0 évaluation0% ont trouvé ce document utile (0 vote)
143 vues2 pages
This document contains 5 questions regarding chemical reaction mechanisms and kinetics. Question 1 asks about reaction mechanisms and rate laws for the hydration of isobutene to t-butyl alcohol. Question 2 asks for a rate expression for the reaction of HCHO and CO. Question 3 asks about a reaction mechanism and rate law that matches experimental data for a reaction between CO and NO. Question 4 asks about a rate limiting step and derivation of a rate law for a reaction between H2 and O2. Question 5 asks for a rate law and conversion calculation for a catalytic reaction of A + B to form C.
This document contains 5 questions regarding chemical reaction mechanisms and kinetics. Question 1 asks about reaction mechanisms and rate laws for the hydration of isobutene to t-butyl alcohol. Question 2 asks for a rate expression for the reaction of HCHO and CO. Question 3 asks about a reaction mechanism and rate law that matches experimental data for a reaction between CO and NO. Question 4 asks about a rate limiting step and derivation of a rate law for a reaction between H2 and O2. Question 5 asks for a rate law and conversion calculation for a catalytic reaction of A + B to form C.
This document contains 5 questions regarding chemical reaction mechanisms and kinetics. Question 1 asks about reaction mechanisms and rate laws for the hydration of isobutene to t-butyl alcohol. Question 2 asks for a rate expression for the reaction of HCHO and CO. Question 3 asks about a reaction mechanism and rate law that matches experimental data for a reaction between CO and NO. Question 4 asks about a rate limiting step and derivation of a rate law for a reaction between H2 and O2. Question 5 asks for a rate law and conversion calculation for a catalytic reaction of A + B to form C.
t-Butyl alcohol (TBA) was produced by the liquid phase hydration (W) of isobutene (I) over an Amberlyst-15 catalyst. The system is normally a multiphase mixture of hydrocarbon, water and solid catalyst.
a) Propose the mechanism of reaction (i) If the mechanism is dual site and surface reaction is reversible. (ii) If reaction follows Eley-Rideal kinetics and surface reaction is irreversible (iii) If isobutene (I) and water are adsorbed on different sites and surface reaction is reversible. (iv) If the mechanism is dual site, irreversible surface and TBA not on the surface.
b) Determine a rate law (i) If the surface reaction is rate limiting (as described in a(i)). (ii) If the adsorption of isobutene is limiting (as described in a(i)). (iii) If the surface reaction is limiting and reaction follows Eley-Rideal kinetics
Question 2
In the reaction of HCHO CO H 2 , gases H 2 adsorbs dissociatively and CO adsorbs without dissociation. Suggest a reasonable rate expression if the surface reaction is irreversible and is rate limiting.
Question 3
The uses of unburned carbon monoxide has been proposed to remove nitogen oxide, NO from automobile exhaust. The process is proceed by the reaction of 2 2 5 . 0 CO N NO CO . Experimental data indicate that the reaction rate can be represented by
2 2 1 1 C N C N N P K P K P kP r
. a) Propose an adsorption-surface reaction mechanism for the above reaction. *Hint: Surface reaction is irreversible and dual site mechanism. b) Derive the theoritical rate of reaction and suggest the rate limiting step that consistent with the theoritical rate law. Compare your answer with experimental rate reaction.
c) Determine the overall rate of reaction if the reaction is carried out at high temperature.
Question 4 The reaction O H O H 2 2 2 2 1 has a rate limiting step S S HO S O S H and the rate of reaction is O H R P P k r . a) Sketch the process assumed in a rate limiting step.
b) Derive a rate reaction expression r(P H2 , P O2 ) for this reaction by assuming Langmuir Hinshelwood kinetics with competitive adsorption. Determine the maximum order for this reaction predicted by this expression.
Question 5 The liquid phase catalytic reaction of A + B C was carried out in a differential reactor. The limiting step in the reaction is known to be irreversible, so that the overall reaction is irreversible. The reaction mechanism is believed to be:
(a) Determine the rate law for this reaction.
(b) Determine the conversion if the number of site A and site C are equal. Given K A =8.73atm -1 and K C = 2.38 atm -1 .
(Water Resource Planning, Development and Management) Cécile Marcil - Drinking Water - Quality Control, Distribution Systems and Treatment-Nova Science Publishers (2022)
ChatGPT Money Machine 2024 - The Ultimate Chatbot Cheat Sheet to Go From Clueless Noob to Prompt Prodigy Fast! Complete AI Beginner’s Course to Catch the GPT Gold Rush Before It Leaves You Behind