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Environmental geophysics is concerned with the location, delineation and monitoring of subsurface hazards, regardless of their causes. It can have major socio-economic impacts at all scales of humanactivity. Environmental geophysics has a bright future provided geophysicists are willing to meet these challenges, if not, other non-specialists will increasingly enter the field.
Environmental geophysics is concerned with the location, delineation and monitoring of subsurface hazards, regardless of their causes. It can have major socio-economic impacts at all scales of humanactivity. Environmental geophysics has a bright future provided geophysicists are willing to meet these challenges, if not, other non-specialists will increasingly enter the field.
Environmental geophysics is concerned with the location, delineation and monitoring of subsurface hazards, regardless of their causes. It can have major socio-economic impacts at all scales of humanactivity. Environmental geophysics has a bright future provided geophysicists are willing to meet these challenges, if not, other non-specialists will increasingly enter the field.
In its broadest sense, environmental geophysics is
concerned with the location, delineation and monitoring of
subsurface hazards, regardless of their causes. The information provided is normally one input to an environmental riskassessment which can have major socio- economic impactsat all scales of humanactivity. Prevailing human tolerance to environmental hazards varies in intensity and geographic location and essentially controls demand for environmental geophysical services. In North America over the past decade in Greenhouse (1991) has notedthatthe developmentof environmental geophysicshas Fig. 1 (modified from Smith, 1992) shows some major environmental hazards fromthe entire spectrumof hazards. These have been qualitatively scaled according to their impacts, which may be intense and local (e.g. volcanic eruption) or diffuse and widespread (e.g. groundwater pollution). Also the degree of direct human responsibility for the hazard may range from involuntary i.e. beyond human control, to voluntaryi.e. controllable. ConsideringFig. 1 from today's perspective there is little doubt that environmental hazards are increasingly manmade, increasingly voluntary and diffuse intheir impact. Natural hazards and disasters are not simply geophysical events but result fromthe interactionof physical and social forces. They are an integral part of human history since people routinely make environmental appraisals and value judgements on the natural processes whenever they settle land or use its resources. Paradoxically, while science and technology have made many people's lives safer and healthier, their by-products have superimposed significant man-made or technological hazards on these natural hazards. Mankind is now at risk from natural geophysical events, such as earthquakes and volcanic eruption, and fromindustrial pollutionwhose accumulated wastes release toxic substances into the environment. Prime importance is nowgivento minimisingenvironmental riskand avertingthe realizationof such risk, environmental disaster. Introduction It is concluded that environmental geophysics has a bright future provided geophysicists are willing meet these challenges, if not, other non-specialists will increasingly enter the field as has beenthe case in NorthAmerica. DIFFUSE VOLUNTARY FIGURE1: Spectrum of Geophysical Hazards underground mining infrastructure failure soil contamination earthquake volcanic eruption groundwater pollution INTENSE INVOLUNTARY NATURAL-------MANMADE Conventional geophysical methods havehadlimitedsuccess in delineating hydrocarbon LNAPL and DNAPL contamination, both major pollutants. InSouthAustralia, the extentof aplume producedbya largediesel oil (LNAPL)spill was mapped with a new method of Radiowave electromagnetic profiling method (R-EM) which overcomes many of the limitations of conventional electromagnetic induction andground probing radar methods. Salinisationofagricultural lands is arguably Australia's major environmental problem. A dryland salinity study in Victoria demonstrates the process by which electromagnetic responses of soils can be expressed in terms of crop productivities for appropriate plant species. This information is of direct useto farmers, land managers and agronomists. There are two major challenges for environmental