MATERIAL SAFETY DATA SHEET

MIL-CLEAN
MIL-CLEAN Material name
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1. Product and Company Identification
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Drilling Fluid Detergent Chemical description
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Baker Hughes Drilling Fluids
2001 Rankin Rd.
Houston, TX 77073
Emergency telephone number 713-439-8900
Supplier
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CAS # Percent
5 - 10 111-76-2
Components
Ethylene Glycol Monobutyl Ether
1 - 5 Proprietary Sodium silicate
80 - 90 Non-hazardous and other components below reportable levels
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2. Composition / Information on Ingredients
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DANGER
Extremely corrosive and destructive to tissue. Toxic in contact with skin. Components of
the product may affect the nervous system.
Emergency overview
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3. Hazards Identification
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Corrosive to the eyes and may cause severe damage including blindness. Eyes
Potential health effects
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May cause burns. May cause toxic effects if absorbed through skin. Skin
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Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Can cause severe central nervous system depression (including unconsciousness).
Inhalation
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Not a likely route of entry. Corrosive and may cause severe and permanent damage to
mouth, throat, and stomach.
Ingestion
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Skin. Eyes. Respiratory system. Target organs
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Repeated absorption may cause disorder of central nervous system, liver, kidneys and
blood. May be harmful in contact with skin (after often repeated exposure). May cause
central nervous system disorder (e.g., narcosis involving a loss of coordination,
weakness, fatigue, mental confusion, and blurred vision) and/or damage. Conjunctiva.
May cause delayed lung damage.
Chronic effects
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Immediately flush eyes with plenty of water for at least 20 minutes. Get medical attention
immediately.
Eye contact
First aid procedures
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4. First Aid Measures
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Remove and isolate contaminated clothing and shoes. Wash off with soap and plenty of
water. Immediately flush skin with running water for at least 20 minutes. Get medical
attention if irritation develops or persists.
Skin contact
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Move to fresh air. If breathing is difficult, give oxygen. Call a physician if symptoms
develop or persist.
Inhalation
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Get medical attention immediately. Have victim rinse mouth thoroughly with water. Do not
induce vomiting without medical advice.
Ingestion
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None known. Flammable properties
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5. Fire Fighting Measures
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Decomposition of this product may yield oxides of sulfur and nitrogen. Carbon monoxide,
carbon dioxide and other hydrocarbon fragments.
Hazardous combustion products
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Dry chemical, foam, carbon dioxide. Use water to cool fire-exposed containers and to
protect personnel.
Suitable extinguishing media
Extinguishing media
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Material name: MIL-CLEAN
Material ID: 1088 Revision date: 21-APR-2006 Print date: 21-APR-2006 1 / 5
MSDS US
Wear full protective clothing, including helmet, self-contained positive pressure or
pressure demand breathing apparatus, protective clothing and face mask. Move
containers from fire area if you can do it without risk.
Protective equipment for
firefighters
Protection of firefighters
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Keep unnecessary personnel away. Remove all sources of ignition. Wear appropriate
personal protective equipment. Ensure adequate ventilation. Do not touch or walk through
spilled material.
Personal precautions
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6. Accidental Release Measures
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Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Prevent entry into waterways, sewers, basements or confined areas.
Methods for containment
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Large Spills: Dike far ahead of liquid spill for later disposal. Absorb with earth, sand or
other non-combustible material and transfer to containers for later disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
Methods for cleaning up
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Use only in well-ventilated areas. Do not get this material in your eyes, on your skin, or on
your clothing. Avoid breathing vapors or mists of this product. Do not handle or store near
an open flame, heat or other sources of ignition. Wash hands after handling and before
eating.
Handling
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7. Handling and Storage
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Keep container tightly closed. Keep in a dry, cool and well-ventilated place. Keep away
from heat, sparks, and flame. Use care in handling/storage.
