PROBLEMA PROPUESTO

Base de Clc: 122.403846

fraccion
Carbono %
83.2
0.832
Hidrogeno %
10.5
0.105
Oxigeno %
4.1
0.041
Azufre %
1.3
0.013
Nitrogeno %
0.9
0.009
Cenizas %
0
0 fraccion
%C(CO2)
86.50
forma
0.865
%C(CO)
10.00
forma
0.1
%C ( C)
3.50
no combustiona
0.035
densidad (d)
0.8500
kg/L
1 galn (g)
3.785
L/gal

a=

El exceso de oxigeno es
La temperatura del aire es
Temperatura de los gases
Temperatura de la flama

Ta =
Tc =
Tf=

0.23
18
500
1500

Calcular el volumen de aire requerido

Composicin de los gases de combustin
Peso molecular aparente de los gases
Volumen de los gases de combustion
Velocidad de salida de los gases

NOMBRES Y APELLIDOS
CURSO Y TURNO
PROFESOR

Base de
datos
C
C
C

Clculo

1 paso : determinar el peso del petrleo (W)

W=

393.803774 kg/h

2 paso. Deteminar mol-kg de cada componente

hC =
hH

27.30 mol-kg
20.67 mol-kg

hO =

0.505 mol-kg

hN =

0.1266 mol-kg

hS =

0.160 mol-kg

h CCO =
2

h CCO =

h CC =

3 paso :Aplicar las ecuaciones estequiometricas, clculo de oxigeno

23.62 mol-kg
mol-kg
2.730372833
mol-kg
0.955630492

O2

23.62

CO 2

23.62

0.5O 2

2.730
H2

CO

1.365

2.730

0,5 O 2

20.67
S

23.62

H2O
10.34

20.67

O2

0.160

SO 2

O 2 (teorico)=

0.160
35.48
35.480 mol-kg

O 2 (correg)=

34.976 mol-kg

O 2 (exceso) =

8.044 mol-kg

O 2 (total) =

43.020 mol-kg

0.160

4 paso : Calculo del aire requerido

h aire =

204.858 mol-kg

hN =

161.837 mol-kg

h N Total =

161.964 mol-kg

V aire =

3
4891.368 m / h

5 paso : Composicin de los gases de combustin

gases
CO2

mol-kg
23.62

PM
44.00

kg
1039.18

CO
C
H2O

2.73
0.96
20.67

28.00
12.00
18.00

76.45
11.47
372.14

1.21
0.18
5.91

16.49

SO2

0.16

64.00

10.24

0.16

O2(exc)

8.04

32.00

257.42

4.08

N2 (TOTAL)

161.96

28.00

4534.99

218.15

PM=
V gas =
v gas =

6301.90

28.89
3
13836.11 m /h

3.84 m/ seg

71.96
100.00

6 paso: resultado en diagrama de flujo

COMBUSTION INCOMPLETA
Petrleo

Carbono (%)
Hidrogeno(%)
Oxigeno (%)
Nitrgeno (%)
Azufre (%)
Cenizas (%)

122.4038462 gal/h

Entrada
mol-kg
27.30

Carbono
Hidrogeno
Oxigeno
Nitrogeno
Azufre
Cenizas

83.2
10.5
4.1
1.3
0.9
0
0.23
Salida
CO2
CO
C
H2O
SO2
O2(exc)
N2 (TOTAL)

10.5
4.1
0.9
1.3
0

kg
1039.18
76.45
11.47
372.14
10.24
257.42
4534.99
6301.90

m3
Aire
Taire C

4891.368
18

7 paso calcular el valor de Nox

NOx T
=

10 6 5340

5, 35

100a 38

Temperatura de flama

Exceso de oxigeno
Galones de petroleo

1500 F
0.23
122.403846

NOx Tf
=

10 6 5340
C=

lbNOx
10 6 BTU

5, 35

a .100 38

0.068402558 Lb Nox/10^6BTU
1 galon <>130000BTU
x
<> 10^6BTU
x=
7.69230769 galones
1 lb = 0,454 kg=454 g=
454000 mg
Contenido de Nox =

Concentracion de NO x
CONTROL DE EMISIONES

1.77846652 lb
807423.7999 mg
58.35629184 mg/m3

PM
Vgas m3/h

28.89
13836.11

vgas m/s

3.84

Tgas C

500

CO
C

SO2
NO x

Mp2.5
MP10
NH3

5525430.57 ug/m3
828814.59 ug/m3
740013.02
58356.29
19069.56636
26185.0762
3415.444722

ug/m3
ug/m3
ug/m3
ug/m3
ug/m3

Valvula de agua
Manometro

Presostato

Llama azul

Volumen de aire que

ingresa : 10577,886
m3/h

Cp 18=

29.12

Decantador de cenizas

EMISIONES

CO
CO2
H2O
O2
N2

mol-kg
2.73
23.62
27.306
8.04
161.96

Cp 18C
29.124
36.425
33.509
29.279
29.12

Cp 350
29.658
42.599
34.796
30.6575
29.4925

EMISIONES
total

Volumen

13836.105 m3

T gases
T ambiente

350 C
18 C

CALCULAR AL CANTIDAD DE AGUA CON EL GAS DE COMBUSTION/HT AGUA 60C

T final
TAgua
TAgua Que ingresa

Magua*Cp*T= 2226765.948
Magua

27490.93763 kg/lb
12480.88569 kg

Cantidad de agua

60C

25037,9 Kg
de agua

Volumen de agua
: 22179,794 m3/h
35C

En el caso del material

particulado en MP10 se

En el caso del material

particulado en MP10 se
forman 32,48mg/m3 que seria
los que quedan en el venturi.