geophysicists, firstly, to understand socio-economic and environmental factors which govern the demand for their services and, secondly, to use improved methods and develop practices which more effectively address environmental problems. Field studies on major environmental problems providesome perspectiveon these challenges. Modern civilizations are at risk from natural geophysical events and from industries whose accumulated wastes release toxic substances into the environment. These environmental hazards are increasingly man-made, increasingly voluntary and diffuse in their impact. Environmental geophysics addresses the quantification and monitoringof subsurfacehazards, irrespectiveof their origin. Abstract: Dr. Robert J. Whiteley Affiliation: Principal Geophysicist Coffey Partners Intemational Ply. Ltd. 12 Waterloo Rd., North Ryde NSW 2113, Australia Environmental Geophysics: Challenges and Perspectives 189 Exploration Geophysics (1995)25, 189-196 Clearly, an understanding of the controlling environmental and socio-economic tolerance factors operating at a particular site is necessary for successful application of environmental geophysics. This may also explain why geophysicists have not yet effectively made the transition In practice, human sensitivity to environmental hazards is controlled by the combination of physical exposure, representing the range and statistical variability of an environmental factor at a specific site, and human vulnerabilityrepresentingthe rangeof social toleranceat the same site (Smith, 1992). Using a similar schematic approach, Fig. 3 shows some examples of the changes in human sensitivity to a single factor environmental hazard over time. In all three cases (a,b and c, Fig. 3) the risk of environmental disaster increases with time. In Fig. 3a, a constant band of tolerance persists, however, the average value increases with time. In Fig. 3b the average value for thefactor remains relativelyconstantbutvariability becomes greater. In Fig. 3c neither the variability nor the average value changes, however, human tolerance decreases with time. Social and economic activity is geared to the complex interaction of environmental factors in which each factor operates over time within an acceptable range and close to its average value. Fig. 2 demonstrates variations of a single environmental factor which maybecomea hazardover time, e.g. the level of groundwater contamination. The shaded area represents an acceptable range of variation or human tolerance within which the level of contamination does not pose a health hazard. However, if the level exceeds the tolerance threshold then the factor imposes a stress on societyand becomes anenvironmental hazard. The intensity of the hazardis determinedbythe peakdeviationbeyondthe thresholdandthedurationbythe lengthof timethe threshold is exceeded. Both peak and duration exert powerful influences on society's attitude to the hazard. This may require a rapid and effective response from a team of technologists which includes geophysicists. Socio-economic factors Based on their experience, Wruble et al. (1986) also conclude that different investigators may obtain misleading data from incorrect or improper use of certain geophysical techniques over waste sites. Similarly, Whiteley and J ewell (1992) established, by direct excavation, that interpretations of Ground Probing Radar data by supposed experts at a waste site in western Sydney were erronous. Considerationof these experiences and manyothers in the unpublished literature demonstrates that there are two principal challenges for geophysicists wishing to be involvedwith environmental problems i.e, - to better understand socio-economic and environmental factors and their inter-relationships, - to develop improvedgeophysical methods and practices. may require modification to produce useable data over waste sites and that proper training of operators and interpreters is essential. WHITELEY FIGURE 2Human Sensitivity to a Single Environmental Factor (modified from Smith, 1992) FIGURE 3 Examples Showing how Environmental Hazards Can Arise Over Time. Constant Tolerance, Diminishing Tolerance FIGURE 3 "TOL ERANCERANGE c B A FIGURE 2 --AVERAGE TOL ERANCE RANGE TIME Other workers (e.g. Wheatcraft et al. 1984) have observed that conventional geophysical hardware and procedural methods developed in petroleum and mineral exploration During the same period the U.S. Environmental Protection Authority (EPA) has recognised that not all available