Liquid Solution

HEAD OFFICE :MUMBAI / AKOLA /NASHIK /DELHI / KOLKATA / LUCKNOW / GOA # 73
II T PACE -ians LIQUID SOLUTION ATM 2013

Q.1 C Q.2 C Q.3 C Q.4 B Q.5 A Q.6 C Q.7 B
Q.8 C Q.9 B Q.10 C Q.11 A Q.12 C Q.13 D Q.14 A
Q.15 D Q.16 C Q.17 A Q.18 D Q.19 B Q.20 D Q.21 D
Q.22 A Q.23 C Q.24 B Q.25 B Q.26 A Q.27 C Q.28 B
Q.29 D Q.30 C Q.31 B Q.32 B Q.33 C Q.34 A Q.35 D
Q.36 D Q.37 A Q.38 C Q.39 B Q.40 D Q.41 C Q.42 B
Q.43 C Q.44 A Q.45 D Q.46 A Q.47 D Q.48 C Q.49 C
Q.50 A

Q.48 Consider following terms:
(I) mK
b
(II) mK
b
i (III)
i
T
b
A
(IV) K
b
Terms which can be expressed in degree (temperature) are:
(A) III, IV (B) I, II (C) I, II, III (D) I, III
Q.49 Ratio of AT
b
/K
b
of 6% AB
2
and 9% A
2
B (AB
2
and A
2
B both are non-electrolytes) is 1 mol/kg in both
cases. Hence atomic masses of A and B are respectively:
(A) 60, 90 (B) 40, 40 (C) 40, 10 (D) 10, 40
Q.50 Which represents correct difference?
(I) (II)
(III)
(A) I, II, III (B) I, III (C) II, III (D) I, II

Q.41 At a temperature, total pressure in Torr of a mixture of volatile components A and B is given by
P =120 75 X
B
hence, vapour pressure of pure A and B respectively (in Torr) are:
(A) 120, 75 (B) 120, 195 (C) 120, 45 (D) 75, 45
Q.42 A mixture contains 1 mol volatile liquid A (
o
A
p =100 mmHg) and 3 mol volatile liquid B (
o
B
p =80 mm
Hg). If solution behave ideally, total vapour pressure of the distillate is approximately:
(A) 85 mm Hg (B) 86 mmHg (C) 90 mm Hg (D) 92 mmHg
Q.43 Moles of K
2
SO
4
to be dissolved in 12 mol water to lower its vapour pressure by 10 mm Hg at a
temperature at which vapour pressure of pure water is 50 m Hg is:
(A) 3 mol (B) 2 mol (C) 1 mol (D) 0.5 mol
Question No. 44 to 50 (7 questions)
Figure explains elevation in boiling point when a non-volatile solute is added to a solvent.
Variation of vapour pressure with temperature and showing elevation in boiling point.
Q.44 Given that AT
b
is the elevation in boiling point of the solvent in a solution of molality m then
0 m
Lt

|
|
.
|
\
| A
m
T
b is equal to:
(A) K
b
(molal elevation constant) (B) L
v
(latent heat of vaporisation)
(C) AS (entropy change) (D) x (mole fraction of solute)
Q.45 Elevation in b.p. of an aqueous urea solution is 0.52. (K
b
=0.52 mol
1
kg). Hence, mole fraction of
urea in this solution is:
(A) 0.982 (B) 0.0567 (C) 0.943 (D) 0.018
Q.46 A complex of iron and cyanide ions is 100% ionised at 1 m(molal). if its elevation in b.p. is 2.08 (K
b
=
0.52 mol
1
kg) then the complex is:
(A) K
3
[Fe(CN)
6
] (B) Fe(CN)
2
(C) K
4
[Fe(CN)
6
] (D) Fe(CN)
4
Q.47 Select correct statement:
(A) Heats of vaporisation for a pure solvent and for a solution are similar because similar intermolecular
forces between solvent molecules must be overcome in both cases.
(B) Entropy change between solution and vapour is similar than the entropy change between pure solvent
and vapour
(C) Boiling point of the solution is larger than that of the pure solvent
(D) All are correct statements

