recorded by a receiver antenna. This trace or waveform con-
tains a first arrival signal as well as other signals eventually produced from reflections or refractions of the radiated waves. The waves are affected in terms of traveltime and amplitude by variations in their propagation speed due to losses caused by traveling through different media. This effect is governed by the dielectric permittivity (), magnetic permeability () and electrical conductivity () of each medium. As the EM waves travel from transmitter to receiver, the time delay of the first arrival signal peak recorded at the receiver is used to determine the velocity of wave propagation. The difference in time delays with respect to a given medium can be inverted to build a to- mographic representation of the medium 9-11 . The review of prior works discussing traveltime tomogra- phy showed that all approaches were based on mapping elec- trical conductivity or permittivity. None considered mapping variations in magnetic permeability. In our approach, we ex- tended the prior works in a new way by employing variations in magnetic permeability to generate new fluid imaging capa- bilities using Magnetic Nano-Particles (MNPs). Magnetic NanoMappers (MNM) is a new approach ex- ploiting the use of MNPs as contrast agents for mapping the flood front inside hydrocarbon reservoirs. This approach em- ploys EM wave traveltime tomography coupled with MNPs to map the subsurface and so enable real-time monitoring of the injected water in reservoirs. It can also be used as a tool to locate bypassed oil, monitor the oil-water contact, and detect super-K zones and fracture corridors prior to early water breakthrough at producing wells. The MNM research pro- gram is a multidisciplinary solution that comprises the iterative parallel development of chemical materials (the MNPs), hard- ware including EM sources, receiver antenna arrays and data acquisition components as well as software, including signal processing, forward modeling and inversion. This article reports progress to date on the road to develop- ing the MNM program, which will be subsequently deployed in real reservoirs. In the lab, EM waves were used to success- fully map a container of high permeability MNPs buried within a 2,000 liter laboratory demonstration reservoir model of water and sand that simulated field conditions. The first arrival traveltimes of EM waves passing through the air, wet sand, water and MNPs were measured and processed to generate The ability to map injected fluids in hydrocarbon reservoirs with high resolution is a key goal for reservoir engineering and optimization. Saudi Aramco is developing tools and method- ologies to map the flood front, locate bypassed oil, monitor the oil-water contact, and detect super-K zones and fracture corri- dors prior to early water breakthrough at producing wells. The use of Magnetic NanoMappers (MNM) is a new approach ex- ploiting Magnetic Nano-Particles (MNPs) as contrast agents for mapping the flood front inside the hydrocarbon reservoir. This approach takes advantage of the fact that the speed of electromagnetic (EM) waves slows down when they pass through magnetic media. Localizing MNPs within an injected fluid could provide a detailed map of the fluids movements. Lab tests have recently demonstrated the capability of MNM to locate MNP volumes hidden within a 2,000 liter tank (reser- voir model) with high resolution. This article will outline the MNM concept, laboratory test bed, results and future plans. INTRODUCTION Tomography is a noninvasive imaging technique that allows the visualization of a slice or section of the internal structures of an object by using penetrating radiation. The technique is based on the mathematical principle of tomographic recon- struction, first developed by Johann Radon in the early 20 th century 1 . Traveltime tomography is widely used in geophysical studies to image subsurface velocity variation, mainly for seis- mic waves. It uses first arrival traveltime information from the transmitted wave as input data to construct earth structure and velocity models 2 . Traveltime tomography measurements can be accomplished using different kinds of waves, such as acoustic or electromag- netic (EM) waves. The basic theory of cross-well EM tomography has been