Académique Documents
Professionnel Documents
Culture Documents
B R I E F S
JUNE 2000
Integrated
Chemical Enterprise
Materials Fabrication Processes Systems
Research Research Research Research
1 20 41 65
NATIONAL TEXTILE CENTER
The National Textile Center (NTC) is a research consortium of six universities: Auburn University, Clemson Univer-
sity, Georgia Institute of Technology, North Carolina State University, University of Massachusetts at Dartmouth and
the Philadelphia College of Textiles and Science. These institutions share human resources, equipment and facilities.
Serving the USA Fiber/Textile/Fabricated Products/Retail Complex, the NTC vision, mission and goals are realized
through innovate research and links to other institutions.
Vision Mission
To be the agent leading change To enhance the knowledge base
in the industry's vision and for a globally competitive
in education for global competitiveness. USA industry.
Goals
1. Research: Design and develop 2. Education: Educate and train 3. Partnerships: Strengthen the
new materials, innovative and personnel in research processes, nation's textile research and educa-
improved manufacturing processes establish industrial partnerships tional efforts by uniting diverse
and integrated systems essential to and create transfer mechanisms to experts and resources in unique
USA competitiveness. ensure utilization of technologies. collaborative
j t
This report is submitted to the Department of Commerce to fulfill the quarterly reporting requirements of the NTC grant.
Table of Contents
Materials
Research in the design, development, manufacture and measurement of natural and synthetic polymers
and fibers, including polymer mixtures and additives.
In This Section
Table of Contents .......................................................................................... i
Index by Project Management ................................................................... vi
Auburn ......................................................................................................... vi
Clemson ...................................................................................................... vii
Georgia Tech ............................................................................................ viii
University of Massachusetts Dartmouth ....................................... ix
North Carolina State ............................................................................ x
Philadelphia University ....................................................................... xi
Abbreviations .................................................................................................. xi
Discontinued Projects ................................................................................. xii
AUBURN Management
Consumer Preferences for Apparel and Textile Products as a Function
of Lifestyle Imagery (Solomon with Berry College) [I97-A11] .................................... 65
Textiles Having the Ability to Deliver Reactive Chemical Systems
(Broughton with Georgia Tech, UC Davis) [C98-A17] ....................................................... 45
Fiber Motion and Yarn Forming in High Speed Air Flows (Oxenham with
Loughborough (ENG), South India TRA) [F99-S6] ............................................................ 39
Abbreviations
The following NTC programs were discontinued Research Briefs or the November 1999 NTC
because they successfully completed their Annual Report. You may also contact the princi-
maximum three-year life span or because other pal investigators whose phone numbers and E-mail
research was of higher priority. For their last addresses are listed therein. However, several new
report, see the NTC Web site at programs grew out of these projects. See the notes
http://www.ntcresearch.org, the April 1999 NTC following the listings below and a page number, if
li bl
Biological Renovation and Reuse of Spent Reactive Dyebaths [C96-G2]
Information Integration in the Textile Complex (with Georgia Tech) [I96-S15]
Production of Fibers From New Polymers Derived from Biotechnology
(with Bioelastics) [M96-A2]
Fluid Flow in Fine Capillarities (Seed Project) [C98-G30] see C99-G8 ......................... 57
Modeling Blood Flow Through Vascular Grafts [C98-P1] see M98-P2 ................ 18
Intelligent Manufacturing and Management Systems for an Agile U.S.
Softgoods Complex (with [TC]2) [I95-S2] see I98-S1 ............................................. 77
100
(No LIB) and testing of fibers and nonwovens.
M93-S5, I95-A11*, M96-A2*, M98-A10,
0
1000 1500 2000 2500 3000 3500 4000 4500 F96-A3, F98-A4*, C98-A17*, M99-G11
Take-up speed(m/min) royalb@eng.auburn.edu
(334)-844-5460
http://www.eng.auburn.edu/department/te/faculty/Broughton
Both permanent and slip-link entanglements likely exist in
polyester fibers and are affected by spinning conditions, such John A. Cuculo, Hoechst Celanese
as take-up speed and cooling conditions. Our model does not Professor Emeritus of Fiber and Poly-
mer Science at NC State, joined the
efficiently characterize both types of entanglements in the faculty in 1968 after an 18-year career
fiber network but we will try incorporating the findings of in fiber research at DuPont. He
Qian, et. al.6 to improve our model. received a Ph.D. in chemistry from
Duke and a Sc.B. from Brown.
[Other Contributors: graduate student: Lewin Guo, Sung Sig John's research interests include
Yang (NC State); Visiting Scholar: Weijun Wang (Auburn)] high performance fibers from polyes-
Industry interactions: none reported ter fiber extrusion and cellulose. He
Project Web Site Address: holds several patents in these areas.
http://www.eng.auburn.edu/department/te/ntc/99/broughton/m98a04.html F98-A4
john_cuculo@ncsu.edu
For further information: (919)-515-6556
1. Y. Ohta and H. Sugiyhama, Polymer Application, 38: 68 (1989).
2. T Nakajima, Advanced Fiber Spinning Technology, Woodhead Publishing
Yasser A. Gowayed, an Associate
Ltd, 172 (1994).
Professor at Auburn joined the fac-
3. T. Kunugi , T. Kawasumi and T. Ito, J. Appl. Polym. Sci., 40:2101 (1990).
ulty in 1992, when he received a
4. Kavesh et al., U. S. Patent 4,413,110.
Ph.D. in fiber and polymer science at
5. John A. Cuculo, Paul A. Tucker and Gao-Y. Chen, J. Appl. Polym. Sci.,
NC State. He also earned a M.S. in
Appl. Polym. Symp., 47:223 (1991).
materials engineering from the
6. Baojun Qian, Panpan Hu, Jianmin He, J. X. Zhao and Chengxun Wu,
American University (Cairo) in 1989
Polym. Eng. and Sci., 32: #17, (Sep 1992).
after an 8-year career in industry as a
structural designer and civil
engineer. Yasser's research interests
include modeling and analysis of tex-
tile composites, image analysis, geo-
textiles and re-utilization of solid
wastes.