Ci
al 100%
740013.02 g/m3
19069.5664 g/m3
58356.29 g/m3
mg/m3
828.814586
mg/m3
5525.43

SO2
Part. susp.
NO2
CnHn
CO

Cs
350
250
200
140
20
Suma =

Ci/Cs
2114.322923
76.27826546
291.7814592
5.920104185
276.2715286
2764.574281

Valaores de Cs

SO2
350

Part. susp.
250
g/m3

NO2
200
g/m3

CnHn
140
mg/m3

CO
20
mg/m3

ORAQUI = 3,5
1

Resultado
ORAQUI =

288671.5217

Part. sedim.
300
mg/m3

Ci

CS

1, 37

Pb
4
g/m3

Ci
al 1%
7400.13 g/m3
190.695664 g/m3
583.56 g/m3
mg/m3
8.28814586
mg/m3
55.25

SO2
Part. susp.
NO2
CnHn
CO

Cs
350
250
200
140
20
Suma =

Ci/Cs
21.14322923
0.762782655
2.917814592
0.059201042
2.762715286
27.64574281

Valaores de Cs

SO2
350

Part. susp.
250
g/m3

NO2
200
g/m3

CnHn
140
mg/m3

CO
20
mg/m3

ORAQUI = 3,5
1

Part. sedim.
300
mg/m3

Ci

CS

Pb
4
g/m3

Pb
4
g/m3

1, 37

Resultado
ORAQUI =

Ci

525.2958159

al 0,1%

740.01

SO2

Cs
350
250
200
140
20

g/m3

19.0695664 g/m3
58.36 g/m3
mg/m3
0.82881459
mg/m3
5.53

Part. susp.
NO2
CnHn
CO

Suma =

Ci/Cs
2.114322923
0.076278265
0.291781459
0.005920104
0.276271529
2.764574281

Valaores de Cs

SO2
350

Part. susp.
250
g/m3

NO2
200
g/m3

CnHn
140
mg/m3

CO
20
mg/m3

ORAQUI = 3,5
1

Resultado

Part. sedim.
300
mg/m3

Ci

CS

1, 37

ORAQUI =

A
u
H
To
T1
Vo
D
Fo
Xo
LN Fo
LN Xo*3,5
Heff

0.125664
30
6
773
291
30.58443618
0.4
7.473297248
49.2122471
2.0113363
5.148905486
9.227976074

X
LnX

4
1.386294361
Iy

22.40804364

m2
m/s
m/s
K
K
m/s
m

LN X2
Jy

Ky

2.772588722
Iz

Jz

Kz

5.357

0.882

-0.0076

6.035

2.1097

0.277

5.058

0.9024

-0.0096

4.694

1.0629

0.0136

C
D

4.651
4.23

0.9181
0.922

-0.0076
-0.0087

4.11
3.414

0.9201
0.7371

-0.002
-0.0316

E
F

3.922
3.533

0.922
0.9181

-0.0064
-0.007

3.057
2.621

0.6794
0.6564

-0.045
-0.054

QCO
QSO2
QNOX
QC
QMP2.5

288661083.4
2844138.368
16.21008107
3185434.972
5.297101768

ug/s
ug/s
ug/s
ug/s
ug/s

A: MUY INESTABLE
X
LNX
LN X2
Yj
Zj
CCO
CSO2
0.01 -4.605170186 21.2075924 3.108257232 8.97080634 32356.52491
318.8044365
0.02 -3.912023005
15.303924 5.991165017 7.545806753 16036.66714
158.0070988
0.03 -3.506557897 12.2959483 8.765001834 7.715200545 11074.79865
109.1184839
0.04 -3.218875825 10.3611616 11.46394273 8.282786361 8670.440459
85.42866985
0.05 -2.995732274 8.97441185 14.10541272 9.032378263 7132.542787
70.27597339
0.06 -2.813410717 7.91527986 16.70011525 9.895498259 5999.152092
59.10882912
0.07 -2.659260037 7.07166394 19.25533185 10.84397919
5106.18675
50.31056313
0.08 -2.525728644 6.37930518 21.77635213 11.86434656 4380.182132
43.15733844

0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

-2.407945609
-2.302585093
-1.897119985
-1.609437912
-1.386294361
-1.203972804
-0.105360516
0
0.693147181
1.098612289
1.386294361
1.609437912

5.79820205
5.30189811
3.59906424
2.59029039
1.92181206
1.44955051
0.01110084
0
0.48045301
1.20694896
1.92181206
2.59029039

