SULIT 4541/2 (PP)

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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT







SMK SULTAN ABDUL JALIL, KLUANG, JOHOR
______________________________________________


PEPERIKSAAN PERCUBAAN SPM 2014 4541/2
TINGKATAN LIMA

Chemistry
Kertas 2
Peraturan Pemarkahan
September 2014


UNTUK KEGUNAAN PEMERIKSA SAHAJA

























___________________________________________________________________________
Peraturan pemarkahan ini mengandungi 11 halaman bercetak

AMARAN

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SULIT 4541/2 (PP)

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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT


Question 1

No. of Q Explanation Marks
Total
Mark
1 (a) (i) Melting point is the temperature at which solid change into
liquid at standard temperature and pressure.
1
(a) (ii) 83
o
C 1
(a) (iii) 136
o
C 1
(a) (iv)
(a)
Solid + liquid 1
(a) (iv)
(b)
Gas 1
(a) (v) 1. Heat energy loss to the surrounding
2. balanced by heat energy liberated by particles to attract
each other.

1

1

(a) (vi)






1

(b) (i) Able to state the meaning of diffusion
Sample answer:
A process when particles of a substance /gas P/Q move between
the particles of another substance/gas Q/P


1

(b) (ii) Able to state the colour correctly
Answer:
Brown // Light brown

1
Total 10

Question 2

No. of Q Explanation Marks
Total
Mark
2 (a) (i) 2.8.4 1
(a) (ii) 14 1
(b) (i) Decrease // become smaller 1
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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT


No. of Q Explanation Marks
Total
Mark
(b) (ii) Proton number / positive charge increase // force attraction
increase
1
(c) Achieve octet electron arrangement // has 8 valence electron
Do not accept or share electron
1
1

(d) (i) Al // Aluminium 1
(d) (ii) Al
2
O
3
1
(e)

Pt 1: Label nucleus and correct number of shell
Pt 2: Octet electron arrangement and correct charges







1
1

Total 10


Question 3

No. of Q Explanation Marks
Total
Mark
3








(a)

Is a representation of a chemical substance using letters for atoms
and subscripts for each type of atoms present

1

1
(b) (i) [ Able to name suitable acid and metal and its equation ]
For example
Hydrochloric acid and zinc metal
1 1
(ii) Zn + 2HCl ZnCl
2
+ H
2
1 1
(c) Hydrogen gas must be flowed/through/into the combustion tube for
a few minutes before heating/ The flow of hydrogen gas must be
continuous throughout the experiment/
[ Accept any one answer]
1 1
(d) (i) Number of mole of copper = 1.62
64
= 0.025mole
1 1
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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT


No. of Q Explanation Marks
Total
Mark
(ii) Number of mole of copper = 0.40
16
= 0.025mole
1 1
(iii) Number of mole of copper: Number of mole of oxygen
0.025 : 0.025
The simplest ratio 1 : 1
The empirical formula of copper(II) oxide is CuO


1
1
2
(e) Iron(II) oxide / Tin(II) oxide / Lead(II) 1 1
(f) Burning of metal in excess oxygen

1 1
Total 10


Question 4

No. of Q Explanation Marks
Total
Mark

4






(a) C
4
H
10
1 1
(b)







1+1



2
(c) - Butene is an unsaturated hydrocarbon/ has double bond
- Butane is a saturated hydrocarbon/ has single bond
1
1

2
C
4
H
8
+
H
2

C
4
H
10

- correct reactants and products
1

- balanced equation


1



1
(e) (i)












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No. of Q Explanation Marks
Total
Mark
- Functional diagram
- Labelled diagram




1
1





2
(ii) Hexene produced more soot
More carbon in one molecule of hexene compare to one
molecule of hexane
1
1