F94-A8, F95-A24*, I95-A11, F98-A4,
I96-A9
ygowayed@eng.auburn.edu
(334)-844-5496
http://www.eng.auburn.edu/~ygowayed
6000
5000-6000
5000
4000-5000
Temperature 4000 3000-4000
An SSP coated fiber swollen with water and an active substance. Swelling 3000 2000-3000
1000
0
10%
5
7 8
30%
9
Amount of
synthesize SSP fibers. For example, fibers could be coated pH Values
10
Ebecryl(%)
with a solution of uncrosslinked SSP, crosslinking monomer
and a photoinitiator which when decomposed with UV would Swelling of UV cured films of chitosan with crosslinking oligomer
produce free radicals, initiating polymerization of the (Ebecryl) [based on the weight of the chitosan].
crosslinking monomer. The already formed SSP could link to
N N O O
Dibutyltin dilaurate
(CH2)4OH
Butyl isocyanatoacetate
(CH2 )4 O (CH2)3CH3
N
8
H
toactive oligomeric molecules with unique abilities to change evaluating these unique materials for their degree and depth of
their absorption and/or reflection of electromagnetic radiation color change. Through X-ray photoelectron spectroscopy,
in the infrared, visible and ultraviolet frequency ranges. We contact angle analysis and atomic force microscopy force
will introduce these molecules with "tunable" properties into curve measurements, we have found that organic species can
polymers, then measure their optical properties under differing be covalently bound to the surface of these polymers in
electrical, magnetic and thermal stress. We already know that densely packed monolayers.
varying the electrical or magnetic field changes the visible [Other Contributors: Graduate Students Steve Hardaker,
radiation absorption and color of these materials, suggesting Mike Pepitone, Jun Wang, Huaidong Meng (Clemson);
applications in coatings, additives or stand alone fibers. Runqing Ou, Tao Liu (Georgia Tech); Post Doctoral: Xingwu
Wang (Clemson)]
We are designing fibers that can Industry interactions: none reported
Project Web Site Address:
quickly change their color, hue, http://www.furman.edu/~hanks/ntc
depth of shade or optical transparency
For further information: nothing reported
by application of Richard V. Gregory, a Professor and
an electrical or magnetic field. Director of the School of Textiles,
Fiber and Polymer Science at Clem-
We have now prepared a series of urethane-based diacety- son, joined the faculty in 1990. He
received his Ph.D. in physical chem-
lenes (See Figure) which are known to undergo a unique solid- istry at Clemson in 1984 and contin-
state photopolymerization to give highly colored, highly con- ued with postdoctoral work in poly-
jugated polymer crystals. These materials are solvotochromic, mer spectroscopy whereupon he
thermalchromic and mechanochromic. The presence of a long- joined the research staff at Milliken.
Dick is thrust leader of NSF Center
chained urethane on one or both sides of the diacetylene for Advanced Fibers and Films, and
increases the solubility of the polymer dramatically in organic on the editorial board of Macro-
solvents. Thus, we can blend polydiacetylenes with both con- molecular Materials and Engineering.
ventional textile polymers and certain piezoelectric materials, His research interests include the for-
mation, characterization and poten-
which results in a mechanical stress upon application of an tial industrial applications of conduc-
electric field. As the conjugated back bone of the polydiacety- tive polymers and the interaction of
lene is stressed, its color changes. These molecules form the ultraviolet radiation with polymers.
initial basis of our investigations into production of true cha- M95-C6*, M95-C4*, M98-C1*
richar6@clemson.clemson.edu
meleon fibers capable of changing their adsorption (864)-656-5961
http://www.eng.clemson.edu/textiles/faculty
Rotor Electrospinner
1500
and deformations in textile architecture, such as yarn orienta- Stroke in Tension (inches)
Computational Approaches
Molecular interactions are the basic building blocks of The structure and location of the discotics in the membrane
nano-technology which has been increasingly used in micro- are the key to success and each specific polymer system must
electronics to design atomic scale gears, rods and bearings. have its own uniquely designed discotic. To accomplish this
The basic idea behind nano-machines has been to tailor a extremely complex task, we are applying molecular modeling
material to function like a machine. The nano-spinning to design and position the discotics. Such "virtual" machine
"machine" we envision consists of membrane containing dis- designs can be done on a computer with good precision. Dis-
cotics (See Figures below) positioned at designed locations. cotics must spin molecular assemblies using non-bonded inter-
As discotics are made to rotate in a synchronized fashion, they actions with the polymer molecules. Using molecular dynam-
will pull polymer molecules supplied at the top surface of the ics, we are attempting to simulate these interactions. Our
membrane, organize and oriented with the required structure, objective is to redesign the chemical compositions of the dis-
and release fiber at the bottom of the surface. To achieve this cotics to improve specific interactions with the polymers, and
synchronization, discotics must be connected by molecular to specify the location of discotics where the spun polymer
We are building a model for non- Acquired Permeability Data for Fabric Series
Newtonian fluid flow through fabrics.
We are now using elevated levels of fluid velocity to push
Assuming the void content in a porous media is a primary the limits of “laminar” flow. As velocity increases, we expect
factor in permeability, the Kozeny-Carman equation was the materials to show increasingly turbulent behavior. We
developed to provide a description of fluid flow based on fil- will then develop bicomponent models of flow for the exhib-
tration media properties.3 MacGregor4 extended the Kozeny- ited permeability.