24.26719984
26.73104228
38.72120122
50.28916037
61.53970658
72.53573977
193.2505742
212.0877279
389.4378817
553.7997872
709.8870372
859.9188564

12.94952514
14.09559033
20.68868146
28.70522825
38.19393471
49.23004299
335.5583471
417.7988096
2059.911072
5925.777657
13253.37019
25538.47974

3780.437279
3280.340071
1730.623861
1007.417645
632.7911359
421.3802249
23.60657804
17.27815746
1.908952292
0.466645879
0.162768522
0.069732231

37.24813402
32.32074429
17.05160137
9.925948955
6.234804943
4.151802009
0.232592401
0.170239334
0.018808647
0.004597798
0.001603736
0.000687062

Ci/Cs
ORAQI
ICA
93.72499134 2797.79011 12555.29126
46.45234594 1069.48255 125.6052972
32.07963187 644.032028 4.762067584
25.11508758
460.55739 -0.16324639
20.66036179 352.461897 -0.102321744
17.37734442 278.067666 0.120091964
14.79075118 222.976882 0.219948481
12.68778194 180.722255 0.251892656
10.95054095 147.706619 0.266452074
9.50194267
121.61194 0.286841505
5.012982908 50.6413235 0.516194938
2.918119616 24.1303963 0.729949484
1.83296395 12.7612758 0.854083275
1.220584041 7.31090183 0.921582661
0.068379603 0.14100114 1.018885671
0.050048488 0.09194727 1.019585999
0.005529535 0.00449631 1.020835705
0.001351702 0.00065265 1.020890667
0.000471481 0.00015418 1.020897795
0.000201989 4.8269E-05
1.02089931

B: MEDIO INESTABLE
X
LNX
LN X2
Yj
Zj
CCO
CSO2
0.01 -4.605170186 21.2075924 2.001899273 1.09153817 2.11684E-10
2.0857E-12
0.02 -3.912023005
15.303924 3.962839234 2.104428879 12.26137619
0.120809671
0.03 -3.506557897 12.2959483 5.883398034 3.108388758 1021.227321
10.06201382
0.04 -3.218875825 10.3611616 7.772566577 4.110598684 3857.131671
38.00379348
0.05 -2.995732274 8.97441185 9.635952066 5.113520794 6099.524494
60.09778482
0.06 -2.813410717 7.91527986
11.4773792 6.118234382 6992.473554
68.8958904
0.07 -2.659260037 7.07166394
13.2996339 7.125266553 6985.930783
68.83142536
0.08 -2.525728644 6.37930518 15.10484288 8.134884759 6549.286934
64.52923294
0.09 -2.407945609 5.79820205 16.89468706 9.147221395 5957.286625
58.69633445
0.1 -2.302585093 5.30189811 18.67053112 10.16233378 5344.209773
52.65577166

0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

-1.897119985
-1.609437912
-1.386294361
-1.203972804
-0.105360516
0
0.693147181
1.098612289
1.386294361
1.609437912

3.59906424
2.59029039
1.92181206
1.44955051
0.01110084
0
0.48045301
1.20694896
1.92181206
2.59029039

27.37392147
35.84367071
44.13143227
52.26961796
142.9808553
157.2756503
292.825484
419.431252
540.1943218
656.6160326

15.27929191
20.46173164
25.70394206
31.00074366
97.72557342
109.2894645
229.8163012
357.1405878
489.619677
626.3438532

3050.980002
1886.104731
1265.757782
904.1153969
109.1098045
88.77653067
22.73768716
10.21977016
5.788953824
3.723185383

30.06089078
18.58353326
12.47133918
8.908125975
1.075044056
0.874703076
0.224031337
0.100694005
0.057037774
0.036684039

Ci/Cs
ORAQI
ICA
6.13172E-13 1.0336E-16
1.0209
0.035516712 0.05747329 1.020078462
2.958121184 24.5847099 0.725431279
11.17269649 151.827235 0.264379017
17.66808648 284.461082 0.103823568
20.25463257 343.013811 -0.072839578
20.23568056
342.57418 -0.071449899
18.97088339 313.583477 0.020192423
17.25607552
275.4126 0.126584934
15.48021662 237.338261 0.201069845
8.837570629 110.115712 0.302338999
5.463353993 56.9760737 0.478442964
3.666436289 32.9904087 0.647557522
2.618890872 20.8062619 0.764014616
0.316051106 1.14826134
1.00461126
0.257153065 0.86563709 1.008596128
0.065862744 0.13393984 1.018986454
0.029602928 0.04478182 1.020259821
0.016768477 0.02055557 1.020606098
0.010784703 0.01122847 1.020739446

