Fulltest IV Advanced Paper 2 Answer Sol Aits Jeea FT IV Paper 2

AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
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1

ANSWERS, HINTS & SOLUTIONS
FULL TEST IV
(Paper-2)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
C C A
2.
A B C
3.
D B A
4.
B C C
5.
A D C
6.
C C B
7.
A A B
8.
A C D
9.
D C C
10.
C A B
11.
A C B
12.
C B B
13.
A B D
14.
B D B
15.
A, B, C A,C A, B
16.
A, B, C A,C A, B, C, D
17.
A, D B,D A, B, C
18.
A, B, D B,D C, D
19.
A, C, D
A, B, D
A, C
20.
C, D
B, C, D
A, C

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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2
P Ph hy ys si ic cs s PART I

SECTION A

1. A is at rest instantaneously (for no slipping at A)
V
B
V
A
=
1
2
B
0
V
R
| |
|
\ .
(2R)
2

V
C
V
A
=
1
2
B
0
V
R
| |
|
\ .
( 3 R)
2

V
B
V
C
=
1
2
B
0
V
R
| |
|
\ .
[R
2
] =
0
BV R
2

2. force = (P P
0
) A = Ma
by P
1
V
1
= P
2
V
2
P
0
hA = P(h x) A
P =
0
P h
h x

So force =
0
0
P h
P
h x
| |
|
\ .

A
M
= a
a =
0
P Ax
M(h x)

0
P Ax
Mh
; (for small x)
T = 2
0
Mh
P A

3.
restoring
= (mg sin L + (mg sin
L
2

+
L L KL L
K sin sin
4 4 2 2
| | | |
+
| |
\ . \ .

restoring
=
2
3mg 5KL
2 16
(
+
(
(

( : small)
frequency of oscillation) =
2
3mg 5kL
1
2 16
2
+

where = mL
2
+
2 2
mL 4mL
3 3
=

4. From law of radioactive decay.
Activity Number of nuclear of that nucleus present in the sample.
Activity does not depend upon the rate of the formation of nucleus.
In given reaction B decays into E and C.
Total activity of B = rate of decay of B into E + rate of decay of B into C = l
5
N
2
+ l
3
N
2

5. The EMF will be induced in the loop, only when there is a change in the flux through the loop.
When the loop was completely inside the field region, for some time (say t
1
) there is no change in
the flux, hence that time would not be included in the calculation.

3
The time for which EMF was induced =
b b 2b
v v v
+ =

6. That wire will break first whose stress reaches the breaking stress (for that
material) first.
Stress =
2
F F
A
r
=
where F is the tension in the wire. F is same in both the wires.

Thus stress
2
1
r
for the wire of smaller radius, the stress is more.
Thus the wire with smaller radius will break first.
If r
A
< r
B
, then wire A will break first.
If r
A
> r
B
, then wire B will break first.
If r
A
= r
B
, either of them could break.

8. As the magnetic field is uniform and the particle is projected in a direction perpendicular to the
field, it will describe a circular path. The particle will not hit the yz-plane if the radius of the circle is
smaller than d. For the maximum value of v, the radius is just equal to d. Thus =
mv
d
Bq
.
=
Bqd
v
m

9. F = A
0
u u
y

u =
F
A
y + u
0

u =
2
1
10 1

y + 1 = 100

y + 1

10. The velocity of upper plate is same as that of the layer in contact with the plate i.e. layer at y = 2
cm.
u = 100 (0.02) + 1 = 3 m/s

11. T
2
r
3
(Kepler's law)

4

2 3
A A
2 3
B B
T r
T r
= =
3
3
r 1
64
(4r)
= Get
A
B
T 1
T 8
=

12. For geostationary satellite, time period = 1 planet day (by def.)
Let T = 1 planet day
T
0
= 1 planet year
Now T
2
=
2
3
G
4
r
Gm
=
2
3
4 m
r
Gm M
| |
|
\ .