geophysical methods for subsurface characterisation are applicable to studies at waste disposal sites, a major environmental problem. Inorder to assure geophysical data quality and standardise practice the EPA has attempted to define those methods which are useful (Benson et. aI., 1984). Having similar concerns, the US Geological Survey (USGS) has produced expert advisor software (Olhoeft, 1992a) specifically designed to assist non-geophysicists in the use of geophysics at hazardous waste sites. taken place mainly outside the established geophysical community and that there are many people calling themselves environmental geophysicists who lack appropriate qualificationsand experience. 190 Remediation measures for the soil salinity problem are required at both the regional and individual farm level. For these to be effective both the extent and severity of the problem must be defined. Remote sensing (Landsat imagery) has been successful in delineating and discriminating salt affected land on a regional scale (e.g. Wheaton et al., 1992). Also airborne and ground geophysics (EM, magnetics and resistivity) have assisted with land management by identifying geological and Salt contamination of soils and salinisation of agricultural land affects productivity and the financial viability of many farmers. This formof land degradation is widely believedto be the major environmental problem for Australia's agricultural industry.The salinisationprocess is not a natural occurrence but has developed since European settlement dueto extensiveclearingof nativevegetationin groundwater recharge and growing areas. Increased recharge and a rising watertable have activated salts in the deeper soil profile bringing them to the root zone and expanding salt affected areas. Over-irrigation and the sowing of shallow rootedpasture haveworsenedthis problemin many areas. Land degradation and dryland salinity The following examples illustrate the application of environmental geophysicsto majortechnological hazards i.e. salinisation of agricultural land and hydrocarbonpollution of urban environments. Field examples For example, ground vibrations from heavy traffic which produce surface seismic waves can be greatly reduced by using downhole detectors and surface-to-borehole seismic methods. This approach was used by Whiteley and Love (1990) to locate shallow abandoned mine workings which posed an environmental hazard to proposed residential developments adjacentto busy roads. Also as many sites are within or close to developed areas, conventional geophysical methods i.e. seismic, resistivity, electromagnetics and magnetics are frequently subject to high levels of vibrational, electrical and electromagnetic interference. These influences, in addition to subsurface factors, may render conventional geophysical methods inapplicable or may necessitate modification and trialing of different methods. Available geophysical methods and practices for environmental studies of contaminated lands derive from related applications such as groundwater and engineering geophysics. However, as Wheatcraft et at. (ibid.) and Whiteley and J ewell (ibid.) have noted such conventional approaches may be inappropriate or inadequate when applied to technological hazards for land modified in the recent past by deliberate or accidental human action rather than by geological processes. Current methods and practice 191 J ewell et al, (1993) have noted that health risk assessment requires direct statistical sampling of a site, which is not without controversy (Ferguson, 1992), and a multi- disciplinary approach. Environmental geophysicists are members of a teamof specialists whose role it is to locate, delineate and quantify property variations in subsurface materials or groundwaters caused by past human practices including waste disposal and industrial accidents. They are also expected to monitor variations in these features resultingfrommigrationof pollution plumes or as a result of remediationactivities. One difficulty is that there is no universally accepted definition of what constitutes contaminated land also contamination can be subtle e.g. decreased agricultural productivity due to salinisation. The National Health and Medical Research Council (NHMRC, 1991) defines contaminated land as "land which because of previous or present uses at or near the site, contains materials that give riseeither directlytoor indirectlyto long-termadverseeffects to health". This is a very general