Carman equation for a textile assembly to model the flow of [Other Contributors: none reported]
dyes through textile yarn packages and to predict permeability Industry Interactions: none reported
based on constituent fabric properties. Project Web Site Address:
http://spike.philacol.edu/perm/
We developed a novel tester (See Schematic) to evaluate For Further Information: nothing reported
the fluid permeability of a fabric. Based on Joule-Thomson 1. H. Darcy, Les Fontaines Publiques de la Ville de Dijon, Paris, 1956.
2. J. Daily and D. Harleman, Fluid Dynamics, Addison-Wesley, Reading,
experiments (changing gas temperature as volume is varied), Mass., 1966, pp. 180-184.
we designed the tester to use a constant volume of fluid in an 3. A. Scheidegger, The Physics of Flow Through Porous Media, revised ed.,
enclosed chamber while the pressure drop across a fabric is University of Toronto Press, Toronto, 1960.
measured at controlled flow. This constant volume approach 4. R. McGregor, Journal of the Society of Dyers and Colourists, Vol. 81,
October 1965, pp. 429-438.
should lead to permeability values untainted by turbulence.
Matthew W. Dunn, a Research Assis-
tant Professor in Textile Engineering
at PhiladelphiaU, joined the faculty in
1998 after serving as Assistant Direc-
tor of Research at Fiber Concepts,
Inc. Matt received his B.S. in 1995 in
textile materials science from NC
State and an M.S. in 1997 in textile
engineering from PhiladelphiaU and
is currently completing his Ph.D. in
materials engineering at Drexel.
Matt's research interests include
composite preform manufacturing
and design and permeability model-
Schematic of Permeability Testing Device ing of textiles.
Testing trials have yielded very reproducible results (with C98-P1*
coefficient of variations below 2%) and the constant volume mdunn@fibers.texsci.edu
(215)-951-2683
design has shown a high correlation to laminar flow (See Fig-
http://fibers.texsci.edu/html/matt.html
ure). Laminar flow is evident in materials when the relation-
ship of the pressure drop caused by forcing a fluid through the
Development and Experimental Validation research focuses on models for specific textile processes that
of Nonlinear Models for involve rotating balloons such as:
High-Speed Yarn Transport Systems • unwinding from cylindrical packages, as in texturing
F97-C5 • unwinding from conical packages, as in warping and
Bhuvenesh C. Goswami, leader; weaving
Christopher D. Rahn (Clemson); • ring twisting and winding, as in ring spinning or ply-twisting
Subhash K. Batra, Tushar K. Ghosh, • two-for-one twisting.
William Oxenham (NC State), The computer models will promote understanding of complex
W. Barrie Fraser (Univ. of Sydney, Australia) process dynamics and can be used to design processes that
High-speed movement of yarns to and from packages is provide low, uniform tension at high speed. This maximizes
common to many textile processes. In both winding and the process efficiency by minimizing yarn breaks and
unwinding the inertial forces tend to create an enveloping maximizing throughput.
surface called a balloon. We pioneered development of
Unwinding Models
computer models for high speed yarn transport systems. In We will be incorporating some important and practical
ring spinning and twisting, for example, we developed models aspects of unwinding into our recently developed inextensible
that predict balloon shapes and tension including the effects of yarn model. Our analysis will include yarn elastic
control rings. These models show instabilities in the process deformation, germane to the textured yarn industry. We will
that could result in yarn breakage. Similar models have been also investigate tension and balloon shape variation due to the
developed for yarn unwinding systems. We have only wind angle change and yarn sliding at the edge of a package.
recently begun experimental validation of the ring spinning Using nonlinear simulations, we plan to predict a fluttering
results and design of an unwinding test stand. dynamic balloon instability, discovered in our earlier research,
We are developing nonlinear models that which can lead to large, rapid tension variations. Finally,
predict the tension and balloon shape these model enhancements will be incorporated into the
process design software.
of yarns undergoing
high speed translation
translation and rotation. Unwinding Experiments
We have constructed a new unwinding test stand consisting
In this project we will develop and experimentally validate of a Reiter yarn transport machine and tension head, a balloon
nonlinear models for high-speed yarn transport systems. The rotation sensor, strobes, a video camera and a PC. The Reiter
machine pulls the yarn from the package at up
to 2000 m/min and measures the real-time
tension. The PC reads the tension and balloon
rotation synch signals, captures 3D strobed
balloon images and displays the results. An
easy to use, graphical user interface allows the
operator to change balloon capture settings and
export the image and tension data (See Figure).
This new system will enable in-depth study of
the unwinding process and extensive verifica-
tion and improvement of the unwinding
models.
Ring Spinning
We will be determining the best ways to
measure the speed, shape and tension of a ring
spinning yarn balloon. The data obtained from
these measurements will be used to verify the
theoretical model and clearly define unstable
operating conditions. This could ultimately be
used as the basis of a control system to
maximize the production capabilities of the
ring frame.
REFLECTANCE (%)
Yong K. Kim, leader; Armand F. Lewis 45
(UMassD) 40
35
The majority of flocking involves the application of finely 30
cut fibers to adhesive coated surfaces. Flock fibers are usually 25
applied to these surfaces either mechanically, electrostatically 20
15
or by a combination of both techniques. Mechanical flocking
10
can be windblown or ”beater-bar” while electrostatic flocking 5
sometimes incorporates a pneumatic process to propel fibers 0
toward a surface in a windstream, allowing flocking of 400 460 520 580 640 700
contoured shapes.