C: LIGERO INESTABLE
X
LNX
LN X2
Yj
Zj
CCO
CSO2
0.01 -4.605170186 21.2075924 1.299286866 0.843975112 1.53058E-20
1.50806E-22
0.02 -3.912023005
15.303924 2.567831726 1.615977093 0.030623005
0.000301724
0.03 -3.506557897 12.2959483
3.81209912 2.360855804 81.88789221
0.806830259
0.04 -3.218875825 10.3611616 5.037980348 3.088205045
1132.98831
11.16317964
0.05 -2.995732274 8.97441185 6.248945125 3.80257288 3391.359465
33.41460332
0.06 -2.813410717 7.91527986 7.447299578 4.506632677 5607.520007
55.25013156
0.07 -2.659260037 7.07166394 8.634697802 5.202147453 7069.215921
69.65202249
0.08 -2.525728644 6.37930518 9.812389405 5.890367938 7766.474218
76.52201361
0.09 -2.407945609 5.79820205 10.98135463 6.572227666
7918.09536
78.0159161
0.1 -2.302585093 5.30189811 12.14238471 7.248450049
7737.31413
76.23470324
0.15 -1.897119985 3.59906424 17.84817485 10.5619907 5546.104609
54.645014
0.2 -1.609437912 2.59029039 23.42230669 13.79043997 3790.058523
37.34293088

0.25 -1.386294361
0.3 -1.203972804
0.9 -0.105360516
1
0
2 0.693147181
3 1.098612289
4 1.386294361
5 1.609437912

X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

D:NEUTRO
X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25

1.92181206
1.44955051
0.01110084
0
0.48045301
1.20694896
1.92181206
2.59029039

Ci/Cs
ORAQI
4.43353E-23 1.3226E-30
8.87036E-05 1.5633E-05
0.237199205 0.77495832
3.281851799 28.3436779
9.823525158 127.285668
16.24292984 253.503176
20.47692707 348.181726
22.49662876 396.071977
22.93581962 406.703363
22.41216267 394.036071
16.06503195 249.707165
10.97841017 148.221864
7.807810887 92.9262351
5.799995998 61.8399545
0.83222331 4.32615276
0.6873019 3.32862873
0.194707408 0.59132632
0.093207523 0.21553661
0.055340132 0.10552085
0.03696735 0.06071337

28.89409865
34.28184742
95.02919348
104.6896229
197.1031082
284.4231603
368.3932867
449.8610424

16.95608784
20.07199423
55.31452808
60.94671757
115.2154455
167.0710663
217.3884439
266.5770293

2695.477736
2002.323098
287.3070872
237.2761068
67.21851886
32.17788003
19.10498279
12.76217749

26.55817534
19.72861701
2.830797634
2.337849192
0.662294919
0.317044273
0.188238796
0.125743998

ICA
1.0209
1.020899776
1.009878013
0.689284344
0.28095601
0.173815924
-0.089070886
-0.21278678
-0.227842037
-0.209195994
0.180801031
0.266182135
0.337220438
0.452447819
0.96088339
0.974397559
1.012478938
1.017822469
1.019392165
1.020032167

LNX
LN X2
Yj
Zj
CCO
CSO2
-4.605170186 21.2075924 0.818343613 0.52171654
4.1593E-62
4.0981E-64
-3.912023005
15.303924 1.632268313 1.047958352 1.30134E-11
1.28219E-13
-3.506557897 12.2959483 2.435078194 1.553894263 0.008891888
8.76106E-05
-3.218875825 10.3611616 3.228618652 2.042049425 8.542882226
0.084171856
-2.995732274 8.97441185
4.01427782 2.514953531
180.892428
1.782308478
-2.813410717 7.91527986 4.793076038 2.974607558 873.4276099
8.605763385
-2.659260037 7.07166394 5.565789089 3.422580662 2121.534898
20.90319465
-2.525728644 6.37930518 6.333026455 3.860124251 3596.614099
35.43694929
-2.407945609 5.79820205 7.095280119 4.288255929 4969.135377
48.96021467
-2.302585093 5.30189811 7.852956073 4.707818078
6066.27941
59.77022553
-1.897119985 3.59906424 11.58305802 6.69862599 7641.588134
75.29152802
-1.609437912 2.59029039 15.23450191 8.549135257
6566.50514
64.69888157
-1.386294361 1.92181206 18.82370226 10.29268208 5288.182168
52.10373929

0.3 -1.203972804
0.9 -0.105360516
1
0
2 0.693147181
3 1.098612289
4 1.386294361
5 1.609437912

X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

1.44955051
0.01110084
0
0.48045301
1.20694896
1.92181206
2.59029039

22.36117028
62.34983509
68.71723217
129.6582003
187.2454034
242.6071907
296.2981553

11.95017413
28.10613774
30.38654768
49.88580391
65.73605326
79.44844436
91.69460174

4253.363917
828.0214493
700.3459207
232.7441185
123.1947307
78.91644471
56.08078783

41.90781588
8.158382663
6.900413054
2.293196128
1.213820918
0.777552991
0.552556371

Ci/Cs
ORAQI
ICA
1.20804E-64
1.506E-87
1.0209
3.77965E-14 2.2724E-18
1.0209
2.58259E-05 2.8833E-06 1.020899959
0.024812262
0.0351614 1.020397316
0.52539064 2.30374293
0.98848354
2.536815367 19.9181482 0.773420309
6.161864212 67.1860069 0.426666328
10.44613865 138.465841 0.271963228
14.43254008 215.611946 0.227811288
17.61912568 283.381689 0.106631269
22.19451044
388.80304 -0.199042112
19.07199974 315.875585 0.013103659
15.35919135 234.799875 0.204763192
12.35362705 174.233502 0.254783885
2.404936039
18.513352 0.788565126
2.034110525
14.717917 0.831153126
0.675990603
3.253808 0.975418971
0.35781132 1.36106638 1.001621246
0.229207833 0.73941384 1.010380934
0.162883109 0.46306655 1.014299562

