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DEFINITION OF CHEMISTRY-
- Greece
- Two major ideas
1. Aristotle- fire, earth, water, air
2. Leucipus and Democritus
Matter is made up of “atoms”
- nature of the substances
- Plato = shape
- Joseph Prestly
o Dephlogisticated air or oxygen
- Antoine Lavosier
o Father of Modern Chemistry
- Law of Conservation of Mass
- Quantitative data
o Mb = Ma (mass before = mass after)
2000 – present
SCIENTIFIC TRAITS
- curiosity
- resourcefulness
- creativeness
- innovativeness
- inventiveness
- open- mindedness
- critical thinking
- intellectual honesty
- skepticism
- perseverance
- dedication
- rationalize
BRANCHES OF CHEMSITRY
1. Organic Chemistry
- concerned with elements containing carbon (all living organisms contain at least some amount of
carbon in their body)
- hydrocarbon (compounds whose main feature is a long chain of carbon atoms bonded to
hydrogen atoms)
- Pharmaceutical, petrochemical, and textile industries.
2. Inorganic Chemistry
- concerned with elements not containing carbon (minerals of the earth’s crust and non- living
matter)
- nuclear science and energy, geo chemistry, dietary minerals (Ca, Cl, Mg, P, K, Na)
3. Physical Chemistry
- behavior of chemical substances
- deals with the relations between physical properties of substances and their chemical formations
along with their changes
4. Biochemistry
- concerned with the chemistry of life processes and living organisms
- also called physiological chemistry or biological chemistry
- study the property of molecules, metabolism, vitamins, etc.
5. Analytical Chemistry
- deals with composition of substances
- quantitative and qualitative methods
SCIENTIFIC TOOLS
1. Bunsen Burner
- used for heating using high tempretures
2. Test tube
- used for containing substances only
3. Test tube holder
- used for holding test tubes
4. Test Tube Rack
- holds many test tubes
5. Rubber Stopper or Cork
- stops the release of gas
- used for shaking
- use cork for acidic substances
6. Graduated Cylinder
- used for measuring the exact volume of liquids
7. Beaker
- used to contain or hold liquids
8. Wire Gauze
- used to aid in heating
- used to spread heat evenly
9. Triple Beam Balance
- measures mass
10. Funnel
- only for liquids
- transferring of liquids
11. Stirring Rod
- used for mixing
12. Thermometer
- used for taking temperatures
13. Florence Flask
- used for distillation or heating
14. Erlenmeyer Flask
- used for mixing
15. Volumetric Flask
- used to measure exact volume
- used for mixing solutions
16. Pipettes
- used to measure a small amount of liquid accurately
17. Burettes
- for filtration
- for acids or bases
18. Dessicator
- used to absorb moisture
19. Mortar and Pestle
- use to pound substances
20. Evaporating dish
- used for evaporation
21. Watch Glass
- used to watch or observer substances
22. Iron Ring
23. Utility Clamp
- used to hold the burette and the Florence flask on the iron ring
24. Crucible and Cover
- used for heating solids at high temperatures
MEASUREMENT:
- process of finding how many measuring units there are in something.
- Quantitative information about the physical world
- SI system – use of prefixes and rootwords
o Giga (9 right)
o Mega (6 right)
o Kilo (3 right)
o Hector (2 right)
o Deca (1 right)
o Deci (1 left
o Centi (2 left
o Mili (3 left
o Micro (6 left)
o Nano (9 left)
SCIENTIFIC NOTATION
- also referred to as exponential notation
- notation based on powers of the base number
N x 10
Where N = number greater than 1 but less than 10
X= exponent is 10
RULES OF SCIENTIFIC FIGURES:
1. All non- zero digits are significant
2. Zeroes between non zero digits are significant
3. Zeros before the first non zero digit are non significant. These are called leading zeroes
4. Zeros after the last non zero digit nay or may not be significant. These are called trailing zeros
5. Exact numbers are considered to have an infinite number of significant figures.
SCIENTIFIC METHOD
- Observe
- State the problem
- Hypothesis
- Experiment
- Record Data
- Analyze
- Conclude/ Give reason of disapproval
MATTER
- has five states (from most dense to least dense
o BEC – super un-excited, low temp
o Solid – compact particles
o Liquid – no definite shape
o Gas – Free moving particles
o Plasma – ionized gas
- Changes
o Physical – varies on temperature, pressure, and is reversible
Solid to…
• Liquid – melting
• Gas - sublimation
Liquid to…
• Solid – freezing
• Gas – evaporation
Gas to…
• Liquid – condensation
• Solid – Deposition
• Plasma – Ionization
Plasma to..
