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JAE S. AN
Apparel & Sweater Technical Service Center, Korea Institute of Industrial Technology
Jung-gu, Seoul, 100195, South Korea
ABSTRACT
Polypropylene nonwoven fabrics are treated by He atmospheric pressure glow dis-
charge plasma. After plasma treatment, weight loss (%), surface properties (wettability,
morphology, and chemical composition changes), tensile strength, low-stress mechanical
properties, and air permeability of the fabrics are examined. Scanning electron microscopy
analysis shows significant surface morphology changes in plasma-treated polypropylene
fiber surfaces, corresponding to reductions in fabric weight. X-ray photoelectron spec-
troscopy analysis reveals that surface oxidation by the formation of hydrophilic groups
enhances the surface wettability of the fabrics. Surface morphology changes with plasma
treatment increase fiber-to-fiber friction, playing an important role in enhancing their
tensile strength, low-stress mechanical properties, and air permeability.
Surface modifications with plasma treatment have sure time [11]. However, intensive plasma treatment can
been studied widely for textile and polymer materials deteriorate nylon 6 fiber strength depending on the
because plasma processes are environmentally friendly weight loss (%) of fibers due to etching effects [15].
and reduce wet chemical and energy consumption. Non- Even in relatively mild low-pressure plasma conditions,
polymerizable gas plasmas have several effects on poly- the tensile strength of polyethylene terephthalate (PET)
mer surface properties such as functionalization, etching, fibers decreased without an apparent etching effect of the
chain scission, and crosslinking [2,7]. Functionalization fiber surfaces, suggesting that a chemically modified
can introduce chemical functional properties on the poly- outer layer or micro-cracks would initiate fracture by a
mer surface, while etching is strongly related to physical stress-concentration effect [1]. Wong et al. [13] showed
property changes of the polymer substrate such as mor- that increased surface roughness by the etching effect
phology, tensile, and friction properties [13,14]. In gen- results in increased interfacial friction, imparting in-
eral, it is known that plasma treatment does not alter the creased fabric strength at shorter exposure times. How-
bulk properties of the substrate, but bulk properties can ever, under more severe plasma conditions (longer ex-
deteriorate in the extreme conditions of plasma treatment posure time or higher discharge power), the apparent
[13,15]. reduction of tensile strength was due to higher degrada-
Early studies of low-pressure plasma treatment for tion of bulk molecular structures. It was apparent that the
cotton yarns showed significantly increased breaking surface-roughness-altered low-stress mechanical proper-
strength and elongation reduction with increased expo- ties of plasma-treated fabrics increased significantly, and
then led to changes in the handle properties [6,14].
In earlier work (McCord et al. [5]), we found that the
1
Current address: CSIRO, Textile and Fibre Technology, P.O. Box tensile strength of nylon 66 fabrics treated by helium and
21, Belmont, Victoria 3216, Australia.
2
Corresponding author: phone: 82-32-860-7493, fax: 82-32-873- helium/oxygen atmospheric plasma glow discharge in-
0181, email:swpark@inha.ac.kr creased with some conditions with no surface morphol-
Textile Res. J. 75(11), 771–778 (2005) DOI: 10.1177/0040517505053805 © 2005 SAGE Publications www.sagepublications.com
772 TEXTILE RESEARCH JOURNAL
TABLE I. Moisture regain (%) of plasma treated polypropylene fabrics with ageing time.
SURFACE WETTABILITY
of polypropylene fabrics are shown in Table II. The Relative area corresponding to different
chemical bonds, %
untreated polypropylene fabric’s carbon content (C1s)
should be 100%, based on the polypropylene molecular Treatment COC COO COO
Chemical
composition, % Atomic ratio, %
MECHANICAL PROPERTIES OF TREATED POLYPROPYLENE
Treatment C1s O1s N1s N/C O/C (O ⫹ N)/C NONWOVEN FABRICS
Control 99.3 0.7 0 0.00 0.01 0.01
He 30 Tensile strength measurements of the treated polypro-
seconds 97.3 2.2 0.5 0.01 0.02 0.03 pylene fabrics are presented in Table IV. There were
He 60 significant increases in tensile strength with increased
seconds 94.9 4.3 0.8 0.01 0.05 0.05
He 90 exposure time. Young’s moduli for all plasma-treated
seconds 90.2 8.6 1.2 0.01 0.10 0.11 fabrics increased slightly, then decreased. Changes in
He 120 tensile properties might result from the combination ef-
seconds 85.4 12.5 2.1 0.02 0.15 0.17
fect of increased fiber-to-fiber friction by etching and the
776 TEXTILE RESEARCH JOURNAL
TABLE IV. Tensile strength results of He atmospheric pressure Tensile linearity (LT) and tensile energy (WT) in-
plasma treated polypropylene fabrics.