WAVELENGTH (NM)
We are developing a fundamental
understanding of flock materials Relationship between reflectance and wavelength for CI
and flocking processes. Acid Blue dyed-fabric (top), dyed-flock (middle) and dyed-
flocked fabric (bottom)
Both natural and synthetic flock materials are applied to
many different surfaces, resulting in end products ranging [Other Contributors: Graduate Students: Cindy (Yue-Jun) Hou,
from retail consumer goods to high-technology military appli- Francis V. Pottakarian, Young-Sil Kim; Undergraduate
cations. Flocked finishes impart friction modification, heat Students: Jacob Knowels, Justin Sylvia]
insulation and thermal stability, transitionless power transmis- Industry Interactions: 3 [OEM/Erie, Erie PA; Claremont Flock,
Claremont NH; Spectro Coating, Leominster MA]
sion, liquid retention or dispersal, buffing, polishing, cushion- Project Web Site Address:
ing and a decorative, tactile and visual appeal. Even though http://www.umassd.edu/engineering/textiles/research.html
flocking technology has existed for a long time, the mecha- For Further Information: none reported
nisms of process and fiber application are not fully Yong K. Kim, a Professor of Textile
understood. Sciences at UMass Dartmouth, joined
Earlier we developed an equation to describe flock motion the faculty in 1981 when he earned a
Ph.D. in fiber and polymer science
trajectory and found that about 60% is the optimum relative from NC State. He holds a BS and
humidity for processing nylon 6/6 flock fibers. Now we are M.S. in textile engineering from Seoul
establishing measurement and interpretation criteria for color National University (Korea) in 1974.
matching between woven fabrics and flocked substrates. To Yong’s research interests include
textile process design and manufac-
compare the different types of textures, such as nylon fabric, turing systems, mechanics of fibrous
nylon (bulk) flock fibers and nylon flocked fabric, we needed structures and composite materials.
to quantify the various parameters which affect surface reflec- F97-D1*, F98-D4
tance. Since flocked fabrics at different angles give inconsis- ykim@umassd.edu
(508)-999-8452
tent reflectance values, we measured reflectance at all eight
viewing orientations. We chose an 80% porosity for bulk Armand F. Lewis, a lecturer of Textile
flock fiber reflectance measurements because we found only Chemistry and Environmental
marginal reflectance increases as fabric porosity decreased. Science at UMass Dartmouth, joined
the faculty in 1993. He earned a Ph.D.
For a given dye concentration, the reflectance of dyed- in surface chemistry from Lehigh in
fabric, dyed-flock and dyed-flocked fabric are at different 1958 following a B.S. in textile
levels, but the curves run parallel to each other (See Figure). chemistry from the New Bedford
The flocked fabrics show a steady rise in reflectance as % dye Textile Institute and an M.S. in
chemistry from Oklahoma State.
increases in lighter shades, but then reflectance remains From 1959-88, Armand was in
constant for darker shades. research at American Cyanamid,
Lord Corp. and Kendall. His research
interests include adhesion science,
flock material and processes,
composite materials and the fibrous
wiping of surfaces by nonwoven
fabrics.
M98-D3, F97-D1, F98-D4
alewis@umassd.edu
(508)-999-8452
Drafting Unit
Staple-Fiber-Roll
Spinning Nozzle
Channel
Nozzle-Holder
&Air-supplier Suction -Tube
Feed Roll Cylinder Doffer
Yarn-Winder
S-1 S-2
rebars to reinforce
reinforce concrete.
concrete. 300
S-4
S-5
S-3
Predicted
for the braid sleeve and the core structure, we can tailor the
50
load-deformation behavior of the braided fibrous assembly.
0
For this research the sleeve is a tough aramid (Kevlar ) and 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0
Strain (%)
the core structure is a high modulus carbon to provide the Comparison of experimental and theoretical stress-strain
initial resistance to deformation. To simulate the surface response for 5 mm hybrid braided rebars.
characteristics of current steel rebars, a rib is built into the [Contributing Graduate Student: Hoa Lam, (Drexel); Under-
sleeve structure during the braiding process. by making one of graduate students: George Papadopolis, Cindy Colluci, Jason
the yarn bundles about five times larger than the others. The Lyons (PhilaU); Research Associates: Moishe Garfinkle,
rib created by this large bundle (See Photo) is used to improve Eileen Armstrong-Carroll (PhilaU)]
mechanical bonding between the resulting composite rebar Industry Interactions: 5 [Amoco, DuPont, Shell,Fiber Concepts,
and the concrete. In pull-out tests, the average bond strength Inc.; Albany International]
of these bars is similar to deformed steel bars of similar Other Interactions Outside NTC: 3 [Drexel, NSF]
Project Web Site Address:
diameter. http://fibers.texsci.edu/F98P01
For Further Information: none reported
Christopher M. Pastore, an Associate
Professor of Textile Engineering and
Technology and Director of Research
of the School of Textiles and Materi-
als Technology at Philadelphia
University, joined the faculty in 1995.
Micrograph of typical hybrid rebar with surface rib yarns Previously he was on the Textile
Materials Science faculty at NC State
Our process, called “Braidtrusion” (See Schematic), takes
and the Materials Engineering faculty
the braided fabric through a forming ring, then runs the braid at Drexel University. Chris holds a
through an infusion zone wherein epoxy resin is dripped onto B.A. and M.S. in mathematics and a
the fell of the cloth. The wet fabric is then run through a Ph.D. in materials engineering from
Drexel in 1988. His research inter-
heated chamber to cure the resin.
ests include modeling of fabric and
Tensile Response composite structures.
The monotonic stress-strain behavior of the composite F98-P1*, I99-P1*
cpastore@fibers.texsci.edu
rebars shows high initial modulus as well as a ductile failure (215)-951-2683
mode characterized by a bi-linear stress-strain curve (See http://fibers.texsci.edu/stmt/cpastore.html
0 .13 P la in Ro vin g
Youjiang is the Associate Technical
0 .12 Editor on Textiles for the Journal of
Manufacturing Science & Technology
0 .11 in textiles. His research interests
include textile processes, mechanics,
0.1
composites and advanced construc-
D ry L ub ric ated tion materials.