definitionwhich apart from providing some geographic limitations does little to assist environmental geophysicists. The socio-economic factors associated with technological hazards are somewhat easier to predict than for natural hazards as there is a worldwide trend of decreasing tolerance (Fig. 3c). Also the bulk of current attention is focussed on assessment of land and groundwater contamination which commenced with industrialisation and large scale land clearing. Technological hazards Such disasters create an increased public perception or decreased tolerance to earthquake risks (Fig. 3c) and demonstratethe needfor improvedseismic riskassessment. This should incorporate comprehensive microzonation studies taking into account existing tectonic features, local soil conditions and engineering structures (Poulos, 1991). Australia has yet to complete such studies and, clearly, environmental geophysicists will have a major role to play once publicdemand asserts itself. Significant socio-economic factors and patterns are not always easy to identify in the case of natural hazards. Fortunately, Australia has not experienced a catastrophic natural disaster, however, the Newcastle earthquake which struck on December28, 1989demonstratedour vunerability to natural hazards. This was the first fatal earthquake in Australia since Europeansettlement and although classified as only moderate, measuring 5.6 on the Richer Scale, it resulted in 12 deaths and total damage of more than $ 1 billion (Slonget al., 1990). Natural hazards frompetroleumandmininggeophysics areas, which operate in very restrictedeconomic frameworks andwhich dominate the geophysical profession. ENVIRONMENTAL GEOPHYSICS: CHALLENGES AND PERSPECTIVES TABLE 1 Salinityclassifications, relationshipsto plantsensitivity, productivity,electrical conductivity(fromNorman,1990) +EC1.5determinedona1soil:5waterextrat *ECedeterminedonasaturationextract(6.4xEC1.5). Groupings ofCropswith Rootzone SalinityLevels(For Corresponding Different Tolerances to Minimum10%YieldLoss) SalinityStatus Rootzone Salinity TDS EC1.5+ ECe* Class (ppmdry (dS /m ) (dS /m ) soil) SENSITIVE CROPS <1800 <0.60 <3.8 LOW (e.g.Whiteclover, Sub- clover) MODERATELY TOLERANT 1800 0.60 3.86.5 MODERATE CROPS 3000 1.01 (e.g.Paspalum, Shaftal Clover, Ryegrass, Wheat) TOLERANT CROPS 3000 1.01 6.58.6 HIGH (e.g.Puccinellia, TallWheat 4000 1.35 grass, Millet) HIGHLYTOLERANT CROPS>4000 >1.35 >B.6 EXTREME (2) ECe(o.zcm)= c d Ea(o.zcm) Over the selected depth interval (0to z cm) the averaged ECa(O-z ern) is then regressed against the averaged ECe (0. z em). i.e. For this procedure to be accurate ECa versus ECe calibrations must be obtained for each soil layer and type in the area. Normally collected soil samples are grouped into a number of soil types based on clay percentage and also into a number of soil moisture groups based on gravimetric moisture contents. Moisture conditions greater than 20%on a gravimetric basis are recommended for accurate calibrations (Norman, ibid.). In the field ECa measurements at the soil sample locations are best made using a simplified resistivity logging device (called a Rhoades or EC-probe) designed by Rhoades and van Schilfgaarde (1976). Wenner resistance readings are taken with this probe at each depth (to 60ern) and converted to ECausing factors obtained by submerging the probe inan extended container filled with solutions of known conductivity. where a and b are constants which depend essentially on soil texture and clay content respectively. This relationship is not strictly correct for low salinity waters and Nadler and Frenkel (1980) have shown that for each soil the ratio between ECa and ECw (the conductivity of the pore water), which is closely related to ECe, is only linear for ECwgreater than 3.5dS/m. .(1) ECa = aECe +b Rhoades (1979) has shown that for a given soil with a standard water content, in practice, taken at field capacity there is a linear relationship between ECa and ECe, i.e- WHITELEY The laboratory methods for determining salinity are costly and time consuming, however, they are essential for calibration of apparent conductivity (ECa) measurements made with resistivity or electromagnetic geophysical methods. As most soil minerals are insulators and ECa of soils depends on a number of soil properties, i.e, porosity, moisture content, temperature, colloid (clay) content together with the concentration of dissolved salts or soil salinity which we wish to determine. In order