=
2
3 3
0
4
r T
GM
= or T = T
0

13-14. =
k
M
, =
k
M m +
=
2500
25
= 10 rad/sec
=
M
M m +

x
1
= A sin
1

Potential energy stored in the spring at (t = t
1
) =
2 2 2
1 1
1 1
kx M sin
2 2
=
Let v and v be the velocity of system just before collision and just after collision, so using COLM
v =
( )
Mv
M m +
=
( )
MA cos
M m

+

Total energy after collision = PE + KE =
( )
2 2
1
1 1
kx M m v
2 2
+ +
=
2
2 2
1 M msin
MA
2 M m
( +
(
+
=
2
2
1 M msin
kA
2 M m
( +
(
+
= 8 J

( )
2 2 2 2
1 1
M m A MA
2 2
+ =
2
M msin
M m
( +
(
+

15.
2
max 1 2
2
min
1 2
I (a a )
I
(a a )
+
=

1 1
2 2
a I 4 2
a I 9 3
= = =

max
min
I
25
I
=
If an identical paper is pasted across second slit shifted C.B.F. will back in central point.
( )
tD
shift 1
d
=
fringe width
n D
d
=

shift ( 1)t
n 15
fringewidth

= = =
.

16. The change in magnetic flux is zero, hence the current in the ring will be zero.

17. Both (A) and (D) depend on g.

5

18.
n(n 1)
6 n 4
2
= =
If the initial state were n = 3, in the emission spectrum, no wavelengths
shorter than
0
would have occurred. This is possible if initial state were n = 2
(A), (B) and (D)
n=4
3
2
1

19. From COE (A) is correct.
The force outside the earth varies as inverse square of the distance.
motion is not simple harmonic. However, from symmetry of motion, the motion will be
periodic.
(C) is correct.
From COE

2
1 GMm 3GMm
mv
2 2R 2R
| |
=
|
\ .

2GM
v
R
=
(A), (C) and (D) are correct.

20. The current through R
1
is constant.

6
C Ch he em mi is st tr ry y PART II

SECTION A
1. pH at isoelectric point =
1 2
pKa pKa 4 9
6.5
2 2
+ +
= =

2. Net reaction does not involve any aqueous species.

5. ( ) ( )
2
3
2 4
Cr SCN NH
+
(

, shows geometrical (or cis-trans) and linkage isomerism.
6.
C H
3
C CH
2
C O CH
2
CH
3
O O
(i) EtO
(ii)
H C H
O
C H
3
C CH C O CH
2
CH
3
O O
CH
2
OH
2
, OH
C H
3
C
O
CH C O CH
2
O CH
3
C H
3
C C C O CH
2
CH
3
O O
CH
2
( ) Michael
C H
3
C CH C O CH
2
CH
3
O O
CH
2
CH C H
3
C C O CH
2
CH
3
O O
EtO
OH
O
C
O
O CH
2
CH
3
C
O
O CH
2
CH
3
Li /
+

CH
3
O
C
O
O Et
2 2
H O CO Et OH + + +

7.
4 2 3 3 2
FeSO Fe O SO SO
+ +

8. Energy of e
in H-atom = - E
Energy of e
in Li
+2
= - 9E
Energy supplied by photon =
2
1
IE mv
2
+
IE E =

2
p
1
E 9E mv
2
= +

( )
p
2 E 9E
v
m
=

9. In reverse osmosis water moves from more concentrated to less concentrated solution

10. = iCRT, (i=2)


7
11. Let conc. of both reactants at equilibrium is x M

2
2
2
PbEDTA H
Keq
x
+
( (

=

x = 10
3

12. Chelation increases stability of complexes

14.
2 3 2
aq.K CO H /H O HCN
heat
P Q R S
+
+
O
OH
O

2
H O
O
OH
O
OH
O H
OH
O
2
H /H O
heat
+
CN
OH
OH
( ) S
HCN
H
OH
O
( ) R
2 3
aq. K CO
O
H H
+
H
O
+
( ) P ( ) Q

15.
Cl
Cl
KCN
Cl
CN
2
H Pt
Cl
NH
2

16. Trans-2-butene
3 3 3 4
CF CO H H O HIO
3
epoxide diol 2CH CHO
+

17. He and H
2
are not hydrogen like particles

18. Radius of cation is smaller than parent atom and that of anion is more than parent atom
19. (A)
H
2
C
CH
O
O
I
O
C
O
CH
2
I
I
2
will attack the double bond to form a cyclic halonium ion. It then undergoes on intramolecular
reaction. Formation of five membered ring is favoured because (i) attack by a nucleophile on a
halonium ion normally takes place at the more substituted site.
(ii) Formation of five membered ring is more probable.

8
(B)
O
C
O
CH
2
Br
O
O
Br
+
C H
3
(C)
Option(C)gives
O
C
C
O
O
(D)
Option(D)gives
C O
1, 4 and 1,5-dicarboxylic acids give anhydrides whereas 1,6 and 1, 7-diacids give ketones when
heated with P
2
O
5
.