Storage
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Ethylene Glycol Monobutyl
Ether
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
111-76-2 20 Ppm TWA
Ethylene Glycol Monobutyl
Ether
ACGIH - Threshold Limits Values - TLV Basis - Critical Effects
111-76-2 Irritation; CNS
Ethylene Glycol Monobutyl
Ether
OSHA - Final PELs - Skin Notations
111-76-2 prevent or reduce skin absorption
Ethylene Glycol Monobutyl
Ether
OSHA - Final PELs - Time Weighted Averages (TWAs)
111-76-2 50 Ppm TWA; 240 mg/m3 TWA
Exposure guidelines
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8. Exposure Controls / Personal Protection
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Provide adequate local exhaust ventilation to maintain worker exposure below exposure
limits.
Engineering controls
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Wear chemical goggles. Face-shield. Eye wash fountain and emergency showers are
recommended.
Eye / face protection
Personal protective equipment
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Use of protective coveralls and long sleeves is recommended. Use of an impervious
apron is recommended.
Skin protection
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Neoprene or Nitrile rubber. Hand protection
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Not normally needed. When workers are facing concentrations above the exposure limit
they must use appropriate certified respirators.
Respiratory protection
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Keep away from food and drink. Avoid contact with the skin and the eyes. Handle in
accordance with good industrial hygiene and safety practice. Wash hands before breaks
and immediately after handling the product.
General hygeine considerations
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Clear. Liquid. Blue. Liquid. Appearance / Color / Form
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9. Physical and Chemical Properties
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Mild. Sweet. Odor
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Not available Clarity
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Not available Odor threshold
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Liquid Physical state
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11 - 12 5% in water pH
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-94 F (-70 C) estimated Melting point
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Not available Freezing point
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339.8 F (170.8 C) estimated Boiling point
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Material name: MIL-CLEAN
Material ID: 1088 Revision date: 21-APR-2006 Print date: 21-APR-2006 2 / 5
MSDS US
> 199.4 F (> 93.4 C) Pensky-Martens Closed Cup Flash point
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Not available Evaporation rate
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Not available Flammability limits in air, lower, %
by volume
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Not available Flammability limits in air, upper, %
by volume
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18.2 Mm Hg @ 21 C Vapor pressure
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> 1 Vapor density
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1.024 - 1.036 @ 16 C Specific gravity
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8.53 - 8.63 lbs/gal @16 C Relative density
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Soluble in water. Solubility
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Not available Octanol/H2O coeff
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Not available Auto-ignition temperature
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Not available Decomposition temperature
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10.5 % estimated VOC (Weight %)
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Stable at normal conditions. Chemical stability
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10. Chemical Stability and Reativity Information
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Heat, flames and sparks. Conditions to avoid
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Incompatible with oxidizing agents. Incompatible materials
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Not applicable. Hazardous decomposition products
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Will not occur. Possibility of hazardous reactions
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Causes severe burns.
Acute LD50: 6131 mg/kg, Rat, Oral
Acute LD50: 2933 mg/kg, Rat, Dermal
Acute LC50: 6000 mg/l/4h, Rat, Inhalation
Acute effects
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11. Toxicological Information
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Ethylene Glycol Monobutyl
Ether
Toxicology Data - Selected LD50s and LC50s
111-76-2 Inhalation LC50 Rat: 2.21 mg/L/4H; Inhalation LC50 Rat: 450 ppm/4H; Oral LD50
Rat: 470 mg/kg; Dermal LD50 Rat: 2270 mg/kg; Dermal LD50 Rabbit: 220 mg/kg
Component analysis - LD50
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Ingestion or inhalation of high concentrations may cause injuries to gastrointestinal tract,
liver, kidneys and central nervous system. Toxic by inhalation, in contact with skin and if
swallowed.
Local effects
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Repeated absorption may cause disorder of central nervous system, liver, kidneys and
blood.
Chronic effects
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Ethylene Glycol Monobutyl
Ether
ACGIH - Threshold Limits Values - Carcinogens
111-76-2 A3 - Confirmed animal carcinogen with unknown relevance to humans
Carcinogenicity
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Components of this product have been identified as having potential environmental
concerns.