to determine the salinity status of an area all conductivity measurements on extracts must be related to soil salinity classes. These classes are based on the response of pasture and/or crop species to soil salinity at various levels which, inturn, will depend on the existing level of soil salinity and current land use. More than two salinity classes are needed for these measurements to be of real value. Table 1 (from Norman, 1990) shows an example of salinity classifications and relationships to plant sensitivity, productivity and electrical conductivity. In this case ECe= 6.4 ECe 1:5but will vary according to soil type. Total Dissolved Salt (TDS) ranges are also shown for compa ison. Traditional direct methods for determining soil salinity in the root zone are laboratory based and use an extract of soil water containing a dilution of the soluble salts existing inthe natural soil. Salt concentration or salinity is determined on the extract by electrical conductivity (EC) measurements (expressed in deciSeimens per metre). There are two accepted methods for obtaining this extract. The first, which provides ameasure of the soluble salt per unit volume of soil is obtained by mixing one part soil to five parts water and removing the extract for EC measurement after settling. The conductivity obtained is referred to as ECe 1:5. The second method is to carefully saturate the soil sample and remove the extract under vacuum. This is known as the saturated extract and the conductivity obtained is referred to as ECe which is indicative of the soluble salt concentration in the most dilute soil water situation from which plants must obtain water for growth. A conversion between these two measures of salinity can be obtained, however, this is highly dependent on soil texture. Although the former measurement is more convenient (Le. ECe1:5)the latter measurement (Le. ECe) is more commonly used to relate plant response to soil salinity. Unfortunately, most environmental geophysical studies completed for salinity purposes have focussed on the deeper regions of the earth whereas farmers, land managers and agronomists require detailed information on the soil profile, particularly on the plant root zone to depths of 0 to 60 cm. These people also require that the geophysical measurements be related to familiar quantities and to pasture and crop responses for those species actually present in the area. This places additional demands on environmental geophysicists, however, the procedures by which this may be achieved are described below. groundwater controls on salinisation, locating saline groundwaters and recharge and discharge areas ( e.g. Williams and Baker, 1982; Street and Engel, 1990; Humphreys et aI., 1990; Street, 1992). 192 For reconnaissancethe EM 38 field measurements maybe made at close intervals along a profile studies or in a grid if an area is to be covered. Inthe latter case, about 11Ha per hour can be coveredwith a 30 60 mgrid. where e and f are the regression equations. Separate regressions must be performed according whether the profile is leached, invertedor normal so that accurate EMv values are also needed. Also all the EM38 readings must be corrected for soil temperature which increases conductivity approximately2% for every 1 degree Celsius rise in temperature. This is achieved by making regular temperature reading in the field using an insertion probe duringthe EM 38 survey. The two regression equations (2) and (3) provide the requiredrelationshipsbetweenthe EM38 readings and ECe values which may in turn be used to predict salinity and productivity of the soils. Fig. 5 schematically illustrates the procedures describedabove. (3) ECa (O-z em) =e f EMh Since the horizontal dipole inherentlyhas a shallower depth of investigation (Fig. 4) and the electric current flow directions are similar to those usedto obtain ECa (O-z cm) with the EC-probe, EMh values may be regressed against ECa (0-z cm) values accordingto Oncethe depth interval (0- z cm) is establishedfor the area the "depthweighted"EMhandEMvvalues maybe calculated usingthe curves inFig. 