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Electronics Assembling Technology
1. Introduction:
The electronics assembly process flow
Chapters
At through-hole technology
(THT), component leads are
inserted through holes in the
printed wiring board (PWB);
and soldered to the lands on
its other side.
A TH component is the DIL IC
(dual-in-line integrated circuit),
whose leads usually have a
pitch of 2,54 mm (0,1”)
Process steps:
1. Solder paste application
2. Adhesive application for wave soldering
3. Components placement
4. Adhesive curing by heat or UV light
5. Reflow or Wave Soldering
6. Board cleaning
The different combinations of electronics assemblies usually require the application of the
combination of the through hole and the surface mount assembling processes as well as the
use of one side or both sides of the printed circuit boards. An example of this complex
approach is the use of automatic insertion of surface mount components and manual insertion
of the through-hole ones, followed by reflow and selective wave soldering of the same
assembly.
According to the usual process flow a surface mount assembling line consists of three main
types of equipment: a stencil printer for the application of solder paste onto the pads of the
printed circuit boards; placement machine(s) for picking up the components and placing them
on the boards; and a reflow oven to melt the solder paste and make the solder joints. In most
cases inspection systems are also included after each main process steps into the complete
assembly line, where conveyors and handling tools move the boards from one machine to the
others throughout the whole line.
Types of discrete components by function and assembling
Active components: amplify the
electric signal, need energy source,
built from semiconductor materials
Passive components: amplify the
electric signal, do not need energy
source, built on insulating materials
Assembling types of components:
Through Hole components
Electronics assembly is the process of placing components onto a printed circuit board
and attaching the leads or terminations of the components to the lands or pads of conductors
on the board and then joins them by soldering.
There are different aspects to categorize discrete components, e.g. according to their
function, materials, size, form of termination, type of packaging, suitability for assembling,
etc.
According to its function a component is either active or passive. Active components
can amplify and modify the input electric parameter, like voltage or current, by using some
supplying power. On the other hand, passive components can only modify the electric
parameters, and do not need any supplying power. Typical examples for active components
are transistors and most ICs, while for passive components there are the resistors and
capacitors.
On the basis of the assembling method, for which the discrete component is suitable,
the classification can be through-hole (TH), surface-mount (SM) and chip components.
Through-hole components have wire or strip leads, which are suitable for inserting through
the holes of a PWB and fixing by soldering. The fix-terminated dual-inline package (DIP or
DIL package) is a characteristic example for TH components.
Surface-mount components (SMCs) have no or have only very small leads, so they are
unsuitable for through-hole assembly. Furthermore, SMCs are usually much smaller than the
through-hole ones.
Chips are leadless functional elements, and generally require special assembling
processes, like eutectic die bonding and thermo-compression wire bonding. Passive chip
components like chip resistors and chip capacitors, however, can be assembled by surface
mounting, while for active components the chip-scale (or chip-size) packaged chips are in use.
Surface Mount passive components and integrated circuits
Thick film chip resistor SOIC:
Small Outline Integrated Circuit
The substrate is made up of an insulating base material, with conductive pattern upon and/or
in it for the interconnections. In some cases the substrate also contains integrated passive
elements formed from other structured layers.
The main aspects and groups for selecting and categorising PWBs are as follows:
In accordance with the everyday usage, a printed wiring board (PWB) is a substrate,
which is made up of an insulating board with copper foil tracks on its outer surfaces
(sometimes only on one of the outer surfaces, more often in the form of inner layers as well).
The components are fixed to the PWB and connected to the conductive copper tracks by
soldering. Sometimes in the technical slang the board is named printed circuit board (PCB)
and the assembly is named printed circuit (PC), but these names are slightly incorrect.
At mixed technology assembly, the assembly operation begins with the surface
mount process from the primary side of the board. After solder paste printing, the surface
mount components are placed in their locations on the circuit board. This is followed by
reflow soldering.
Next, the board is flipped over and adhesive is applied so that the chip components
can be placed and glued onto the secondary side of the board. Adhesive may be applied using
an adhesive dispenser or stencil printer. The glue dots are applied between the chip
component lands. After adhesive application, the SM components are positioned using
automated placement equipment. The adhesive is then cured.
Next, the through-hole components are inserted from the primary side of the board.
The fully assembled circuit board is then passed through a wave solder machine. The solder
wicks up the holes to solder the through-hole leads. The surface mount chip components
glued to the bottom side of the board are also soldered at this time.
Soldering is the process of joining metallic surfaces through the use of solder without
fusion of the base metals. Soldering is used to prepare conductive electrical connection in
electrical or electronic circuits.
In electronics, the solder joint is usually connects a component lead to a solder pad.
The lead is a solid wire, which extends from and serves as a connection to a component. The
solder pad is a termination area of a printed circuit conductor, which is a patch or track on a
printed circuit board, serving as an electrical interconnection between terminations.
Flux is a material used for soldering technology, which, during soldering, removes the
oxide film, protects the surface from oxidation, and permits the solder to wet the surfaces to
be joined. Activity is the property of a flux that helps to achieve a small contact angle
between molten solder and a solid surface. The most popular flux material is rosin, a natural
resin obtained as the residue after removal of turpentine from the oleoresin of the pine tree.
Resin is a usually transparent or translucent and yellowish to brown substance. Resins are
soluble in organic solvents, but not water. It is non-corrosive and electrically non-conducting.
Rosin is the specific term for resin with regard to soldering.
A soldering process is called no-clean, when low residue fluxes are used so the
assembly do not need to be cleaned after soldering.
Solder pastes are formulated to be printable mixtures, and they are applied to
the pads of the board using stencil printing.
The application of solder paste is commonly done using a stencil printing process.
Solder paste is pressed through openings in a stencil screen onto the corresponding circuit
board lands with a squeegee made of hard rubber or stainless steel. The stencil openings are
called apertures. They are designed to make sure the right amount of solder paste is deposited
onto each land. The apertures must be in perfect alignment with the surface mount lands.
When designing the aperture of the stencil mask, it should be taken into consideration
that the HASL finish is not in use any more for lead-free soldering. When HASL finish was in
use, the PCBs arrived at assembly with a thick layer of solder and this coating readily
provided much of the volume of the solder joint. The most popular lead-free finishes, i.e.
imm-Ag, imm-Sn and OSP are extremely thin and flat, therefore no solder is present on the
board incoming to assembly. PCBs coated by these finishes may require stencil apertures with
a ratio of 1:1. In current practice, an aperture ratio of 1:1 is in use on feature sizes greater than
0.6 mm, and 0.9:1 is used for features 0.6 mm and smaller. Alternately, a thick stencil may be
used to supply the required bulk of solder needed for flat finishes. In addition, print cycle
times may need to be slowed, to avoid solder paste sticking to squeegee blade.
Placement of SM components for reflow soldering
Once solder paste is properly applied to the lands, the circuit board is typically moved
to one or more automatic placement machines for component placement. Surface mount
components are usually supplied in three different ways - on tape and reel, in tubes or in
matrix trays.
Chip shooters with rotating turrets and many nozzles are used for the placement of the
small size SM chip components. Slower pick and place machines with nozzles of different
sizes are in use for larger QFP and BGA components: the nozzles pick up the component
from the trays, tubes or reels, and accurately place them into the solder paste on the lands of
the circuit board.
Other features of placement machines are a conveyor system to transfer circuit boards
into and out of the machine; a table that keeps the board stationary using vacuum or clamping;
and pins or fixtures used to support the board on the table.
A vision system is used to verify correct board and component orientation; and a
computer program which contains the description of the board to be assembled. The program
also specifies the components required, their location on the board in X/Y coordinates, their
orientation and the order in which they will be placed.
SMT pick-and-place head and machine
The high speed automatic assembly lines have to use in-line inspections to find the
failures of the subsequent process steps.
Automatic Optical Inspection (AOI) systems are used after each of the solder paste
stencil printing, the component placement and the reflow soldering step. Most of the failures
can be recognized and corrected.
Reflow soldering
Reflow soldering is
usually carried out in
• a convection type or
• a combined IR heated
hot-air (or N2) furnace.
Conveyor belt type
ovens are applied in
both cases.
After component placement, the surface mount assemblies are ready for reflow
soldering. The two most common heating methods to reflow the solder are forced convection
and infrared.
In convection systems, air or nitrogen is heated and blown onto the circuit board to
melt or reflow the solder. Infrared uses heat panels that radiate the heat to reflow the solder.
The first area inside a reflow soldering machine is a preheat zone. Preheating allows
the circuit board to be exposed to a controlled temperature rise. If all the required heat were
applied immediately, the circuit board and some of the components might be damaged from
heating up too quickly. The preheat operation also causes the flux in the solder paste to
activate. As in wave soldering, this activation allows the oxides to be removed from the metal
surfaces. If the assembly is in the preheat area too long, the flux may “burn out” and oxidation
will recur before solder reflow. When this happens proper wetting may not occur.
The assembly proceeds by conveyor to the next heating zones where higher
temperatures cause reflow and solder wetting to take place.
The final step is a cool down zone, which may or may not be augmented by cooling
fans. Reflow soldering completes the surface mount assembly process.
pump pump
Flux Pre-heating Solder wave
application 80…120 ºC 240…260 ºC
Testboard
used to determine proper
parameters for component
placement and soldering
A printed wiring board (or PWB) is used to mechanically support and electrically connect
electronic components using conductive pathways, or traces, etched from copper sheets
laminated onto a non-conductive substrate.