creased after plasma treatment. Surface roughness can
Tensile strength, Young’s modulus, increase fiber-to-fiber contact, thus enhancing fiber-to-
N Mpa fiber friction. Increased friction results in increased ten-
Number of Standard Standard sile linearity (LT) and tensile energy (WT) and reduced
Treatment specimens Mean deviation Mean deviation tensile resilience (RT). Tensile resilience (RT) of the
fabric might be hindered by cohesiveness enhancement
Control 6 85.4a 3.7 35.3a 0.9
He 30 between fibers due to surface roughness when the stress
seconds 6 88.4a 4.3 37.4ab 2.2 is removed [14]. Shear stiffness (G) and bending rigidity
He 60 (B) were also enhanced due to increased surface rough-
a ab
seconds 6 90.7 4.0 37.0 1.4
He 90 ness as well as shear and bending hysteresis (2HG,
seconds 6 94.0ab 5.3 36.9a 1.4 2HG5, 2HB). Compression properties might be affected
He 120 by surface roughness. Plasma treatment increased fabric
ab a
seconds 6 95.4 3.2 36.1 1.4
thickness (T0 and Tm). It is suggested that the surface
a,b
Means with different letters are statistically significantly different roughness of fibers enhances compression resistance,
at p ⬍ 0.05.
that is, the fullness of the fabric increases under constant
pressure. Compression and compression energy (WC)
crosslinking reaction between molecules [5]. The struc- increased and compression resilience (RC) decreased
ture of polypropylene nonwoven fabric consists of bonds after plasma treatment.
between fibers, which are relatively weaker than those of Considering bending rigidity (B) and bending hyster-
woven or knitted fabrics consisting of yarns. Therefore, esis (2HB), increased fiber- to-fiber friction might en-
the increased tensile properties might be affected mainly hance the resistance of bending deformation. also, cross-
by fiber-to-fiber friction when the fabric structure is link formation in the subsurface of polypropylene fibers
deformed. might reduce bending hysteresis. However, the results
Table V shows the low-stress mechanical properties of show that the cross linking did not affect bending prop-
plasma-treated polypropylene fabrics by the KES-FB sys- erties significantly.
tem. He atmospheric pressure plasma imparts significant
surface roughness to polypropylene fibers (Figure 4), and AIR PERMEABILITY
increased roughness affects the surface properties of
polypropylene fabrics. Values of the surface coefficient Figure 6 shows that all the plasma-treated fabrics pos-
of friction (MIU) and surface roughness (SMD) increased sessed higher air permeability than the untreated control.
considerably with increased exposure time. In addition, Air permeability is related to the fabric structure and to the
frictional smoothness (MMD) increased after plasma portion of empty space occupied by air. The etching effect
treatment. did not alter the fabric structure but rather fiber surface
TABLE 5. KES-FB results for He atmospheric pressure plasma treated polypropylene fabrics.a
Tensile LT 0.881 0.887 (0.7%) 0.928 (5.4%) 0.909 (3.2%) 0.903 (2.6%)
WT, gf 䡠 cm/cm2 0.180 0.188 (4.6%) 0.188 (4.6%) 0.200 (11.1%) 0.183 (1.9%)
RT, % 55.858 52.227 (⫺6.5%) 54.852 (⫺1.8%) 53.592 (⫺4.1%) 53.557 (⫺4.1%)
Bending B, gf 䡠 cm2/cm 0.369 0.375 (1.6%) 0.383 (4.0%) 0.393 (6.5%) 0.375 (1.7%)
2HB, gf 䡠 cm/cm 0.282 0.296 (5.0%) 0.299 (6.0%) 0.290 (2.8%) 0.288 (2.2%)
Shear G, gf/cm 䡠 degree 7.02 7.24 (3.0%) 7.33 (4.3%) 7.45 (6.1%) 7.08 (0.8%)
2HG, gf/cm 10.53 10.79 (2.5%) 11.28 (7.2%) 11.54 (9.6%) 11.53 (9.5%)
2HG5, gf/cm 17.51 18.10 (3.4%) 17.63 (0.7%) 17.87 (2.0%) 18.48 (5.5%)
Surface MIU 0.175 0.177 (1.0%) 0.191 (9.1%) 0.195 (11.0%) 0.204 (16.3%)
MMD 0.015 0.016 (6.8%) 0.015 (1.1%) 0.015 (3.4%) 0.017 (13.6%)
SMD, m 6.976 7.829 (12.2%) 8.195 (17.5%) 8.849 (26.9%) 8.186 (17.3%)
Compression LC 0.710 0.757 (6.5%) 0.796 (12.1%) 0.793 (11.6%) 0.784 (10.4%)
WC, gf 䡠 cm/cm2 0.037 0.043 (13.6%) 0.047 (27.3%) 0.043 (18.2%) 0.047 (27.3%)
RC, % 65.043 60.133 (⫺7.5%) 59.773 (⫺8.1%) 59.037 (⫺9.2%) 59.440 (⫺8.6%)
Tm, mm 0.553 0.567 (2.4%) 0.573 (3.6%) 0.563 (1.8%) 0.593 (7.2%)
To, mm 0.650 0.672 (3.3%) 0.683 (5.1%) 0.687 (5.6%) 0.707 (8.7%)
a
Values with parentheses represent property changes (%) of plasma treated samples compared with the control sample.
NOVEMBER 2005 777
ACKNOWLEDGMENTS
This research was supported financially by the Na-
FIGURE 6. Air permeability of plasma-treated polypropylene fabrics. tional Textile Center and in part by Inha University
(30283-01).
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