4andthe ECafield values measured with the EM 38. Froma practical viewpoint, if the vertical dipole value obtained with the EM38 (EMv) is greater than the horizontal dipolevalue (EMh)i.e. EMy!EMh<=1.05, then the soil conductivityis greaterat depthin thesubsoil thanthe rootzone and the soil profile is termed "leached". In the opposite situation the profile is said to be "inverted" when EMy!EMh>1.05. When EMy!EMhis close to 1.05, the soil profileis termed"uniform"andat individual sites itis possible for profiledescriptions to change duringthe year as a result of alternatingleachingand capilliaritycycles. Over a wide range of ground conductivities the EM 38 operates in the low induction number domain in which the magnitude of quadrature component of the received signal provides ECa directly (in miliiSeimens/metre). However, this ECa represents the total signal received from all depths sensed by the EM 38 and the signal contribution from the rootzone must be extracted. Fortunately, the low induction number domain allows the signal contribution below any depth in either uniform or layered earths to be simply computed. The cumulative relative signal contribution from materials below any depth (z) is independent of the magnitude of conductivity and is a single valued function of depth, R(z), which depends on the coil configuration(Fig. 4 from McNeill, ibid.). An "effective depth of investigation", for the EM 38 taken as approximatelythe skin depth, is about 1.5mfor the vertical dipoleconfigurationandabout half this for the horizontal dipole configuration. For the vertical dipole 22%of the total signal comes fromthe top 0.4 mof soil and 78%frombelow. For the horizontal dipole, 53%comes from above and 47%frombelowthe top O.4m. Direct soil sampling and measurement is impractical to extendto an entire area, however, electromagnetic induction methods offer the means by which ECa values may be accurately and rapidly obtained between sample locations. Currently, the Geonics EM 38 Terrain Conductivity Meter (McNeill, 1980) is the only suitable commercial instrument suitablefor this purpose. The EM38 operates at a frequency of 13.2KHz andthe transmitter-receivercoil spacing(1m) to achieve the shallow depth of investigation required. Either vertical or horizontal co-planar configurations may be used. While this method is of critical importance for correlation direct sampling results with indirect geophysical measure- ments it is also time consuming and costly. Careful consideration must also be given to the number sample locations, in practice, the number of samples and resistivity measurements requiredwill depend on the actual variability of field conditions, (Norman ibid.). where c and d are the regressioncoefficients. As a result of the non-linear effects mentioned earlier it is not uncommon for the above equationto predict negative ECe values at low ECa levels. However, this does not cause a problemsince accuracy is not required for low ECe values as the soils would normallybe inthe lowsalinityclass (Table 1). Figure4Cumulative RelativeContribution to the EM Signal Measured with an EM38in Various Configurations (after McNeill, 1980) DEPTH Z (rn) 2.6 3.0 1.4 1.8 2.2 0.2 0.6 1.0 CUMULATIVE RELATIVE CONTRIBUTION TO EM SIGNAL 193 ENVIRONMENTAL GEOPHYSICS: CHALLENGES AND PERSPECTIVES Many studies have shown that, following underground release, LNAPL hydrocarbons tend to migrate vertically under gravitythrough the dry or partiallysaturatedzone. As the hydrocarbons have a lower density than water they displace any residual moisture within this zone. Above the water table, the vertically migratinghydrocarbons encounter the capilliaryfringe which is thicker infine-grainer materials. At this level there are normally insufficient fluid pressures away from the immediate source of the spill to continue vertical migration. The LNAPL become "perched" immediatelyabove the watertable and move laterallyonthe capilliary fringe frequently in the direction of regional groundwater flow. Local permeability variations exert a considerable influence causing extended movement or "fingering" of the plume in the more permeable materials For safety and asthetic reasons fluid hydrocarbons are commonly stored in underground tanks and supplied by buried pipelines. Leaking tanks or supply lines can directly contaminate groundwater and pose a major environmental hazard. Shouldleaks occur, the initial problems areto locate sources and to define the lateral extent of the pollution plume. Once this has been achieved and remediation is undertaken, the problemis to monitorthe plumeas recovery proceeds. 