• one sided
• double sided
• multilayer
• metal substrate
• metal core
The single-sided boards have only one patterned conductive layer, and are used for very
simple applications.
Nowadays the double-sided PWBs are the most widespread, where there are two conductive
layers in the laminate, on the two outer sides of the board. The tracks formed from the two
conductive layers are interconnected where necessary by plated-through, i.e. metallized holes.
The components are usually assembled onto the board by the insertion of their leads through
the same holes. This process is called through-hole assembly. If surface mounting
technology (SMT) is used, where components are assembled onto the surface of the board
without the insertion of the leads into the holes, the holes only serve as interconnections, they
are usually produced with smaller diameters and called vias.
Multilayer printed wiring boards contain more than two, typically four-eight conductive
layers. However the number of conductive layers can be twenty or more. Since there are a
significant decrease in the average size of components and an increase of the component
density on the cards, the need for and the production of the multilayer printed wiring boards
are going up.
PWB categories according to types and materials
For circuit cards and modules the rigid printed wiring boards are used, while flexible
and rigid-flex printed wirings are popular for the interconnection of cards placed in
different position in equipment or of different modules and units.
Rigid printed wiring board Flexible printed wiring board
The base material, i.e. the insulating board of a rigid PWB is a sheet of laminated
reinforced resin. Large majority of the laminates are produced using phenol or epoxy resins,
and polyimide is also in use for advanced applications. Reinforcing materials include paper,
glass cloth, asbestos, aramid, nylon, and so on. The FR-4 type epoxy-fiberglass (glass cloth)
laminate is the standard for all high technology and professional electronic assemblies, as its
dimensional stability and heat resistance are excellent. Polyimide resins are also used with
fiberglass reinforcement for rigid PWBs, as they retain their flexural strength up to 250 oC or
higher. This value is much higher than the soldering temperatures encountered, and than the
125-170 oC glass transition temperature for epoxy laminates. On the other hand, polyimide
laminates are considerably more expensive than their epoxy equivalents.
For flexible PWBs it is also the polyimide insulating material which is used without
any reinforcement, or with low percentage of filler like quartz powder. In some cases
photosensitive polyimide is used in order to make via formation easier and more economical.
The boards are generally produced with one or both sides covered by a copper foil, and called
copper clad laminates. The foil is produced by electrolytic plating onto a stainless steel drum
slowly rotating in the liquid electrolyte. The side of the foil in contact with the drum is
smooth and shiny whereas the other side is matt and granular. The thickness of the copper foil
most commonly used is 17-35 µm, but for fine line circuits, in order to obtain better resolution,
foils as thin as 5 µm are also in use. The adhesion of the foil to the organic reinforced prepreg
(preimpregnated laminate) is achieved at the lamination stage, by pressing the granular side of
the foil to the resin of the laminate and curing at increased temperature.
Recent developments in PWB base materials have been directed toward improving their
dimensional stability and surface smoothness to allow the definition of smaller features,
reducing their dielectric constant to meet the requirements of high frequency applications, and
replacing glass reinforcement with laser processable materials to make laser drilling easier.
Linear laminates use glass filaments for reinforcement, but instead of being woven the very
thin filaments are placed parallel to form a layer and such layers are oriented alternately
perpendicular one to another to make a smooth reinforcing fabric, reducing the surface
roughness of the final resin impregnated insulating board. Aramid paper reinforced laminates,
using paperlike nonwoven aramid fabric with epoxy resin impregnation, exhibit very good
dimensional stability with near-to-silicon CTE, have a smooth surface, and can be easily
processed by laser.
A new class of base material is opened by the invention of resin-coated copper, where the
copper foil, which serves as both supporting and reinforcing material, is covered by thin resin
layers, resulting in a very thin and smooth laminate of high thermal conductivity.
In rigid PWBs based on polyimide insulating material, and in conventional flexible PWBs as
well, an adhesive layer of acrylate or epoxy resin, is applied to bond the copper foil to the
polyimide base material. Most flexible laminates used for advanced applications like
laminated multichip modules (MCM-Ls), however, are based on adhesiveless polyimide films,
where either a polyimide film is cast onto a copper foil (as in the case of resin-coated copper),
or copper metallization, produced by the combination of vapor deposition and electroplating,
is applied to a polyimide film. With the latter technology a copper conductive layer as thin as
1 µm, or even thinner, can be achieved.
The choice of the appropriate base material for a given application is determined by the
following aspects: electrical and mechanical properties, environmental resistance, price, etc.
For commercial applications cheap phenol resin - paper laminates are usually used. They
have good heat resistance, good mechanical processing properties, but their water absorption
is high, and mechanical strength is low. Nowadays self-extinguishing laminates are produced,
therefore in case of fire gaseous combustible products are formed which extinguish the fire.
The code of substrates with such features identified with the abbreviation FR (Flame
Retardant).
Paper based epoxy resin laminates have small dissipation factor and good insulating features
even in wet environment. Mechanically well processable, flexural strength is better, than that
of phenol resin - paper laminates. Through plated holes can also be produced when using this
kind of substrate.
Polyimide-fiberglass laminates are also frequently used. They have good isolation properties
and better heat resistivity, than epoxy resin based substrates.
Characteristics of PWB substrates
Resin phenol epoxy epoxy epoxy
Core material paper paper fibergl./paper fiberglass
Standard (NEMA) FR2 FR3 CEM1 FR4
Flexural strength (N/mm 2) 135 150 330 500
Water absorption (mg) 28 25 10 7
Solderbath resistance (sec) 15-20 25-30 30-40 >120
Adhesion of Cu foil (N/mm) 2,0 2,2 1,7 2,0
11 11 12 12
Sheet resistance (ohm) 10 2x10 10 >10
Cutting properties +++ +++ ++ +
Flammability V0 V0 V0 V0
Price percentages 55 65 80 100
FR flame retardant
CEM Composite Epoxy Material:
Cu
epoxy
paper
fiberglass
Table below provides information on the main characteristics of base materials of usual
reinforcement/resin combinations. The main parameters include: the glass transition
temperature, Tg, at which the amorphous polymer changes from being in a hard and relatively
brittle condition to being in a viscous or rubbery condition, thus it characterizes the heat
resistance of laminates; and the coefficient of thermal expansion, CTE, which value
numerically describes the dimensional stability.
Through-hole
mounted:
SMT, COB,
MCM-L:
The applicability of a PWB, and, as a consequence, the quality of its conductive pattern can
be characterized by the minimal width and spacing of conductive lines, which value is also
called resolution. The quality of the pattern and the resolution can also be characterized on the
basis of a typical pattern part around two holes next to each other. In a normal (or
conventional) configuration the distance between these holes is the usual 2.54 mm (1/10 inch).
For normal patterns the minimal value of the line width and spacing is 0.3 mm or higher. If
the diameter of the hole is 0.9 mm, there is space only for a single track line between the holes.
For fine patterns the typical line width is around 0.2 mm and if the hole diameter is the same
0.9 mm, two lines can be conducted between two holes. For very fine patterns the resolution
is less than 0.1 mm, and the hole diameter can be 0.3 mm or less, if necessary, so more than
two conductive lines can be placed between the holes. PWBs with fine and very fine pattern
resolutions, however, are more frequently used for surface mounting technology (SMT),
therefore the characteristic resolution patterns are from SMT boards.
Nonmetallized holes with round, rectangular or any other shape are used for fixing
components onto the board either by inserting the component leads through them or by using
surface mounting technology (SMT) or chip-on-board (COB) assembling methods. The
metallized holes are used not only for through-hole assembling the components, but for
producing interconnections between the tracks of different conductive layers. Vias are not
intended to insert component leads into them, they are only interconnections, electrically or
thermally joining different conductive layers of a multilayer structure. A through-board via
connects both outer layers and, not necessarily, inner layer(s). A blind via connects an outer
layer and at least one inner layer, but does not connect both outer layers. A buried via makes
interconnection between only inner layers of the board. The aim of a thermal via is to conduct
heat from a component heat source to a heat sink layer of the structure.
Typical through-hole failures
pad lifting
missing pad rotation corner crack
plating
delamination
imprecise
barrel
fitting
crack
break between
layer and plating
pull away
nodule
misalignment plating void
of PCB during
drilling
1. Hole formulation
Removal of material by the relative movement of the tool and the workpiece
a) Punching
The shape is formed by pressing
the material against a die with a
huge force
The shear forces generated
between the material and die
separate the material into the
desired shape
Hole formation:
Punching is the process of using a machine to press a shape through a sheet of material into a
die to create the desired shape in the metal. This is most commonly done by machines which
use hydraulic, pneumatic, or electrical power to press the shape with enough force to shear the
metal.
The shape is formed by pressing the material against a die with a huge force. The shear forces
generated between the material and die separate the material into the desired shape. The
desired shape is not obtained, however, as burred edges and rough surfaces are formed. These
edges and surfaces must be further processed until the desired shape is achieved.
Holes for single sided boards can be made by punching. It is not used for double-sided or
multilayer boards, because punched holes can hardly be metallized. Phenolic resin laminate is
more suitable for punching. Punching is very economical, which is an advantage, when
producing high volume PWBs at a fairly reasonable price.
