Vous êtes sur la page 1sur 5

titi{, rj tqEi}ff ieL.

2 *35 otU,xa ,lLic

:pit."rqrf r l[jgll
114 20131L2 t20

t#l

J:4lb $ Ar-ti

A{,.lt, .el.c..<:rt, ACtl ut

;l*4*rrl

(.Ii3 7)
Ke:L0-14

rtr$ gfuf$ ,l.l"ll U- 25oC t *tl +rr ..c rlJi. ;3hrl d!rl*.tl C#?

Mg(OH) 2 tejirf.t

i+,

4rytl

@t4.

sle pHJSB (Jai3 2) rclfTl Jr.irl


Mg(OH)2 Jij#i-ll g*s3-.l{g,ffi

A{3br3

tull l.rtr-dl .#o +Jt"lt ,J+Jl^"ll

,i

?-'

Mg(OIrra

Mg';

+ ZHO;q
:.rLri

- 10-11 Or+sill iltrr.+ fusj.tt f

,Mg'* ltl sJrill ,JJJI jsl+ J*;ii4!l r*u.<3-.1{4J s 4JCl

.Ho-s Ms'*

crcrJ q,r.$

i.:,

a:.,f

q3$ u,+i

ucr jr-tr e+ -"*-lif;'rlr-,i*

-t lu dJl. i ero+"i^lt {*seqa 4*si i d,Jri-(2


Los(r) - 17 -2pH
. PHz = 12 e pH1:3 , pH :li c.t+l:r.ll 4#Jl! s i"ro ,+ ..-i
:4urlt

ljill dil{y.rss+ d,.i 4J""

e+t-,.sill

sle pH#ii drii*t i+ .tS -(3


(Ji3 5)

or5

or5

rstlttl rJ.ill

: Sm2mol-l ;.r.jt-, 4;iju

:
CH3CO2H/CH3CO] bs.r,lll pKa :4rB , l*o, :
7rro, = 7, = 5.46.10-3, lrurro,

(.0r

ir

nr = 2r5 L0-3 mol

JcrJ,Jl lJj+l

t tz

7z

- 4.09.10-3

7, = 5.01.10-3

,dt dJl*. ,Jl9 ,J.a.l


5,0 10-3 mol J HCOzH l;.rll#lt

e.jla+

, V = 50ml 4i+s

.(l'/oiu + CH rCO;,r)
o :01973

?3

cH 3co

S.m-l

i.+*ill cjlJll .rje i,,$,a3"ll o"S

; rrriJr ir.r+is rrco2H Orffi

;hsl

*""i[;J,

lrr rco;]. ,Wro;1. ilr+ asr, &r;r c1ssr i, err*r-(2


lt ,il.l jlJill tb
0,910 + !,37. 10-3
:ii>t

6-

Lrti.ll

!l,as^ o iJl d$l-(3

fuco;l

(s.*-')

a,6

orf
4

tjL, .jL?EiTt A.k


-ur -1,it, tLj**t

214

-&s

o/4;*a;t

#-lb

-.1'l! i Ai_it3

*gt rl rLr ,rt n{l

2013 ltz t20

A*c*.;l}{

:atl:tt +hill qt_rtt jlrf-Jl3lf


n*, ,Ojfgft_e .r.13t-(4

,5'

,lru rco;1. , fruc;i

lcn rcozHT, ,lruco rH)"

. K - Q.uq jl_Frlt 4i i* .l.ra-(S .S


.jlJiJl ge L.,lill pH {.41 ,.. ....i -(6 /1
I

rI SLl-r{" AI*
fu;sll
5,496.10-"

o-,-1
1,009665

(t-:15) rl

:*q!r"It

Ss*ll

O-r+*,rSSYl

1,007276

f-l+-r*lt

15,995

l4l,g0g

lMev = 116 10-"j


J$ &Li" C rJJs ,1)t U

*l*i*i

Lu :

e,*$*-il

p3gl_.p!l

aJt

90,905

235,044

(u) e:ts

116610-''Kg : 93115 Mev c


J+Eill gJc s3a+ 3Jl , UOz es+lJsyt qy",rs3t ,J4!+
.a*!*S Ar.l

Z. es+tsrJl3 Ce l+-**Jl Js c,Jl 3)t tl 'rO,

Jr,i,it dlstij c.r.! r3i


:-rlEll dJrll i+i t nlt ilrh-oll q!.,,.

