JEE Advanced 2014 Solution Paper 2

PAPER () - 2
Max. Marks : 180 |=r+n= + : 180

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
qr ; | rr +r =r = a | r+r 5 |=c |r r = = ;= +r= + | | n ; |
Time : 3 Hrs. == : 3 r c
A. General =r=r- :
1. This booklet is your Question Paper. Do not break the seal of the booklet before being instructed
to do so by the invigilators.
r l-ni ii i r | ;i - r n+ n ni + n liii ,ii ;i l i li i |
2. The question paper CODE is printed on the left hand top corner of this sheet and on the back
cover page of this booklet.
i i i (CODE) ; - +i +i) i i ; l-ni ls - si r |
3. Blank spaces and blank pages are provided in the question paper for your rough work. No additional
sheets will be provided for rough work.
i l iii - i iii -ii ; l-ni - ri r | i l) i ; lnln in ri li
i ni|
4. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers
and electronic gadget of any kind are NOT allowed inside the examination hall.
i in, l +i , i n nili, -i;, - -, -i, i , i li i ; - i l
i iii - - -ni ri r |
5. Write your Name and Roll number in the space provided on the back cover of this booklet.
; l-ni ls - l) n) -ii - i i- i i + lli)|
6. Answers to the questions and personal details are to be filled on an Optical Response Sheet,
which is privided separately. The ORS is a doublet of two sheets - upper and lower, having
identical layout. The upper sheet is a machine-gradable Objective Response Sheet (ORS) which
will be collected by the invigilator at the end of the examination. The upper sheet is designed in
such a way that darkening the bubble with a ball point pen will leave an identical impression at
the corresponding place on the lower sheet. You will be allowed to take away the lower sheet at
the end of the examination. (see Figure-1 on the back cover page for the correct way of darkening
the bubbles for valid answer.)
i -i i i lnnn iili ) i -i l-i ii-, i n li i)ni, ii i ni|
i .i.). - l(i (ii +i i li i ii-i i - r | +i - -iii i l-( l-i ii-
(i .i.)-., ORS) r , i lii ,ii (i i i ni| +i - ; i li; li ni r l + +
i ii r l - nn -ii - lii si ni r | i l - i iii -iln
ii i n r | ( i ls - i(i li1 ( i -i l) + + i i i ri nii)
7. Use a black ball point pen only to darken the bubbles on the upper original sheet. Apply
sufficient pressure so that the impression is created on the lower sheet. See Figure-1 on the
back cover page for appropriate way of darkening the bubbles for valid answers.
=| = a + r (BUBBLES) +r + +r r r; c += = +rr + | ;ni +i( i l l
i - - lii + i | ( i ls - i(i li1 ( n -i l) + + i i i ri
nii)
INSTRUCTIONS (|r)
Page || 1
Page || 2
JEE-ADVANCED-2014 | DATE: 25-05-2014 | PAPER-2 | CODE-2
8. DO NOT TAMPER WITH/MULTIPLE THE ORS OR THIS BOOKLET.
r .r.=. (ORS) r ;= |n+r = ; ,|q|n + |
9. On breaking the seal of the booklet check that it contains all the 60 questions and corresponding answer
choices are legible. Rad carefully the instruction printed at the beginning of each section.
; l-ni i - r ni in i i l ;- ii 60 i -i l(- -i i n r |
ii i i i i - l r ) l ii i i |
B. Filling the right part of the ORS r .r.= (ORS) + r -rrn +r -rr|
10. The ORS also has a CODE printed on its left and right parts.
i .i.) i) i +i) iin - ii i s r ) r |
11. Verify that the CODE printed on the ORS (on both the left and right parts) is the same as that on this
booklet and put your signature in the Box designated as R4.
lln l i .i.). (+i) i i) i i iini ) si i ; l-ni s i -i ri r i ll - +i
R4 - r-nii |
12. IF THE CODES DO NOT MATCH, ASK FOR A CHANGE OF THE BOOKLET/ORS AS APPLICABLE.
| +r = |-r- ; nr ;= |n+r,r .r.=. +r rr =r +| =r n + |
13. Write your Name, Roll No. and the name of centre and sign with pen in the boxes provided on the upper
sheet of ORS. Do not write any of the anywhere else. Darken the appropriate bubble UNDER each
digit of your Roll No. in such way that the impression is created on the bottom sheet. (see example in
Figure 2 on the back cover)
i i-, i . i iii i i- i .i.). +i - - l n iii - - i i r-nii |
;= = +r ; -r| r+r| +;| r |=r | i + r i + + (BUBBLE) i ; nr ii
l l - ii lii + i)| ( i iri ls - li2)
C. Question Paper Format >r +r r=
The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists
of three sections.
; i n| -rrn (ii ln l(ni, i l(ni i nlin) r | r iin n| i r |
14. Section 1 contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE is correct.
=r = 1 - 10 ; |+- r | r - i l(- (A), (B), (C) i (D) r l- + =;| r |
15. Section 2 contains 3 paragraphs each describing theory, experiment and data etc. Six questions
relate to three paragraphs with two questions on each paragraph. Each question pertaining to a partcular
passage should have only one correct answer among the four given choices (A), (B), (C) and (D).
=r= 2 - l,ini , i ni i i i il i ii (i 3 s r | ni s i + lin e: r , l- r
s i r | li ii s - r i l(- (A), (B), (C) i (D) r l- + + ;| =;|
r |
16. Section 3 contains 4 multiple choice questions. Each question has two lists (list-1 : P, Q, R and S;
List-2 : 1, 2, 3 and 4). The options for the correct match are provided as (A), (B), (C) and (D) out of
which ONLY ONE is correct.
=r = 3 - 4 ; |+- r | - - i li ( i-1 : P, Q, R i S; i-2 : 1, 2, 3 i 4) r | ri l-i
l) l(- (A), (B), (C) i (D) r l- + + =;| r |
D. Marking Scheme + r r
17. For each question in Section 1, 2 and 3 you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus
one ( 1) mark will be awarded.
=r= 1, 2 r 3 r - ( ri -i (i + + i ii 3 + i i ; ii + + i ii ri
i (0) + i l) i n | ii l-ilni - +rr-=+ + ( 1) + i li i ni|
Page || 3
PHYSICS
PART - I : PHYSICS
SECTION-1 : (One one options correct Type)
This section contains 10 multiple choice questions. Each questions has four choices (A), (B), (C) and
(D) out of which Only ONE option is correct
=r= 1 : (+ + =;| |+- +r)
; i - 10 ; |+- r | - - i l(- (A),(B),(C) i (D) r , l- + + ri r |
1. A glass capillary tube is of the shape of a truncated cone with an apex angle so that its two ends have cross
sections of different radii. When dipped in water vertically, water rises in it to a height h, where the radius of its
cross section is b. If the surface tension of water is S, its density is , and its contact angle with glass is , the
value of h will be (g is the acceleration due to gravity)
ls i (truncated cone) i iln (ii i i ) ii, li iii i i r, i n li -i i-
i lii) li r | ii i ii - ( n +i ii - ii h + i; n ini r , ri ;i -i
i- i lii b r l ii i - ni( (surface tension) S, i-( nii i ii ;i -i i i ri n+
h i -i r (g n -(i -(i r )
(A)
) cos(
g b
S 2
(B)
) cos(
g b
S 2
(C)
) 2 / cos(
g b
S 2
(D)
) 2 / cos(
g b
S 2
Ans. (D)
Sol. Using geometry il-ln i n :
2
cos
R
b
e
Using Pressure method i+ l(li : P
0

