Chemistry, Solutions MCQs Questions: Paper - 1

Sr. No.
Questions
Answers
1.
p
A
and p
B
are the vapour pressure of pure liquid components, A and B, respectively of an
ideal binary solution. If x
A
represents the mole fraction of component A, the total pressure
of the solution will be [CBSE AIPMT 2012]
(A) pB
+
x
A
(p
B
p
A
!
(B) pB
+
x
A
(p
A
p
B
!
(C) pA
+
x
A
(p
B
p
A
!
(D) pA
+
x
A
(p
A
p
B
!
Answer: (B)
".
#issolvin$ 1"% $ of urea (mol. wt. &%! in 1%%% $ of water $ave a solution of density 1.1'
$(m). *he molarity of the solution is [IIT JEE 2011]
(A) 1.+, -
(B) ".%% -
(C) ".%' -
(D) "."" -
Answer: (C)
..
A solution of two liquids boils at a temperature more than the boilin$ point of
either of them. /ence, the binary solution shows 000000. [Karnataka CET 2011]
(A) ne$ative deviation from 1aoult2s law
(B) positive deviation from 1aoult2s law
(C) no deviation from 1aoult2s law
(D) positive or ne$ative deviation from 1aoult2s law dependin$ upon the composition
Answer: (A)
3.
A '." molal aqueous solution of methyl alcohol, 4/
.
5/ is supplied. 6hat is the mole
fraction of methyl alcohol in the solution7 [AIEEE 20118
(A) %.%'%
(B) %.1%%
(C) %.19%
(D) %.%,&
Answer: (D)
'.
*he molality of a urea solution in which %.%1%% $ of urea, :(;/
"
!
"
458 is added to %..%%%
dm
.
of water at <*= is [AIEEE 2011]
(A) .... > 1%
"
m
(B) %.''' m
(C) '.'' > 1%
3
m
(D) .... m
Answer: (C)
&.
1.%% $ of non?electrolyte solute (molar mass "'% $ mol
1
! was dissolved in '1." $ of
ben@ene. If the free@in$ point depression constant, A
f
of ben@ene is '.1" A B$ mol
1
, the
free@in$ point of ben@ene will be lowered by [CBSE AIPMT 2006]
(A) %.. A
(B) %.' A
(C) %." A
(D) %.3 A
Answer: (D)
+.
A solution of acetone in ethanol [CBSE AIPMT 2006]
(A) shows a positive deviation from 1aoult2s law
(B) behaves liBe a near ideal solution
(C) obeys 1aoult2s law
(D) shows ne$ative deviation from 1aoult2s law
Answer: (A)

,.
1, $ of $lucose (4
&
/
1"
5
&
! is added to 1+,." $ of water. *he vapour pressure of water for
this aqueous solution at 1%%4 is [AIEEE 2006]
(A) +.&% torr
(B) +&.%% torr
(C) +'".3% torr
(D) +'9.%% torr
Answer: (C)
9.
#ensity of a ".%' - solution of acetic acid in water is 1."% $(m). *he molarity of the
solution is [AIEEE 2006]
(A) ..", mol B$
1
(B) ".", mol B$
1
(C) %.33 mol B$
1
(D) ".13 mol B$
1
Answer: (B)