E: LIGERO ESTABLE
X
LNX
LN X2
Yj
Zj
CCO
CSO2
0.01 -4.605170186 21.2075924 0.631475899 0.358404055 7.5358E-138
7.4249E-140
0.02 -3.912023005
15.303924 1.242554915 0.748634042 1.67118E-27
1.64659E-29
0.03 -3.506557897 12.2959483 1.840909144 1.128993911 2.29165E-09
2.25793E-11
0.04 -3.218875825 10.3611616 2.429984929 1.497569549 0.002393573
2.35835E-05
0.05 -2.995732274 8.97441185 3.011681642 1.85493742 1.158273355
0.01141231
0.06 -2.813410717 7.91527986 3.587219996 2.20203331 29.78803265
0.293497432
0.07 -2.659260037 7.07166394 4.157457031 2.539770832 197.1472346
1.942464874
0.08 -2.525728644 6.37930518 4.723030444 2.868964679 640.5990763
6.311735527
0.09 -2.407945609 5.79820205 5.284434727 3.190324581 1385.137732
13.64757358
0.1 -2.302585093 5.30189811 5.842065386 3.504466413 2334.800912
23.00447567
0.15 -1.897119985 3.59906424 8.583324959 4.983531576 6446.814129
63.51958233
0.2 -1.609437912 2.59029039 11.26297037 6.340672368
7436.39903
73.2698277
0.25 -1.386294361 1.92181206 13.89511031 7.603966876 6940.291943
68.38175209
0.3 -1.203972804 1.44955051 16.48844696 8.791550622 6089.750502
60.00148301

0.9 -0.105360516
1
0
2 0.693147181
3 1.098612289
4 1.386294361
5 1.609437912

X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

F: ESTABLE
X
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9

0.01110084
0
0.48045301
1.20694896
1.92181206
2.59029039

45.82301882
50.50134654
95.39315269
137.9920475
179.0855821
219.0552315

19.78489025
21.26367037
33.32486479
42.48217116
50.01719501
56.48013876

1515.060017
1297.920144
463.6068865
255.1404677
168.0794858
122.1349845

14.92768018
12.78823056
4.567855566
2.513864309
1.656064302
1.203379382

Ci/Cs
ORAQI
ICA
2.1828E-140 2.569E-191
1.0209
4.8408E-30 3.8345E-40
1.0209
6.63806E-12 2.7013E-15
1.0209
6.9333E-06 4.7584E-07 1.020899993
0.003355093 0.00226772 1.020867572
0.086285011 0.19391199 1.018130817
0.571063268
2.5824422 0.984632824
1.855580692 12.9774872 0.851516278
4.012236242 37.3261091 0.611441565
6.763062345 76.3255015 0.388792624
18.67405724 306.881155
0.04058607
21.54052194
373.19365 -0.162082569
20.10348157 339.511797 -0.061741374
17.63977481 283.836786 0.105450442
4.388573474 42.2042554 0.573898611
3.759598862 34.1442116 0.637686364
1.3428992 8.33283341
0.90851196
0.739048405 3.67667356 0.969660505
0.486864655 2.07549896 0.991648458
0.353780277
1.3401033 1.001915389

LNX
LN X2
Yj
Zj
CCO
CSO2
-4.605170186 21.2075924 0.847253117 0.212876371
0
0
-3.912023005
15.303924 1.255529702 0.461504351 4.00786E-81
3.94889E-83
-3.506557897 12.2959483 1.657353369 0.708442903 1.87133E-31
1.8438E-33
-3.218875825 10.3611616 2.054016853 0.949924457 2.52679E-15
2.48961E-17
-2.995732274 8.97441185
2.44635867 1.185284814 3.63702E-08
3.58351E-10
-2.813410717 7.91527986 2.834971013 1.41460748 0.000219485
2.16255E-06
-2.659260037 7.07166394 3.220296369 1.638189812 0.037369348
0.000368195
-2.525728644 6.37930518 3.602678953 1.856381639 0.986314008
0.009718018
-2.407945609 5.79820205
3.98239477 2.069530131 8.946552574
0.088149165
-2.302585093 5.30189811 5.847771756 2.277960778 31.40985664
0.309477043
-1.897119985 3.59906424 7.669435543 3.258871511 1112.036904
10.95674829
-1.609437912 2.59029039 9.457333409 4.156566085 3313.611665
32.64856482
-1.386294361 1.92181206 11.21761953 4.989114955 4946.286122
48.73508407
-1.203972804 1.44955051 31.06838693 5.768640996 2376.948154
23.41974671
-0.105360516 0.01110084 34.22649323 12.82301896 2693.248114
26.53620717

