Designation: D 1784 03

Standard Specication for

Rigid Poly(Vinyl Chloride) (PVC) Compounds and
Chlorinated Poly(Vinyl Chloride) (CPVC) Compounds
1
This standard is issued under the xed designation D 1784; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope*
1.1 This specication covers rigid PVC and CPVC com-
pounds intended for general purpose use in extruded or molded
form, including piping applications involving special chemical
and acid resistance or heat resistance, composed of poly(vinyl
chloride), chlorinated poly(vinyl chloride), or vinyl chloride
copolymers containing at least 80 % vinyl chloride, and the
necessary compounding ingredients. The compounding ingre-
dients may consist of lubricants, stabilizers, non-poly(vinyl
chloride) resin modiers, pigments, and inorganic llers.
NOTE 1Selection of specic compounds for particular end uses or
applications requires consideration of other characteristics such as thermal
properties, optical properties, weather resistance, etc. Specic require-
ments and test methods for these properties shall be by mutual agreement
between the purchaser and the seller.
1.2 Rigid PVC compounds intended for pipe, ttings, and
other piping appurtenances are covered in Specications
D 3915 and D 4396.
1.3 Rigid PVC compounds for exterior building product
applications are covered in Specication D 4216.
1.4 The text of this specication references notes and
footnotes that provide explanatory material. These notes and
footnotes (excluding those in tables and gures) shall not be
considered as requirements of this specication.
1.5 Rigid PVC recycle plastics meeting the requirements of
this specication may be used in some applications. Refer to
the specic requirements in the materials and manufacture
section of the applicable product standard.
1.6 The values stated in SI units are to be regarded as the
standard. The values given in brackets are for information only.
1.7 The following safety hazards caveat pertains only to the
test methods portion, Section 11, of this specication: This
standard does not purport to address all of the safety concerns,
if any, associated with its use. It is the responsibility of the user
of this standard to establish appropriate safety and health
practices and determine the applicability of regulatory limita-
tions prior to use.
NOTE 2This specication is similar in content (but not technically
equivalent) to ISO 1163-1: 1985 and ISO 1163-2: 1980.
2. Referenced Documents
2.1 ASTM Standards:
D 256 Test Method for Determining the Izod Pendulum
Impact Resistance of Plastics
2
D 618 Practice for Conditioning Plastics for Testing
2
D 635 Test Method for Rate of Burning and/or Extent and
Time of Burning of SelfSupporting Plastics in a Horizon-
tal Position
2
D 638 Test Method for Tensile Properties of Plastics
2
D 648 Test Method for Deection Temperature of Plastics
Under Flexural Load
2
D 883 Terminology Relating to Plastics
2
D 1600 Terminology for Abbreviated Terms Relating to
Plastics
2
D 1898 Practice for Sampling of Plastics
3
D 3892 Practice for Packaging/Packing of Plastics
4
D 3915 Specication for Rigid Poly(Vinyl Chloride) (PVC)
and Chlorinated Poly(Vinyl Chloride) (CPVC) Com-
pounds for Plastic Pipe and Fittings Used in Pressure
Applications
4
D 4216 Specication for Rigid Poly (Vinyl Chloride)
(PVC) and Related PVC and Chlorinated Poly (Vinyl
Chloride) (CPVC) Building Products Compounds
4
D 4396 Specication for Rigid Poly(Vinyl Chloride) (PVC)
and Chlorinated Poly(Vinyl Chloride) (CPVC) Com-
pounds for Plastic Pipe and Fittings Used in Nonpressure
Applications
5
1
This specication is under the jurisdiction of ASTM Committee D20 on
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic
Materials.
Current edition approved July 10, 2003. Published September 2003. Originally
approved in 1960. Last previous edition approved in 2002 as D 1784 02.
2
Annual Book of ASTM Standards, Vol 08.01.
3
Discontinued; see 1997 Annual Book of ASTM Standards, Vol 08.01.
4
Annual Book of ASTM Standards, Vol 08.02.
5
Annual Book of ASTM Standards, Vol 08.03.
1
*A Summary of Changes section appears at the end of this standard.
Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D 4703 Practice for Compression Molding Thermoplastic
Materials into Test Specimens, Plaques, or Sheets
5
D 5260 Classication for Chemical Resistance of Poly(Vi-
nyl Chloride) (PVC) Homopolymer and Copolymer Com-
pounds and Chlorinated Poly(Vinyl Chloride) (CPVC)
Compounds
5
2.2 ISO Standards:
6
ISO 1163-1: 1985
ISO 1163-2: 1980
3. Terminology
3.1 DenitionsDenitions are in accordance with Termi-
nology D 883 and abbreviations with Terminology D 1600
unless otherwise indicated.