1%.
A solution has 1 C 3 mole ratio of pentane to hexane. *he vapour pressure of pure
hydrocarbons at "%4 are 3%% mm /$ for pentane and 1"% mm /$ for hexane. *he mole
fraction of pentane in the vapour phase would be [CBSE AIPMT 2005]
(A) %."%%
(B) %.'39
(C) %.+,&
(D) %.3+,
Answer: (D)
11.
*he vapour pressure of two liquids = and D are ,% and &% torr respectively. *he total
vapour pressure of solution obtained by mixin$ . mol of = and " mol of D would
be [CBSE AIPMT 2005]
(A) +" torr
(B) 13% torr
(C) &, torr
(D) "% torr
Answer: (A)
1".
A solution of urea (mol. mass E '& $ mol
1
! boils at 1%%.1,4 at the atmospheric
pressure. If A
f
and A
b
for water are 1.,& and %.'1" A B$ mol
1
respectively, then the above
solution will free@e at[CBSE AIPMT 2005]
(A) %.&'34
(B) %.&'34
(C) &.'34
(D) &.'34
Answer: (B)
1..
*wo solutions of a substance (non?electrolyte! are mixed in the followin$ mannerC
3,% m) of 1.' - Frst solution + '"% m) of 1." - second solution.
6hat is the molarity of the Fnal mixture7 [AIEEE 2005]
(A) 1."% -
(B) 1.'% -
(C) 1..33 -
(D) ".+% -
Answer: (C)
13.
Gquimolar solution in the same solvent have [AIEEE 2005]
(A) same boilin$ point but diHerent free@in$ point
(B) same free@in$ point but diHerent boilin$ point
(C) same boilin$ point and same free@in$ point
(D) diHerent boilin$ point and diHerent free@in$ point
Answer: (C)
1'.
-olarity of %." ; /
"
<5
3
is [Karnataka CET 2005]
(A) %."
(B) %.3
(C) %.&
(D) %.1
Answer: (D)
Chemistry, Solutions MCQs Questions: Paper - 2
Sr. No. Questions Answers
1. ',.' $m of ;a4l and 1,% $m of $lucose were separately
dissolved in 1%%% ml of water. Identify the correct statement
re$ardin$ the elevation of boilin$ point (b.p.! of the resultin$
solutions [!est Ben"a# JEE]
(A) ;a4l solution will show hi$her elevation of b.p.
(B) Ilucose solution will show hi$her elevation of b.p.
(C) Both the solutions will show equal elevation of b.p.
(D) *he b.p. elevation will be shown by neither of the solutions
Answer: (A)
". *he free@in$ point (in J4! of a solution containin$ %.1 $ of
A
.
:Ke(4;!
&
8 (-ol. 6t. ."9! in 1%% $ water
(A
f
E 1.,& A B$ mol
1
! is [IIT JEE 2011]
(A) ".. > 1%
"
(B) '.+ > 1%
"
(C) '.+ > 1%
.
(D) 1." > 1%
"
Answer: (A)
.. Gthylene $lycol is used as an antifree@e in a cold climate. -ass
of ethylene $lycol which should be added to 3 B$ of water to
prevent it from free@in$ at &J4 will beC (A
f
for water E 1.,& A B$
mol
1
and molar mass of ethylene $lycol E &" $ mol
1
! [AIEEE
2011]
(A) .%3.&% $
(B) ,%3.." $
(C) "%3..% $
(D) 3%%.%% $
Answer: (B)
3. A 'L solution of cane su$ar (molar mass .3" is isotonic with 1L
of a solution of an unBnown solute. *he molar mass of unBnown
solute in $(mol $s [AIEEE 2011]
(A) .3."
(B) 1.&."
(C) 1+1."
(D) &,.3
Answer: (D)
'. A solution of sucrose (molar mass E .3" $ mol
1
! has been
prepared by dissolvin$ &,.' $ of sucrose in 1%% $ of water. *he
free@in$ point of the solution obtained will be (A
f
for water E
1.,& A B$ mol
1
! [CBSE AIPMT 2010]
(A) + %..+"4
(B) %.'+%4
(C) %..+"4
(D) %.'"%4
Answer: (C)
&. An aqueous solution is 1.%% molal in AI. 6hich chan$e will cause
the vapour pressure of the solution to increase7 [CBSE AIPMT
Answer: (B)
2010]
(A) addition of 1.%% molal AI
(B) addition of water
(C) addition of ;a4l
(D) addition of ;a
"
<5
3
+. "'.. $ of sodium carbonate, ;a
"
45
.
is dissolved in enou$h
water to maBe "'% ml of solution. If sodium carbonate
dissociates completely, molar concentration of sodium Ion,
;a
+
and carbonate ions, 45
.
"
are respectively (-olar mass of
;a
s
45
.
E 1%& $ mol
1
! [CBSE AIPMT 2010]
(A) 1.9% - and 1.91% -
(B) %.3++ - and %.%3++ -
(C) %.9'' - and 1.91% -
(D) 1.91% - and %.9'' -
Answer: (D)
,. 5n mixin$, heptanes and octane form an ideal solution. At .+.
A, the vapour pressures of the two liquid components (heptanes
and octane! are 1%' B=a and 3' B=a respectively. Mapour
pressure of the solution obtained by mixin$ "'.% $ of heptanes
and .' $ of octane will be (molar mass of heptanes E 1%% $
mol
1
and of octane E 113 $ mol
1
! [AIEEE 2010]
(A) 9&." B=a
(B) 133.' B=a
(C) +".% B=a
(D) .&.1 B=a
Answer: (C)
9. If sodium sulphate is considered to be completely dissociated
into cations and anions in aqueous solution, the chan$e in
free@in$ point of water
(N*
f
!, when %.%1 mol of sodium sulphate is dissolved in 1 B$ of
water is (A
f
E 1.,& A B$ mol
1
! [AIEEE 2010]
(A) %.%+33 A
(B) %.%1,& A
(C) %.%.+" A
(D) %.%'', A
Answer: (D)
1%. *he molarity of a ;a5/ solution by dissolvin$ 3 $ of it in "'% ml
water is [!est Ben"a# JEE 2010]
(A) %.3 -
(B) %., -
(C) %." -
(D) %.1 -
Answer: (A)
11. 6hat is the osmotic pressure of a %.%%"% mol dm
.
sucrose
(4
1"
/
""
5
11
! solution at "%47
(-olar $as constant, 1 E ,..13 OA
1
mol
1
, 1 dm
.
E %.%%1 m
.
7
[De#%$ PMT 2010]
(A) 3,+% =a
(B) 3.,+ =a
(C) %.%%3,+ =a
(D) %... =a
Answer: (A)
1". *he /enry2s law constant for the solubility of ;
"
$as in water at
"9, A is 1.% 1%
'
atm. *he mole fraction of ;
"
in air is %.,. *he
number of moles of ;
"
from air dissolved in 1% moles of water at
"9, A and ' atm pressure is [IIT JEE 200&]
(A) 3.% 1%
3
(B) 3.% 1%
'
(C) '.% 1%
3
(D) 3.% 1%
&
Answer: (A)
1.. %.' molal aqueous solution of a weaB acid (/P! is "%L ioni@ed. If
A
f
for water is 1.,& A B$ mol
1
, the lowerin$ in free@in$ point of
Answer: (D)
the solution is [CBSE AIPMT 200']
(A) %.'& A
(B) 1.1" A
(C) %.'& A
(D) 1.1" A
13. A solution containin$ 1% $ per dm
.
of urea (molecular mass E
&%! is isotonic with a 'L solution of a non?volatile solute. *he
molecular mass of this non?volatile solute is [CBSE AIPMT
2006]
(A) .%% $ mol
1
(B) .'% $ mol
1
(C) "%% $ mol
1
(D) "'% $ mol
1
Answer: (A)
1'. Ben@ene and toluene form nearly ideal solutions. At "%4, the
vapour pressure of ben@ene is +' torr and that of toluene is ""
torr. *he partial vapour pressure of ben@ene at "%4 for a
solution containin$ +, $ of ben@ene and 3& $ of toluene in torr
is [AIEEE 2005]
(A) "'
(B) '%
(C) '..'
(D) .+.'
Answer: (B)