c
R
S 2
+ h g = P
0
h =
g R
S 2
e
=
2 / cos
g b
S 2
Page || 4
PHYSICS
2. A planet of radius R =
10
1
(radius of Earth) has the same mass density as Earth. Scientists dig a well of
depth
5
R
on it and lower a wire of the same length and of linear mass density 10
3
kgm
1
into it. If the wire is not
touching anywhere, the force applied at the top of the wire by a person holding it in place is (take the radius of
Earth = 6 10
6
m and the acceleration due to gravity on Earth is 10 ms
2
)
(i -i -i i-( (i ) n r i lii R =
10
1
( (i i lii) r | ( nil ; n r -
5
R
nri; (ii
) i ii n r i ;- ni ri +i; nii 10
3
kgm
1
ii -i i-( (ii ) ni in r , i ) i ri
ii -i ri ni r | ni i ii-ii i l) ) ln ,ii nii ni + r (i ni i (i
i lii = 6 10
6
m nii (i i nr n -(i -(i 10 ms
2
)
(A) 96 N (B) 108N (C) 120N (D) 150N
Ans. (B)
Sol. Given, R
planet
=
10
R
earth
and
density, =
3
planet
Planet
3
earth
earth
R
3
4
M
R
3
4
M
M
planet
=
3
earth
10
M
g
surface of planet
= 2
planet
planet
R
GM
=
2
e
3
2
e
R . 10
10 . GM
= 2
e
e
R 10
GM
=
10
g
earth of surface
g
depth of planet
= g
surface of planet