4. Classication
4.1 Means for selecting and identifying rigid PVC and
CPVC compounds are provided in Table 1. The properties
enumerated in Table 1 and the tests dened are expected to
provide identication of the compounds selected. They are not
necessarily suitable for direct application in design because of
differences in shape of part, size, loading, environmental
conditions, etc.
4.2 Classes are designated by the cell number for each
property in the order in which they are listed in Table 1
including a suffix letter specifying the requirements for chemi-
cal resistance.
NOTE 3The manner in which selected materials are identied by this
classication system is illustrated by a Class 12454 rigid PVC compound
having the following requirements (see Table 1). The two-digit cell limits
10 and 11 are rarely used, only for special high-temperature grades of
CPVC compound:
NOTE 4The cell-type format provides the means for identication and
close characterization and specication of material properties, alone or in
combination, for a broad range of materials. This type format, however, is
subject to possible misapplication since unobtainable property combina-
tions can be selected if the user is not familiar with commercially available
materials. The manufacturer should be consulted.
4.3 Product application chemical resistance when specied
shall be classied in accordance with the classication section
of Classication D 5260.
5. Ordering Information
5.1 The purchase order, or inquiry, for these materials shall
state the specication number and identify the class selected,
for example, D 1784, Class 12454.
5.2 Further denition, as may be required for the following,
shall be on the basis of agreement between the purchaser and
the seller:
5.2.1 Physical form and particle size (see 6.1),
5.2.2 Contamination level (see 6.2),
5.2.3 Color (see 6.3),
5.2.4 Other supplementary denition if necessary, and
5.2.5 Inspection (see 12.1).
6. Materials and Manufacture
6.1 Materials supplied under this specication shall be PVC
and CPVC compounds in the form of cubes, granules, free-
owing powder blends, or compacted powder blends.
6.2 Materials shall be of uniform composition and size and
shall be free of foreign matter to such level of contamination as
may be agreed upon between the purchaser and the seller.
6.3 Color and transparency or opacity of molded or ex-
truded articles formed under the conditions recommended by
the seller shall be comparable within commercial match
tolerances to the color and transparency or opacity of standard
molded or extruded samples of the same thickness supplied in
advance by the seller of the material.
7. Physical Requirements
7.1 Test values for specimens of the material prepared as
specied in Section 9 and tested in accordance with Section 10
shall conform to the requirements given in Table 1 for the class
selected.
8. Sampling
8.1 A batch or lot shall be considered as a unit of manufac-
ture and may consist of a blend of two or more production runs
of material.
8.2 Unless otherwise agreed upon between the seller and the
purchaser, the material shall be sampled in accordance with the
procedure described in the General and Specic Sampling
Procedures, as applicable, of Practice D 1898. Adequate statis-
tical sampling prior to packaging shall be considered an
acceptable alternative.
9. Conformance Testing
9.1 The minimum properties identied by the class desig-
nations in Table 1 specied in the purchase order (see 5.1) shall
be veried by the tests described in Section 11.
9.2 Conformance with this specication shall be determined
with one set of test results. If there are multiple test results, the
average value for all test samples shall be used to determined
conformance.
9.3 If the average test value produces values below the
minimum property values of the Class designation in Table 1,
the material does not conform to this specication.
10. Specimen Preparation
10.1 Compliance with the designated requirements chosen
from Table 1 shall be determined with compression-molded,
extruded, or injection-molded test specimens for Izod impact
resistance, tensile strength, tensile modulus of elasticity, de-
ection temperature under load, and ammability. Specimens
6
Available from American National Standards Institute (ANSI), 25 W. 43rd St.,
4th Floor, New York, NY 10036.
D 1784 03
2
cut from laminates of compression-molded or extruded sec-
tions (see Practice D 4703) shall not be used unless it can be
shown by test that complete fusion is obtained. Procedures
used in preparing the test specimens shall be as recommended
by the seller for each specic compound.
11. Test Methods
11.1 ConditioningThe test specimen for deection tem-
perature (Test Method D 648) shall be conditioned in accor-
dance with Procedure B of Practice D 618, except that the
minimum conditioning time in the circulating air oven shall be
24 h. All other molded test specimens shall be conditioned in
accordance with Procedure A of Practice D 618. The minimum
conditioning time shall be 24 h.
11.2 Test ConditionsUnless otherwise specied in the test
methods or in this specication, tests shall be conducted in the
standard laboratory atmosphere of 23 6 2C [73.4 6 3.6F]
and 50 6 5 % relative humidity. In cases of disagreement, the
tolerances shall be 61C [61.8F] and 62 % relative humid-
ity.
11.3 Tensile Strength and Modulus of ElasticityTest
Method D 638, using Type I specimens of 3.2 6 0.4 mm [0.13
6 0.02 in.] thickness and testing speed of 5.1 mm [0.20
in.]/min 6 25 %. Report tensile strength at the yield point if the
material yields, otherwise at break.