studied and detailed in many papers 3-5 . Also, several types of equipment have been developed for cross-hole EM tomography 6 . Most of this equipment uses a low frequency controlled source EM (CSEM) method and system to image subsurface and subsea conductivity 7, 8 . To conduct traveltime measurements using EM waves, a signal is launched into a medium by a source antenna and is 40 FALL 2013 SAUDI ARAMCO JOURNAL OF TECHNOLOGY Illuminating the Reservoir: Magnetic NanoMappers Authors: Abdullah A. Al-Shehri, Dr. Erika S. Ellis, Jesus M. Felix Servin, Dr. Dmitry V. Kosynkin, Dr. Mazen Y. Kanj and Dr. Howard K. Schmidt 65165araD7R1_65165araD7R1 8/7/13 2:11 PM Page 40 an accurate 1D image of the MNP volume within the lab scale reservoir. 3D imaging and inversion experiments using the same test bed are currently ongoing. The next step is to demonstrate the concept in shallow wellbores in the field. This article will outline the MNM concept, experimental test bed, results and discussion. MAGNETIC NANO-PARTICLES (MNPS) MNPs are the enabling element in MNM technology. They are used as contrast agents due to their super paramagnetic (high ) properties. Once they are injected (with the fluid) into the fracture/reservoir, they will significantly slow the propagation of EM waves between the transmitter and receiver as the waves pass through the front. A matrix of traveltimes collected over the entire reservoir should differentiate between sand/rock, injection fluid and MNP-loaded volumes. We expect to use the resulting matrix of time delays, with inversion, to create a 3D image of the flood front. The MNPs were selected because of the ease of preparing them in large amounts, their high chemical stability in water in the absence of oxygen and their high magnetic permeability, Figs. 1 and 2. We adapted the preparation procedure described in Lu, et al. (2007) 12 , to prepare a mixture of MNPs at a con- centration of 10,000 ppm. THE CONCEPT OF THE MNM PROGRAM The MNM approach capitalizes on the MNPs super paramag- netic property to delay the propagation of EM waves while passing through the injected fluid. EM waves travel at c = 3.010 8 m/s in a vacuum, but they slow down substantially when they pass through a medium and interact with the atoms of the medium. This interaction denotes the permittivity and/or permeability of the medium. Equation 1 describes the speed of the EM waves in a given medium. (1) where c is the speed of light in a vacuum, V is the speed in the medium, r is the relative magnetic permeability of the medium, and r is the relative electrical permittivity of the medium. According to the above equation, as the EM waves pass through the MNP concentration with high , the propagation speed will decrease, showing an increased time delay in the received signal along the MNP front. Figure 3 illustrates the transmitter receiver array configuration of MNM across a fluid injected in the reservoir and the resulting time delay as the EM waves pass through the MNP front. A pulsed transmitter is located in a borehole to emit the EM waves. The radiated waves propagate through the reservoir and are detected at the receiving array located in a parallel borehole. The first peak arrival time information (first significant received signal peak from the receiver array) is used to produce a matrix of travel- time vs. antenna position throughout the reservoir, which can SAUDI ARAMCO JOURNAL OF TECHNOLOGY FALL 2013 41 Fig. 1. TEM image of MNPs. Fig. 2. Super paramagnetic MNPs are attracted to a magnet outside the sample jar. 65165araD7R1_65165araD7R1 8/7/13 1:19 PM Page 41 be processed by 3D inversion software to produce the spatial tomography maps 11 . 