Mechanical technologies in PWB-production
b) Drilling
Dominant factors:
• the material of workpiece
• the material of tool and it's geometry
• the speed components of relative movement (main-
and side movements)
Primary movement: rotation of drill → cutting speed (v, m/min)
Secondary movement: perpendicular to the surface
→ feedrate (f, mm/rot.)
Composition:
• 88...94 % tungsten carbide (WC)
• 6...12 % cobalt (Co)
Drilling is one of the most critical processes of PWB manufacturing. During drilling, the drill
bit reaches hundreds of oC. This melts the epoxy resin and smears it around the inside of the
hole. For double sided boards this can be a problem because electroless copper will not adhere
well to smeared epoxy. Smear inside the hole is even more problematic when producing
multilayer boards. This type of board has layers of circuitry laminated together. Electrical
connections are made with the inner layers by the plated hole. If the plating is done on top of
epoxy smear, no electrical connection can be made. The drill bit must be hard and sharp. A
dull drill bit can create the problem of having to deposit over loose bundles of glass fibers. It
is difficult to get adequate coverage in cases like this.
Backup plate
For CNC drilling, packet should be prepared. The FR4 epoxy fiberglass substrate, the entry
and backup plates are cut to size and fitted together with 3mm diameter pins. The entry plate
is a 0,24mm thick aluminium plate. For backup 2,5 mm thick plate is used made from resin
and wood fibre. For increasing productivity, more substrates are put together, and drilled at
the same time (Figure 1.). The number of substrates, which can be drilled in the same packet,
is determined by the ratio of the length of the hole and the diameter of the hole, this ratio
should not be more than 7-8 in practice. The aim of entry and backup plates is to avoid burr
formation. The backup plate is intended to protect the work table of CNC also. Set-up of the
packet followed by drilling with CNC machine.
The packet is fixed on the working table by the help of pneumatic device built in the table,
which clamp the two pins. The drill spindle and table is moved by servomotors in the
direction of the three axes. Chips generated during the operation of CNC are removed by the
exhaust system.
d) Plasma etching
High voltage, high energy, rapid rise time electrical pulses are delivered many
times per second to an electrode assembly in contact with the material body to
generate therein elongate plasma channels which expand rapidly following
electrical breakdown of the material causing the material to fracture and fragment.
Plasma etching: Material is removed from a body of material, e.g. to create a bore hole, by
plasma channel drilling. High voltage, high energy, rapid rise time electrical pulses are
delivered many times per second to an electrode assembly in contact with the material body to
generate therein elongate plasma channels which expand rapidly following electrical
breakdown of the material causing the material to fracture and fragment.
3. Milling (routing)
Milling is the process of cutting away material
by feeding a workpiece past a rotating multiple
tooth cutter
In contrast to drilling, where the drill is moved
exclusively along its axis, the milling operation
involves movement of the rotating cutter
sideways as well
Brushing:
The first step in surface finishing is the brushing of drilled boards. The board must be free of
burr, caused by drilling. Brushing is used to clean the surface of laminate, to set the necessary
surface structure, roughness, and to make a smooth surface, having no burrs. PWB is
scrubbed after drilling, before plating, before photoresist mask preparation, and before contact
finger plating. Scrubbing is usually made by conveyor machines, containing rotating and
oscillating brushes. The brushing mashine contains rotating brushes with various corning and
a conveyor system for feeding the board into them. For better efficiency the boards are
continuously washed by water spraying. Water is applied to cool the brushes, the laminate and
to carry away the removed particles. This process removes not only burrs, but other
contaminations as well.
Milling (routing):
CNC routing is used to get the exact shape and dimensions of the PWB. A milling machine
is a tool used for shaping solid materials. Its basic form is a rotating cutter which rotates
around the spindle axis (similar to a drilll), and a table to which the workpiece is fixed. In
contrast to drilling, where the drill is moved exclusively along its axis, the milling operation
involves movement of the rotating cutter sideways as well as vertically. The cutter and
workpiece move relative to each other, generating a toolpath along where material is removed.
The movement is precisely controlled, usually with slides and lleadscrews or analogous
technology. Often the movement is achieved by moving the table while the cutter rotates in
one place. Milling machines can be operated manually or by CNC (Computer Numerical
Control).
2. Printed wiring boards
2.3 Chemical technologies in PWB-production
Me n+ + ne - = Me (reduction)
_
1. Electroplating
+
Can be applied only onto
conductive surfaces, for selective Men+
coatings it is not suitable.
Electroplating:
In this process electrical current is used to reduce cations of a desired material from a solution
and coat a conductive object with a thin layer of the material.
The part to be plated is the cathod of the circuit. The anode is made of the metal to be plated
on the part. Both components are immersed in a solution (called electrolyte) containing one or
more dissolved metal salts and other ions that permit the flow of electricity. A rectifier
supplies a direct current to the cathode causing the metal ions in the electrolyte solution to
lose their charge and plate out on the cathode. As the current flows through the circuit, the
anode slowly dissolves and replenishes the ions in the bath.
Electroplating is primarily used for depositing a layer of material to bestowe a desired
property (e.g., abrasion and wear resistance, corrosion protection, lubricity, aesthetic qualities,
etc.) to a surface that otherwise lacks that property. Another application uses electroplating to
build up thickness on undersized parts.
2. electroless deposition
Men+ + reducing material = Me
3. „direct plating”
after deposition of conductive chemical compound onto the
insulator surface it can be electroplated
The purpose of the electroless copper deposition process is to metallize the isolating
wall of drilled holes. This metallization provides an electrical connection between the sides of
a panel, and to the inner layers of multilayer boards.
Before electroless copper process, the drilled PWB is mechanically and chemically
cleaned by scrubbing, removing of grease, micro-etching and oxide-removing.
The surface of the PWB must be activated. Activating is necessary, because the copper
coating must be deposited onto the isolating surface of epoxy-resin. After this stage PWB is
ready to metallization, which usually means through-hole plating.
The electroless copper deposition process is based on the chemical reduction of
copper initialized by the activating particles. Slow operating type of electroless copper bath is
used to deposit a very thin, but continuous layer of copper. Electroless copper layers,
deposited from a room temperature bath, are only ca 1 micrometer thick. The advantage of
this type of bath is the careless operation. When using slow operating type of electroless
copper bath, the thin coating of electroless copper is thickened by electroplating. In this way
the copper coating being inside the holes is formed by a two-stage depositing process:
electroless copper followed by electroplating. By using quick operating electroless copper
bath, it is possible to deposit the copper coating by a single-stage process, without
electroplating.
Immersion deposition: The process needs neither power supply nor reducing agent. The
material of work piece (Me2, it can be only metal) oxidizes, i.e. transmits its electrons to
Me1n+ which will be reduced and deposited on the surface of work piece. The condition of
the process is that the normal potential of Me2 is more negative than that of M1. It means,
that only certain metals can be coated using this process.
2. Printed wiring boards
2.4 Patterning processes of PWBs: Masking technologies
Masking technologies
For patterning (or imaging) with a mask, the dry film photoresist method
is the most popular in the PWB industry.
1. Screen printing
Screen printing is an old process, however it has taken giant technological steps forward.
Nowadays stainless steel or polyester screens, UV exposure, rubber or plastic squeegee are
used. There are different types of stencil medias: indirect, direct or direct/indirect.
Direct/indirect system's advantages over indirect system are the longevity of the stencil and its
ability to hold sharp lines. The main advantage of direct system is that the stencil thickness
can be controlled as required.
Lot of manufacturers have automatic screen printers. Advantages to using this type of
equipment are:
- the pressure used during the printing is uniform and consistent;
- the squeegee angles with respect to the surface of the panel is consistent;
- the throughput is higher.
In the PWB industry etching resists, plating resists, solder resists and legend resist are applied
by screen printing.
Masking technologies
2. Dry film photoresist technology
1. step: Lamination 2.step: Photoresist exposure 3.step: Developing dry film photoresist
Cu-layer
Photoresist Cu-layer
2. Photoresist exposure
After laminating the panel is exposed using the phototool or artwork for masking. Important
elements of a good exposure are the cleanliness and the correct developing. It is necessary to
control humidity and temperature according to the film manufacturer’s limit. The phototool
(or photomask) must be fitted correctly to the panel, with its good contact to the dry film
coated panel during vacuum pump down and exposure. The emulsion of the phototool must
be placed directly against the photoresist covered sheet for maximum resolution and accuracy.
Exposure is a fairly important factor, because almost every aspect of dry film imaging has an
effect on exposure. Step wedges are useful to determine correct exposure.
Photoresist is a combination of monomers, free radical photo initiators, plasticizers, dyes,
adhesion promoters and a methacrylic binder which holds it all together. When this resist film
is exposed to UV radiation the photo initiators generate free radicals. A free radical chain
reaction (polymerization) is set off. What had formerly been a soft, gelatinous film, easily
washed away by the developing solvent, has now become a hard, chemically resistant surface,
suitable as plating or etching resist.
3. Developing
The unexposed resist is washed away in conveyorized or non-conveyorized developer.
Nowadays, fully aqueous developing photoresists are in use to meet the environment
protection requirements.
Processing possibilities:
• Subtractive technology
The raw material is a dielectric plate with copper cladding on one or both sides.
The copper layer is removed (usually by chemical etching) where the wiring is
not needed.
The resolution is limited by the adhesion of the conducting layer and the
undercutting effect.
• Additive technology
The conducting layer is deposited on the insulating substrate in a particular
pattern using a mask.