11.4 Impact Resistance (Izod)Method A of Test Method
D 256, using 3.2-mm [0.125-in.] thick specimens. The speci-
mens may be compression-molded, extruded, or injection-
molded with the provision that compression-molded or ex-
truded specimens built up as laminates in which complete
fusion is obtained shall be acceptable. Complete fusion means
there shall be no evidence of fraying or delamination at the
break.
11.5 Deection TemperatureTest Method D 648Method
A- using 127 mm [5 in.] long, 12.5 mm [0.5 in.] wide, and 3.2
mm [0.125 in.] thick specimens under 1.82 MPa [264 psi] ber
stress. Materials that require high-temperature annealing prior
to testing shall be annealed at 50C [122F] for 24 h or at the
manufacturers recommendation. Specimens shall be cooled in
accordance with Procedure B of Practice D 618. The test report
for annealed specimens shall include the time and temperature
of annealing used.
11.6 FlammabilityTest Method D 635. All compounds
covered by this specication, when tested in accordance with
Test Method D 635, shall yield the following results: average
extent of burning of <25 mm; average time of burning of <10
s.
12. Inspection
12.1 Inspection of the material shall be made as agreed upon
between the purchaser and the seller as part of the purchase
contract.
13. Packaging and Package Marking
13.1 PackagingThe material shall be packaged in stan-
dard commercial containers, so constructed as to ensure
acceptance by common or other carriers for safe transportation
at the lowest rate to the point of delivery, unless otherwise
specied in the contract or order.
TABLE 1 Class Requirements for Rigid Poly(Vinyl Chloride) (PVC) and Chlorinated Poly(Vinyl Chloride) (CPVC) Compounds
NOTE 1The minimum property value will determine the cell number although the maximum expected value may fall within a higher cell.
Desig-
nation
Order
No.
Property and Unit
Cell Limits
0 1 2 3 4 5 6 7 8 9 10 11
1 Base resin unspecied poly(vinyl
chloride)
homo-
polymer
chlorinated
poly
(vinyl
chloride)
vinyl co-
polymer
2 Impact resistance
(Izod), min:
J/m of notch unspecied <34.7 34.7 80.1 266.9 533.8 800.7
ftlb/in. of notch <0.65 0.65 1.5 5.0 10.0 15.0
3 Tensile strength,
min:
MPa unspecied <34.5 34.5 41.4 48.3 55.2
psi <5 000 5 000 6 000 7 000 8 000
4 Modulus of
elasticity in
tension, min:
MPa unspecied <1930 1930 2206 2482 2758 3034
psi <280 000 280 000 320 000 360 000 400 000 440 000
5 Deection
temperature
under load, min,
1.82 MPa
[264 psi]:
C unspecied <55 55 60 70 80 90 100 110 120 130 140
F <131 131 140 158 176 194 212 230 251 266 284
Flammability
A A A A A A A A A A A A
A
All compounds covered by this specication, when tested in accordance with Test Method D 635, shall yield the following results: average extent of burning of <25 mm;
average time of burning of <10 s.
D 1784 03
3
13.2 MarkingUnless otherwise agreed upon between the
purchaser and the seller, shipping containers shall be marked
with the name of the material and the name of the manufac-
turer; class, batch, or lot number; quantity contained therein, as
dened by the contract or order under which shipment is made;
the name of the seller; and the number of the contract or order.
13.3 All packing, packaging, and marking provisions of
Practice D 3892 shall apply to this specication.
14. Keywords
14.1 chlorinated poly(vinyl chloride) (CPVC); CPVC com-
pounds; poly(vinyl chloride) (PVC); PVC compounds; recycle
plastics; rigid PVC
SUMMARY OF CHANGES
This section identies the location of selected changes to this specication. For the convenience of the user,
Committee D20 has highlighted those changes that may impact the use of this specication. This section may
also include descriptions of the changes or reasons for the changes, or both.
D 1784 03:
(1) Revised 11.5 to change cooling language.
D 1784 02:
(1) Revised 11.6 to include cooling language.
(2) Revised 11.3 to include point of tensile strength measure-
ment.
(3) Made several suggested editorial changes throughout stan-
dard.
D 1784 99a:
(1) 11.5Revised minimum HDT specimen annealing tem-
perature.
(2) 1.2Added reference to CPVC compounds.
(3) 2.1Corrected Specication D 3915 and Specication
D 4396 titles.
(4) 4.1Added reference to CPVC compounds.
(5) 6.1Added reference to CPVC compounds.
D 1784 99:
(1) Thickness of impact strength (Izod) test specimens in 11.4
was changed to 3.2 mm [0.125 in.].
D 1784 97:
(1) 1.3Corrected Specication D 4216 reference.
(2) 1.3, 2.1, 4.1, 4.2, 4.3, 10.1, 11.8, and Tables 2, X1.1, and
X2.1Deleted sulfuric acid test.
(3) Section 9Detailed conformance tests.
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D 1784 03
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