9
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. Normal to y
2
= 4ax with slope m is
y = mx 2am am
3
..... (1)
(1) touches x
2
y
2
= a
2
if
(2am am
3
)
2
= a
2
(m
2
1)
i. e. if m
6
+ 4m
4
+ 3m
2
+ 1 = 0 ..... (2)
(2) is a sixth degree equation in m with no odd power terms and whose coefficients are all
positive.
(2) has no real root
|S| = 0

2. Given x + y + z = 5 (1)
and x
2
+ y
2
+ z
2
= 9 (2)
We have yz = ( )
( )
2
2 2
1
y z y z
2
(
+ +
(

= ( )
( )
2
2
1
5 x 9 x
2
(

(

(using) (1) & (2))
= x
2
5x + 8
y, z must be the roots of the equation
( )
( )
( )
2 2
u 5 x u x 5x 8 0 3 + + =
As y, z are real, we must have discriminant of (3) 0
(5 x)
2
4 (x
2
5x + 8) 0
3x
2
10x + 7 0
(3x 7) (x 1) 0
x
7
1,
3
(
(

Number of integer values that x can take is 2

3. 2 sin
2
x + sin
2
2x = 2
2(1 sin
2
x) + 4 sin
2
x cos
2
x = 0
cos
2
x.cos 2x = 0 (1)
sin 2x + cos 2x = tan x
2 sin x cos
2
x + cos 2x cos x = sin x
sin x cos 2x + cos 2x cos x = 0
cos 2x (sin x + cos x) = 0 (2)
Common roots of (1) and (2) are given by cos 2x = 0

( ) 2n 1
x ,n N
4

=
In [0, 4] we have x =
n
,
4
where n = 1, 3, 5,,15 (3)

Now, 2 sin
2
x + sin x 0
2 sin
2
x sin x 0
(sin x) (2 sin x 1) 0
sin x [1, 0] or
1
sinx 1
2
(4)
Among the 8 values given by (3), only 4 values, i.e.,
5 7 13 15
x , , ,
4 4 4 4

= satisfy (4)

10

4. We have
1
w z
z
= +
Take z = e
i
(|z| = 1).
We have
i i
w e e 2cos

= + =
We know that w is real and | w | 2

5. The scalar triple product of the three given vectors is
( ) ( )
2 2 2
2 2 2
2 2 2
x 1 2 x 1 3 x 1
2x 1 2x 1 x
3x 2 x 4 x 1

+
+ + +

( )
2 2 2 2
2 2 2
1 2 3
x 1 2x 1 2x 1 x
3x 2 x 4 x 1
= +
+ + +

( )
2 2 2 2
2 2 2
1 2 0
x 1 2x 1 2x 1 5x
3x 2 x 4 5x 7
= +
+ + +
(using C
3
C
3
+ C
2
+ C
1
)

( )
2 2 2 2
2 2 2
1 0 0
x 1 2x 1 2x 3 5x
3x 2 5x 5x 7
= +
+ +
(using C
2
C
2
2C
1
)
=
( )( )
2 4 2
x 1 15x x 21 + +
Vector are noncoplanar Scalar triple product 0 x
2
1 0 (15x
4
+ x
2

+ 21 0) x 1

6. We have ( )
( )
1/ n
n
f x a x = so that
( )
( )
1/ n
n
f f x f a x
| |
=
|
\ .

( )
1/ n
n
1/ n
n
a a x
| |
| |
= |
|
|
\ .
\ .

( ) ( )
1/ n
n
a a x =
( ) ( )
2mtimes
g x f f .....f x x

= =

( ) ( ) ( ) ( )
( )
( )
1/ n 1/ n
n n n n
dx dx
x 1 x
g x 1 g x
=
+
+

( )
1/ n
n 1 n
dx
x 1 x
+
=
+
=
1/ n
dt
nt
(using t = 1 + x
n
)

1/ n 1
1 t
c
1
n
1
n
+
| |
|
= +
|
|
+
|
\ .
=
( )
1
1
n
n
1
1 x c
1 n

+ +

7. Given ( ) ( ) y f x ,z g x = = we have

( )
( )
f x
dy dy / dx
dz dz / dx g x
= =
and
2
2
d y d f dx
dx g dz
dz
| |
=
|
\ .