It results in finer resolution but worse adhesion.
• Semi-additive technology
It combines the advantages of both previous technologies
The subtractive process uses copper clad laminates and subtracts the unnecessary pattern of
copper layer from the surface by etching.
In the course of the additive process the wiring pattern is deposited physically, chemically or
mechanically onto the originally insulating surface of the board.
Etching
wire pad
Positive mask:
Starting with a copper clad laminate, the pattern of the wiring is screen printed onto the
surface as a positive mask. Alternatively photoresist technology can also be used to make the
same mask, but the much cheaper screen-printing is sufficiently good for the rough resolution
of common single-sided boards. From the uncovered places the copper foil is removed by
etching, then the mask layer is stripped, and in the last step the holes are drilled.
Negative mask
2. Printed wiring boards
2.6 Subtractive technology of double sided, through-
hole metallized boards
Sn reflow
Multilayer printed wiring boards contain typically 4 to 20 conductive layers. Since there
are a significant decrease in the average size of components and an increase of the component
density on the cards, the need for and the production of the multilayer printed wiring boards
are going up.
The number of layers is determined by the number of conducting layers.
The manufacturing of multilayer printed wiring boards contains three separate process
sequences: at first the panels with the inner conductive layers are produced by simple double-
sided etching from copper clad prepreg laminates; then these etched panels, adhesive prepregs
and unetched outer panels are laminated, pressed and cured (heat treated) to get a rigid board;
and at last this board is processed by a sequence corresponding to pattern or panel plating of
double-sided boards.
The special and most important steps of this usual manufacturing process of multilayer
PWBs involve the lamination of etched and unetched panels. Any combination of single-sided
and double-sided prepreg panels can be used to form the required multilayer structure, with
the only condition that all inner layers must be patterned before lamination.
Technology of multilayer boards II.
Cu plating
Sn/Pb plating
resist stripping
Cu etching
Fabrication of multilayer printed wiring boards contains three separate process sequences:
- at first the panels with the inner conductive layers are produced by simple double-
sided etching from copper clad prepreg laminates;
- then these etched panels, adhesive prepregs and unetched outer panels are laminated,
pressed and cured (heat treated) to get a rigid board
- at last this board is processed by a sequence corresponding to pattern or panel plating
of double-sided boards.
1. Lamination of the boards.
2. Drilling
3. Currentless copper plating
4. Applicate photoresist
5. Copper plating
6. Surface plating
7. Stripping of the photoresist
8. Etching
Via types and layers of multilayer boards
Vias are plated-through holes on two-sided and multilayer boards that are used to interconnect
layers or traces, but they are not used for component mounting. Vias are usually smaller in
diameter than component holes. There are two special types of vias:
1. Blind vias. Blind vias are visible from one exterior side of the board. The other end of blind
vias terminate on interior layers.
2. Buried vias. Buried vias are not visible from an exterior layer of the board. They connect
conductive layers in the interior of the PCB.
A multilayer board is created by applying conductive and insulating layers one after each
other.
Multilayer boards are produced by applying layers one after the other.
Producing layers connected by vias:
• Applying metallized vias
• Applying column vias
• Advantages of microvias
• Examples presenting the technological process:
• laminating and drilling by laser or plasma
• using photosensitive dielectrics
• Combining thin-film technologies and chip attachment on flexible substrates
Advantages of microvias:
• Shorter wires (higher speed)
• Smaller number of layers
• Smaller size
• CSP and BGA packages can be used
• Smaller parasitic effects (lower noise)
• Better thermal conductivity
• Improved reliability
• Lower cost
Comparison of structure of
different microvias
Laser
Plasma
Drilling
The low cost photo via processing requires layers of photoimageable dielectric materials.
These photosensitized polymers, mainly on polyimide or epoxy basis, work like photoresists:
after having been exposed through a mask, the vias and windows of any geometry defined by
the mask can be developed. Curing is used to improve the dielectric properties of the
materials.
Plasma-etched via (PEV) technology applies vacuum process to remove the polyimide
dielectric layer. All vias for one layer are generated simultaneously. The previously patterned
copper layer serves for masking, i.e. the polyimide is etched through the openings of the
copper layer, etching automatically stops at the inner copper layer. Blind vias can be
generated from any side of the board. Typical via holes are 60-90 µm in diameter and require
200-300 µm capture pads. Regarding the processed geometry, PEV is a very flexible process:
in addition to through and blind vias it can create slots, windows, stepped windows (using
controlled etch time), slanted vias and unique structures as well.
An alternative technology is laser via generation. Similarly to PEV, laser vias can be
generated through polymer films applying the patterned copper layer for masking by exposing
the entire surface with UV excimer lasers, or by punching, one hole after the other, using a
frequency multiplied UV Nd:YAG defocused laser beam. PEV and excimer laser via
generation technologies need expensive equipment, however, they can be economic for mass
production. Nd:YAG laser technology has the advantage that copper layers can also be
processed with focused beam by trepanning along the hole perimeter. Blind vias can also be
generated by the combination of focused beam spiraling and defocused beam punching. In
general, it is less effective, but more flexible; it is preferred for prototyping or smaller batch
manufacturing.
Any of these three processes can be used for via hole generation in the pastevia process. After
the holes are opened into a single dielectric layer, they are filled with conductive paste. The
copper foils are laminated and photo-imaged later on the dielectric layer. The complete board
is finally prepared by co-lamination and curing.
All four via preparation and wall metallization methods have particular advantages:
- photovia technology is very productive, resolution is high, but provides irregular hole
wall quality, and needs special photodielectric materials;
- plasmavia process provides even hole uniformity and cleanliness, it is productive, but
needs expensive equipment;
- laser via drilling provides very clean surface and suitable wall shape, it is very flexible,
but less economic than photovia processing;
- paste vias are very cheap, but less reliable than wall metallized vias.
For Insulated Metal Substrates bare metal sheet base materials are used. At first larger holes
are drilled into the metal sheet; liquid epoxy is used to fill up the holes and cover the surfaces
on both sides; the required diameter holes are drilled; and finally additive electroless plating
combined with photoresist processing and etching is applied for copper deposition and
patterning.
V=0.12..1.5 mm
•Aim: to minimize the thermal expansion mismatch between the substrate and the
components / to adjust the thermal expansion coefficient of the substrate to that of the
components
Thermal expansion coefficient: Core materials (≈≈ 5 ppm/°C):
• epoxy-woven fiberglass 12..16 ppm/°C • Cu-Mo-Cu (CMC)
• CCC encapsulation 5.9…7.4 ppm/°C • Cu-Invar-Cu (CIC)
Metal core printed boards have the advantages of both lower thermal expansion and higher
heat dissipation. An approach can be to laminate single-sided boards onto each sides of a
metal sheet with low CTE, like invar. The holes, that should be insulated from the metal core,
are prepared by the following process sequence: drill larger than required holes; fill up the
holes with epoxy resin and cure; and drill holes to the same positions with required diameter.
Then the usual double-sided PWB technology can be applied.
Flexible PWBs
Materials: plastic (polyimide
- Kapton, polyester - Mylar,
PTFE - Teflon)
foil without rreinforcement
Flexible printed wirings are used for cables to electrically interconnect distant or moving
boards or modules; for foil keyboards to overpass level or angle deviations; for three
dimensional modules to be realised on a single board, etc.
For flexible PWBs it is the polyimide insulating material which is used without any
reinforcement, or with low percentage of filler like quartz powder. In some cases
photosensitive polyimide is used in order to make via formation easier and more economical.
The boards are generally produced with one or both sides covered by a copper foil, and called
copper clad laminates. The foil is produced by electrolytic plating onto a stainless steel drum
slowly rotating in the liquid electrolyte. The side of the foil in contact with the drum is
smooth and shiny whereas the other side is matt and granular. The thickness of the copper foil
most commonly used is 17-35 µm, but for fine line circuits, in order to obtain better resolution,
foils as thin as 5 µm are also in use. The adhesion of the foil to the organic reinforced prepreg
(preimpregnated laminate) is achieved at the lamination stage, by pressing the granular side of
the foil to the resin of the laminate and curing at increased temperature.
Rigid-flex combined PWB
Metallized holes
Wiring pattern
Adhesive foil
Flexible
substrate
Metallized through
Rigid
Rigid substrate holes
substrate
Rigid and flexible PWB technologies can be combined, as in the rigid-flex board, where a
flexible board is laminated into rigid multilayer boards forming the inner layers of them.
Technologies based on copper clad laminates and on polymer thick films both are in use for
the manufacturing of flexible interconnections and rigid-flexible combinations.
Rigid-flex circuit boards provide opportunity for building higher component density modules
of 3-D folded configurations in size-limited applications. They are also used in pocket
calculators, laptop computers, mobile phones and similar lightweight, portable electronic
equipment, where there are folding p
arts containing electronics on the rigid boards interconnected by the in-built flexible wiring.
The technology of a multilayer rigid-flex printed circuit board usually starts with the
preparation of a flexible double-sided foil, which will serve as flexible part of the board and
inner layers of the rigid parts as well. It is followed by lamination of rigid prepregs, but not
onto the entire surface, thus leaving flexible areas in the board. The further steps are
conventional multilayer PWB processes.
3D MIDs (Molded Interconnection Devices)
SMD
Shock resistant
plastic, e.g.