2
Total 10


Question 5


No. of Q Explanation Marks
Total
Mark
5 (a) (i) Acid (substance) which ionises partially// has lower degree
of dissociation in water to produce low concentration of H
+
ion
1
(a) (ii) The concentration of hydrogen ions in hydrochloric acid is higher 1
The higher the concentration of hydrogen ions, the lower the pH
value
1
(b) (i) Neutralisation 1
(b) (ii) Sodi um chl ori de 1
(b) (iii) Pi nk t o col ourl ess 1
(b) (iv) HCI + NaOH NaCI + H
2
O
No of mole of NaOH = 0.1 (25)
1000
= 0.0025 mol

1 mol of NaOH react completely with 1 mol of HCl
0.0025 mol of NaOH react completely with 0.0025 mol HCI



1


1

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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT


No. of Q Explanation Marks
Total
Mark
Molarity of HCI = 0.0025 x 1000
12.5
= 0.2 mol drri
3



1
Total 10


Question 6

No. of Q Explanation Marks
Total
Mark
6 (a) (i) Ethanol 1
(ii)
The heat released when one mole of ethanol completely burnt
in Oxygen (under standard condition) is 1260 kJ
1
(b) (i) No of moles of alcohol = 0.23 /46
= 0.005 mol
1 mol of alcohol burnt released 1260 kJ
Thus 0.005 mol of alcohol burnt released 6.3 kJ
1

1
1

(ii) = H
mc
= 6300
200 x 4. 2
= 7. 5
o
C


1

1

(c) Heat is lost to the surrounding // Heat is absorbed by the
apparatus or containers // Incomplete combustion of alcohol
1
(d)


Label energy and di agram has 2 di fferent energy
l avel s
Bal anced chemi cal equati on









Total 10


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Question 7

No. of Q Explanation Marks
Total
Mark
7 (a) (i) Electrode P : Iodide ion / I
-
ion and hydroxide ion / OH
-
ion
Electrode Q : Hydrogen ion / H
+
ion and Potassium ion / K
+

ion
1
1

2
(ii) Electrode P : Oxygen molecule gas // Oxygen gas
Electrode Q : Hydrogen molecule gas // hydrogen gas
R : formula
1
1

2
(iii) Electrode P : iodine molecule // iodine
Electrode Q : hydrogen molecule // hydrogen gas

Half equation :
Electrode P : 2 I
-
I
2
+ 2e
Electrode Q: 2 H
+
+ 2 e H
2


Confirmatory test at P :
Starch solution is added into the solution around electrode P
Blue colouration / precipitate is formed
1
1


1
1


1
1









6
(b) Cell X Cell Y
Type of cell Electrolytic cell Voltaic cell
The energy
change
Electrical energy
to chemical
energy
Chemical energy
to electrical
energy
The terminal of
cell
Anode : Copper
electrode


Cathode : Copper
electrode
Anode :
Aluminium
electrode

Cathode : Copper
electrode

Ions present in the
electrolyte
Cu
2+
, H
+

SO
4
2-
, OH
-

Observation Anode : Become
thinner

Cathode : Brown
deposit // brown
solid is deposited
// become thicker


Anode : become
thinner

Cathode : Brown
deposited // brown
solid deposited //
become thicker

1


1

1


1



1

1




1

























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No. of Q Explanation Marks
Total
Mark
Half equation for
both electrodes
Anode :
Cu Cu
2+
+ 2e

Cathode:
Cu
2+
+ 2e Cu
Anode :
Al Al
3+
+ 3e

Cathode :
Cu
2+
+ 2e Cu
Name of the
process occurred
at both electrodes
Anode : Oxidation process
Cathode : Reduction process


1


1

1












10


Total 20



Question 8

No. of Q Explanation Marks
Total
Mark
8 (a) The temperature in a refrigerator is lower
Bacterial activity is lower, less toxin is produced by bacteria
In a kitchen cabinat, the temperature is higher , bacteria
activity is higher
Therefore the rate of food spoilage is faster in a kitchen cabinet
than in a refrigerator.
1
1

