NS 201 1

ST
SEM 2014-2015
LECTURE 2 CHEMICAL BASIS OF LIFE
Atoms
A. Lifes unique properties start with the properties of atoms.
1. Atoms are the smallest building block of all substances.
2. Atoms are composed of positively charged protons, negatively charged electrons,
and neutral neutrons.
. !rotons and neutrons are located in a central nucleus while electrons orbit the
nucleus.
". Atoms differ in their number of subatomic particles #protons, neutrons, and
electrons$.
%. &lements consist of atoms that share the same number of protons in their nucleus.
'. (he same elements e)ist in living organisms and the earths crust and seawater, but they
e)ist in different amounts.
*. +sotopes are elements with different numbers of neutrons in their nucleus.
1. ,ass number is a measure of the protons and neutrons in a nucleus.
2. -ome isotopes are radioactive, or radioisotopes, which means they are unstable, and
they degenerate.
&. .hy &lectrons ,atter
1. &lectrons are small but confer important properties to their atoms.
2. &lectrons sit in special and predictable orbits, orbitals, around the nucleus of an
atom.
a. (he farther an orbital is away from the nucleus, the higher the energy that the
electrons have in that orbital.
. A shell model is used to describe how the electrons e)ist in the orbital.
a. (he first shell holds two low/energy electrons.
b. (he more electrons an atom has, the more it fills the outer shells.
c. +f the outer shell of an electron is full, the molecule tends to be stable and non/
reactive.
d. +f an atom has vacancies in its outer shell, it will react with other molecules to
balance that outer shell.
0.+ons
1. &lectrons and protons both have charges that equally balance each other out.
2. 'hanging the number of electrons in an atom changes its overall charge and creates
an ion.
a. 'hlorine has 11 protons and 11 electrons and room for one more electron in its
outer shell. %y accepting one more electron, chlorine has a stable outer shell but
also gains a negative charge or 'l
/
.
b. -odium has 11 protons and 11 electrons or only 1 electron in its outer shell. +n
losing that one electron, sodium has a more stable outer shell and gains a
positive charge or 2a
3
.
From Atoms to Molecles
A. Atoms can interact with other atoms and form unions called bonds.
1. A molecule is a union of two or more atoms of the same element.
2. A compound is a union of two or more different elements.
. (here are several different types of bonds that are described based on how the
interaction occurs between participants in the bond.
%. +onic %onds
1. +onic bonds are formed by the mutual attraction of two differently charged ions.
2. +onic bonds form because of differences in charge.
'. 'ovalent %onds
1. 'ovalent bonds form when two atoms share pairs of electrons in their outer shells.
2. Atoms can share up to three pairs of electrons.
. -ome covalent bonds can create polarity, or an uneven pull on the shared electrons.
a. 2onpolar bonds represent equal electron sharing between atoms.
b. +n a polar bond, one atom e)erts a stronger pull on the shared electrons, creating
partial charges on the atoms. (he best e)ample is 4256
". (he o)ygen e)erts a stronger attraction on the shared electron. %ecause the
negatively charged electrons are pulled closer to the o)ygen, it confers a partially
negative charge on that o)ygen.
7. %ecause the shared electrons are pulled away from the hydrogen, the proton of the
hydrogen now creates a partial positive charge.
8. 5verall, one water molecule has no charge. (here is a negative pole at the o)ygen
and positive poles at the hydrogen.
*. 4ydrogen %onds
1. (he partial charges created by a polar covalent molecule can create interactions
with other polar covalent molecules.
2. 4ydrogen bonds are created by mutual attractions of two opposite partial charges.
. 4ydrogen bonds are much weaker than ionic or covalent bonds.
2
!"ter
A. Life emerged in water9 living things are composed of mostly water9 all metabolic
reactions are carried out in water9 water is important for life.
%. .aters special properties are based on the nature of its structure.
1. .ater is a polar covalent molecule as described in the previous section.
2. (his polarity causes attraction and hydrogen bonding and leads to the characteristics
of water.
'. !roperties of .ater
1. .ater is an e)cellent solvent.
a. -olvents are substances that dissolve substances and then distribute the solute.
b. -alts and sugars are two e)amples of solutes that dissolve easily in water.
2. A salt is a solution that dissolves in water and releases ions other than 4
3
and 54
/
.
. .ater creates special interactions with other compounds.
a. ,olecules that easily dissolve in water are called hydrophilic.
b. ,olecules that do not dissolve in water are considered hydrophobic.
". .ater has temperature stability.
a. (emperature is a measure of the energy of molecular motion.
b. 4ydrogen bonding restricts motion in water molecules, reducing the effect of
adding energy to water. (his allows water to absorb more energy than other
substances before changing temperatures.
7. .ater has cohesion.
a. %ecause of the hydrogen bonds between water molecules, they resist being
separated from each other.
i. 'ohesion leads to surface tension, which helps to resist the effects of
evaporation, or the vapori:ation of water.
***** End******