PEI=polyetherimid
A possible approach for the increase of wiring density of PWBs is the application of real
three-dimensional (3D) construction. The edges of a traditional multilayer board are ground to
get clear metallic cross surfaces of the printed wires, which are intentionally led to the rim of
the board. Then the edges are electroless copper plated or covered by copper using any other
edge-contacting process. An appropriate insulating pattern is cut by laser direct writing to
prepare tracks between the lines on surfaces and inner layers.
Another popular 3D construction is a molded case of any shape with patterned conductive
layer, which follows the 3D shape of the inner surface of the case. The pattern can be
prepared by electroless copper deposition, photolithography and etching. Alternatively, the
surface is spread with silver powder, and a hot photogravure tool is used to press and fix the
pattern onto the surface while the powder can be removed from the unpressed areas.
Multiwire PWB
Multiwire PWB: combining the PWB technology with the conventional wiring.
Metallised through holes are made after sticking insulation covered wires
into the cover prepreg film.
Wire peaces are laid down (pressed into) the B-stage prepreg laminated onto the substrate
between the through-holes to be drilled later.
After that the epoxy layer will be cross-linked (solidified). Then the board will be drilled and
the holes will be metallised.
The wires are connected to the electric circuit through the metallised through-holes.
Former surface coatings, like electroplated tin or tin-lead on the whole pattern are not
proper anymore because of „orange-effect” and incompatibility with environmental
aspects.
Approximate incidence of
different surface finishes
Applying leaded soldering the most commonly used and one of the cheapest surface finish of
PWBs was the selective eutectic (63Sn37Pb) alloy made by Hot Air Solder Leveling (HASL).
To comply the requirements arising from RoHS, surface finishes of substrates and
components must not contain the banned elements, e. g. lead, of course. Surface finishes are
usually selective, namely they are only on the pads. Eliminating the tin- or tin/lead coating
under the resist reduces the possibility of the resist lifting during the assembly soldering
operation.
However there is an other requirement arising from the technology: the higher heat-resisting,
because the melting point of lead-free solder alloys and therefore the soldering temperature
are usually much higher.
HASL (Hot Air Solder Level)
• Coatings
– SnCu
solder
– SnCuAg
– e.t.c.
• Advantages
– Current technology
– Multiple reflows
– Long shelf-life
– Low cost
finishing
• Disadvantages
– Uneven surface
– Corrosion of equipment
The board is first fluxed and then immersed into molten solder. When the board is
withdrawned from the solder pot, jets of hot gas ‘air knives’ are directed at both sides of the
board through angled nozzles. These clear solder from the holes and blow away excess solder
from the pads, a process called as levelling. The temperature of the air used is usually at
around 240°C, a little lower than the solder bath.
The process can be carried out with the board held either vertically or horizontally: vertical
HASL gives better hole coverage and horizontal HASL gives flatter surface mount pads.
One of the problems with the vertical process is that one end of the panel receives a longer
dwell time than the other, resulting in differences in the growth of the intermetallic which
grows between tin and copper.
Immersion Sn
• Coating
– Sn
• Advantages
– Simple technology
– Low price Whisker-formation
finishing
• Disadvantages
– Danger of whisker-
formation
– Limited shelf-life
– Limited reflows
Immersion tin deposits 0.75 to 1.25 microns of tin utilizing an immersion plating process.
The tin deposit is modified by low levels of co-deposited organic and metallic additives. This
eliminates tin whiskers and limits the growth of tin-copper intermetallic. Immersion tin is the
thickest alternative coating to HASL and provides the best surface for compliant pins and In-
Circuit Test. The chemicals are delivered with superior performance and no-clean assembly
operations.
Immersion Ag
• Advantages
– Simple technology
– Low price
– Multiple reflows
finishing
• Disadvantages
– Limited shelf-life (Must be
vacuumed packed for storage)
– Chloride or sulfide atmosphere
causes tarnish
Immersion Silver consists of a very thin coating of nearly pure silver. A slight amount of
organic material is typically deposited within the immersion silver intended to prevent tarnish
and electromigration. The metal coating is deposited via a relatively simple conveyorized or
vertical chemical process. Benefits of immersion silver include flatness, lead-free,
inspectability at assembly, lack of solder mask attack, and surface contact functionality.
Relative to other PCB coatings, immersion silver does not suffer from the black-pad
interfacial fracture phenomenon, tin-copper intermetallic shelf-life reduction, whisker
formation, or sensitivity to weak fluxes. Immersion silver plated on today’s clean, well
formed; well tested PCB’s is proven to be very functional in billions of solder joints in
existing electronics devices. For these reasons, OEM’s fabricators and assemblers have
increasingly used and specified immersion silver during the past 10 years.
Manufacturing Immersion Ag and Sn finishes
Laboratory equipment
for immersion tin
Cleaning
Cleaning
Microetching
Microetching
Preperation
Preperation
Immersion
Immersion process
process
Drying
Drying
Both Immersion Ag and Sn processes are easier to control, have short process times (high
throughput), and operate at moderate temperatures compared with ENIG. The coating
thickness depends on immersion time and coating bath temperature.
The typical process steps for immersion tin are the following:
1. Pre-cleaning: the acid cleaner removes oxides, organics and developer residues.
2. Microetching: on the copper to produce a highly active polished copper surface
3. Preparation: a conditioner creates an active copper surface on which the reaction can
take place. Prepares the surface for coating, and reduces the formation of oxide.
4. Immersion process carefully controlled to give a fine dense deposit of pure tin or
silver.
5. Drying: A warm-air drying stage, removes any residual moisture from the board.
OSP (Organic Solderability Preservative)
• Coatings
– Water-based organic compounds: solder
Benzotriazol
Benzimidazol
• Advantages
– Simple technology
– Very low cost
– Flat surface
– Almost invisible
finishing
• Disadvantages
– Limited shelf-life
– Limited reflows
– Not compatible with some types
of flux
The protective coatings are generally defined as organic coatings. The most common
coatings are benzotriazole and imidazole; both are organic nitrogen compounds.
Benzotriazole has long been recognized as an antitarnish coating used in the general metal
finishing industry. Inhibitor coatings are extremely thin and essentially invisible on the copper
surface.
The coatings protect the copper by chemically bonding to the surface and prevent the reaction
between the copper and oxygen.
The protective coatings have been used for many years by large volume manufacturers for
surface mount products. The limitations of the coating is its general inability to stand up to
multiple soldering operations. The coatings are degraded by exposure to high temperature and
become unsolderable with mildly activated soldering fluxes. The use of high activity water
soluble fluxes have often been used on second side wave soldering processes requiring
thorough cleaning.
The coatings are also susceptible to damage by high humidity storage which can degrade the
solderability. Incorrect handling by assembly staff has also been seen to affect the coating due
to the introduction of handling soils.
Manufacturing OSP finishes
Cleaning
Microetching
Microetching Ide is kéne
valami
Air
Air knives
knives animáció
OSP
OSP application
application
Air
Air knives
knives
Drying
Drying
The OSP process selectively applies a flat, anti-oxidation film onto the exposed copper
surfaces of the PWB to preserve the solderability of the copper.
1. Cleaning: the board must be cleaned by a series of cleaning chemicals. Each pre-
treatment chemical must be followed by water rinsing (normally two to three times) to
remove the chemical that adheres to the surface.
2. Microetching: on the copper to produce a highly active polished copper surface
3. Air knives: it removes the remaining water on the panel to limit oxidation formation
on the copper surfaces prior to coating application.
4. OSP application: the board is dipped in a solution of the OSP for 1–3 minutes. This
forms a chemical layer on the surface of the copper 2–10nm thick, depending on the
formulation.
5. Air knives: it removes the remaining OSP from the panel and promotes even coating
across the entire PWB surface.
6. Drying: A warm-air drying stage, removes any residual moisture from the board.
ENIG (Electroless Nickel/Immersion Gold)
solder
• Coating finishing
– Ni + Au
• Advantages
– Multiple reflows
– Long shelf-life
– Good Wettability
• Disadvantages
– More complicated technology than
the Sn or Ag
– „Black pad” effect
– Expensive
Gold is a traditional finish used in the electronics industry due to excellent electrical finish,
corrosion resistance and good solderability.
There has been some resistance to the use of gold due to concerns of reliability of the final
solder fillet. In the past, gold has been widely used for connectors; it was also used in the
1970's for a solderable coating on boards. The use of thick > 1µm gold coating lead to the
formation of gold/tin intermetalics which in turn lead to weak and fragile solder joints.
Ever since, soldering to gold has been avoided particularly in high reliability applications like
military and aerospace. Many existing standards relating to assembly and soldering require all
gold coatings to be removed prior to the final soldering operations.
Over the last ten years thin gold <0.25 µm over nickel have become popular finishes for
surface mount boards. They have provided an ideal assembly surface, highly solderable and
an aid to inspection due to the contrasting color between component leads and the solder paste.
Cleaning
Microetching
Microetching
Catalyst
Catalyst
Acid
Acid bath
bath
Electroless
Electroless nickel
nickel
Immersion
Immersion gold
gold
The gold coating does not oxidise, its excellent wettability by molten solder does not degrade
with time, and a plated finish maintains the flat surface of the copper lands. For these reasons
a gold finish fulfils the requirements for boards designed for fine-line printing. However, thin
gold plating is porous, and will not protect the underlying copper against oxidation. Oxidised
spots at the base of pores are a cause of dewetting, and copper can also diffuse to the gold
surface during heat treatments, where it can oxidise and thus impair wettability. To prevent
this, an electroless nickel underlayer is first deposited, to act as a barrier to copper diffusion:
1. Cleaning: the board must be cleaned by a series of cleaning chemicals. Each pre-
treatment chemical must be followed by water rinsing (normally two to three times) to
remove the chemical that adheres to the surface.