31r'u

p.e,!r-,pyr g,o

+in+':1ce+llZr

.rrr3,'r

+ x[n + lF

rffi' ffi.,,il,.'l,l;

.tloz ts+l-Yl +usst cr l

g JrLi.rl ilo i*uJt itLlt

elr-,t
a
M\ry q*. -egilt dtet.ll tr:r.xsrr -,r.rrlt o uo-(3
4Ju*3."l Jll tloz
es+l-,,sYl {y".si {,..,..-i ,rr,.xs f,ir} sJr dJ.r t rlr
ittt

45o/o gl3 900

.r.lS e.* rltf

'et"lct

dJ+Jt+

L._ru.Il +St+J+SJt o.tt d*i.j,tl

dl ri

s-l..lt deLi"Jr cj.r'r-*r.,,gTr crt-,1^ir.!r g.q. ds-(4


rs+l;-lYl l9 rru'rnil 6e sjJ. rl- {g.J g Lj,air
6&ll ts
ie '41itl
irs,l os-r-*rrr rll ai.-., ^t
J#l-pYl cr
.lr l,.r.aut .Js
"li3
.235 e.rft.,,Ot lS J*i l.rrl3 Lil.j.l ct-,.l t = 0 r*s.,;u A.t
"luo',

si

:'t

l!

.ee,.lt det.ll

{::lO,
'=t ,tu'
t!-30ans :s .LtiJr
r*vl
2

IlOz

p-9rl-,pl rr,,'(3i

G.rutr so

{-:r,

4*u,

irr t crl

r42 r-*j+-dt +s.r L.i,ajlr ,.o-(5

cx 1g JrL lil Cp i*ujt diss cr ::i:rtl p3j*-Jt Ss .rq,3i


.

i,,"Jll iJ"

,.,

_y

.lr+

or5

L.jt'r{,

rjq$

&t".

;{axrlrt r lrl&*l
314 2o13lr2l2o

sp4;@*J&

*l*l rylc

lf

sx*[ea dt &r**t5

dtlrl jsrt

A++trtl

(Jl8) r2 *lr-i$
ti3 *!r
d.,.3" ,iqJ{s .ls" (Gr) :u,a ipiJts (1) ds,fll ** i.l" tt ,,r!-XSt *Jill i+''

RC .#Irl

,/Jl ,rt-.g" ,C=0r1F 4it*.r t< ,I : 16 4i3r. tr LilJ# lJt+ ei^+ '-!ijl
.K lh:ll *l!s Us str.J#ll 4JJ,e jJsX d-3" tls" (Gr) 'R'tj^s&
u #JiIr j]l J3}lt ,;J,(2) ds,i,ll s+.alu:" dsly edi Jtll g! L,-.J$
LiSS^ll
,tl+
"J+y
2._
.

Kt

L{.

'

U,
"

ql

cT

u*
1{
Uo'

2,t
1r5

(v)

lu

l.iL;lr sjl'Xl f'!'

-r{an +)vt r tLi*ltl


414 zDfi fi2120

A{U,

.(1) ,Js-ill o" ,l ,yrs"lr K


(1) eJJt

*3s

*.1l;3Jl

o$at

gla LJb

$b.li

ACtl

-;.ol!a

Ai*rl

&t A*

AJ.Urtl

*t ts"+ di.4ll gr*r rll ^ ej+ ,Js O+t-(t

15-

C *ll 6;s e u -Jill rt-iCl 4*1.L1ll il$r-oll s.3i-(2


.Io ;!!l r t+ Ojld

.(2)efu.Ilkl$Il

&t3-tS

a,*U,aUtl lltr.ll rSi-1S.f


u j3ll r(ti-,r
":l
js^ill
43+lJl
:
.,
o.t
A.e-"
u(t)
4Jll i.l.rla-ell A ,+isJ"-(3.2
=
,,le
*i
. RC ,.,Ltl dtjil "ill aS..t3 t .+Jl .ill J,.i s
. A i+i3 ,+-:l .t 3 ts ,U6 q A i# .rr.3l-i