3D TOMOGRAPHY OF RESERVOIRS USING MNM As previously mentioned inversion software is needed to process and interpret the time delay measurements produced from a MNM test and to produce tomographic maps of the flood front. A tomographic inversion method that uses first arrival traveltime information is the appropriate method to analyze MNM collected data and surveys. There are many inversion methods developed to extract the first arrival travel- time and amplitude spectra information from cross-hole radar measurements to reconstruct electromagnetic velocity and attenuation distribution in earth materials. These methods in- clude straight-ray tomography 13 , curved-ray tomography 14 and traveltime tomography 11 . Since the goal of MNM is to map the variations in magnetic permeability using first arrival traveltime information, the traveltime tomographic inversion method will be used. EXPERIMENTAL TEST BED The experimental setup used a 2,000 liter tank half filled with wet sand as a reservoir model. In addition, a PVC pipe was placed through the center of the tank to mimic the borehole for the transmission source, as depicted in Fig. 4. The tank was divided into four quadrants, three of them containing a buried five gallon plastic container each (diameter of 27 cm) filled with different media: air, water and MNPs. The last quadrant was empty, containing wet sand only. For each quadrant, the total distance from the borehole (transmitter) to the volume side was 13.5 cm. The distance from the opposite side of the vol- ume to the outside wall of the tank was also 13.5 cm. There- fore, for shots directly through the volumes, the EM wave traveled through 13.5 cm of wet sand and 27 cm of volume medium plus an additional 13.5 cm of wet sand to the receiver antenna (a total distance of 54 cm). This is depicted in Fig. 5. An in-house built 1 kV spark gap with 3 cm loop was used to generate 2 GHz pulsed EM waves with a wavelength of 15 cm, Figs. 6a and 6b. A single loop of 3 cm magnetic wire 42 FALL 2013 SAUDI ARAMCO JOURNAL OF TECHNOLOGY antenna was attached on top of and normal to the face of the spark gap to record the magnetic portion of the transmission waveform. The spark gap and its antenna were fixed to a moveable sliding plate attached to a wooden slat placed down the center of the PVC pipe (borehole) to easily change the posi- tion of the transmission source. The receiver antenna was made of a 3 cm single loop of magnetic wire and placed out- side the tank, positioned 90 radially from the spark gap face to obtain the maximum far field magnetic signal. An Agilent DSO7104 oscilloscope capable of 4 GHz time capture was used to monitor transmission and receiver waveforms. Lab- view 2010 was used to control the scope and capture wave- form data. MatLab software was used to filter and process the Fig. 4. 2,000 liter tank (reservoir model). Fig. 5. Top-down schematic of volume placement in tank. Fig. 3. Schematic cross section of the transmitter receiver array configuration across a fluid injected in the reservoir and the corresponding delay in the received waveform as the EM waves pass through the MNP front. 65165araD7R1_65165araD7R1 8/7/13 1:19 PM Page 42 SAUDI ARAMCO JOURNAL OF TECHNOLOGY FALL 2013 43 data; it includes a first arrival peak picking routine. For each data set, 100 shots from the scope were captured and averaged to improve the signal to noise ratio. The experiment was performed in two phases. The first phase of the experiment was to determine the time delays based on the different media contained in the buried volumes. For these tests, the transmitter and receiver antennas were fixed on the tank with the EM waves shooting directly through the middle of the buried volume (i.e., the signal passing through both wet sand and the volume medium). This data showed the basic differential time delays for air, sand, water and MNPs, which inversely compared their respective material properties (permittivity and permeability). The second phase of the experiment was to create a 1D image of a single quadrant of the tank to find the buried vol- ume with respect to the vertical position of the transmitter and receiver. In this case, the transmitter (spark gap) and receiver antenna positions were varied over 10 vertical positions down the tank in 10 cm increments, starting with air, moving through the buried volume and then going below the volume through wet sand only. This data presented a 1D vertical im- age of the MNP volume based on the time delay differences as the transmitter and receiver moved vertically down the tank. Figure 7 shows a schematic of the 1D imaging experiment. RESULTS AND DISCUSSION The first phase results show fundamental time delay differ- ences and corresponding material properties for four different media: air, sand, water and MNPs. Figure 8 (top) shows the signal from the spark gap transmitter antenna (Tx), and Fig. 8 (bottom) shows the entire received