2. Microetching: on the copper to produce a highly active polished copper surface
3. Catalyst: The electroless nickel is an autocatalytic process that deposits nickel on the
palladium-catalysed copper surface.
4. Acid bath
5. Electroless nickel plating is an auto-catalytic reaction used to deposit a coating of
nickel on a substrate. Unlike electroplating, it is not necessary to pass an electric
current through the solution to form a deposit.
6. An overlay of gold to prevent corrosion.
4…6 +
Thickness (µm) 1…25 0,8…1,2 0,05…0,20 0,2…0,5
0,05…0,10
Process temperature
240…260 70 50 40 80
(oC)
Number of reflow
6 2-3 6 2 6
cycles
Shelf-life
18 6 12 6 24
(months)
HASL (Hot Air Solder Level) is the predominant final finish applied worldwide. HASL is a
predictable, well-known coating, it is used in billions of solder joints daily. However, the
uneven surface of lead-free HASL, which limits its application to fine pitch components, is
pushing the electronics industry to consider alternatives to HASL.
Numerous papers have been published over the last decade predicting the replacement of
HASL with organic solderability preservatives (OSPs), electroless nickel/ immersion gold
(ENIG) or new metallic immersion technologies such as silver and tin. So far, none of these
coatings has yet become so popular as HASL.
HASL alternatives allow a lead-free printed wiring board (PWB) and also provide flat
coplanar surfaces to meet technology demands. Finer pitch and area array devices have
allowed increased functionality of electronics. Typically, higher technology opposes lowering
cost. However, most alternatives improve high technology assembly and long term reliability
while still reducing cost.
Cost savings are the function of the entire process, i.e. costs that includes process chemistry,
labor and overhead. Alternatives like OSPs, immersion silver and immersion tin can provide a
20 to 30 percent reduction in final finishing costs. Although the percent saving per board may
be low in large high-layer count multilayer products, the cost savings with disposable
electronics, along with greater functionality and elimination of lead, will drive a dramatic
increase in the use of alternatives.
The use of alternatives would not only increase but would replace HASL as the final finish of
choice. ENIG, OSPs, immersion tin and immersion silver all provide lead-free, highly
solderable, coplanar surfaces that, under production conditions, provide significant
improvement in first pass assembly yields.
Solder Mask Interface Attack: The existing acid based aqueous processes contain toxic and
corrosive chemicals which degrade copper tracks. Corrosive chemicals in the ImAg process
get trapped under the soldermask edge and may erode the copper trace at the interface
between the solder mask and the copper trace.
Black Pad: Black pad forms during the immersion gold deposition step and it is a low-level
nickel corrosion defect. A compromised nickel surface and prolonged dwell in the immersion
gold bath is needed for its form. On an ENIG-finished board, the purpose of gold is to
preserve gold. If soldered properly, gold will dissolve and migrate into the solder ball, and
older will adhere to the nickel layer directly. Although if the nickel layer has small amounts of
contaminates that prevent good adhesion, gold dissolves, but the solder cannot mix and adhere
to the tin. This causes the black pad effect.
Whisker: The tin whisker is an electrically conductive single crystal structure of tin which
grows spontaneously. It has been observed of growing to lengths of several millimeters and
up to 5 µm in diameter. The mechanism of whisker growth had been studied for many years.
Although it is not well understood, it is thought that compressive mechanical stresses cause its
growth like residual stresses caused by electroplating, mechanically induced stresses; stresses
caused by diffusion of different metals, and thermally induced stresses. In the presence of
compressive stress, whiskers are extruded over time as a stress release mechanism.
Dendrite: Due to the electrochemical migration phenomenon. It develops when the circuit is
operating because it needs electrical voltage (DC) and a film of moisture. Metal ions are
formed due to anodic dissolving, they migrate through the electrolyte, and they exude on the
cathode in a dendrite form.
Definition:
– lead-free package is a standard package with lead removed from the lead finish
coating or solder ball alloy.
– lead-free package must be capable of withstanding reflow conditions with peak
temperatures reaching 260 degree C.
– lead-free package is part of Green package that is lead free, halogen free and high
temperature capable.
There are a variety of surface finishes available for lead-free components leads, including:
- Tin (Sn), e.g. matte tin (100%Sn)
- Tin Copper (SnCu) (e.g. Sn/0.7%Cu)
- Nickel Palladium (NiPd), e.g. Ni-Pd/Au pre-plated lead frame
- Palladium (Pd)
- Tin Bismuth (SnBi) (e.g. Sn/2~3%Bi)
- Tin Silver (SnAg) (e.g. Sn/3.5%Ag)
- Tin Silver Copper (SnAgCu)
Market demands will determine the alternative finish of choice.
Recent studies showed that most manufacturers are producing lead-free components with a
matte tin finish. Component manufacturers cite the low cost of converting existing equipment,
compatibility with the current group of popular lead-free solders, and low risk of whisker
related failure in consumer products as the main reasons for producing tin finished
components.
The most popular lead-free finish is the matte tin despite industry concerns of tin whisker
formation. The problem of tin whiskers on component leads has been well documented. While
there is limited information on the exact growth mechanism, there are a number of mitigation
strategies available. These strategies range from simple processes such as annealing the tin
finish, to more complex processes such as plating underneath the tin finish with a stress
reducing under-plating.
Because the direct measurement of contact angle is difficult, there are different test
methods in use for determination of solderability.
A contact angle can be measured by dropping pure liquid on a solid. The angle formed
between the solid/liquid interface and the liquid/vapor interface and which has a vertex where
the three interfaces meet is referred to as at the contact angle.
They are suitable for comparison and/or optimization of different solder alloys,
fluxes, surface finishes, technological parameters of soldering etc.
However the results of tests performed with different methods mostly are not
comparable.
A quantitative method for determining the solderability is the Wetting Balance Test method.
This method measures the time for the solder to wet the component termination or pad. Two
important attributes of the wetting balance curve are the time to 2/3 of maximum force (t2/3)
and maximum force (Fmax).
In the conventional wetting balance test the leaded components after fluxing are immersed in
a bath of molten solder and the time taken to wet the leads and the wetting force is measured
and a wetting balance curve produced.
However for specimens having small wettable areas such as chip resistors, chip capacitors,
pads etc., a globule of molten solder is substituted for the solder bath. The specimens are
tested using zero immersion depth; this method has so far shown to produce reproducible
results.
0,1 µN
Performance of the
Wetting Balance Test
ms
Bridging Test
Excellent solderability
Using permanent wetting test patterns can be simple and eliminate the need for costly test
equipment. It is easy to build up a library of data which can be compared with changes in
production profiles, new pastes and other process changes. The test method can be used to
compare the degree of wetting between different alloys.
By simply adding a group of parallel lines on panel areas of a circuit board or on an open area
of a board, testing can be conducted on every board produced. It is also possible to select
sample boards at goods receipt, if required to check solderability using a true production
environment and the intended combination of materials. In this case the paste is printed only
on the test pattern of 72 dots using a mini stencil prior to running a board through reflow.
Each time a panel is printed with solder paste the test coupon is also printed. Solder paste dots
are printed along the parallel tracks with decreased spacing between the dots. During reflow
and depending on the solderability of the surface finish, paste
type, the atmosphere used and the temperature profile will then reflow the paste and wet the
tracks. A measure of the solderability is taken by counting the number of dots that do not
completely coalesce together after reflow. If the test pattern is incorporated on to both sides of
the panel, assessment can be made on the impact of two reflows. The test can be used to judge
the effect of other processes like board baking, wash off of paste, nitrogen levels and of
course alternative PCB finishes and suppliers.
Bridging Test
Ag HASL
Spreading Test
The test process is the following: paste circles have to be printed to the contact test-pad, and
after the reflow soldering the spreading (the surface of molten and solidified solder) has to be
measured. The bigger is the spreading, the better is the wetting. The diameter of printed paste:
5,08 mm. The dimension of contact test-pad is 27.94 mm x 27.94 mm.
The test can be used to judge the effect of different solder alloys, fluxes, different process
parameters, alternative PCB finishes and/or suppliers, etc.
4. Solder paste stencil printing
4.1 Stencil manufacturing technologies
The solder paste can be applied in two ways to the pads; by dispensing or by stencil printing.
Due to its productivity stencil printing is the method for mass applying solder paste, where a
squeegee forces the paste through the apertures to pads in one step. Dispensing is slower
process because the paste is applied to pads one by one, therefore this method is used mainly
at prototyping. Its advantage is that a relatively expensive stencil is unnecessary.
Stencil Manufacturing Technologies – chemical etching
Chemical etched stencils are the workhorses of the stencil world. They are the most cost
effective and the quickest to turn around. (Same day shipments are a daily occurrence.)
Chemical etched stencils are created by coating a metal foil with resist, exposing an image
onto both sides with a pin-registered photo tool and then etching the foil from both sides
simultaneously using a dual-sided process. Since the process is dual-sided, the apertures, or
openings, are created as the etchant works through the metal not only from the top and bottom,
but also horizontally. Inherent in this technique is the creation of a knife edge, or hourglass,
configuration. While at 0.5 mm pitch and under, such a profile presents an opportunity for
paste adherence into apertures.