8 Throughout the world large quantities of hydrocarbon products are present in shallow soils mainly within urban areas. These rangefromlocalisedconcentrations near petrol stations and small industry sites to large concentrations at refineries, fuel depots, and airports. In high concentrations these organic fluids pose a major environmental hazard to surface water and groundwater resources in their liquid phaseand a direct healthhazard intheir vapour phase. Hydrocarbon contamination Actual hydrocarbon contaminants are found in many different forms, concentrations and densities. They can be presentas light, non-aqueousphaseliquids (LNAPL)suchas tolueneand benzeneaboveor atthe water table or as dense non-aqueousphaseliquids (DNAPL)suchasTrichloroethane (TCE) and Tetrachloroethane (PCE) belowthe water table. Toluene and benzene are major constituents of liquid fuels and oils. TCE and PCE are used extensively in industries which requiremetal finishingand garment cleaning. Fig. 6 shows an application of the above procedures to obtain ECe(0-60 em) froman EM38values measuredalong a reconnaissance profile in the Wimmera region of Victoria. About 185 EM 38 readings were taken along the 7.4 km profile and were calibrated with the EC probe at 10 soil sample locations. At this site the profile shows soil salinity values fall mainly into the very lowclass (Table1) and may be correlated with relative productivity of plant species common to the area using Table 2 which is based on published datafor Victorianconditions. This informationis of direct use to farmers and agronomists and shows high productivities canbeexpectedfromthecommoncrops inthe area apart from one local regionnear Ch. 0.4 Km. WHITELEY TABLE 3 Examples of Dielectric Constants of earth materials (from Whiteley and J ewell, 1991) MATERIAL RELATIVEDIELECTRIC PERMITIIVITY Air 1 FreshWater 81 SeaWater 81 Sand(dry) 4 Sand(35%water) 10-30 Sand(6-30%kerosene 3 Clay 10 Soil 30-50 Sandstone 6 Shale 7 Basalt 8 Granite 7 TABLE 2 Correlation of soil salinities with plant species common to Victoria, (Norman, ibid) ECe Perennial ANNUAL UCERNE WheaV Millet Faba (dS/mj) pasture pasture Barley bean <1.8 100-95 100-95 100 100 100 100 1.8-3.8 95-80 95-73 100-85 100 100 100-80 3.8-6..5 80-55 75-50 85-70 10090 100 80-55 6.5-8.6 55-35 50-25 70-50 90-75 10080 55-35 >8.6 <35 <25 <50 <75 <80 <35 FIGURE 6Calibrated EM38Measurements, Soil Types and Recommended Land use from Salinity Assessment. 2-13- Survey marker points ECe Values 2 6 4 Distance (kilometres) o II II 1213 10 7 ~ 2.5 rJ l ~ 2 3 .. I I o 2 w i ~ ~ 1.5 Ii II -: I I 1 131.1 2 1 ROOTZONE SOIL SALINITY MEASUREMENTS Transect A FIGURE 5 Outline of the Method for Dryland and Salinity Assessment using Both Field and Laboratory Measurements. c.d.e.f Regression Constants FIELD 'r"OO"""~ >C. rec., Ecr'Obe EC'IO."ml=cdEC,IO."ml EM38 ------- ,J ~~ "'''M, LABORATORY DRYlAND SALINITY ASSESSMENT 194 Fig. 7shows a typical radiowaveprofileobtainedwith a loop spacing of 5m across the diesel plume. The interpreted section, derived from subsequent test pits, is also shown. Clearly the fluid-phase diesel plume is defined by a "low" anomaly. The character of this anomaly reflects the level of contamination with the greatest reduction in field intensity occurring where the plume is shallowest, thickest and most concentrated. The steep-sided anomaly indicates that hydraulic gradients aroundthe margins of the plumearealso steepwhich is consistentwiththe model for lateral migration of LNAPL plumes. In South Australia, a review of inventory records and fuel consumptionat a major diesel train refuellingstationover a 2 year period revealed a discrepancy of over 500,000 litres. Subsequent pressure testing of buried delivery pipes indicated a majorleakbetweenthefinal pumpingstationand dispensing points. Flow fromthe main storage tank, which was found to be intact, was interruptedand several test pits were dug along the delivery line. Clayand sandysediments were encountered together with diesel product at several locations generally within 2mof the surface belowthe depth the sediments were saturated. The problemwas to define the extent of LNAPL contamination at the site which was traversedbyrail lines, buriedservices, concreteandbitumen roads as well a various buildings. EM31 profilingand GPR proved ineffective, however, the combination of R-EM profiling with the GRC-2 instrument and follow-up, drilling andtest-pittingwas ableto delineatethe plume. stations spacings of 0.5 to 1m to be used for detailed studies. Figure 7 GRC-2 Profile with Idealized Subsurface Conditions Based on Test Pit Results . CHAINAGE!ml 50 150 195 At the frequency of R-EM method the dielectric constant of earth materials is typically in the range