( )
2
g f f g 1
.
g
g

=

8. ( ) f x is continuous at x = 3

( )
f 3
= ( )
( )
f 3 f 3
+
=
Now
( )
( )
2
2
2 2
x 3 x 3
a x x 6
a | x x 6 |
f 3 lim lim
6 x x 6 x x

= =
+ +
= a

11

( )
x 3 x 3
x [x] x 3
f 3 lim lim 1
x 3 x 3
+ +
+

= = =

( )
x
3
x 3
x tdt
0
f 3 b lim form
x 3 0
| |
|
| |
=
|
|
\ .
|
|
\ .

x
2
3
x 3
x tdt
b lim
1
| |
|
+
|
= |
|
|
|
\ .
= 9b
a = 9b = 1 b =
1
9
and a = 1

9. ( )
n n
n r
r 1 r 1
V S 2 r n n 1
= =
= = = +

n
2
n n
V n 1
lim lim 1
n
n

+
= =

10. (i) V
n
= n (n + 1) V
1
< V
2
< V
3
< .....
Statement 2 is true
(ii)
( )
n n
n
r r 1
r 1 r 1
1 1 1
Q
S S 4 r r 1
+
= =
= =
+

n
r 1
1 1 1 1 1
1
4 r r 1 4 n 1
=
| | | |
= =
| |
+ +
\ . \ .

Q
1
< Q
2
< Q
3
< .
Statement 1 is false

11. We have
( )
x
x x
2a , x 0
f x
a a , x 0
<
=

+

Clearly, f(x) is continuous in R.
For x 0, > ( )
x x
e e
f x a log a a log a
= + = ( a
x
a
x
) log
e
a
2x
e
x
a 1
log a
a
| |
=
|
|
\ .
> 0 for x > 0
( ) f x is monotonic increasing for x > 0
For x < 0, ( )
x
f x 2a
= ( )
x
e
f x 2a log a
= < 0
( ) f x is monotonic decreasing for x < 0

12. Required area
( )
0 1
x x x
1 0
2a dx a a dx

= + +

0 1
x x x
e e
1 0
2a a a
log a log a

+
= +
` `

) )

( )
e e
1 1 1
2 2a a 0
log a log a a
( | |
( = + +
| (
\ .

2
e
3a 2a 1
alog a

=

15. The equation of the line is
1 1 2 2
3 3 3 3
b y a x a b 0 + + =
This can be written as
1
2 1
3
3 3
1
3
a
y x a b
b
=
1
2 1
3
3 3
1
3
a
m , c a b
b
= =
Consider the parabola y
2
= 4ax

12

1
2 1
3
3 3
1 1
3 3
1
3
a a ab
a b c
m
a a
b
= = = =

Condition for tangency for the parabola y
2
= 4ax is satisfied
The given line touches y
2
= 4ax
Similarly the line touches x
2
= 4by

16. ( )
1
5 x iy a ib + = +
x + iy = ( a + ib)
5
= a
5
+ 5a
4
(ib) + 10a
3
( b
2
) + 10a
2
(ib
3
) + 5ab
4
+ ib
5

Equating the real and imaginary parts x = a
5
10a
3
b
2
+ 5ab
4
y = 5a
4
b 10a
2
b
3
+ b
5

x y
p
a b
= = (a
4
10a
2
b
2
+ 5b
4
) (5a
4
10a
2
b
2
+ b
4
) = 4a
4
+ 4b
4
= 4 (a
4
b
4
)
= 4(a
2
b
2
) (a
2
+ b
2
) = 4(a + b)( a b) ( a +ib) (a ib)
a b, a + b, a + ib and a ib are all factors of p.

17. Since
2 2 2
0 ,0 sin , cos , tan 1
4
< < < <

( )
2k 2
2
k 0
1
A sin sec
1 sin
=
= =

(B)
2k 2
2
k 0
1
cos cosec
1 cos
=
= =

(C)
2
2k
2 2 2
k 0
1 cos
tan
1 tan cos sin
= =

2
cos
cos2

(D) cot > 1 in 0 < < .
4
Hence,
2k
k 0
cot
does not exist.

19.
y x x
3 9 3 9 3 0 = > x 2 <
Similarly, y < 2

20. Area
( )
2 3
c.c c
T
2 2
= =
Area
( )
c
3
2
0
c
R x dx
2
=

3 3 3
c c c
2 3 6
= =

( )
( )
3
3
c 0 R 0
Area T c 6
lim lim . 3
Area R 2
c
+ +

= =

Fulltest IV Advanced Paper 2 Answer Sol Aits Jeea FT IV Paper 2

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where F is the tension in the wire. F is same in both the wires.

where n = 1, 3, 5,,15 (3)

< < < <

does not exist.

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