Laser cutting
- Subtractive technology, medium price
- Trapezoidal aperture, material: nickel or stainless steel
- Appropriate for pitch size: >0.4 mm
Produced directly from the customer's original Gerber data, laser-cut stainless-steel
stencils feature an absence of photographic steps. Hence, eliminating the opportunity for
mis-registration. A stencil can be made with excellent positional accuracy and
reproducibility The Gerber file, after the necessary modifications, is transferred to (and
directly drives) the laser. Less physical intervention means fewer opportunities for error.
Although there were initial concerns about the dross (vaporized molten metal) created by
the laser beam, the current generation of laser cutters produces minimal dross that is
removed easily. The major drawback of the laser-cut process is that the machine cuts each
aperture individually. Naturally, the more apertures, the longer it takes and the more
costly the stencil. The laser technique is the only process that permits an existing stencil to
be reworked, e.g., to add apertures, enlarge existing apertures or add fiducials.
Trapezoidal Apertures
A trapezoidal aperture may be used to enhance solder paste release. In chemical etch
processes, the trapezoidal dimension, Z, can be specified. At lasercut process trapezoidal
apertures are created automatically per the laser beam's focus, which aids paste release.
The aperture openings actually are cut from the contact side of the stencil, the stencil then
is flipped and mounted with the squeegee side up.
Stencil Manufacturing Technologies - electroforming
Electroforming
- Additive technology, expensive,
- Material: nickel
- Appropriate for pitch size up to: 0.2 mm
Electroforming creates a nickel stencil with a unique gasketing feature that reduces
solder bridging and minimizes the need for underside stencil cleaning. This process
provides near-perfect registration with no geometric limitations, smooth vertical side-
walls with a built-in taper and low surface tension to enhance paste release. The stencil is
created by imaging photoresist on a substrate where the apertures are intended and then
plating - atom by atom, layer by layer - the stencil around the resist to the desired
thickness. During the process the nickel atoms are deflected by the photoresist to create a
trapezoidal configuration. Next, when the stencil is removed from the substrate, the top
becomes the contact side to create the gasketing effect. A continuous nickel thickness
range of 25 to 300 µm may be selected. This process is ideally suited for ultra-fine-pitch
requirements (0.2 to 0.4 mm). As for drawbacks, since a phototool is involved (albeit one-
sided) the potential for misregistration exists. And if the plating process is not uniform,
the gasketing effect is negated.
Electroformed Stencils
Solder paste
http://engweb.gre.ac.uk/emerg/images/solder%
20paste%20particles.jpg
© Senju
Solder paste is a combination of pre-alloyed spherical metal powder and flux medium.
Solder paste formulations are designed with specific characteristics of tack time, stencil
life, and rheology (flow characteristics). As solder paste ages and is used in production,
these characteristics will change. Handling solder paste properly will preserve the original
characteristics of the solder paste longer, resulting in less paste waste, better process yield,
and lower defect rates.
Properties of Solder Pastes
Moisture
Moisture is a contaminant, and is perhaps the most detrimental element that solder paste
can be exposed to. Moisture can cause and increase powder oxidation, which in turn
requires more of the activator to expend itself on cleaning the solder powder and less for
cleaning the components and substrate. This may result in poor or non-wetting. Moisture
also causes slumping that can lead to bridging, may result in solder balling when the paste
is reflowed, can result in flux/solder spatter, and can reduce tack time.
Excessive Heat
Because solder paste is made of two ingredients with very different densities, it is normal
in some formulations for a bit of flux to separate out of the paste and rise to the top of the
material. If a solder paste is exposed to excessive heat for a prolonged period of time,
however, the separation of the flux medium from the body of the paste may increase
dramatically. This is recognizable when opening a jar of solder paste or viewing the
contents of a container; although it is natural and acceptable for some flux to appear on
the surface of the solder paste, if the paste has become heat damaged a thick deposit of
flux will be floating on top of the paste.
The manufacturer of the paste always gives recommendations for the printing speed and
squeegee pressure settings. The possible printing speed is determined by the solder pastes
thixotropic behaviour. Usually it is in the range from 25 mm/s to 200 mm/s, while
pressure is between 2N and 10N. The initial settings should be 40 mm/s and 4N. The
speed can be increased until solder paste rolls perfectly on top of the stencil . Medium
speed should be set for fine pitch applications such as 50-100 mm/s.
The printing speed can be increased until solder paste rolls perfectly on top of the stencil,
if speed is set too high, the solder paste will slide on the stencil, and willl not fill the
apertures.
The squeegee pressure should be as low as possible because too much pressure abrades
the stencil. Pressure should be increased only when paste remains on stencil after printing,
the squeegee does not wipe the stencil thoroughly. If adjusted correctly, a thin layer of
flux will remain on top of the stencil and paste is rolling in front of the squeegee. The
amount of pressure is determined by printing speed and stencil type.
The squeegee down stop is a mechanical stop that prevents the squeegees to move further
down. It must be adjusted only to just touch the stencil surface. However, if the squeegee
axis and the stencil are not perfect parallel it can be necessary to over-adjust the down
stop to compensate. But, if the down stop is adjusted too far down, both stencils and
squeegees will wear out rapidly. Some machines do not have a mechanical down stop but
a squeegee origin point. Usually were the squeegee just touches the stencil.
The snap off speed of, which means the speed of separation between stencil and PWB
after printing is important. A too rapid separation speed when printing fine pitch will
result in clogging of the stencil apertures. A too fast or slow separation will also result in
tailing and form high edges around the solder paste deposits. The ideal separation speed
depends on the solder paste and the stencil aperture wall smoothness. On the other hand, a
slow separation speeds will slows down the printing cycle time.
In the surface mount assembly, the stencil-printing method is used to deposit the solder
paste onto the printed circuit boards (PCBs). The need for higher pin count, higher
performance, smaller size, and lighter weight has driven the development of fine pitch and
ultra-fine stencil-printing applications. Many surface mount assembly manufacturers
encounter significant trouble-shooting time associated with problems of solder-paste
printing quality, and this can be as high as 40% of production time. The stencil-printing
stage is the most critical step of the surface mount assembly process. Industry reports have
shown that about 60% of soldering defects for the end products are related to the solder-
paste printing. The earlier a defect is detected in the assembly process, the less expensive
are the fixing costs required to compensate for it. Repair and rework costs vary. However,
usually, a 5 to 10-fold increase in cost occurs after each successive production step.
Accordingly, the quality of solder-paste printing is one of the key factors by which a
manufacturing firm can gain a competitive edge.
The objective of a stencil-printing process is to transfer the solder paste into the stencil
aperture by the action of squeegee, leaving a desired amount of solder paste on the pads of
the substrate. The deposited height, area, and volume are the determinant factors of
printing quality.
Troubleshooting Printing Failures
The paste bleeding under the stencil can lead to solder bridging after soldering, which
cause electrical short between two or more adjacent component leads. The bleeding can be
prevented by increasing the frequency of under stencil cleaning, and gasketting (gap
between the board and the stencil) should be zero. The proper settings for board height,
board support and print pressure should be checked as well.
The paste buildup on one side of the stencil can be prevented by the before mentioned
methods too.
Incomplete paste transfer onto the board can lead to open joints (i.e. there is no joint
between the board and the component lead). In the case of this failure the mass of paste on
stencil, the cleanliness of apertures the printing speed (proper rolling of paste during
printing) and paste abandon time should be checked.
When too much paste is transfered onto the board (which can lead to bridging) the
squeegee pressure should be increased, and gasketing, board support and stencil thickness
should be checked.
Troubleshooting Printing Failures
Poor print definition can be prevented by increasing printing speed. Stencil separation
speed, tackiness of paste and board support should be checked as well to prevent this
failure.
Paste scooping (which can lead to open joints) usually caused by too high squeegee
pressure. Although the edge of the printing blade and board support should be checkek
also.
Troubleshooting Printing Failures
Paste bridging and smearing can be prevented by reducing squeegee pressure. In addition
the gasketing and understencil cleanliness should be checked.
If the deposited paste partially removed during stencil separation, the cleanliness of the
board should be checked. Usually board contamination is the cause of this failure.
Troubleshooting Printing Failures
Smudge prints are usually caused by human mistakes, when the operator disturbs the
deposited paste accidentally after printing.
The slumping of paste usually caused by improper ambient conditions, by excessive heat
or moisture. The paste abandon time on stencil and after printing should be checked and
controlled.
The ideally deposited paste has brick shape with sharp and definite edges.
4. Solder paste stencil printing
4.5 Stencil life and care
Cleaning stencils
Stencil should be cleaned thoroughly before and after manufacturing as
well. The cleaning solvent can be isopropyl alcohol or solvents
recommended by the manufacturer of the paste or stencil.
The stencil is the prime element in determining the application of the exact amount of
material in the exact location. Therefore it is important that a stencil is considered as a
precision engineered tool that is vital to the overall process performance and should be
cared for as such. Most stencils will not be used to the end of their stencil life due to:
- Design Revision (layout change)
- Process Optimization (corrective action)
- Damage (handling)
- Wear (use)
Even so monitoring stencil life is critical to the overall print process performance and
consistency.