Q.35 The diagram given below represents boiling point composition diagram of solution of component A
and B, what is true among the following?
(A) The solution shows negative deviation
(B) A-B-interactions are stronger than A-A and B-B
(C) The solution is ideal solution (D) The solution shows positive deviation.
Q.36 Two elements A and B form compounds having molecular formulae AB
2
and AB
4
. When dissolved
in 20.0 g of Benzene, 1.00 g of AB
2
lowers f.p. by 2.3C whereas 1.00 g of AB
4
lowers f.p. by
1.3C. The molal depression constant for benzene is 5.1. The atomic masses of A and B are
respectively
(A) can't be predicted (B) 42.6, 25.5 (C) 30.60 (D) 25.5, 42.6
Q.37 Two beakers, one containing 20 ml of a 0.05 M aqueous solution of a non volatile, non electrolyte and
the other, the same volume of 0.03 M aqueous solution of NaCl, are placed side by side in a closed
enclose. What are the volumes in the two beakers when equation is attached ? Volume of the solution in
the first and second beaker are respectively.
(A) 21.8 ml and 18.2 mL (B) 18.2 mL and 21.8 mL
(C) 20 mL and 20 mL (D) 17.1 mL and 22.9 mL
Q.38 Insulin (C
2
H
10
O
5
)
n
is dissolved in a suitable solvent and the osmotic pressure p of the solution of
various concentration (in kg/m
3
) is measured at 20C. The slope of a plot of p against c is found to be
8.134 10
3
(SI units) The molecular weight of the insulin (in kg/mol) is :
(A) 4.8 10
5
(B) 9 10
5
(C) 293 10
3
(D) 8.314 10
5
Q.39 When only a little quantity of HgCl
2
(s) is added to excess KI(aq) to obtain a clear solution, which of the
following is true for this solution? (no volume change on mixing)
(A) Its boiling and freezing points remain same (B) Its boiling point is lowered
(C) Its freezing point is raised (D) Its boiling point is raised
(E) Its freezing point is lowered.
Q.40 An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour pressure of 1
atmat a certain temperature. Another mixture with 1 mole of A and 3 moles of B has a vapour pressure
greater than 1 atm. But if 4 moles of C are added to the second mixture, the vapour pressure comes
down to 1 atm. Vapour pressure of C, P
c
0
=0.8 atm. Calculate the vapour pressures of pure A and pure
B.
(A) P
A
0
=1.4 atm, P
B
0
=0.7 atm (B) P
A
0
=1.2 atm, P
B
0
=0.6 atm
(C) P
A
0
=1.4 atm, P
B
0
=0.6 atm (D) P
A
0
=0.6 atm, P
B
0
=1.4 atm
Question No. 41 to 43 (3 questions)
The partial vapour pressure of any volatile component of an ideal solution is equal to the vapour pressure
of the pure component multiplied by the mole fraction of that component in the solution

(A)
A
P / P and
A
P
) P P (
(B)
A
P / P and
B
P
) P P (
(C)
B
P / P and
A
P
) P P (
(D)
B
P / P and
B
P
) P P (
Q.32 Given P-x curve for a non-ideal liquid mixture (Fig.1). Identify the correct T-x curve for the same
mixture.
(A) (B) (C) (D)
Q.33 When 100 ml of 0.2M BaCl
2
(aq) is added to 100ml of 0.2M K
2
SO
4
solution, _______of K
2
SO
4
solution is lowered. Assume 100% dissociation of soluble salts and 100% precipitation of insoluble
ones.
(A) Freezing point (B) Boiling point (C) Vapour pressure (D)Osmotic pressure
Q.34 Solubility curves of four ionic salts X, Y, Z, W are given below :
In which case the value of DH
sol.
<0
(A) X (B) Y (C) Z (D) W.

Q.27 At 323 K, the vapour pressure in millimeters of mercury of a methanol-ethanol solution is represented by
the equation p =120 X
A
+140, where X
A
is the mole fraction of methanol. Then the value of
A
A
1 x X
p
lim
A

is
(A) 250 mm (B) 140 mm (C) 260 mm (D) 20 mm
Q.28 Assuming the formation of an ideal solution, determine the boiling point of a mixture containing
1560 g benzene (molar mass =78) and 1125 g chlorobenzene (molar mass =112.5) using the
following against an external pressure of 1000 Torr.
benzene
chlorobenzene
90
2200
100
t(c)
110 120
1800
1350
1000
540
400
300
200
Vapour
Pressure
(A) 90C (B) 100C (C) 110 (D) 120C
Q.29 The vapor pressures of benzene, toluene and a xylene are 75 Torr, 22 Torr and 10 Torr at 20C.
Which of the following is not a possible value of the vapor pressure of an equimolar binary/ternary
solution of these at 20C ? Assume all form ideal solution with each other.
(A)
2
1
48 (B) 16 (C)
3
2
35
(D)
2
1
53
Q.30 Observe the P-T phase diagramfor a given substance A. Then melting point of A(s), boiling point of A(l),
critical point of A and triple point of A (at their respective pressures) are respectively.
(A) T
1
, T
2
, T
3
, T
4
(B) T
4
, T
3
, T
1
, T
2
(C) T
3
, T
4
, T
2
, T
1
(D) T
2
, T
1
, T
3
, T
4
Q.31 Consider two liquids A & B having pure vapour pressures
A
P &
B
P forming an ideal solution.
The plot of
A
X
1
v/s
A
Y
1
(where X
A
and Y Y
A
are the mole fraction of liquid A in liquid and vapour phase
respectively) is linear with slope and Y intercepts respectively :

