PETROLEUM REFINERY ENGINEERING (CHL 794)

DEPARTMENT OF CHEMICAL ENGINEERING, IITD

TUTORIAL SHEET -1
1.1. Create one material stream that contains only water with following
conditions:
Fluid Package: Peng-Robinson
Flowrate: 100 kgmole/h
Pressure: 1 atm
a!or/Phase Fraction: 1.00
What is the temperature of this stream? ________________
1.". Re!eat the abo#e !rocedure by re!lacing !ressure with tem!erature of
1$0
o
C.
What is the pressure of this stream? %%%%%%%%%%%%%%%%%%%
1.&. 'ith the same condition in (")* reduce the tem!erature to +0oC.
What is the new pressure of this stream? %%%%%%%%%%%%%%%%
1.,. Create one new materials stream that contains only water with
following conditions:
Fluid Package: Peng-Robinson
Flowrate: 100 kgmole/h
Pressure: " atm
a!or/Phase Fraction: 1.00
What is the temperature of this stream? %%%%%%%%%%%%%%%%
1.$. 'ith the same condition in (,)* increase the !ressure to $ atm.
What is the new temperature of this stream? %%%%%%%%%%%%%%%%
1.-. 'ith the same condition in (,)* decrease the !ressure to 0.$ atm.
What is the new temperature of this stream? %%%%%%%%%%%%%%%%
1.7. What can you conclude from these problems (1-6)? %%%%%%%%%%%%%