Stencil should be cleaned thoroughly before and after manufacturing as well. The
cleaning solvent can be isopropyl alcohol or solvents recommended by the manufacturer
of the paste or stencil.
Damaged stencils
The stencils have to be inspected also before and after manufacturing. Damaged stencils
have to be replaced immediately, since they can cause serious failures.
Usually in the case of repair or rework of BGA (ball grid array), CSP (chip scale package) or
FC (flip chip) components with bump terminations on the bottom side of their package, or
rework of very fine pitch surface mount components, like QFPs (quad flat packs), those
components are placed by hand to a board using highly sophisticated place machines with
precise optical alignment systems.
Component placement failures
6. Reflow soldering
Soldering is the process in which two metals are joined together by means of a
third metal or alloy having a lower melting point.
Soft soldering is characterized by the value of the melting point of the third
metal or alloy, which is below 400 °C. The third metal or alloy used in the
process is called solder.
We need heat transport:
- to melt the solder
- to heat up the soldered samples
- to activate the flux
Infra Radiation (IR) occurs when two bodies of different temperatures are in sight of
each other.
The heat is transferred by electromagnetic waves of 0.78 to 1000 micron wavelengths. All
objects emit some level of infrared energy. Fluxes, plastic components, and epoxy glass
laminate absorb IR very well. Shiny surfaces will reflect the IR energy away.
Conduction heat transport occurs when two solid masses on different temperatures are in
contact with each other. Conduction heat will penetrate from the hotter solid to the cooler
solid. The most important thing in this heat transfer method that the solids most be in
contact.
Convection heat transfer occurs when a fluid (gas or liquid) passes over an object.
Temperature differences between the fluid and the objective create the convective heat
transfer. Convection heating or cooling requires contact of the flow with the solid part.
Convection may be classified as natural or forced. Natural convection occurs when no
flow is being forced over the object. Forced convection requires an external force that
pushes or pulls the flow over the object. The forced convection heating or cooling rates
are higher than natural convection rates.
Terms of soldering
Process Window:
a temperature interval where the
peak temperature should be
existed during the soldering
Infra Radiation (IR) occurs when two bodies of different temperatures are in sight of
each other. The heat is transferred by electromagnetic waves of 0.78 to 1000 micron
wavelengths. All objects emit some level of infrared energy. Fluxes, plastic components,
and epoxy glass laminate absorb IR very well. Shiny surfaces will reflect the IR energy
away.
Conduction heat transport occurs when two solid masses on different temperatures are in
contact with each other. Conduction heat will penetrate from the hotter solid to the cooler
solid. The most mportant thing in this heat transfer method that the solids most be in
contact.
Convection heat transfer occurs when a fluid (gas or liquid) passes over an object.
Temperature differences between the fluid and the objective create the convective heat
transfer. Convection heating or cooling requires contact of the flow with the solid part.
Convection may be classified as natural or forced. Natural convection occurs when no
flow is being forced over the object. Forced convection requires an external force that
pushes or pulls the flow over the object. The forced convection heating or cooling rates
are higher than natural convection rates.
Terms of soldering
Solder
Soldering surface
Thermal profile
The profile can be broken down into five zones: pre-heat, pre-flow or soak, rump-up,
reflow, and cool down.
During the pre-heat phase, the solvents evaporate from the solder paste. If the
temperature rises too rapidly during the pre-heat, two problems can occur. First, solder
balls can be spread when the solvents burst through the flux surface membrane. This is
called solder balling. Second, the solder paste can slump, because too rapid a temperature
rise changes the viscosity of the solder paste. This will result in bridging. A typical
preheat phase has a slope of 0.5…1.0 °C/s.
The pre-flow or soak and the rump-up section, also called the flux activation stage, brings
the entire assembly device up to the temperature at which the paste changes from solid to
liquid, and becomes active. This soak time should be long enough to allow the flux to
clean the bonding surfaces, but not so long that the flux is evaporated prematurely.
During the reflow phase, the temperature increases to melt the solder paste alloy and
subsequently the solder and the copper begin the formation of intermetallic solder joints.
The typical solder temperature is 30…40 °C above the solder paste melting point.
In the cool down phase, a reliable solder joint is formed. For a strong bond between the
pad and the terminal, the cooling should be fast.
After suitable pre-heat, soak and rump-up sections, during the reflow phase, the
temperature increases to melt the solder paste alloy and subsequently the solder and the
copper begin the formation of intermetallic solder joints. The typical solder temperature is
30…40 °C above the solder paste melting point. It is important to monitor the time at peak
reflow temperature in several areas of the PCB.
The cool down phase is a critical step in the formation of a reliable solder joint. For the
solder joint to perform as a strong bond between the solder pad and the component
terminal, the cooling should be as fast as possible. A slower rate may increase the grain
size of the intermetallic compounds making the solder joint brittle and weak. On the other
hand, the components can crack if the temperature drops too rapidly. The cooling should
therefore be 3…4 °C/s down to around 130 °C. Below 130 °C the cooling rate is not
critical to the solder joint quality, however fast cooling is beneficial for copper OSP board
rather than a very slow cooling rate. The solderability will be maintained for second side
reflow, wave or selective soldering.
Conveyor speed is a critical component of the reflow profile speeding up or slowing the
conveyor results in altered temperature profiles.
Thermal profile
Reflow profiles
The applied reflow profile (soak or linear) dependent on the size and complexity
of the circuit board.
Reflow ovens
Reflow ovens
IR heating + convectional aid:
• some batch ovens applies convection heating as aid
• fans mix the hot air in the oven
• ∆T is smaller!
• thermal distribution in these ovens is better than in the
pure IR ovens
Conveyor ovens
Conveyor ovens
Reflow failures
Reflow failures
Reflow failures
80…120 ºC
pre-heating
pump
foamed flux pump Solder wave
240…260 ºC
Wave soldering is used for both through-hole printed circuit assemblies, and surface mount.
In the latter case, the components are glued by the placement equipment onto the printed
circuit board surface before being run through the molten solder wave.
As through-hole components have been largely replaced by surface mount components, wave
soldering has been supplanted by reflow soldering methods in many large-scale electronics
applications. However, there is still significant wave soldering where SMT is not suitable (e.g.
large power devices and high pin count connectors), or where simple through-hole technology
prevails (certain major appliances).
Roles of the flux:
• making the surface oxide-free,
• preventing the Cu layer from re-oxidation.
Role of pre-heating: evaporating the solvents from the flux, pre-heating the PWB.
Process of soldering:
• the surface of the continuously moving solder wave is metallic colored and oxide-free,
• drops of the soldering material, making electrical contacts, can adherence on the metal
surface; solution is to apply two separate waves.
• the first wave (that gets into contact with the surface of PWB on a smaller region) is
vibrated, hence the wetting of the surface will be effective due to the mechanical effect.
The second, flat wave is the so called Λ wave that removes the remanent, unwanted
solder material.
Wave soldering
Wave soldering is usually the best method to use when high throughput
rates are required. The single wave soldering principle is the most
straightforward method and can be used on simple substrates with two-
terminal SMD components. More complex substrates with increased circuit
density and closer spacing of conductors can pose the problem of non-
wetting (dry joints) and solder bridging.
Wave soldering is usually the best method to use when high throughput rates are required.
The single wave soldering principle is the most straightforward method and can be used on
simple substrates with two-terminal SMD components. More complex substrates with
increased circuit density and closer spacing of conductors can pose the problem of non-
wetting (dry joints) and solder bridging. Bridging can occur across the closely spaced leads of
multi-leaded devices as well as across adjacent leads on neighboring components. Non-
wetting is usually caused by components with plastic bodies. The plastic is not wetted by
solder and creates a depression in the solder wave, which is augmented by surface tension.
This can cause a shadow behind the component and prevent solder from reaching the joint
surfaces. A smooth laminar solder wave is required to avoid bridging and a high pressure
wave is needed to completely cover the areas that are difficult to wet. These conflicting
demands are difficult to attain in a single wave, but dual wave techniques go a long way in
overcoming the problem.
Dual-wave soldering
In a dual wave machine the substrate first come into contact with a
turbulent wave which has a high vertical velocity. This ensures good
solder contact with both edges of the components and prevents joints
from being missed. The second smooth laminar wave completes the
formation of the solder fillet, removes excess solder, and prevents
bridging.
Wörthmann wave
Wörthman wave:
• Only one wave is enough
• Turbulent wave
• Latest technology
Preheating
The temperature of the board (component side) during preheating should go as quick as
possible to 45 °C (with maximum slope of 2 °C/Sec) and just before soldering at temperature
of 85°C.
Wetting time
The time between the moment of first contact (between the parts to be soldered) and the
solder, and the moment that the solder in the joints starts solidifying.
Dwell time
The time between the moment of first contact (between the parts to be soldered) and the
solder, and the moment of last contact with the solder.
(This time should be between 2 and 4 seconds.)
Soldering time
The time between the board actually contacts the solder and the onset of solidification.
(Dwell time + approximately. 5-10 Sec.)
Solidification time:
The time solder is getting solid on the bottom of the board.
Cooling time:
Forced cooling after soldering reduces the maximum temperature reached in the areas on the
component side of the board.
However, forced cooling directly after solder bath, may cause unequal contractions, which
will initiate cracks and therefore not advised.
If cooling down is needed because of the temperature from the carrier is rising to high, the
best place will be before or in the lift itself.