signals shot from Tx through the center of each buried volume for each of the four tank quadrants. The red dotted line represents the beginning of the transmission pulse (time = 0). The first peak for each wave- form was determined by a statistical Matlab subroutine and is shown for each quadrant (medium) in Fig. 8 (bottom). The time at which the first peak appears in Rx is the time delay for the transmitted EM wave to travel through 27 cm of wet sand plus 27 cm of volume medium. Note that although the entire Tx and Rx waveforms are shown in Fig. 8, the area of interest is the first peak of the Rx past Tx time = 0. The rest of the waveform is ignored for traveltime tomography. Fig. 6a. In-house built 1 kV spark gap with 3 cm loop used as a pulsed DC transmission source. Fig. 6b. Actual photo of the in-house built 1 kV spark gap. Fig. 7. Experimental schematic of 1D MNP volume imaging in the lab scale reservoir. 65165araD7R1_65165araD7R1 8/7/13 1:19 PM Page 43 Table 1 shows the measured time delays (first peak from Fig. 8 waveforms) and calculated time delays for EM waves traveling through the air, wet sand, water and MNP volumes in addition to the wet sand surrounding the volumes. The EM waves traveled a distance of 54 cm; part of it was within the volume medium, while the other part was in the wet sand sur- rounding the volume on both sides, as previously illustrated in Fig. 5. Comparative time delay values for each medium were calculated based on Eqns. 1 and 2 using the published values of and for air (1, 1.3), water (1, 80), wet sand (1, 25) and MNP (2, 80), respectively. t = d __ V (2) where t is traveltime, V is the speed in the medium, and d is the distance. The of wet sand was chosen as 25 for our calculation, from published values that vary from 20 to 30 depending on the type of sand 15 . The of MNPs was the same as for water, 80, while the could not be measured due to the large paramagnetic properties of the fluid, but it was estimated to be 2. It is noted that the delay for the air volume quadrant was smaller than expected because the calculated time was a line- of-sight estimate neglecting multipath, refraction and air-short effects. Such effects are apparently non-negligible in the case of the air volume. In this case, the EM waves should have trav- eled through two different media (wet sand and immersed air volume) in three stages: from the transmitter through 13.5 cm of wet sand, then through the immersed air volume, and finally through 13.5 cm of wet sand from the other side, Fig. 5. Sub- sequently, it seems that it traveled through the shortest path. For the other three quadrants and for the entire air medium in the top of the tank, the measured and expected delays are in general agreement. This data show that the lab scale system can accurately model propagation speeds of EM waves through selected medium based on differences in their and . To verify known medium permeabilities with measured time delays, a back calculation of Eqns. 1 and 2 was used to solve for . The calculated values are shown in Table 2. It is obvious that the back calculated for the air volume is 44 FALL 2013 SAUDI ARAMCO JOURNAL OF TECHNOLOGY Fig. 8. The Tx signal (top) and the Rx signal (bottom) for each of the four main quadrants showing different measured arrival times for air, sand, water and MNPs. Fig. 9. Vertical position vs. arrival time for the MNP quadrant of the tank showing a 1D image of the MNP volume. Medium Time Delay (ns) Measured Time Delay (ns) Calculated Air only through 54 cm near top of the tank 2 2 Air volume (27 cm) plus wet sand (27 cm) 3.5 5 Wet sand (54 cm) 9.5 8-10 Water volume (27 cm) plus wet sand (27 cm) 12 12 MNP volume (27 cm) plus wet sand (27 cm) 24.5 16
Table 1. Measured vs. calculated time delays of different media in lab scale system