Ecotoxicity
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12. Ecological Information
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Ethylene Glycol Monobutyl
Ether
Ecotoxicity - Freshwater Fish Species Data
111-76-2 96 Hr LC50 bluegill: 1490 mg/L (static);24 Hr LC50 goldfish:1650 mg/L
Ethylene Glycol Monobutyl
Ether
Ecotoxicity - Water Flea Data
111-76-2 24 Hr LC50 water flea: 1720 mg/L
Environmental effects
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Dispose of waste material according to Local, State, Federal, and Provincial
Environmental Regulations.
Disposal instructions
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13. Disposal Considerations
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Material name: MIL-CLEAN
Material ID: 1088 Revision date: 21-APR-2006 Print date: 21-APR-2006 3 / 5
MSDS US
Department of Transportation (DOT) Requirements
Corrosive liquid, basic, inorganic, n.o.s. (SODIUM
SILICATE)
8
UN3266
III
B10, T14, TP2, TP27
None
201
243
154
Additional information:
Basic shipping requirements:
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
ERG number
Proper shipping name
Hazard class
UN number
Packaging group
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14. Transport Information
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IATA
Corrosive liquid, basic, inorganic, n.o.s. (SODIUM
SILICATE)
8
3266
III
Basic shipping requirements:
Proper shipping name
Hazard class
UN number
Packaging group
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IMDG
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
(SODIUM SILICATE)
8
3266
III
88
C5
8
g/cc
Additional information:
Basic shipping requirements:
Hazard ID
Item
Labels required
Transport Category
Proper shipping name
Hazard class
UN number
Packaging group
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Ethylene Glycol Monobutyl
Ether
CERCLA/SARA - Section 313 - Emission Reporting
111-76-2 1.0 Percent de minimis concentration (applies to R-(OCH2CH2)n-OR' ethers, where
n = 1,2, or 3, R=alkyl C7 or less or R = phenyl or alkyl subst. phenyl, R' = H or alkyl
C7 or less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
Ethylene Glycol Monobutyl
Ether
FDA - Direct Food Additives
111-76-2 21 CFR 173.315
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
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15. Regulatory Information
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Yes 29 CFR 1910.1200 hazardous
chemical
Occupational Safety and Health Administration (OSHA)
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None CERCLA (Superfund) reportable
quantity
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Material name: MIL-CLEAN
Material ID: 1088 Revision date: 21-APR-2006 Print date: 21-APR-2006 4 / 5
MSDS US
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
Superfund Amendments and Reauthorization Act of 1986 (SARA)
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No Section 302 extremely
hazardous substance
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Yes Section 311 hazardous chemical
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No
Yes
No
No
Yes
Yes
No
No
No
No
Yes
Inventory status
Country(s) or region On inventory (yes/no)*
Australia
Canada
Canada
China
Europe
Europe
Japan
Korea
New Zealand
Philippines
United States & Puerto Rico
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
Inventory name
Australian Inventory of Chemical Substances (AICS)
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)
Inventory of Existing Chemical Substances in China (CCS)
European Inventory of New and Existing Chemicals (EINECS)
European List of Notified Chemical Substances (ELINCS)
Japanese Inventory of Existing and New Chemical Substances (ENCS)
Korean Inventory of Chemicals (KICS)
New Zealand Inventory
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Toxic Substances Control Act (TSCA) Inventory
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The product is classified and labelled in accordance with EC directives or respective
national laws.
International regulations
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Ethylene Glycol Monobutyl
Ether
Massachusetts - Right To Know List
111-76-2 Present
Ethylene Glycol Monobutyl
Ether
New Jersey - Right to Know Hazardous Substance List
111-76-2 sn 0275
Ethylene Glycol Monobutyl
Ether
Pennsylvania - RTK (Right to Know) List
111-76-2 Present
This product does not contain a chemical known to the State of California to cause
cancer, birth defects or other reproductive harm.
State regulations
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Health: 3*
Flammability: 1
Physical hazard: 0
Personal protection: H
HMIS ratings
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16. Other Information
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Health: 3
Flammability: 1
Instability: 0
NFPA ratings
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The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless specified in the
text.
Disclaimer
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Cheryl Hood US preparer
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04-21-2006 Issue date
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Material name: MIL-CLEAN
Material ID: 1088 Revision date: 21-APR-2006 Print date: 21-APR-2006 5 / 5
MSDS US