.L.lls4ll

. R L3.ll
:ix+-,!fJl c1.rl,JlJf u+1.Jg+ dJr^.3 r.q.oll

i.+ L-c;

sr5

\ili &f-Hl 1+l ,-31-(3.3


.tt: 3s J to = 1-r5s

(3) er,.I| el-rldirl

&tl-t+
v,l

AjJ q rei-r .,5Jl 4*Itilll l.rtr-oll ,'r,'ti=(4.L


:4i-jll fulSq 4!.tJl 4J,ag lrh-oll cJ. ip sp,;-(4.2
.L.iisrll

-(t-tt)

u:C(IJr-Uo)

F=CUo:l

# q(t):d '
:.t, rjJt

q(t+

;xI.3i io

+P

.,ltj-(4.3

L,t)-q(t).(#),o,
cj3+ll Y.

i(mA)

q(c)

t(s)

e^,t

7r1

es puii cr"!t + (t) -,rhllt r^r J*Fi tr,Jl-(S


6l.Bt+ K .,r$ll
"f
.(S) s(Z)
ci$l.b..aTl
'(t)
lJJ g" i(t) ifo{J di^4ll sirj,.ll C-, Os+ *,Jl

er,.lJ"ll

&ls

*t!

.Cu;lsIl

t -cL* tjQfl3'l-o
t{an +)Vl r tt-.:.,ltf

414

2 ts

o$t*t glj LJA

.;.ot!r &l A*$

A*8, aeb.I+ CtXl }tut

2ot3l12l2o

**.l4-;ll

,l ers"tr K Jlt5jl *tI t-r+ di,4ll gt*i,ll " ej+ , O*t-(t


(1) e.JJl C *l3ll es rie u,Jill ret-ic#Jl 4*llll il$r"ll s.3i-(2

.(1) ,Js*lll i

.Io ;!!l

.(2) C3l.I|

.r*t

t+ ex,,.,|

kll#Il &E<f

u jJ3ll r(ti-.r C,jll 4.tlll lrtr.ll rSi-1S.f


4!.tJl 4*1..lll i.l.r-qll d qis,-(3.2
H o.r , u(t) = A.e-il" : js^ill
,.,Ltl
. RC"rT,,
s$jil "Jl aS. t .&Jl .jll ,J,.i sP
. A i4i3 qi,,.sJ .t 3 ts ,Us + A i# .tr.3l-i
.L.I!s4lt

0rf

dH

. R L3t.Il
:iX+.,/fJl c1rr,-rldf u1.JS+ dJri.+ r.ryoll Wi &f-Hl

1+ L-c;

1+l

4
6r5

,.rr,,31-(3.3

.tr: 3s J to= 1-r5s


(3) errert el-rk]Il CItl-(4
.L.ls..lt

:4i-jll

ijr.i q ret-'r.,pr lf,.afSfl il.rh-oll c,+ti-(4.1

JlSq

4EUl 4J.ag lrlgll cJ. Cro sp,;-(4.2


-(t-tt)

q(t):d'

u:C(Ilr-Uo) J F=CUo:l #

:.1,

q(t+

r:Jl

Jjl."

+P

Jl A.blg s.Ld-(4.3

L,t)-q(t).(#),o,
cj-r+ll Y. e^,t

i(mA)

q(c)

t(s)

(,

7r1

+ (t) -,rhllt & J#ri tr,sl-(S


r,.lJ"ll "f eJ.Bt+ K .,rl+jll *t! es p$i cr"!l
cj-ls crl$l.h,.aTl lJrl - i(t) ifo{J di^.oll iri.ll C-,Oo+ f*'Jl '(S) -{Z) '(t)
.Cu;lS.ll

v,6
4