Medium Calculated from Measured Time Delay Air only 1.0 Air volume 1.1 Water volume 1.0 Wet sand 1.0 MNP volume 6.2 T Table 2. The back calculated values of from measured time delays in the reservoir model 65165araD7R1_65165araD7R1 8/7/13 1:19 PM Page 44 SAUDI ARAMCO JOURNAL OF TECHNOLOGY FALL 2013 45 higher than the known permeability (Eqn. 1) for the same reason as given for the difference between calculated and measured time delay, as was seen in Table 1. The second phase of the experiment was to image the vol- ume of MNPs vertically through the tank, starting with the air in the empty space at the top of the tank, moving down through the volume and finally moving through the wet sand underneath the volume. Figure 9 illustrates the vertical posi- tion of the transmitter and receiver vs. arrival times for the MNP quadrant of the tank. The first five stations correspond to wave propagation through air only. Stations 6 and 7 show the time delays getting longer as the wave starts moving through the neck, tapering off the volume, while the largest time delay (24.5 ns) occurs at Station 8 when the wave moves through the entire 27 cm diameter of the volume. Station 9 at the interface of the bottom of the volume with the wet sand is reflected in the time delay as the wave moves partially through the MNPs and partially through wet sand. At Station 10, the wave travels through the wet sand only, with the same time de- lay as obtained in the first phase of the experiment at 9.5 ns. The plotted data thereby revealed a 1D image of the volume of MNPs through the received time delays. The success in accurately differentiating time delays with re- spect to different reservoir-like model media and the ability to create a 1D image of the MNPs using traveltimes demonstrate the concept of using MNPs in the injected fluids to spatially map the flood front inside the reservoir. CONCLUSION Lab tests have demonstrated the capability of using traveltime tomography to differentiate between different media in a 2,000 liter tank (reservoir model). The first arrival traveltimes of EM waves passing through air, wet sand, water and MNPs were accurately measured and processed to generate a 1D image of the container within the lab scale reservoir at good resolution. This achievement is a big step forward on the road to exhibiting the concept in shallow wellbores in the field. The next phase involves 3D vertical imaging of the tank quadrants using the MNM system and specialized bh_tomo software to automate first peak picking, data sequencing and inversion to create an accurate 3D image of the lab scale reservoir. The first field test in shallow wellbores is planned for the second quarter of 2013. ACKNOWLEDGMENTS The authors would like to thank the management of Saudi Aramco for their permission to publish this article. We would also like to acknowledge the valuable assistance received from Jim J. Funk and Mohammed H. Subahi. This article was presented at the SPE Middle East Oil and Gas Show and Exhibition, Manama, Bahrain, March 10-13, 2013. REFERENCES 1. Radon, J.: On Determining Functions from Their Integral Values along Certain Manifolds, translated by P.C. Parks in 1986, IEEE Transactions on Medical Imaging, Vol. 5, No. 4, November 12, 2007, pp. 170-176. 2. Brzostowski, M.A.: 3D Tomographic Imaging of Near- Surface Seismic Velocity and Attenuation, Geophysics, Vol. 57, No. 3, 1992, pp. 396-403. 3. Zhou, Q.: Audio-Frequency Electromagnetic Tomography for Reservoir Evaluation, Ph.D. thesis, Lawrence Berkeley Laboratory, University of California, Earth Sciences Division, October 1989, p. 175. 4. Nekut, A.G.: Electromagnetic Ray-Trace Tomography, Geophysics, Vol. 59, No. 3, March 1994, pp. 371-377. 5. 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Martinez, A. and Byrnes, A.P.: Modeling Dielectric- Constant Values of Geologic Materials: An Aid to Ground Penetrating Radar Data Collection and Interpretation, Current Research in Earth Sciences, Bulletin 247: part 1, 2001. 46 FALL 2013 SAUDI ARAMCO JOURNAL OF TECHNOLOGY BIOGRAPHIES Abdullah A. Al-Shehri joined Saudi Aramco in 2002 as a Communications Engineer. He first worked with the Communication Engineering & Technical Support Department. Abdullah undertook a number of advanced development projects as well as the design and implementation of the latest technologies related to satellite and wireless communications systems. In late 2009, he moved to the Exploration and Petroleum Engineering Center Advanced Research Center (EXPEC ARC) and joined the in situ sensing and intervention focus area of the Reservoir Engineering Technology Team. Abdullah participated in industry leading research on nanotechnology to employ the concept of sending nano-agents (Resbots) through the reservoir to collect data for engineering