./01P2. 34 C02C5203. 36. PR4P.R37.8 4F 0 83R.01
4!en a new case by using one of the following:
1. 9o to the File menu* select New* followed by C!e* or
". Press C"#l N* or
&. Click the New icon on the toolbar.
1$ A%%i&' C()*(&e&"! "( "+e Si),l"i(&
3he first ste! in establishing the simulation basis is to set the chemical
com!onents which will be !resent in your simulation.
1. 3o add com!onents to the simulation* click on the A%% button in the
8imulation :asis 1anager.
". Clicking on A%% will bring u! the C()*(&e&" Li!" -iew which is a list
of all the com!onents a#ailable in 6;8;8.
&. 8elect the desired com!onents for your simulation. ;ou can search
through the list of com!onents in one of three ways:
a. 8im <ame = b. Full <ame = c. Formula
.$ Sele/"i&' Fl,i% P/0'e
1. From the simulation basis manager* select the Fl,i% P0'! tab.
". Click the A%% button to create a new fluid !ackage as shown below:
&. From the list of fluid !ackages* select the desired thermodynamic
!ackage. 3he list of a#ailable !ackages can be narrowed by selecting a filter
to the left of the list (such as .48s* acti#ity models etc.).
,. 4nce the desired model has been located* select it by clicking on it once
(no need to double click). For e>am!le* select Pe&'-R(1i&!(& !ro!erty
!ackage for your simulation.
2$ E&"e# Si),l"i(& E&3i#(&)e&"
;ou ha#e now com!leted all necessary in!ut to begin your simulation.
Click on the E&"e# Si),l"i(& E&3i#(&)e&" button
S(l3e# H(l%i&' button (the #e% light button ) located in the toolbar .
7f this button is selected* then 6;8;8 will &(" sol#e the simulation
and it will &(" !ro#ide any results. 7n order to allow 6;8;8 to return
results* the S(l3e# A/"i3e button (the '#ee& light button ) must be
selected.
4$ A%%i&' M"e#il S"#e)!
1. Click on the blue arrow button on the 4b?ect Palette (!ress F,).
". 8electing the @FlowsheetA menu and selecting @0dd 8treamA
&. Pressing F11
,. 3o enter information about the material stream* double click on the
stream to show the 'indow. For material stream that will be used as an
in!ut* we need to s!ecify 4(,# #ariables. 'ithin 6;8;8 en#ironment* in!ut
material stream always ha#e four degree of freedoms. 1eaning* we need to
su!!ly four information in order to fulfill the reBuirement for 6;8;8 to
start its calculations.
you will see the warning yellow message bar at the bottom of the
window indicating what information is needed.
<e>t* the warning yellow message bar indicates that you need to
s!ecify the in!ut tem!erature for this stream.
<e>t* the warning yellow message bar indicates that you need to
s!ecify the in!ut tem!erature for this stream.
<e>t* the last #ariable that you need to s!ecify is flowrate.
4nce all of the stream information has been entered* 6;8;8 will calculate
the remaining !ro!erties and data* !ro#ided* it has enough information from
the rest of the flowsheet. 4nce a stream has enough information to be
com!letely characteriCed* a green message bar a!!ears at the bottom of the
window within the stream in!ut #iew* indicating that e#erything is @4DA.
4therwise* the in!ut window will ha#e a yellow message bar at the bottom
of the window indicating what information is missing.
What is the Vapor!hase "raction of this stream? __________________
Royal :lue E !ro!erly s!ecified and com!letely sol#ed.
2ight blue E incom!letely s!ecified* !ro!erties &(" sol#ed
De4i&i&' "+e Si),l"i(& 5!i!6
1. .nter the following #alues in the s!ecified fluid !ackage #iew:
". Click the E&"e# Si),l"i(& E&3i#(&)e&t button when you are ready to
start building the simulation.
I&!"lli&' S"#e)7
3here are se#eral ways to create streams. (For com!lete descri!tion* see
the !re#ious cha!ter.)
Press F11. 3he 8tream !ro!erty #iew a!!ears* or
Fouble-click the S"#e) icon in the O18e/" Ple""e.
De4i&i&' Ne/e!!#9 S"#e)
0dd a stream with the following #alues.
8ol#ing:
1. 9o to the File menu.
". 8elect S3e A!.
&. 9i#e the 6;8;8 file the name EOS SR: then !ress the 4D button.
P#e3iew "+e Re!,l" ,!i&' ;(#01((06
3o !re#iew the result for the simulation:
1. 9o to the T((l! menu and select ;(#01((0! or click C"#l<; as shown
in Figure below.
". <e>t* click -iew and the :ookwork can be seen as shown in ne>t Figure.
&. 8!ecific #olume in 6;8;8 is defined as 1olar olume. From abo#e
Figure* there is no 1olar olume shown in the 'orkbook. 7n order to
!re#iew the #alue of 1olar olume* we ha#e to add it to the 'orkbook.
,. 3o add the 1olar olume or other #ariables* go to the ;(#01((0 menu
and click Se",*. 3he setu! window for 'orkbook can be #iewed as shown
in below Figure.
$. 7n the -#i1le! tab* click the A%% button at the right side of the window.
-. 'indow for you to select #ariables will a!!ear as shown in below Figure.
+. 7n the -#i1le tab* scroll down until you find the 1olar olume and then
click O:. Close the 8etu! window by clicking the #e% = at the to! right
corner.
G. 3he 1olar olume #alue is !resented in the 'orkbook as shown in below
Figure.
What is the #olar Volume of n-butane?%%%%%%
A&l9>e "+e P#(*e#"9 ,!i&' C!e S",%9
7n this section* we will analyCe the s!ecific #olume of n-butane when the
tem!erature is changing. 3o do this analysis* do the following:
1. 9o to the T((l! menu and select D"1((0 or click C"#l<D as shown in
below Figure.
". <e>t* click I&!e#" button then -#i1le N3i'"(# #iew dis!lays as
shown in below Figure.
&. 7n the O18e/" column* select stream 1* and in the -#i1le column* select
1olar olume. 3hen* click O: button.
,. Re!eat ste! & to insert Te)*e#",#e. 3he new u!dated Fatabook is
shown in below Figure.
$.
8witch to the Case 8tudies tab. Com!lete the tab as shown in the following
figure.
-. Click the -iew button and com!lete the !age as shown in the below
Figure. (2ow :ound: ,$0 D= 6igh :ound: $$0 D= 8te! 8iCe: 10 D)
+. Click the S"#" button to start the analysis. 4nce the analysis finished*
click Re!,l"! to #iew the result.
What can you conclude from this $raph?
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
C+&'i&' "+e Fl,i% P/0'e
1. Press the E&"e# 5!i! E&3i#(&)e&" icon which is located on the menu
bar.
". 3his should take you to the Fluid Package window. Click on the P#(* P0'
tab.
&. 7n the list in the left of the window* scroll and select Pe&' R(1i&!(& .48.
,. Press the green arrow in the menu bar to return to the PFF.
$. 8ince the conditions are the same* use the sa#ing EOS SR: and sa#e it
with the new name EOS PR.
-. Pre#iew the result with 'orkbook and Case 8tudy.
%ompare the result usin$ two different fluid pac&a$es' (oa)e-*edlich-
+won$ and !en$-*obinson.
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
P#(1le)!6
1. Find the molar #olume of ammonia gas at $- atm and ,$0 D using 8oa#e-
Redlich-Dwong (8RD) eBuation of state.
". Find the molar #olume of methanol gas at 100 atm and &00
0
C using
Peng-Robinson (PR) eBuation of state. Com!are its molar #olume when you
are using 8oa#e-Redlich-Dwong (8RD) eBuation of state.
&. Consider the following mi>ture going into a 'ater-9as-8hift reactor to
make hydrogen for the hydrogen economy. C4* -&0 kmol/h= 6
"
4* 11&0
kmol/h= C4
"
* 1GH kmol/h= 6
"
* -& kmol/h. 3he gas is at 1 atm and $00 D.
Com!ute the s!ecific #olume of this mi>ture using 8oa#e-Redlich-Dwong
(8RD) eBuation of state.
,. Consider a mi>ture of "$ !ercent ammonia* and the rest nitrogen and
hydrogen in a 1:& ratio. 3he gas is at "+0 atm. and $$0 D. 5se Peng-
Robinson (PR) eBuation of state to com!ute the s!ecific #olume of this
mi>ture.
$. Consider the following mi>ture that is coming out of a methanol reactor:
C4* 100 kmol/h= 6
"
* "00 kmol/h= methanol* 100 kmol/h. 3he gas is at 100
atm and &00
o
C. Com!ute the s!ecific #olume using 8oa#e-Redlich-Dwong
(8RD) eBuation of state and com!are it with Peng-Robinson (PR) eBuation
of state.