1
2
3
4
5

0
0.693147181
1.098612289
1.386294361
1.609437912

Ci/Cs
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.15
0.2
0.25
0.3
0.9
1
2
3
4
5

0
1.16093E-83
5.42056E-34
7.31918E-18
1.05351E-10
6.35767E-07
0.000108245
0.00285699
0.025914883
0.09098284
3.221163259
9.598318281
14.32757767
6.885147455
7.801352488
3.995798597
2.0519019
1.306784131
0.935092114
3.636045687

0
0.48045301
1.20694896
1.92181206
2.59029039

ORAQI
0
1.331E-113
1.4826E-45
1.8607E-23
1.1923E-13
1.8026E-08
2.0536E-05
0.00181957
0.03731949
0.20852
27.6280778
123.304967
213.466593
78.2193797
92.8209449
37.1167669
14.8945626
8.02735552
5.07508992
32.6163535

64.45809066
93.05468206
120.5788829
147.3031804
34.22649323

ICA
1.0209
1.0209
1.0209
1.0209
1.0209
1.0209
1.020899706
1.020873981
1.020366471
1.017922509
0.695997707
0.284977128
0.229885929
0.381849763
0.3374865
0.613124829
0.829116021
0.912398724
0.950862852
0.650798872

13.74946618
21.11613302
26.49494241
30.78987086
34.38290057

1379.462991
708.374725
451.1389405
322.8203157
1255.276923

13.59166113
6.97951977
4.44501059
3.180704641
12.3680727

JORGE JULINHO MARTINEZ RUIZ

CONTAMINACION ATMOSFERICA- TA
VICTOR TERRY CALDERON

BHP=
psi=

500
120

Qt=

15912500 BTU

PC

122.4038462 gal/hor

BTU
EFICIENCIA
1gal

33500
0.95
130000 BTU

VALOR MAXIMO DE ESE CALDERO , SIEMPRE SE TRABAJA CON E

TRABAJAS CON ESTE VALOR PARA A BASE DE TU CALDERO

Valvula de
Seguridad

GASES EMITIDOS:
CO = 6855,79 mg/m3
C = 1028,37mg/m3
S02= 918,19 mg/m3
NOx= 33,48 mg/m3
MP2,5= 23,660 mg/m3
MP10= 32,489 mg/m3
NH3 =4,237mg/m3
Volumen de gas:
24115,20 m3/h

Cp 1100=

QX
-26910.74031
-336647.0523
-316078.91
-82077.91222
-1586958.661

31.593

-2348673.276
KJ
-2226765.948 BTU
-17.12896883 Gal/h

El negativo indica que el gas de combustion esta cediendo calor al aire

17.12896883 Gal/h
1100 C

60 C
TAgua Que ingresa

15 C

15C
25037,9 Kg
de agua

En el caso del material

particulado en MP 2,5 se
forman 23,66mg/m3 que
serian los que quedan en el

forman 23,66mg/m3 que

serian los que quedan en el
venturi.
24,8 Kg de Carbono que no
vombustiona se convierte en
lodo.

ICA

Cl2
50
g/m3

Comp. Fluor
20

g/m3

2.07602E+12

%
50
%

2.07602E+14

Cl2
50
g/m3

ICA

Comp. Fluor
20

g/m3

0.460531767

Cl2
50
g/m3

Comp. Fluor
20

g/m3

%
50
%

46.0531767

%
50
%

ICA

0.747377195

74.73771945

Muy inestable
Medio
inestable
Ligero inestable
Neutro
Ligero estable
Estable

CNOX
CC
CMP2.5
0.001817016
357.0609683
0.000593761
0.000900557
176.9679504
0.000294282
0.000621918
122.2127018
0.000203229
0.000486898
95.68011006
0.000159108
0.000400536
78.70909006
0.000130886
0.000336889
66.2018885
0.000110088
0.000286744
56.34783062
9.37015E-05
0.000245974
48.33621897
8.03789E-05

0.000212295
0.000184211
9.71851E-05
5.65726E-05
3.55351E-05
2.36631E-05
1.32565E-06
9.70274E-07
1.07199E-07
2.6205E-08
9.14045E-09
3.91589E-09

41.71791003
36.19923355
19.09779351
11.11706281
6.982981527
4.650018243
0.260503488
0.190668054
0.021065685
0.005149534
0.001796184
0.00076951

6.93733E-05
6.01962E-05
3.1758E-05
1.84867E-05
1.16121E-05
7.73258E-06
4.33195E-07
3.17064E-07
3.50304E-08
8.56323E-09
2.9869E-09
1.27963E-09

CNOX
CC
CMP2.5
1.18874E-17
2.33598E-12
3.88453E-18
6.88551E-07
0.135306831
2.25004E-07
5.73481E-05
11.26945547
1.87401E-05
0.000216601
42.56424864
7.07806E-05
0.000342526
67.30951891
0.00011193
0.00039267
77.16339714
0.000128316
0.000392303
77.0911963
0.000128196
0.000367782
72.27274079
0.000120183
0.000334538
65.7398945
0.00010932
0.00030011
58.97446417
9.80694E-05