0 .09 R ov in g
F94-A8, F98-G15*, F98-S9
0 .08
youjiang.wang@tfe.gatech.edu
0 1 2 3 4 5 6 7 8 9 10 (404)-894-7551
T im e [m in ]
we are
are analy
analyzing
zing the transient nature of Subhas Ghosh, a Professor and
variability and Director of Research at ITT, joined
the faculty in 1976. He earned a B.S.
variability conservation laws. in textile technology in 1967 from
This index basically confirmed what is already known (fiber Calcutta University and a M.S. and
Ph.D. in fiber science in 1994 from
blending performance depends on the fiber surface, resiliency the University of Manchester (ENG).
and compatibility). However, our index provides for the first He was also a Quality Control Direc-
time a quantitative measure of multi-component blending tor at National Spinning Company
which industry can use to establish reference values and deter- (North Carolina). Subhas’ research
interests include near infrared
mine the optimum mix. To examine the impact of mixing on spectroscopy, textile material charac-
yarn quality we are focusing our study on cotton/polyester terization, polymer recycling, and
blends. filament processing.
F99-A13
[Contributing Graduate Student: Weiping Du (Auburn)] (804)-296-5511
Industry Interactions: none reported subhasg@itt.edu
Project Web Site Address: none reported
Investigation of literature values and the Young’s modulus is very close to that
of normal viscose rayon. Thus, the procedures for producing
Flexible Crosslinking Systems for
model structures are reasonable, and we will use them to
the Retention of Mechanical Strength generate models for further simulations.
and Abrasion Resistance Average mechanical properties of amorphous cellulose models:
in Durable Press Cotton Fabrics Young’s Bulk Compress Shear Poisson’s
C97-C3 modulus modulus -ibility modulus ratio
Gary C. Lickfield, leader (Clemson); GPa GPa GPa GPa
Charles Q. Yang (University of Georgia) 9.7 5.4 0.18 4.0 0.2
Severe tensile strength loss has been the major disadvantage
for durable press finished 100% cotton fabrics. The loss of 1
tensile strength in resin finished cotton has been attributed to 0.9
two main factors: reduction in the degree of polymerization of 0.8
the cellulose due to acid degradation under high temperature 0.7
curing conditions; and formation of the network polymer
stress (GPa)
0.6
itself. The latter is related to the rigidity of the crosslinks
0.5
formed. To develop a fundamental understanding of the
0.4
mechanism of tensile strength loss in crosslinked cotton
fabrics, we are investigating the relationship between the 0.3
strength loss due to crosslinking and the molecular structure of 0.2
the crosslinking agent. 0.1
0
We are investigating the relationship -0.1 0 5 10
strain (%)
15 20
between the loss of mechanical strength in Average stress-strain diagram for amorphous cellulose 3D
durable press finished cotton fabrics and model structures using molecular mechanics calculations.
the molecular structure From these initial amorphous cellulose 3D models we
of the crosslinking agent. generated stress-strain data (See Graph) by calculating the
internal stress within the periodic cell due to an applied strain
along one axis of the cell. These data represent the average of
Studies presented earlier focused on the response of single each direction and each amorphous structure. Interesting, these
crosslink model structures and single polymeric chain models amorphous cells appear to deform elastically up to an applied
to an applied strain, providing such information as molecular strain of approximately 5-8%, above which there appears to be
extensibility and ultimate modulus. We are now extending plastic deformation and chain slippage. We are currently
that stress-strain work to three dimensional model structures to investigating the affect that water content and crosslink density
better understand the influence of intermolecular interactions has on these predicted mechanical properties.
on the extension and elastic recovery potential of crosslink
[Other Contributors: Graduate Student: Wei Chen (Clemson)]
structures in cellulosic models, specifically for amorphous
Research Scientists: Zhiping Mao, Lei Quian (Georgia)]
cellulosic structures.
Industry Interactions: 4 [Calloway Chemical, FMC Corp.,
Under periodic boundary conditions using Monte Carlo Sequa, Oxford Intl.]
Project Web Site Address: none reported
methods we generated amorphous cells consisting of cellulose
chains with a degree of polymerization of forty. These
For Further Information
amorphous cells were relaxed and optimized using a combina- 1. I. Kang, C. Q. Yang, W. Wei, and G. C. Lickfield, The Mechani-
tion of molecular mechanics minimization and molecular cal Strength of the Cotton Fabrics Crosslinked by Polycarbox-
dynamics, first at high temperature (1000 K), then at room ylic Acids: Part I. Acid Degradation and Crosslinking of
temperature (300 K). The fully optimized structures had an Cellulose, Textile Res. J. 68:856 (1998).
2. W. Wei, C. Q. Yang and G. C. Lickfield, The Mechanical
average density (1.42 g/cc) very close to literature values and Strength of Durable Press Finished Cotton Fabrics: Part II.
a minimal internal stress indicating that the models are fully Effects of the Catalysts Used for DMDHEU, submitted to Textile
relaxed. Res. J.
