SAMPLE PAPER

CLASS XI
CHEMISTRY
Time: 3 Hours Maximum Marks: 70
General Instructions:
(3) All questions are compulsory.
(4) Marks of each question are indicated against it.
(5) Question nos. 1 to are !ery short ans"er questions and carry 1 mark each.
(#) Question nos. $ to 1 are short ans"er questions and carry % marks each.
(&) Question nos. 1$ to %& also short ans"er questions and carry 3 marks each.
() Question nos. % to 3' are long ans"er question and carry 5 marks each.
($) (se log ta)les if necessary* use of calculators is not allo"ed.

Q1 +o" are '.5' mol ,a
%
-.
3
and '.5' M ,a
%
-.
3
different/
Q% +o" many su)shells are present in M shell/
Q3 0hich property of element is used to classify them in long form of periodic ta)le/
Q4 0rite resonance structure of .1one or sulphurdio2ide.
Q5 0rite con3ugate )ase for "ater and ,+
4
4 species.
Q# 0hat do you understand )y +ydrogen economy/
Q& 5ind out o2idation num)er of chromium in 6
%
-r
%
.
&
molecule
Q 7ndicate sigma and pie )onds in -+
%
8-8-+
%
. 1 9 8 Marks
Q$ -alculate num)er of photons "ith a "a!elength of 3'''pm that pro!ides 1 :oule of
energy. % Marks
Q1' ;2plain "hy )ond angle in ,+
3
is more than in +
%
. molecule though )oth ha!e sp3
hy)ridi1ation. % Marks
Q11 At constant temperature if the pressure of a fi2ed mass of gas is dou)led "hat happens
to its !olume / 0hich la" go!erns this )eha!ior of gases/ % Marks
Q1% +o" many grams of o2ygen is required for complete com)ustion of %$g of )utane as per
the equation -
4
+
1'
4 4.5.
%
8%-.
%
45+
%
. % Marks

Q13 -alculate )ond order of o2ygen molecule. <ist all the information pro!ided )y the )ond
a)out this molecule. % Marks
Q14 -alculate the total pressure in a mi2ture of 1# g of o2ygen and 4g of +ydrogen confined
in a !essel of 1dm=
3
at %& degree celsius. (Molar mass of o2ygen 3% +ydrogen % >8
'.'3)ar dm
3
6=1mol=1) % Marks
Q15 ?alance follo"ing equation in acidic medium sho"ing all steps*
?r
%
4 +
%
.
%
= ?r.
%
4 +
%
. % Marks
Q1#+o" are silicones prepared/ 0rite necessary reaction. 0rite t"o uses of silicones.
% marks
Q 1& 0hat is demineralised "ater/ +o" is it o)tained/ % Marks
Q1 0hat is the reason of diagonal relationship of elements/ 0rite t"o properties of any t"o
diagonally related elements.
Or
@i!e reasons
(1) "hy alkali metals "hen dissol!ed in <iquid ammonia gi!e )lue solution/
(%)?eryllium and Magnesium do not impart colour to the flame "hile other mem)ers do.
Q1$ (1) Atate +eisen)erg s (ncertainty principle.
(%) 0rite electronic configuration of -u metal (B8%$) and -r
34
ion.
(3)0hich or)ital is represented )y n84 and l83/ 3 Marks
Q%' ;2plain "hy
(1) +alogens act as good o2idi1ing reagent.
(%);lectron gain enthalpy of inert gases is 1ero.
(3)7oni1ation enthalpy of Mg is higher than that of ,a. 3 Marks
Q%1 (1) 0hat do you mean )y ?ond ;nthalpy/
(%) -alculate )ond enthalpy of -l===-l )ond from follo"ing data.
-+
4
(g) 4 -l
%
(g)==-+
3
-l(g) 4+-l (g) C+=8 ==1'$.3k: mol=1
?ond enthalpy of -D+ ?ond 8 413k:* -D-l ?ond 83%# k: and +D-l ?ond 8431k: mol =1
3 Marks
Q%% (1) 0hat are e2tensi!e properties/
(%) 0rite @i))s free energy equation gi!ing meaning of each term used.
(3) (nder "hat condition C (8 C+ / 3 Marks