R
x
where x = distance from centre of planet
T =
R
x
g dx
R
5 / R 4
=
R
5 / R 4
2
2
x
R
g
= 108 N
HINDI li r i r , R
planet
=
10
R
earth
nii
i-(, =
3
planet
Planet
3
earth
earth
R
3
4
M
R
3
4
M
M
planet
=
3
earth
10
M
g
nr i nr
= 2
planet
planet
R
GM
=
2
e
3
2
e
R . 10
10 . GM
= 2
e
e
R 10
GM
=
10
g
earth of surface
g
nr i nri;
= g
nr i nr

R
x
ri x = n r i r
T =
R
x
g dx
R
5 / R 4
=
R
5 / R 4
2
2
x
R
g
= 108 N
Page || 5
PHYSICS
3. Charges Q, 2Q and 4Q are uniformly distributed in three dielectric solid spheres 1, 2 and 3 of radii R/2, R and
2R respectively, as shown in figure. If magnitudes of the electric fields at point P at a distance R from the
centre of spheres 1, 2 and 3 are E
1
E
2
and E
3
respectively, then
li - ii ) n) ni i( n n (dielectric) ni i , li lii) -i R/2, R nii 2R r , i( i Q, 2Q nii
4Q -i -i l(nln r | l l+ P, i - ni R i r , ni 1, 2 nii 3 ii
l(n n i i i l-ii -i E
1
, E
2
nii E
3
r n+
(A) E
1
> E
2
> E
3
(B) E
3
> E
1
> E
2
(C) E
2
> E
1
> E
3
(D) E
3
> E
2
> E
1
Ans. (C)
Sol. E
1
=
2
R
KQ
E
2
=
2
R
) Q 2 ( k
E
2
=
2
R
kQ 2
E
3
=
3
) R 2 (
R ) Q 4 ( k
E
3
=
2
R 2
kQ
E
3
< E
1
< E
2
4. If
Cu
is the wavelength of K X-ray line of copper (atomic number 29) and
Mo
is the wavelength of the K X-ray
line of molybdenum (atomic number 42), then the ratio
Cu
/
Mo
is close to
ni + (-ii -i 29) i K X-li ii i n n
Cu
r nii -i l - (-ii -i 42) i K X-li ii
i n n
Mo
r , n+ in
Cu
/
Mo
nin r
(A) 1.99 (B) 2.14 (C) 0.50 (D) 0.48
Ans. (B)
Sol. Using Mosley's law, for K line : = a (z b) where b = 1
K ii l -i l- i n : = a (z b) ri b = 1
1