3. W. Wei, C. Q. Yang and G. C. Lickfield, Mechanical Strength of
The average Hildebrand solubility parameter, which can Durable Press Finished Cotton Fabric: Part III. Comparison of
sometimes be used as a rough indicator of mechanical proper- Crosslinking Agents with Different Molecular Structures and
ties of the polymer, was comparable with the experiment Reactivity, submitted to Textile Res. J.
values. Calculated mechanical properties are very close to
(CF 3(CF2)nCO)2O
n = 0 ,1 NaO3S SO3Na
Reactive Dyes
We recently prepared water-repellent reactive dyes 1 and 2 Cl
(See Figure below), which give water repellency on mercer-
Cl N N
H O
OH N N NHC(CF2)nCF3
N N NaO3S N N
R H
OH N N NH NaO3S SO3Na
N N
Synthesis of a fluoroacyl-containing reactive dye
SO3Na
media. To circumvent this problem, we designed type 5 dyes
NaO3S SO3Na (See Scheme below), which would be much less prone to acid-
induced cleavage. We have already synthesized the tosylate
1 R = C12H25 (A) and coupler (B) precursors.
2 R = C14H29 (Pyridine)
ized cotton but not on unmercerized cotton, because of N + TsCl N
expected low fixation on the latter type substrate. The best -10 to -20°C
water repellency we obtained (80 in AATCC 22-1989) was OH OTs
A
with type 3 dyes containing a second hydrophobic group (See
Figure); however, the low water solubility of these dyes limits CH3(CH2)11NH2
their application to the pad-dry-cure process. 65-70°C
Cl (CH3CN)
N N
H29C14 H N
OH N N NHC12H25
N N B NH(CH2)11CH3
Ar N N
NaO3S SO3Na
3
Our most recent studies involve the synthesis of reactive
dyes containing a perfluoroacyl group (See 3-step sequence in
Scheme at top right). Ar N
N N
Disperse Dyes
Earlier we prepared a series of water-repellent disperse NH(CH2)11CH3
5
dyes (See Insert) in which the Ar-group included substituted
benzenes and heteroaromatic O R [Contributing Graduate Students: Monthon Nakpathom, Xin
N N Chen (NC State)]
systems and the R-group
Ar N O Industry Interactions: none reported
included alkyl and perfluoroal-
Project Web Site Address:
kyl chains. Such dyes, however, http://www2.ncsu.edu/unity/lockers/project/ntcprojects/projects/C98-S04
lost the acyl group during dye application, even in weakly acid
For Further Information: nothing reported
measurements (data fusion) which will be used in our time For Further Information:
series analysis. 1. Jooyong Kim, On-Line Measurement and Characterization of
Yarn and Fabric Qualities Using a Wavelet-Stochastic Hybrid
The heart of the experimental test-bed is a Lawson- Method, Ph.D. Thesis, NC State (1998)
Hemphill Constant Tension Transport system which allows us 2.Jooyong Kin, Wavelet-Stochastic Models And Their Application
to sample the yarn every millimeter to produce a 1024 pixel To Yarn And Fabric Quality Measurement And Control, The Fiber
(12 bit) line-scan image. We also measure the linear mass Society Symposium “100 Years of Modern Fiber Science”,
Asheville, NC (Jul 1998) - Best Student Paper Award
density using a capacitance sensor with an 8 mm sensing zone. 3.Moon W. Suh and Jooyong Kim, Wavelet-Stochastic System for
We applied wavelet transforms to represent all the yarn Measurement and Analysis of Yarn and Fabric Qualities, 11th
EFS Systems Research Forum, Raleigh NC (Nov 1998)
characteristics from only a minimal amount of data without 4.Sugjoon Lee, Development of a Measurement System for Yarn
losing significant information. In this method the original Mass Variation, Masters Thesis, NC State (Dec 1998)
density profile of yarns is decomposed into different
Habit Stock
Because of nearly unlimited substitution possibilities, 5.15
fashion-oriented textile and apparel demand may only be 4.85
accurately predicted if all available information is incorpo-
rated using a systems approach. Only by combining both 4.55
quantitative information (relating to demographic and socio- 4.25
economic changes) and qualitative information (on social, 1990 1990 1991 1992 1993 1994 1995 1996 1997 1998
political and technological trends) can we design a compre- Year
hensive and theoretically consistent system of consumer
demand equations for predicting consumer purchases in interrelationships for the past nine years. The model incorpo-
textiles and apparel. rates a measure of the psychological stock of habits as well.
Information and Data Acquisition The notion is if there is ‘persistence’ in consumer expenditure
At the statistical and econometric modeling level, we patterns for men’s clothing, then this habit stock variable
merged demographic and economic data with measurable should help determine the current demand for the various
social, political and technological trends and other nontradi- categories of men’s apparel. Using 1990 to 1998 monthly
tional qualitative and quantitative data pertaining to fashions purchasing statistics, most equations fit the data well, with
and their intensities. We applied a first-order differential individual equation correlation coefficients (R2) generally in
demand system (the Rotterdam Demand System) and specified the 0.80 to 0.95 range. Overall, the Rotterdam model used in
the parameters of this system as a function of the consumer's conjunction with consumer habit stock formation provided a
"habit stocks," the mix of various types of clothing that the good fit to the data and demonstrated the apparel purchase
consumer purchases. We specified these habit stocks as a behavior patterns of men (See Figure). Of interest is that total
dynamic state-adjustment equation. With this approach, repre- expenditure for all men’s clothing is increasing over time and
sentative consumer's preferences for particular textile or the habit stock variable is not represented by a simple linear
apparel categories were allowed to evolve systematically over trend, but instead cycles with the seasons.
time. For example, with the advent of a more casual business We have attempted to link habit stock variables to some of
attire, dress shirts have declined as a percentage of men’s habit the social trend data to see how well consumers’ response
stock of shirts. rates correlate with apparel purchase volumes. We ran a
correlation analyses with the GSS cumulative dataset that
We are designing consumer demand merges 20 years of annual data consisting of over 1000
equations to predict consumer purchases in questions about socioeconomic status, social mobility, social
textiles and apparel. control, the family, race relations, sex relations, civil liberties
and morality. From this GSS data we selected 12 questions
We have now used our estimated demand systems to link that are likely to be correlated with consumer purchasing
habit stock variables to observed social, economic, behavior. Although the sample size is rather small, it seems
demographic, technological and other industry-specific that, in general, there is a positive correlation between the
fashion trend variables. In addition to commonly deployed response rates and apparel purchase sales volumes (See Figure
econometric variables, we incorporated General Social below for the buying habits of people who favor abortion at
Survey1 (GSS) data, standard industry advertising expendi- the woman’s discretion - a GSS question).