Q%30rite chemical equation only for preparation of

(1) Elaster of Earis
(%) Quick lime
(3) slaked lime. 3 Marks
Q%4 (1) 0hat do you mean )y functional isomerism/
(%) 0hat are electrophiles/
(3) 0hat is inducti!e effect / @i!e an e2ample. 3 Marks
Or
(1) 0rite 7(EA- names for -
#
+
5
-+
%
-+. and (-+
3
)%D-+(,+
%
)D-+
3
(%) 0rite an e2ample of geometrical isomerism.
(3) 0hat do you mean )y electromeric effect/ 3 Marks
Q%5(1) Fra" eclipsed and staggered conformations of ethane.
(%)0rite one equation each to sho" 0urt1 reaction and 5riedal craft alkylation. 3 Marks
Q%# (1) +o" nitrogen is detected in an organic compound./0rire necessary reactions.
(%) +o" a molecular formula is different from empirical formula/ 3 Marks
Q%& (1) 0hat do you mean )y green chemistry/
(%) ;2plain terms ?.F and -.F "ith reference to en!ironmental chemistry. 3 Marks
Q% (1) 5or the reaction ,
%(
g) 4 3+
%
(g)G%,+
3
(g) the !alue of 6p is 3.# 21'
%
=4 %=% at 5'' 6.
-alculate the !alue of 6c for the reaction at the same temperature. >8'.'3 )ar < 6=1 mol=1.
(%) 0hat do you understand )y (1) -ommon ion effect (%) ?uffer solution.
34% Marks
Or
(1) 5or the reaction E-l
5
GE-l
3
4-l
%
at 4&36 the !alue of equili)rium constant 6c is .3
21'
=3
(1) 0rite an e2pression for 6c (%)0hat is the !alue of 6c for re!erse reaction at same
temperature.(3) 0hat "ould )e effect on 6c if pressure is increased.
(%) Atate +enryHs <a". 0rite p+ !alue of 121'=5 M +-l solution. 34% Marks
Q%$ @i!e reasons for
(1)IAi5
#
%
J= is kno"n "hereas IAi-l
#
J=
%
is not kno"n.
(%) Fiamond is a co!alent solid* yet it has highest Melting Eoint.
(3) ?oric acid is considered a "eak )ase.
(4) ?53 )eha!es as <e!is acid.

(5) -.
%
is a gas "hile Ai.
%
is a solid at room temperature.
Or
(1) 0hat are fullerenes/=
(%) 0hy is )oric acid mono)asic/
(3)0hat is inert pair effect/
(4)0hy is E)-l
%
is a good o2idi1ing reagent/
(5)0rite the formula of inorganic )en1ene.
Q3' (1) Atate Marko!nicoffHs rule. (sing this "rite the reaction of propene "ith +-l.
(%) -arry out follo"ing con!ersions
(1) ;thyl alcohol to ethane.
(%) Aodium acetanilide to )en1ene.
(3) ?en1ene to nitro)en1ene. %43 Marks
Or
(1')0rite t"o reactions to sho" acidic nature of ethyne
(11)-omplete the follo"ing reactions=
o1oneKBnK+
%
.
(1%)-+
3
D-+8-+
%=============

aquous 6Mn.
4
(13)-+
3
D-+8-+
%
======================
(14)-+8-+ 4 ?r
%
"ater============
Marking S!eme
SESSIO" E"#I"$ EXAMI"ATIO"
CLASS XI
CHEMISTRY
%& -orrect meaning L 41K%
%' M"o one s and one p L 41K%
%3 Atomic ,um)er
%( -orrect structure 1 mark
%) -orrect ans"er L 41K%

%* correct ans"er 1mark

%7 4# 1mark
%+ Aigma # pie % 1mark
%, ;8hN L
8 #.#%# 21'=
34
23'''21'
=1'
81$.&2 1'=
41
: 1mark
1K1$.&21'=
41
8 5.'32 1'=
3$
photons L mark
%&0 -orrect e2planation "ith correct structure 141 mark
%&& Fecreases to half* ?oyleHs <a" 141 mark
%&' -orrect formula L mark
-orrect !alues and calculation 1mark
Ans. %.'# molK 6g L mark
%&3 correct formula L mark
-orrect !alues and calculation 1mark
-orrect ans"er "ith units L mark
%&( correct )ond order 1mark 4 correct information 1mark
%&) correct steps 421K% 8%
%&* correct method 4correct uses 141 mark
%&7 correct reasons 141 or correct reason 1mark4 t"o properties 1mark
% &+ correct definition 4 .ne correct method 141 mark
%&, (1) correct definition 1mark
(%) -orrect configuration L 41K%
(3) 4f 1mark
%'0 correct ans"er 1mark each
%'& correct definition 1mark
O ?ond enthalpy of reactants = O ?ond enthalpy of Eroducts L mark
-orrect !alue and calculation 1 mark
Ans"er %34.& k: L mark

%'' -orrect ans"er 1mark each

%'3 -orrect method "ith equation 1mark each
%'( -orrect Ans"er of each part 1mark each
%') -orrect Ans"er of each part 1mark each
%'* -orrect method "ith equation %mark
-orrect relation 1mark
%'7 correct ans"er of each part 1mark each
%'+ (1) -orrect relation L mark* C n8=% L mark
-orrect !alue and calculation 1 mark * ans"er L mark
(%) -orrect meaning 1mark each
.r (1) -orrect ans"er of each part 1mark each
(%) -orrect statement 1mark* p+85 1mark
%', -orrect ans"er of each part 1mark each.
%30 (1) -orrect rule 1 mark * correct reaction 1mark
(%) -orrect ans"er of each part 1mark each
.r
(1) t"o correct reaction % mark
(%) -orrect ans"er of each part 1mark each.