of 1 (air) to 81 (water) although certain saturated clays can have larger values (Arulanandan et aI., 1994). The dielectric constant is greatly reduced by the addition of hydrocarbons. As shown inTable 3 (after Whiteley and J ewell, ibid.) the presence of 6to 30% kerosene, an LNAPL, inpartiallysaturated sand(3 - 5% water) could be expected to reduce the dielectric constant bya factor of 3to 6. This factor would be greater if the sandwas fully saturatedor if the hydrocarbonsaturation was increased. Other common hydrocarbons have similar lowdielectric constants. The GRC-2 instrument is similar in operation to other frequency domain electromagnetic systems and is described by Whiteley and Zaderigolova (ibid.). Small mobile transmitter and receiver loops are maintained in a null coupled configuration with a vertical loop transmitter and horizontal loop receiver which measures vertical magnetic field intensity (Hz) in relative units. These loops are aligned so that the plane of the transmitter loop passes through the axis of the receiver loop and are maintainedat a constant spacing, typicallyfrom5to 15mthroughout the study. Transmitter power is also kept constant throughout the survey and it is not uncommon for An R-EM method (GRC-2) has been under development in Ukraine for a number of years specifically for engineering and environmental problems (Whiteley and Zaderigolova, 1993). This method operates at about 1.2 MHz and has a maximumdepth of investigationof about 30 mthrough soils and weathered rocks. At this frequency the response of the GRC-2 systemis dominatedby dielectric propertyvariations and surrounding metals, which adversely affect induction methods, and conductive soils, which severely attenuate GPR signals, have little influenceon the GRC2system. The detectionof hydrocarboncontaminants by conventional electrical, electromagnetic induction and ground probing radar is very difficult and is not routinely performed (Olhoeft,1992) eventhough electrical and dielectric property contrasts are substantial (Kutrubes, 1986). Electromagnetic induction methods, such as the EM 38 discussed in the previous section, operate in the audio to Very Low Frequency (VLF) range from about 50 Hz to 25 kHz and respond to subsurface variations in electrical conductivity. Ground probing radar (GPR) methods operate at much higherfrequencies intheVHF andUHF rangefromabout 13 to 1000 Mhz and respond mainly to variations in dielectric permittivity. Radiowave methods (R-EM) operating in the frequency rangefromabout30kHzto5Mhz respondto both properties but have beenlargelyneglectedas a geophysical tool apartfromthe Radio ImagingMethod, which operates in the frequency range of 50 to 520 kHz and is used in coal exploration (Stolarczyk, 1990). such as backfilleddrains. As the hydrocarbon layer thickens pore pressures increase, driving these fluids into the capilliary fringe and eventually forming a hydrocarbon-water interface. Further addition of hydrocarbons eventually causes a depressionof the water table andthe development of a "pod-like" plume. ENVIRONMENTAL GEOPHYSICS: CHALLENGES AND PERSPECTIVES Nadler,A. and Frenkel, H. 1980. Determinationof Soil Electrical Conductivity Measurements by the four-electrode method. Soil Sci. Soc. Am. Proc., 44,6, 1216-1221. 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References A major environmental problemof salinisationof agricultural land can be effectively addressed by careful calibration of electromagnetic induction measurements which allow results to be provided to farmers, land managers and agronomists in terms of likely crop productivities for appropriate plant species which are of direct use. Another major environmental problemof groundwater contamination by LNAPLand DNAPLhydrocarbonspills maybe addressed with a new method of radiowave electromagnetic profiling which responds mainly to the large dielectric contrasts caused bythe introductionof these contaminants into soils and groundwater. The interactionof socio-economicand environmental factors governs the demand for environmental geophysics. The challenges for geophysicists, if they wish to address the expanding spectrum of environmental problems, are to better understand these factors and to develop improved methods and practices. If geophysicists are prepared to meet these challenges environmental geophysics has a bright future, if not, other non specialists will increasingly enter thefield as has beenthe case in NorthAmerica. Conclusions 196