGAS PLANTS AND ECONOMIC SUBSIDES Since last decade of previous century, biogas power plants are in big expansion in the world. In Europe the number of new plants increases every year. Main reason for this expansion is the high financial support from authorities of European Union aimed at renewable energy sources. There is the target in energy policy to reach 22,1% of whole electricity production from renewable sources until 2010. Biogas applications are very attractive, because with producing biogas we produce green energy and also reduce waste which could be the source of high pollution (organic materials could be a danger if they are not disposed properly, they can cause bad smell,). In Europe the leaders in these technologies are Germany and Great Britain, but in the last period Austria has strong growth in this area. When we look at investment and operational costs, we are coming to the conclusion that the lowest economical price for electricity from biogas is 0,08 Euro/kWh. If the price is lower then there is no reasonable economy. In Austria this price is between 0,103 and 0,163 Euro/kWh. The difference between the market price and this price is covered by the government by so called the feed in tariff. This is most popular incentive for all renewable sources. Government supports producers 13 years with this price, and this is the period when they make the pay back of all investments and also earn some money. After this period there are no any subsidies and they are going to the market and try to sell their products. This is not the only way for subsidy implementations. There are also RES obligations, tenders and fiscal incentives. Also the new system of green certificates exist which is still in testing period. All those systems we can split in two groups:
Instruments which are based on the required minimum share (specified goals) of producing the electricity from RES, but without guaranteed prices, All energy produced from RES has guaranteed prices, but there are no obligations that the total electricity produced from RES is going to be bought. In the first group are the tender scheme, and the system of green certificates. In the tender schemes, the specific country supports investments in new power plants based on RES, but later they do not care for the electricity price. It is not so good system and it is approved in UK where many plants had not success. The better solution is the tender for electricity from renewable energy sources, and then subsidies for produced electricity. The second system from the first group is the quota obligation system which is relatively new and there is the minimum share of renewables which is imposed on producers, suppliers and consumers. This system is often combined with the green certificate system. This is the system where producers for each produced unit of electricity get the certificate and then sell it independently of the electricity market. This is good solution because electricity market is not disturbed in such a way. Disadvantages in this approach are: the implementation is very expensive and it is bad for small producers. Here exists the risk of supporting only lower-cost technologies. The most popular instrument for supporting renewable energy is the feed in tariff. There are guaranteed prices for electricity from renewable sources. A specific country makes decision about prices from different sources depending of technology costs and size of plants. Suppliers buy electricity with guaranteed prices from producers (Germany) or producers sell it on the market and later get the premium for selling the electricity (Spain). The feed in tariff is approved as the most effective system for promoting RES. This system is very cheap for implementation, but it can slow down technology prospects. But for now situation in West Europe disproves it.
IV. BIOGAS POTENTIAL IN SERBIA Serbia is country of agriculture and has big potential for biogas power plants. In this moment it is still only potential because system of supporting this technology is not developed. Subsidies do not exist, however there are some ideas how to make start-up biogas power plant projects in Serbia. The main idea is to establish small scale biogas power plants on the big farms or in food factories where a lot of waste materials exist and also the high demand for energy (heat and electricity) is present. For example if we have one big chicken farm with 60 000 chicken then with the average production of manure from one chicken of 27 kg/year we will have the total manure production on this typical farm of 1620 t for one year. Depending of manure quality we can extract around 80 m 3 of biogas from 1t fresh manure. In our example that means that yearly biogas production will be around 130000 m 3 . Biogas in amount of 1m 3 has energy equivalent of 1,7kWh in electric energy and 2kWh in thermal energy. Therefore, the farm from our example could produce 221000 kWh of electricity and 260000 kWh of thermal energy during one year. Half of produced thermal energy has to be spent for heating of digestion process and around 10 % of electricity for the process inside power plant. If we would take gas machine which would work continuously with full capacity the install power of generator would be 35 kW. With this power we can not reach so high efficiency because electricity price during low tariff is cheap and more economical is to install generator with 50 kW of power and during low tariff produce as much energy as we need on the farm in this moment. Rest of produced biogas we can put in the gas storage and use it later in high tariff and also to produce enough power for covering pick demand during day. With this we would have bigger install power and we could control the power production. Unused electricity we can sell to the network and also earn some money. Summarize with this system we would save about 8500 Euro for electricity which we use in this farm, we would earn 3200 Euro from electricity which we can sell to the network, and we would save about 6000 Euro for heating purposes. The total effect is about 17 700 Euros. Investments for this plant are around 120 000 Euros. In this scenario the payback period would be between 8 and 10 years. This time we can decrease if we would receive some grant from outside (EU, EBRD) for promotion biogas systems in this region. Also, similar solutions can be implemented on the pig and cattle farms. Here we can combine substrates which we feed into the digestor. If we have farm as an integral part of food factory, the waste from food producing can be treated also in biogas plant. In this case we have to care about C:N ratio and ratio in digestor between waste from food factory and manure. The advantage of this system (biogas power plant on the farm) in comparison to the plant where the production of electricity for the external network is the only goal, is the own input substrate, which is free, and because of that the lower electricity price. When farmers bay electricity, they pay it with higher prices, then the price for the electricity which power plant owners can sell it to the grid (for example, if you would selling electricity directly to the grid you can not reach price higher then 0,04 Euro/kWh, but when farmers buy it they have pay price of 0,051 Euro/kWh). This is reason why farmers have interest to build power plant for covering their own needs for electricity (and heat). It is also important to emphasize that these farmers and factories owners solve the ecological problem which they face with manure and waste.
