Rapunzel was kidnapped as a baby and is being kept in a tower by Mother Gothel, she dreams of leaving the tower to see the floating lanterns, but is being kept by the fear of the monsters and people that mother Gothel has told her about.
The Mentor + The Herald: Flynn Ryder Flynn steals a crown from the royal palace and ends up hiding in Rapunzels tower. He becomes the herald when Rapunzel strikes a deal for a trade, he takes her to see the lanterns and get her back safely to the tower in exchange she will return his satchel with the crown in it, this is her call for adventure. He then becomes her mentor when he starts to help her through all the new experiences she has outside the tower.
The Threshold Guardian: The Tower The threshold guardian would be the tower because in order for Rapunzel to cross the threshold and go to see the lanterns she must be able to get out of the tower. She manages to do this by using her hair as rope and climbs down from the window.
The Shadow + The shapeshifter: Mother Gothel Mother Gothel was the one take kidnapped Rapunzel as a baby for the magical healing element of her golden hair. She brought as her own and doesnt want her to leave the tower because she doesnt want to lose the magical hair. She is the shadow of the story because of the kidnapping and entrapment of Rapunzel, she also does whatever it take to get Flynn away from Rapunzel later in the film. But in the eyes of Rapunzel she is considering caring up until the very end when Rapunzel realises shes the missing princess and Gothel only cared for the hair and not her, which makes Gothel the Shape shifter as well.
The Trickster: Maximus The super cop horse starts off by trying to find Flynn because of the stolen crown, but he eventually becomes one of the allies, but until that point he distracts the hero from the adventure, but injects humour into the film throughout by him and Flynn acting like children towards each other.
Allies: Flynn, Pascal, Maximus Pascal the chameleon is Rapunzels sidekick, being by her side throughout the entire film, Flynn Ryder help Rapunzel and becomes a romantic interest and finally Maximus the guards horse, gives a helping hand every now and then.