Q.21 A liquid mixture having composition corresponding to point z in the figure
shown is subjected to distillation at constant pressure. Which of the
following statement is correct about the process
(A) The composition of distillate differs fromthe mixture
(B) The boiling point goes on changing
(C) The mixture has highest vapour pressure than for any other
composition.
(D) Composition of an azeotrope alters on changing the external pressure.
Q.22 The vapour pressure of a saturated solution of sparingly soluble salt (XCl
3
) was 17.20 mm Hg at
27C. If the vapour pressure of pure H
2
O is 17.25 mm Hg at 300 K, what is the solubility of
sparingly soluble salt XCl
3
in mole/Litre.
(A) 4.04 10
2
(B) 8.08 10
2
(C) 2.02 10
2
(D) 4.04 10
3
Q.23 At 300 K, the vapour pressure of an ideal solution containing 3 mole of A and 2 mole of B is 600 torr. At
the same temperature, if 1.5 mole of A & 0.5 mole of C (non-volatile) are added to this solution the
vapour pressure of solution increases by 30 torr. What is the value of
o
B
P
?
(A) 940 (B) 405 (C) 90 (D) none of these
Q.24 The following graph represents variation of boiling point with composition of liquid and vapours of binary
liquid mixture. The graph is plotted at constant pressure.
Which of the following statement(s) is incorrect. Here X & Y stands for mole fraction in liquid and
vapour phase respectively
(A) X
benzene
=0.5 and Y
toluene
=0.2 (B) X
toluene
=0.3 and Y
benzene
=0.6
(C) X
benzene
=0.3 and Y
toluene
=0.4 (D) if X
benzene
=0.7 than Y
toluene
<0.3
Q.25 The freezing point depression of a 0.1 M aq. solution of weak acid (HX) is 0.20C.
What is the value of equilibriumconstant for the reaction?
HX (aq)
H
+
(aq) +X (aq)
[Given : K
f
for water =1.8 kg mol
1
K. & Molality =Molarity ]
(A) 1.4610
4
(B) 1.35 10
3
(C) 1.21 10
2
(D) 1.35 10
4
Q.26 The vapour pressure of an aqueous solution is found to be 750 torr at certain temperature 'T'. If 'T' is the
temperature at which pure water boils under atmospheric pressure and same solution show elevation in
boiling point AT
b
=1.04 K, find the atmospheric pressure (K
b
=0.52 K kg mol
1
)
(A) 777 (B) 779 (C) 782 (D) 746

Q.11 Assuming each salt to be 90 % dissociated, which of the following will have highest boiling point?
(A) Decimolar Al
2
(SO
4
)
3
(B) Decimolar BaCl
2
(C) Decimolar Na
2
SO
4
(D) A solution obtained by mixing equal volumes of (B) and (C)
Q.12 The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was added to
the solvent. The mole fraction of solute in solution is 0.2, what would be mole fraction of the solvent if
decrease in vapour pressure is 20 mm of Hg
(A) 0.2 (B) 0.4 (C) 0.6 (D) 0.8
Q.13 Elevation of boiling point of molar aqueous glucose solution (density =1.2 g/ml) is
(A) K
b
(B) 1.20 K
b
(C) 1.02 K
b
(D) 0.98 K
b
Q.14 A soluteS undergoes a reversible trimerization when dissolved in a certain solvent. The boiling
point elevation of its 0.1 molal solution was found to be identical to the boiling point elevation in
case of a 0.08 molal solution of a solute which neither undergoes association nor dissociation. To
what percent had the solute S undergone trimerization?
(A) 30% (B) 40% (C) 50% (D) 60%
Q.15 1.0 molal aqueous solution of an electrolyte A
2
B
3
is 60% ionised. The boiling point of the solution at 1
atm is (
1
) O H ( b
mol kg K 52 . 0 K
2