4.1. Biogas power plant connection to the public grid (the Serbian law) Biogas plants can work in regime of parallel work (sending electricity only to the grid, without possibility for isolated operation), in combine regime (parallel or island regime) and in an island regime, when power plant only produce electricity for self consumption and for power supply to the consumers which are connected to the plant. If we want to connect the biogas power plant to the grid, the next criterions have to be fulfilled: Criterion of allowed power Criterion of allowed higher harmonics current Short circuit criterion The first criterion guaranties that in transient process the voltage rise in the connection point will not be bigger then 2%. The criterion is fulfilled if 500 ks ng S S
, where ng S
represents the total install power of all generators in
the power plant, and S ks is the three phase short circuit power in the connection point to the grid. In that case power plant can be connected to the grid without any bad influences. The second criterion is fulfilled if vhdoz vhs ks I I S = . Here I vhdoz
represents the allowed higher harmonics current on the generators voltage level [A], and I vhs is the higher harmonics current reduced to the short circuit power in the connected point to the grid [A / MVA]. This value is specified in this recommendation. The last criterion should be checked only if the install power is bigger then 1MVA, what is often case in biogas power plants. Since in the biogas power plant synchronous generators are used, they can be synchronized to the network, if:
Voltage difference: U < 10% U n
Frequency difference: f < 0,5 Hz Phase angle difference: < 10%
In Austria one interesting project for controlling power of biogas plants, which deliver electrical energy into the grid, has been started. This concerns the active power control and reactive power control. Up to now neither the first, nor the second possibility is used. The first possibility was not usable for producers because they try to produce as much active power as they can and work under maximum load condition as long as possible, due to economic reasons. Barriers against making use of second option are missing control equipment, unclear advantage of reactive power control for the operator, and low or even detrimental effect to the grid stability, if singular biogas plants are feeding reactive power into the grid without any common control strategy. Now idea is to connect a certain number of biogas plants together to a big centrally controlled Virtual Biogas Power Plant. Benefits from this control system are for producers and for grid operators also. Expected benefits for the biogas plant operator are possible improvement of the economical situation of his plant by operation of his generators with a better power factor, so they could feed more active power into the grid and therefore increase the profit of the plant. Also reactive power market could be established as it is realized in United Kingdom. Expected benefits for the grid operators might be reduction of transmission losses and the optimized operation of large power plants used for reactive power control so far.
V. CONCLUSION
Biogas technologies are very popular in Europe and these trends are attractive for West Balkan countries. Their applications solve one additional big problem, the ecological one. The question is why we would throw away our organic waste when we can produce energy from this. If we use the animal manure just as fertilizer, we still have the problem of odours. If we put it into the digestor, we again have fertilizer, but now without any odours. Also, this can improve the overall farm economy. Cultivating energy crops (grass and other quick growing plants) and by applying the anaerobic digestion of these crops results in biogas production. The utilization of the biogas in order to produce electric power and heat offers a new source of income to the farmer. The farmers can start to produce energy and earning also by selling energy. Start-up projects in biogas technology should be supported and promoted. With some subsidies to the investors during installation, payback period would be shorter and building of biogas power plants more economical. The other possibility is to apply for the grants in EU available for the renewable energy sources promotion. The need for wider applications of renewable energy sources comes from the fact that we are simultaneously solving the problem of energy demand and the ecological problem also.
ACKNOWLEDGEMENT
This work was supported by European Commission, Directorate General on Research and Technology Development and International Co-operation Activities (INCO) under contract no FP6-509161 (RISE Project )
REFERENCES
[1] M.Harasek, K.Mairitsch, A. Friedl: Evaluation of the Potential of Biogas Upgrading; Proceeding of Twelfth European Biomass Conference, Biomass for Energy, Industry and Climate Protection, Volume II, Amsterdam, The Netherlands 17-21 st
June 2002 [2] Salah M. Al-Azzam: Biogas a Source of Energy [3] K. Joergensen, L. Kranzl, E.Tsioliaridou, M.A.Lopez-Polo, M.Stadler, G.Resch, R.Haas: Rational Use of Energy and Renewable Energy Sources a Review of Current Policy Strategies and Promotion Schemes, Final report of Work Phase 1 of the project Invert. February 2004 [4] EPS: Technical recommendation No. 6, Beograd, 2003