0.000171331
0.000105916
7.108E-05
5.07716E-05
6.12718E-06
4.98534E-06
1.27686E-06
5.73902E-07
3.25085E-07
2.0908E-07

33.66819763
20.81355722
13.96789986
9.977101078
1.204049341
0.979667444
0.250915098
0.112777285
0.063882307
0.041086124

5.59873E-05
3.46111E-05
2.32274E-05
1.65911E-05
2.00223E-06
1.6291E-06
4.1725E-07
1.87539E-07
1.06231E-07
6.83227E-08

CNOX
CC
CMP2.5
8.59514E-28
1.68903E-22
2.80871E-28
1.71967E-09
0.000337931
5.61951E-10
4.5985E-06
0.903649888
1.50269E-06
6.36242E-05
12.50276118
2.0791E-05
0.000190446
37.42435566
6.22335E-05
0.000314896
61.88014726
0.000102901
0.00039698
78.01026509
0.000129724
0.000436135
85.70465513
0.00014252
0.000444649
87.37782591
0.000145302
0.000434497
85.38286751
0.000141984
0.000311448
61.20241559
0.000101774
0.000212835
41.82408253
6.95499E-05

0.000151368
0.000112443
1.6134E-05
1.33245E-05
3.77473E-06
1.80698E-06
1.07286E-06
7.16674E-07

29.74515634
22.09605102
3.170493345
2.618391092
0.741770309
0.355089585
0.210827451
0.140833278

4.94637E-05
3.67439E-05
5.27226E-06
4.35416E-06
1.2335E-06
5.90484E-07
3.50588E-07
2.34194E-07

CNOX
CC
CMP2.5
2.3357E-69
4.58988E-62
7.63257E-70
7.30779E-19
1.43605E-11
2.38803E-19
4.99334E-10
0.009812383
1.63171E-10
4.79735E-07
9.427247866
1.56767E-07
1.01582E-05
199.6185492
3.31948E-06
4.90483E-05
963.8454978
1.60279E-05
0.000119137
2341.157798
3.89314E-05
0.000201972
3968.938315
6.6E-05
0.000279047
5483.544035
9.11866E-05
0.000340659
6694.26525
0.00011132
0.000429122
8432.651127
0.000140228
0.000368749
7246.274726
0.000120499
0.000296964
5835.618793
9.70413E-05

0.000238852
4.64985E-05
3.93287E-05
1.307E-05
6.91814E-06
4.43164E-06
3.14928E-06

4693.675372
913.738857
772.846261
256.837966
135.9479426
87.08593486
61.88631347

7.80517E-05
1.51947E-05
1.28518E-05
4.27099E-06
2.2607E-06
1.44816E-06
1.02912E-06

CNOX
CC
CMP2.5
4.2318E-145
8.3159E-140
1.3829E-145
9.3847E-35
1.84418E-29
3.06672E-35
1.2869E-16
2.52888E-11
4.20531E-17
1.34414E-10
2.64136E-05
4.39235E-11
6.50441E-08
0.012781787
2.1255E-08
1.67278E-06
0.328717124
5.46628E-07
1.1071E-05
2.175560656
3.61777E-06
3.59735E-05
7.06914378
1.17554E-05
7.77839E-05
15.28528239
2.54181E-05
0.000131113
25.76501271
4.2845E-05
0.000362028
71.14193211
0.000118303
0.000417599
82.06220691
0.000136462
0.00038974
76.58756223
0.000127358
0.000341977
67.20166088
0.000111751

8.50799E-05
7.28861E-05
2.60344E-05
1.43277E-05
9.43869E-06
6.85862E-06

CNOX
0
2.25066E-88
1.05087E-38
1.41895E-22
2.04241E-15
1.23254E-11
2.09852E-09
5.53875E-08
5.02404E-07
1.76386E-06
6.24477E-05
0.00018608
0.000277764
0.00013348
0.000151242

16.71900177
14.3228182
5.115998227
2.815528023
1.854792015
1.347784906

CC

2.78022E-05
2.38176E-05
8.50746E-06
4.68198E-06
3.08436E-06
2.24125E-06

CMP2.5
0
4.42275E-83
2.06505E-33
2.78836E-17
4.01353E-10
2.42206E-06
0.000412379
0.01088418
0.098727065
0.346614288
12.27155807
36.56639255
54.58329408
26.23011628
29.72055199

0
7.35466E-89
3.434E-39
4.63681E-23
6.67415E-16
4.02768E-12
6.8575E-10
1.80994E-08
1.64175E-07
5.76389E-07
2.04065E-05
6.08067E-05
9.07673E-05
4.36184E-05
4.94227E-05

7.74653E-05
3.97796E-05
2.53342E-05
1.81283E-05
7.04915E-05

15.22266045
7.817062132
4.978411854
3.562389193
9.456796812

2.5314E-05
1.29991E-05
8.27867E-06
5.92394E-06
2.30351E-05

E CALDERO , SIEMPRE SE TRABAJA CON EL VALOR MAXIMO

ALOR PARA A BASE DE TU CALDERO

PROBLEMA

400 galones de petrleo bunker nro 5 por hora el petrleo tiene la siguiente composicin elemental
C= 80% H= 12% S=3% O=2% Cenizas = 1% N= 2 % la combustin indsutrial del petrleo es incompleta
esto quiere decir que una fraccin de carbono forma monxido y otra fraccin de carbono no combustiona
saliendo como hidrocarburo aliftico de cadena corta. 10% de carbono formara monxido y el 1% no combustiona.