functions. Also, he worked on the Magnetic NanoMappers research program in an effort to develop new technology for tracking flood front in the reservoir. Abdullah received his B.S. degree from King Fahd University of Petroleum and Minerals (KFUPM), Dhahran, Saudi Arabia, in 2002, and his Applied Science M.S. degree from Concordia University, Montreal, Quebec, Canada, both in Electrical Engineering. Dr. Erika S. Ellis is a Petroleum Engineer working in Saudi Aramcos Reservoir Engineering Group researching nano and micro electro- mechanical systems (NEMS/MEMS) to help illuminate oil reservoirs. Prior to joining the company in 2013, she spent 9 years at Argonne National Laboratory in Chicago, IL, developing thick-film gas micro-sensors for a variety of applications. Erika spent the last 14 years in R&D in Dallas, TX, developing and characterizing new materials and process integration schemes for MEMS applications for Fortune 500 semiconductor companies. She received her B.S. degree in Applied Physics from Lewis University, Romeoville, IL, and her M.S. degree in Applied Physics from Northern Illinois University, Dekalb, IL. Erika then received her Ph.D. degree in Materials Science and Engineering from the University of Texas at Arlington, TX. Jesus M. Felix Servin has been working with Saudi Aramcos Reservoir Engineering Technology Team focused on in situ sensing since February 2012. In this short time, he has made major contributions in the ongoing success of the Magnetic Nano-Mappers project, including hardware design and in-house fabrication, instru- mentation, computer programming and data processing. Jesuss interests include the development of nano-scale strategies for reservoir illumination and electromagnetic methods for reservoir description and monitoring. He received his B.S. degree in Engineering Physics from Instituto Tecnologico y de Estudios Superiores de Monterrey, Monterrey, Mexico, and a M.S. degree in Chemical and Biological Engineering from King Abdullah University of Science and Technology, Thuwal, Saudi Arabia. Dr. Dmitry V. Kosynkin is a Petroleum Engineer in Saudi Aramcos Reservoir Engineering Technology Division. Before joining Saudi Aramco, he worked as a Research Scientist at Rice University, Houston, TX, studying synthesis and applications of hybrid nanomaterials. Dmitry received his M.S. degree in Chemistry from M.V. Lomonosov Moscow State University, Moscow, Russia, in 1989 and then received his Ph.D. degree in Organic Chemistry from the University of Houston, Houston, TX, in 1997. Dr. Mazen Y. Kanj is a Petroleum Engineering Specialist with the Reservoir Engineer Technology Team of the Exploration and Petroleum Engineering Center Advanced Research Center (EXPEC ARC). He is the focus area champion on reservoir in situ sensing and intervention. Before joining Saudi Aramco in 2003, Mazen held a Senior Scientist position with the Poromechanics Institute of the University of Oklahoma, Norman, OK. He was an invited member of the Poromechanics Committee of the American Society of Civil Engineers and an Associate Editor for the Society of Petroleum Engineers SPE Journal. Mazen received his B.S. and M.S. degrees from the American University of Beirut, Beirut, Lebanon, and a Ph.D. degree from the University of Oklahoma, Norman, OK, all in Civil Engineering. 65165araD7R1_65165araD7R1 8/7/13 1:19 PM Page 46 SAUDI ARAMCO JOURNAL OF TECHNOLOGY FALL 2013 47 Dr. Howard K. Schmidt is a Petroleum Engineering Consultant with the Reservoir Engineering Technology Team of the Exploration and Petroleum Engineering Center Advanced Research Center (EXPEC ARC). He leads the Magnetic NanoMappers project within the In-Situ Sensing and Intervention (ISSI) focus area. Prior to joining Saudi Aramco, Howard was at Rice University where he served as Senior Research Fellow in the Chemical and Biomolecular Engineering Department and Executive Director of the Carbon Nanotechnology Laboratory. While there, Howard also served as the founding Senior Nanotechnology Advisor to the Advanced Energy Consortium (AEC). He received his B.S. degree in Electrical Engineering in 1980, and his Ph.D. degree in Chemistry in 1986, both from Rice University, Houston, TX. Howard has 50 peer-reviewed publications and a dozen issued patents. 65165araD7R1_65165araD7R1 8/7/13 1:19 PM Page 47