1

1





4
(b) (i) Volume of gas released = 50 cm
3

Time taken = 55 s
Average rate of reaction = 50/55
= 0.91 cm
3
s
-1



1
1



2
(b) (ii) Experiment I and Experiment II
The temperature for the reaction II is higher than experiment I
Increase the kinetic energy of the reacting particle
Increase the rate of collision between calcium carbonate
particles and hydrochloric acid particles
Increase the rate of effective collision.
Hence, experiment II has a higher rate of reaction than
experiment I

Experiment II and Experiment III
The size of calcium carbonate in reaction III is smaller than

1
1

1
1

1














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4541/2 (PP) 2014 Hak Cipta Panitia Kimia SMKSAJ SULIT


No. of Q Explanation Marks
Total
Mark
reaction II
Smaller size of reactant has bigger total surface area exposed
Increase the rate of collision between calcium carbonate
particles and hydrochloric acid particles
Increase the rate of effective collision.
Hence, experiment III has a higher rate of reaction than
experiment II


1
1

1
1

1








10
(b) (iii) No. moles of HCl = 0.5 x 30
1000
= 0.015 mol

2 mol of HCl produce 1 mol of CO
2

Therefore 0.015 mol of HCl produce 0.0075 mol CO
2


Volume = 0.0075 x 24 = 0.18 dm
3



1

1
1

1







4
Total 20


Question 9

No. of Q Explanation Marks
Total
Mark
9 (a) (i) NaOH 1 1
(ii) Materials : Solid sodium hydroxide and distilled water
Apparatus : 50cm
3
beaker, 250cm
3
volumetric flask, electronic
balance, glass rod, filter funnel.

Calculation : Determine the mass of sodium hydroxide, NaOH:

No. of moles of NaOH = MV = 1 x 250 = 0.25 mol
1000 1000

Mass of NaOH needed = No. of moles x Molar mass, of NaOH
= 0.25 x [23 + 16 + 1 ]
= 10 g

Steps :
1. Using an electronic balance, 10 g of sodium hydroxide is exactly
weighed and placed into a beaker,
1
1




1


1
1



1















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No. of Q Explanation Marks
Total
Mark
2. Distilled water is added to the beaker to dissolve all the solid sodium
hydroxide,
3. Then the solution is poured into a 250cm
3
volumetric flask. The beaker is
rinsed with distilled water and the solution is poured into the volumetric
flask.
4. The solution in the volumetric flask is topped up with distilled water until
its calibration mark.



1


1

1








9
(ii)
To identify Mg
2+
ion
-Magnesium nitrate solution is poured into a test tube
-NaOH solution is added until excess
-white precipitate formed and insoluble in excess and
-test with NH
3
solution
-same step and same result will obtained when test with NH
3
solution

NO
3
-
ion
-Magnesium nitrate solution is poured into a test tube
-dilute sulfuric acid is added
-followed by iron(II) sulphate solution
-shake the test tube
-concentrated sulphuric acid is added slowly/through the wall of
the test tube
-brown ring formed

1
1
1
1




1
1
1
1

1
1
















10
Total 20

Question 10


No. of Q Explanation Marks
Total
Mark
10 (a) Part X hydrophobic/hydrocarbon
Part Y hydrophilic/ionic
Part X dissolves in grease
Part Y dissolves in water
1
1
1
1



4
(b) 1.The cloth in experiment II is clean whereas the cloth
in Experiment I is still dirty.
2.In hard water,soap react with magnesium ion / calcium ion

1
1



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No. of Q Explanation Marks
Total
Mark
3.to form scum
4.Detergent are more effective in hard water
5.Detergent does not form scum
6.Detergent are better cleansing agen then soap to
remove oily stain.

1
1
1

1




6
(c)(i) Pure metal atoms has similar size and shape
Easily to slide

1
1

2

(c)(ii) Draw for pure copper
Draw for its alloy and labels for copper and zinc

1
1

2

(c)(iii) Increase the strength and hardness of metal
Prevent the corrosion of metal
Improve the appearance
1
1
1


3

(c)(iv) Duralumin
Its stronger / harder
Can withstand compression

1
1
1


3
Total 20




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