PRACTICA N COMBUSTION INCOMPLETA

NOMBRE DE LA PRACTICA
Ing Vctor Terry C
Ing Elia Rojas R

Base de Clc:
Carbono %
Hidrogeno %
Oxigeno %
Azufre %
Nitrogeno %
Cenizas %
%C(CO2)
%C(CO)
%C ( C)
densidad (d)
1 galn (g)

400

fraccion

80
12
2
3
2
1
89.00
10.00
1.00
0.9
3.785

0.8
0.12
0.02
0.03
0.02
0.01 fraccion
forma
forma
no combustiona
kg/L
L/gal

El exceso de oxigeno es
La temperatura del aire es
Temperatura de los gases
Temperatura de la flama

=
Ta =
Tc =
Tf=

0.89
0.1
0.01

0.23
20
350
1500

Calcular el volumen de aire requerido

Composicin de los gases de combustin
Peso molecular aparente de los gases
Volumen de los gases de combustion
Velocidad de salida de los gases

Base de
datos
C
C
C

Clculo

1 paso : determinar el peso del petrleo (W)

W=

1362.6 kg/h

2 paso. Deteminar mol-kg de cada componente

hC =

90.84 mol-kg

hH =

81.76 mol-kg

h CCO =
2

h CCO =

80.85 mol-kg
mol-kg

hO =

0.852 mol-kg

hN =

0.9733 mol-kg

hS =

1.277 mol-kg

h CCO =

9.084

h CC =

0.9084

3 paso :Aplicar las ecuaciones estequiometricas, clculo de oxigeno

C

O2

CO 2

80.85

80.85

0.5O 2

9.084
H2

CO
4.542

9.084

0,5 O 2

H2O

81.76
S

80.85

40.88

81.76

O2

1.277

SO 2

O 2 (teorico)=

1.277
127.55
127.545 mol-kg

O 2 (correg)=

126.693 mol-kg

O 2 (exceso) =

29.139 mol-kg

O 2 (total) =

155.833 mol-kg

1.277

4 paso : Calculo del aire requerido

h aire =

742.061 mol-kg

hN =

586.229 mol-kg

h N Total =

587.202 mol-kg

V aire =

3
17718.143 m / h

5 paso : Composicin de los gases de combustin

gases
CO2

mol-kg
80.85

PM
44.00

kg
3557.29

%
15.64

CO
C
H2O

9.08
0.91
81.76

28.00
12.00
18.00

254.35
10.90
1471.61

1.12
0.05
6.47

SO2

1.28

64.00

81.76

0.36

O2(exc)

29.14

32.00

932.46

4.10

mol-kg

N2 (TOTAL)

587.20

28.00

16441.65

790.21

22750.03

PM=
V gas =

72.27
100.00

28.79
3
40394.16 m /h

v gas =

11.22 m/ seg

6 paso: resultado en diagrama de flujo

COMBUSTION INCOMPLETA
Petrleo

Carbono (%)
Hidrogeno(%)
Oxigeno (%)
Nitrgeno (%)
Azufre (%)
Cenizas (%)

400 gal/h

Carbono
Hidrogeno
Oxigeno
Nitrogeno
Azufre
Cenizas

Entrada
mol-kg
90.84

80
12
2
3
2
1
0.23
Salida
CO2
CO
C
H2O
SO2
O2(exc)
N2 (TOTAL)

12
2
2
3
1

kg
3557.29
254.35
10.90
1471.61
81.76
932.46
16441.65
22750.03

m3
Aire
Taire C

17718.143
20

7 paso calcular el valor de Nox

NOx T
=

10 6 5340

5, 35

100a 38

lbNOx
10 6 BTU

Temperatura de flama

1500 F

Exceso de oxigeno

0.23
400

Galones de petroleo

NOx Tf
=

10 6 5340

5, 35

a .100 38

PM
Vgas m3/h

28.79
40394.16

vgas m/s

11.22

Tgas C

350

NOx Tf
=

10 6 5340
C=

5, 35

a .100 38

0.06840256 Lb Nox/10^6BTU
1 galon <>130000BTU
x
<> 10^6BTU
x=
7.692307692 galones
1 lb = 0,454 kg=454 g=
454000 mg
Contenido de Nox =

Concentracion de NO x
CONTROL DE EMISIONES
CO
6296.75 mg/m3
C
269.86 mg/m3

SO2
NO x

Mp2.5
MP10
NH3

2023.96
19.99
22.6008436
31.0339942
4.04791229

mg/m3
mg/m3
mg/m3
mg/m3
mg/m3

1.77846652 lb
807423.8 mg
19.9886291 mg/m3

ono no combustiona
xido y el 1% no combustiona.