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The document contains a series of chemistry questions related to isotopes, relative atomic mass, the periodic table, electron configuration, ionization energy, and chemical equations. Specifically, it asks the student to:
1) Define isotopes and explain how a mass spectrometer works.
2) Calculate the relative atomic mass of iron using given isotope abundance data.
3) Identify the electron configuration of Fe2+ and explain why iron is in the d-block.
4) Draw conclusions about periodic trends in ionization energy from a graph.
5) Write equations and explain trends related to electron affinity and ionization energy.
The document contains a series of chemistry questions related to isotopes, relative atomic mass, the periodic table, electron configuration, ionization energy, and chemical equations. Specifically, it asks the student to:
1) Define isotopes and explain how a mass spectrometer works.
2) Calculate the relative atomic mass of iron using given isotope abundance data.
3) Identify the electron configuration of Fe2+ and explain why iron is in the d-block.
4) Draw conclusions about periodic trends in ionization energy from a graph.
5) Write equations and explain trends related to electron affinity and ionization energy.
The document contains a series of chemistry questions related to isotopes, relative atomic mass, the periodic table, electron configuration, ionization energy, and chemical equations. Specifically, it asks the student to:
1) Define isotopes and explain how a mass spectrometer works.
2) Calculate the relative atomic mass of iron using given isotope abundance data.
3) Identify the electron configuration of Fe2+ and explain why iron is in the d-block.
4) Draw conclusions about periodic trends in ionization energy from a graph.
5) Write equations and explain trends related to electron affinity and ionization energy.
Instructions: Answer the ALL the questions in a separate answer sheet.
1. A sample of iron from a meteorite was found to contain the isotopes
54 Fe, 56 Fe and 57 Fe. (a) The relative abundances of these isotopes can be determined usin a mass spectrometer. !n the mass spectrometer, the sample is first vaporised and then ionised. (i) "tate what is meant b# the term isotopes. (ii) $%plain how, in a mass spectrometer, ions are detected and how their abundance is measured. (5) (b) (i) &efine the term relative atomic mass of an element. (ii) The relative abundances of the isotopes in this sample of iron were found to be as follows. m/z 54 56 57 'elative abundance (() 5.) *+.6 ,.6
-se the data above to calculate the relative atomic mass of iron in this sample. .ive #our answer to one decimal place. (4) Addu High School/Department of Chemistry/Holiday Assignment/June 201 CHEMIST! H"LI#A! ASSI$%ME%T (c) (i) .ive the electron arranement of an Fe ,/ ion. (ii) "tate wh# iron is placed in the d bloc0 of the 1eriodic Table. (iii) "tate the difference, if an#, in the chemical properties of isotopes of the same element. $%plain #our answer. (4) &. (a) 2omplete the followin table. 1article 'elative chare 'elative mass 1roton 3eutron $lectron (') (b) An atom of element ( has two more protons and two more neutrons than an atom of " 44 +6 . .ive the s#mbol, includin mass number and atomic number, for this atom of (. (&) (c) 2omplete the electronic confiurations for the sulphur atom, ", and the sulphide ion, " ,5 . (d) "tate the bloc0 in the 1eriodic Table in which sulphur is placed and e%plain #our answer. (&) 3. (a) &efine the terms )irst e*ectron a))init+. (') (b) 6rite the e7uation for the process occurrin when the secon, electron affinit# of sulphur is measured. (&) (c) $%plain wh# (i) the electron affinit# of noble ases are least in a period. Addu High School/Department of Chemistry/Holiday Assignment/June 201 (1) (ii) electron affinit# of nitroen is almost 8ero (1) 4. First ioni8ation eneries of the elements show periodicit#. The raph below shows the first ioni8ation ener# of twelve successive elements in the 1eriodic Table in order of increasin ato-ic nu-.er .The letters are not the s#mbols for the elements. (a) .ive the letters of the two elements in $roup / (the noble ases).$%plain #our answer in terms of ioni8ation ener#. (&) (b) .ive the letter of the $roup ' element. $%plain #our answer in terms of ioni8ation ener#. (&) (c) $%plain wh# there is an increase in the first ioni8ation ener# of the elements )ro- 0 to H shown on the raph (') (d) $%plain wh# there is a drop in first ioni8ation ener# from H to 1 (&) (e) "uest whether the first ioni8ation ener# of another element M comin 9ust after :L2 has a lower or a hiher than that of the element #. 9ustif# #our answer. (&) Addu High School/Department of Chemistry/Holiday Assignment/June 201 (f) The chart shows the first ionisation ener# of some elements in the third period of the 1eriodic Table.
(i) 6rite the chemical e7uation, with state s#mbols, which corresponds to the first ionisation ener# of aron. (ii) ;n the chart, add a cross to show the first ionisation ener# of potassium. <ustif# #our choice of the position of the cross. (iii) $%plain wh# there is a small decrease in first ionisation ener# oin from phosphorus to sulphur. (iv) $%plain wh# there is an increase in first ionisation ener# oin from sulphur to chlorine. () The table below ives some ionisation eneries for sodium and manesium. (i) 6rite the chemical e7uation, with state s#mbols, which corresponds to the )irst ionisation ener# of manesium. (ii) $%plain wh# the first ionisation ener# of manesium is reater than the first ionisation ener# of sodium. (iii) 1redict a value for the secon, ionisation ener# of manesium. $%plain #our choice. Addu High School/Department of Chemistry/Holiday Assignment/June 201 Addu High School/Department of Chemistry/Holiday Assignment/June 201