tures, indicators for ethnic diversity and measures related to
sudden changes in political and technological climates. In this Correlation of Pro-Abortion Support with
way, we are able to identify which factors, aside from prices Casual Women's Shorts Purchases
and income, are important in explaining consumers' buying
casual units purchased
patterns. 300000
Concurrently, we have also updated all relevant U.S. 250000
government statistics (e.g. Census, Economic Analysis and 200000
Labor Statistics) in our Textile and Apparel Business Informa- 150000
tion System (TABIS) database. y = 87.602x + 176432
100000
R2 = 0.7064
Modeling, Analysis and Results 50000
We have now applied the so-called “habit-stock” model to 0
fifteen categories of men’s apparel items, including knit shirts, 0 200 400 600 800 1000
dress shorts, jeans, shorts, suits, blazers and casual slacks to
Abortion for any reason
examine consumption trends and price-consumption
A retailer or manufacturer can now when domestic, quick response manufacturing is cost
effective. However, a cooperative environment has to be
analyze the accuracy
established early in the planning cycle, and involve everyone
of their sales forecast, and in decision making and sharing of data. It naturally emerges
determine how much that a successful domestic manufacturer must evolve well
Quick Response Manufacturing beyond the old fashioned “cut and sew,” and invest in CAD
is cost-effective. systems, computer-controlled cutting, logistics support and
most importantly, rapid exchange of sales and production data
We are researching these questions in four ways. First, we between retailers and manufacturers.
have developed an analytical model that includes both domes- [Contributing Graduate Student: Maged S. Fanous (UMassD)]
tic and offshore manufacturing. Our model has the advantage
Industrial interactions: “several companies” but none reported
that its parameters are readily observable and can be tuned to
an organization’s individual business situation. Retailers can Project Web Site Address:
http://www.umassd.edu/1academic/cengineering/textiles/index.html
use the model to determine when it is cost effective to employ
domestic manufacturers. Second, we are testing and evaluat- For Further Information
1. Lowson, R. E. King and A. Hunter, Quick Response: Managing
ing the Sourcing Simulator4 (See I98-S12 on p.81) to compare the Supply Chain to Meet Consumer Demand [in-depth account].
its predictions to real-world sales data for several athletic wear 2. R. E. King and A. Hunter, The Quick Response Advantage
styles. Bobbin (Mar 1997) [some advantages of QRM].
3. J. Lovejoy, Sourcing Simulator, [TC]2 (1999).
Third, we have received encouraging support from several
quite diverse manufacturers. U.S. companies typically use Roger Warburton, an Adjunct Profes-
sor in the Department of Textiles at
off-shore manufacturing for high volume, basic styles; but they UMass Dartmouth since 1999, earned
also struggle with the quick response demands of their custom- a Ph.D. in physics from the Univ. of
ers. Thus they often use a mixture of off-shore and on-shore Pennsylvania in 1976, then managed
manufacturing. software projects for Jaycor (Defense
Dept. contractor). Roger also earned
Fourth, standard accounting practices often make offshore a B.Sc. in physics in 1969 from
manufacturing appear more financially attractive than it Sussex (UK) Univ. Since 1989, he has
been Director of Management Infor-
actually is. One has to look carefully at the raw labor rate mation Systems (MIS) for Griffin
because staff turnover rates in the Caribbean often exceed Manufacturing where he designed
40%, while sewing efficiencies are sometimes only 25% of software to manage factory workflow,
U.S. factories. Also, there is evidence that off-shore logistics purchasing and inventory and
garment costing. His research inter-
costs actually exceed labor costs, off-shore minimums and ests include apparel MIS and supply
guaranteed contracts make small production runs expensive, chain management
and their long lead times conflict with quick response require- I99-D16*
ments and tie up capital. Therefore, it is absolutely vital to roger@griffinmanufacturing.com
(508)-677-0048
determine the true offshore manufacturing costs. http://www.umassd.edu/engineering/textiles/faculty.html
Our analytical model links the accuracy of sales forecasting
to product margins, and can be used to determine precisely
Abbott, Albert (C) 8 Goswami, Bhuvenesh C. (C) 20, 23, 26 Salem, David (TRI) 14
Abelson, Joseph (P) 86 Govindaraj, Muthu (P) 85 Samuels, Robert J. (G) 6