• Gas – Deionization
- Properties
o Physical – visible
Intensive – not affected by quantity
Extensive – affected by quantity
o Chemical – observable only during a reaction
Corrosiveness
Electronegativity
Ionization potential
pH balance
Reactivity
Heat of combustion
Enthalpy of formationj
Toxicity
Chemical stability
Flammability
Oxidation
Coordination number
- Classification
o Pure Substance
Elements – substances with only one type of atom
Compounds – mixture of elements
o Mixtures
Homogenous – cannot define the components used
• Solutions – the pattern between components Is uniform
Heterogeneous – easily separated
• Colloid – large components
• Suspension – smaller components
SEPARATION TECHNIQUES
- Decantation – separation by pouring / colloids
- Filtration – separation with the use of a filter / suspension
- Centrifugation – separation with the use of a centrifuge and the spinning force / suspension
- Evaporation – separation by evaporating / solution
- Crystallization – separation by heating first followed by cooling / solutions
- Distillation - separation by using a combination of evaporation and condensation
- Fractional Distillation – similar to distillation but with the exception of antibumping granules,
fractionating column and glass beads/ liquid solutions
- Chromatography - separation using the different physical properties of the components such as
absorbtion, solubility, etc. / solution
ATOM
- Contributions (bold letters are the models)
o John Dalton
Came up with the Billiard ball-like atomic model
No sub atomic particles
Indivisible and indestructible
o Micheal Faraday
Studied the electrical decomposition of numerous compounds
Proposed the quantative law
Suggested the suggested the existence of fundamental unit of electricity to
account for his results involving the electrolysis of solutions of aqueous acids
and salts.
o Joseph John Thomsom
an English physicist who established the particle nature of cathode rays.
determined the charge-to-mass-ratio of the particles in the cathode ray.
cathode rays are negatively charged particles called electrons.
Proposed the Plum Pudding Model, where negatively charged particles were
embedded in a positive mass. The neutralization of the two formed neutral
atoms
o Robert Millikan
Determined the charge of electrons with the oil drop experiment
o Eugen Goldstein
Studied electrical phenomena of gases
Canal rays are positively charged massive rays left after the electrons are
discharged from an atom, a.k.a. ions, or charged particles
o Henri Becquerel
Accidentally discovered radioactivity from uranium, coined Becquerel rays, now
known as X-rays
Overthrew the idea of the atoms indestructibility
o Marie and Pierre Curie
Discovered polonium in a radium
o Ernest Rutherforf
Gold foil experiment
Discovered positive alpha, negative beta, and neutral gamma rays in the
Becquerel rays
Made the Nuclear Model, a positive mass surrounded by a negative coat
o James Chadwick
Discovered neutrons, and proposed that an atom’s mass is concentrated in the
nucleus
o Niel Bohr
Proposed the orbital model, or the Bohr model, which had electrons revolving
around defined paths around the nucleus
o Erwin Schrodinger
Quantum Mechanical model, similar to the orbit model but with the
electron’s position not pinpointed, but are found in electron clouds
- Sub-atomic particles
o Proton
Common to all atoms of an element. Positive charged
o Neutron
Found with the protons in the nucleus. No charge
o Electrons
Orbits around the nucleus. Negative Charged
- Atom values
o Atomic Mass (A) – the superscripted number before a element. A = P + N
o Atomic Number (Z) – the subscripted number. Z = P = N
o Charge – the exponent. If positive, the proton number is added with the exponent.
Electron if negative
- Quantum numbers
o n – energy level, principal quantum number
o L – azimuthal quantum number. Dependent on n. If n 5, the L is 0,1,2,3, and 4
o mL - magnetic quantum number . if l is 3, then ml is -3, -2, -1, 0, 1, 2, and 3
o ms - spin projection quantum. only has 2 values: 1/2, and -1/2. The number of 1/2 is
determined by the orbitals, and the number of -1/2’s is the difference between the # of
orbitals and the maximum number of electrons
Main Energy No. of Sublevel Identity of Sublevels No. of Orbitals Max. No. of
Level (L) (n2) Electrons
(n) (2n2)
1 1 1s (l=0) 1 2
2 2 2s (L=0) 1 2
2p(L= -1,0,1) 3 6
3 3 3s (l=0) 1 2
3p(L= -1,0,1) 3 6
3d(L= -2, -1,0,1, 2) 5 10
4 4 4s (l=0) 1 2
4p(L= -1,0,1) 3 6
4d(L= -2, -1,0,1, 2) 5 10
4f(L=-3, -2, -1,0,1, 7 14
2,3)