=
)
(A) 274.76 K (B) 377 K (C) 376.4 K (D) 374.76 K
Q.16 Which of the following plots represents an ideal binary mixture?
(A) Plot of P
total
v/s 1/X
B
is linear (X
B
=mole fraction of 'B' in liquid phase).
(B) Plot of P
total
v/s Y
A
is linear (Y
B
=mole fraction of 'A' in vapour phase)
(C) Plot of
total
P
1
v/s Y Y
A
is linear (D) Plot of
total
P
1
v/s Y Y
B
is non linear
Q.17 x mole of KCI and y mole of BaCl
2
are both dissolved in 1 kg of water. Given that x +y =0.1 and K
f
for
water is 1.85 K/molal, what is the observed range of AT
f
, if the ratio of x to y is varied ?
(A) 0.37
0
to 0.55
0
(B) 0.185
0
to 0.93
0
(C) 0.56
0
to 0.93
0
(D) 0.37
0
to 0.93
0
Q.18 Two liquids A & B forman ideal solution. What is the vapour pressure of solution containing 2 moles of
A and 3 moles of B at 300 K? [Given : At 300 K, Vapour pr. of pure liquid A (
o
A
P
) =100 torr,,
Vapour pr. of pure liquid B (
o
B
P
) =300 torr ]
(A) 200 torr (B) 140 torr (C) 180 torr (D) None of these
Q.19 A solution of x moles of sucrose in 100 grams of water freezes at -0.2
0
C. As ice separates the freezing
point goes down to -0.25
0
C. How many grams of ice would have separated?
(A) 18 grams (B) 20 grams (C) 25 grams (D) 23 grams
Q.20 FeCl
3
on reaction with K
4
[Fe(CN)
6
] in aqueous solution gives blue
colour. These are separated by a semipermeable membrane AB as
shown. Due to osmosis there is
(A) blue colour formation in side X.
(B) blue colour formation in side Y.
(C) blue colour formation in both of the sides X and Y.
(D) no blue colour formation.


Single correct
Q.1 Osmotic pressure of 30% solution of glucose is 1.20 atm and that of 3.42% solution of cane sugar
is 2.5 atm. The osmotic pressure of the mixture containing equal volumes of the two solutions will
be
(A) 2.5 atm (B) 3.7 atm (C) 1.85 atm (D) 1.3 atm.
Q.2 Mole fraction of A vapours above the solution in mixture of A and B (X
A
=0.4) will be
[Given :
A
P
=100 mmHg and
B
P
=200 mm Hg]
(A) 0.4 (B) 0.8 (C) 0.25 (D) none of these
Q.3 The exact mathematical expression of Raoults law is
(A)
N
n
P
P P
0
s
0
=
(B)
n
N
P
P P
0
s
0
=
(C)
N
n
P
P P
s
s
0
=
(D)
0
s
0
P
P P
=n N
Q.4 A mixture contains 1 mole of volatile liquid A (

A
P
=100 mm Hg) and 3 moles of volatille liquid
B (

B
P
=80 mmHg). If solution behaves ideally, the total vapour pressure of the distillate is
(A) 85 mm Hg (B) 85.88 mm Hg (C) 90 mm Hg (D) 92 mmHg
Q.5 Relative decrease in vapour pressure of an aqueous solution containing 2 moles [Cu(NH
3
)
3
Cl] Cl in 3
moles H
2
O is 0.50. On reaction with AgNO
3
, this solution will form
(A) 1 mol AgCl (B) 0.25 mol AgCl (C) 2 mol AgCl (D) 0.40 mol AgCl
Q.6 The van't Hoff factor i for an infinitely dilute solution of NaHSO
4
is
(A) 1/ 2 (B) 1/ 3 (C) 3 (D) 2
Q.7 Barium ions, CN and Co
2+
forman ionic complex. If that complex is supposed to be 75% ionised in
water with vant Hoff factor

i

equal to four, then the coordination number of Co
2+
in the complex can
be :
(A) Six (B) Five (C) Four (D) Six and Four both
Q.8 A 0.001 molal solution of a complex [MA
8
] in water has the freezing point of 0.0054C. Assuming
100% ionization of the complex salt and K
f
for H
2
O =1.86 km
1
, write the correct representation for
the complex
(A) [MA
8
] (B) [MA
7
]A (C) [MA
6
]A
2
(D) [MA
5
]A
3
Q.9 The vapour pressure of a solution of a non-volatile electrolyte B in a solvent A is 95% of the vapour
pressure of the solvent at the same temperature. If the molecular weight of the solvent is 0.3 times the
molecular weight of solute, the weight ratio of the solvent and solute are
(A) 0.15 (B) 5.7 (C) 0.2 (D) 4.0
Q.10 At a given temperature, total vapour pressure in Torr of a mixture of volatile components A and B is
given by
P
Total
=120 75 X
B
hence, vapour pressure of pure A and B respectively (in Torr) are
(A) 120, 75 (B) 120, 195 (C) 120, 45 (D) 75, 45

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HEAD OFFICE :MUMBAI / AKOLA /NASHIK /DELHI / KOLKATA / LUCKNOW / GOA # 73

II T PACE -ians LIQUID SOLUTION ATM 2013

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