Abou-iiana, Mohamed (P) 86 Gowayed, Yasser A. (A) 1 Schork, F. Joseph 57
Acar, Memis (Loughborough Univ.) 39 Grasso, Maureen (UNC-G) 73 Seyam, Abdelfattah (N) 33
Adanur, Sabit (A) 35 Gray, Stephen (Nottingham Trent) 73 Shalev, Itzhak (N) 37
Ahmed, Anwar (A) 35 Gregory, Richard V. (C) 6 Sharov, Alexei (Virginia Tech) 88
Armstrong-Carroll, Eileen (P) 92 Hanks, Timothy (Furman) 6 Slaten, Lewis (A) 3, 45
Aspland, J. Richard (C) 61 Hauser, Peter (N) 49, 51, 63 Smith, C. Brent (N) 59
Bakhtiyarov, Sayavur I. (A) 35 Hinks, David (N) 55 Solomon, Michael (A) 65
Barker, Roger L. (N) 37 Hodge, George L. (N) 33, 95 Srinivasarao, Mohan (G) 61
Basu, Arindam (S.India TRA) 39 Hodgson, Thom J. (N) 81 Suh, Moon W. (N) 37, 67, 79
Batra, Subhash K. (N) 20 Holt, Matthew T. (N) 79 Sun, Gang (Univ. of California Davis) 45
Beale, David G. (A) 35 Hudson, Samuel (N) 4 Sundermann, Christine A. (A) 45
Bechtel, Steve (Ohio State) 14 Istook, Cynthia (N) 94 Sztandera, Les M. (P) 83
Beck, Keith R. (N) 59 Jacob, Karl (G) 14, 16 Teulé, Florence (C) 8
Beckham, Haskell (G) 43 Jasper, Warren (N) 59, 67 Thomas, Howard (A) 88
Berkstresser, Gordon (N) 77 Kamath, Y. K. (TRI) 47 Thommesen, Sven (A) 75
Bock, Charles (P) 83 Kim, Hyung Bum (N) 37 Thompson, Henry L. (A) 88
Brannon, Evelyn (A) 71, 73, 75 Kim, Jai-Ok (A) 69 Tincher, Wayne C. (G) 57
Broughton, Roy M. Jr (A) 1, 3, 19, 43 Kim, Yong K. (D) 22, 25 Tonelli, Alan E. (N) 49, 61
Buschle-Diller, Gisela (A) 4, 53 King, Russell E. (N) 77, 81, 90 Trachtman, Mendel (D) 83
Cahill, Neil (ITT) 88, 95 Ko, Frank K. (Drexel) 28 Ulrich, Pamela (A) 71, 73, 75
Carr, Wallace W. (G) 26, 43, 57 Lee, Gordon K. L. (N) 59 Vaughn, Edward A (C) 23
Carrere, Carol G. (N) 81 Leisen, Johannes (G) 43 Walsh, William K. (A) 4
Chapman, Leon (Sandia) 69 Lewis, Armand F. (D) 12, 22, 25 Wang, Youjiang (G) 26, 32
Chen, Julie (U. Massachusetts Lowell) 12 Lickfield, Gary C. (C) 8, 41, 55 Warburton, Roger D. H. (D) 90
Chen, Xuemin (TRI) 47 Lin, Weiping (A) 4 Warner, Steven B. (D) 10, 12, 43, 90
Clapp, Timothy G. (N) 30 Little, Trevor J. (N) 77, 81 Welters, Linda (Univ. Rhode Island) 90
Connell, Lenda Jo (A)71, 73, 75 Luke, John E. (P) 86 Wilson, James R. (N) 77
Cook, Fred L. (G) 26 Mahrous, Mohamed (UNO) 36 Woo, Jae L. (N) 37, 67
Cuculo, John (N) 1 Marcotte, William R. Jr. (C) 8 Worley, Dave (A) 45
Cuomo, Jerome J. (N) 63 May, Sheldon W. (G) 19 Yang, Charles Q. (UG) 41
Dawson, Darren (C) 30 McClain, Aliecia (A) 4 Zeronian, S. Haig (UC Davis) 53
Dorrity, J. Lewis (G) 26 McCord, Marian G. (N) 37, 63 Zhu, JunYong (IPST) 57
Dozier, Gerry (A) 69 Mi, John Z. (Cotton, Inc.) 32 Zumbrunnen, David A. (C) 23, 26
Drews, Michael J. (C) 55 Michielsen, Stephen (G) 45, 61 (A): Auburn
Du, Weiping (A) 36 Mills, German (A) 3, 45 (C): Clemson
Duenas, Guillermo (P) 86 Morris, Jeffrey F. (G) 57 (D): University of Mass. at Dartmouth
Dunn, Matthew W. (P) 18 Neimark, Alexander V. (TRI) 47 (G): Georgia Tech
Early, Judson H. [TC]2 73 Nuttle, Henry L. W. (N) 77 (IPST): Inst. of Paper Science & Technology
Eischen, Jeffrey W. (N) 30 Oxenham, William (N) 20, 33, 39, 95 (ITT): Institute of Textile Technology
El Mogahzy, Yehia (A) 36 Parachuru, Radhakrishnaiah (G) 26, 53 (MIT): Mass. Inst. of Technology
Ellison, Michael S. (C) 8, 23 Pastore, Christopher M. (P) 28, 92 (N): North Carolina State University
Englis, Basil G. (Berry College) 65 Paul, Frank (C) 30
(P): Philadelphia University
Fang, Shu-Cherng (N) 77 Petee, Thomas (A) 69
[TC]2: Textile/Clothing Technology Corp
Forsythe, Sandra M. (A) 69 Pierce, John D. Jr. (P) 92
(TRI): Textile Research Institute
Fowler, Alex (D) 25 Polk, Malcolm (G) 16
(UNC-G): Univ. of North Carolina Greenville
Fraser, W. Barrie (U.Sidney,Australia) 20 Presley, Ann Beth (A) 71, 73, 75
(UNO): University of New Orleans
Franzon, Paul (N) 33 Qiu, Yiping (N) 32, 63
Rahn, Christopher D. (C) 20, 30 For more abbreviations see p. xi. See the page
Freeman, Harold S. (N) 51, 53 cited for the report authored by the principal
George, Brian (P) 92 Realff, Mary Lynn (G) 26
contributors whose bios, photos, E-mail
Ghosh, Subhas (ITT) 36 Reese, D. Michelle Benjamin [TC]2 81 addresses, telephone numbers and web address
Ghosh, Tushar K. (N) 20 Russo, Paul (Louisiana State) 61 (if available) follow each report.
Rutledge, Gregory C. (MIT) 10
DIRECTORY
FEATURING
BIOGRAPHIES
with
PHOTOS
NTC PROJECT N O S.
E-MAIL ADDRESSES
PHONE NUMBERS
WEB ADDRESSES
JUNE 2000
NTC Principal Investigators: A - C
Key:
Short biography (experience, degrees, research interests)
NTC project(s) as investigator ( * = project leader)
[old# to new# style: G92-1=F92-G1, G94T-2=C94-G2T]
E-mail address
Phone number
Personal web page URL