mo
cu
1
1
=
) 1 42 ( a
) 1 29 ( a
mo
cu
=
28 28
41 41
=
784
1681
= 2.144
Page || 6
PHYSICS
5. A wire, which passes through the hole is a small bead, is bent in the form of quarter of a circle. The wire is fixed
vertically on ground as shown in the figure. The bead is released from near the top of the wire and it slides
along the wire without friction. As the bead moves from A to B, the force it applies on the wire is
) ni i ) si - -i ni - - l-in ls n ni r , i ) n ii i ( -i -i i ni r | ni i i l-
+( n - l-in li ni r i li - ii i ni r | -i ni i ni +i l si i ini r , l r ni
li l+i li ii i ni r | + -i ni A B n ni r , n+ ; ,ii ni n (ii + r
(A) always radially outwards
(B) always radially inwards
(C) radially outwards initially and radially inwards later
(D) radially inwards initially and radially outwards later.
(A) r- ii li lii - +lr- ii (radially outwards)
(B) r- ii li n- ii (radially inwards)
(C) ii - li lii - +lr- ii n-in li lii - n- ii
(D) ii - li lii - n- ii n-in li lii - +lr- ii
Ans. (D)
Sol. Using conservation of energy : mgR (1- cos ) =
2
1
mv
2
Radial force Equ
n
: mgcos N =
R
mv
2
N = mgcos
R
mv
2
= mg (3 cos 2)
Normal act radially outward on bead if cos >
3
2
Normal radially inward on bead if cos <
3
2
Normal on ring is opposite to reaction on bead.
Page || 7
PHYSICS
HINDI: +i ii : mgR (1- cos ) =
2
1
mv
2
lii + -ii : mgcos N =
R
mv
2
N = mgcos
R
mv
2
= mg (3 cos 2)
-i ni li+ li +ir i i ri ni l cos >
3
2
-i ni li+ li +ir i i ri ni l cos <
3
2
-i ni lnli ( li+ l(in r
6. A metal surface is illuminated by light of two different wavelengths 248 nm and 310 nm. The maximum speeds
of the photoelectrons corresponding to these wavelengths are u
1
and u
2
, respectively. If the ratio u
1
: u
2
= 2 : 1
and hc = 1240 eV nm, the work function of the metal is nearly
li iin i ) nr i nn n n i 248 nm nii 310 nm in li ni r | ; nn i nn
(corresponding) l (i ii ; - i i (photoelectrons) i lin- nln -i u
1
nii u
2
r | l in
u
1
: u
2
= 2 : 1 nii hc = 1240 eV nm r , n+ iin i i nin r
(A) 3.7 eV (B) 3.2 eV (C) 2.8 eV (D) 2.5 eV
Ans. (A)
Sol. 248 nm 1240 / 248 ev = 5 ev
310nm 1240 / 310 ev = 4 ev
W ev 4
W ev 5
1
4
E . K
E . K
2
1
16 4W = S W
11 = 3 W
W =
3
11
= 3.67 ev 3.7 ev
Page || 8
PHYSICS
7. A tennis ball is dropped on a horizontal smooth surface. It bounces back to its original position after hitting the
surface. The force on the ball during the collision is proportional to the length of compression of the ball. Which
one of the following sketches describes the variation of its kinetic energy K with time t most appropriately ?
The figures are only illustrative and not to the scale.
) - l i n i ) i ln li nr lnii ini r | n nr -i in - -ii
r ini r| i; (collision) ii, n n (ii + i i +i; -iini r| l - ii
iili, - t ii n i nln +i K l(n i (i li ln li n ni r | (li ( i ln
r i -i ri r )|
(A) (B)
t
K
(C) (D)
Ans. (B)
Sol.
K =
2 2
t mg
2
1
2
t K : parabolic graph
then during collision kinetic energy first decreases to elastic potential energy and then increases.
Most appropriate graph is B.
Hindi
K =
2 2
t mg
2
1
2
t K : (ii i i
n+ - i i nln +i r i- ni -i-i l-iln +i + ni )( n+ nln +i + ni| + ri i i B
r|
Page || 9
PHYSICS
8. During an experiment with a metre bridge, the galvanometer shows a null point when the joceky is pressed at
40.0 cm using a standard resistance of 90 , as shown in the figure. The least count of the scale used in the
meter bridge is 1 mm. The unknown resistance is :
) -i- + i 90 -i lni i ii ) i n n -, + i i i ni +i l 40.0 cm
+ii ini r , n+ n -(i -i- i l(i li n ri ni r , i li - liii ni r | -i- + i - - -i i
-n-i (least count) 1 m.m. r | nin lni i i -i r
(A)
15 . 0 60
(B)
56 . 0 135
(C)
25 . 0 60
(D)
23 . 0 135
Ans. (C)
Sol. For balanced meter bridge n n l
R
X
=
100
40
X
=
60
90
60 X
X = R
100
60
1 . 0
40
1 . 0
100 X
X
X
= 0.25
so n X = (60 + 0.25)
9. Parallel rays of light of intensity = 912 Wm
2
are incident on a spherical balck body kept in surroundings of
temperature 300 K. Take Stefan-Biltzmann constant = 5.7 10
8
Wm
2
K
4
and assume that the energy
exchange with the surroundings is only through radiation. Th final steady state temperature of the black body
is close to:
) ni ii lii(black body) i 300 K ni-i (i (ini(i - ii ni r | ; i -in li , li
ni( ni = 912 Wm
2
r , ilnn r | --i (i -- -i lni = 5.7 10
8
Wm
2
K
4
i -i r -in r )
l +i i ii i l l(li ,ii ri ri ri r , lii i -iii (-ii - ni-i nin r
(A) 330 K (B) 660 K (C) 990 K (D) 1550 K
Ans. (A)
Page || 10
PHYSICS
Sol. In steady state -iii (-ii -
2 4
0
4 2
R 4 ) T T ( R
(T
4

4
0
T ) 4
T
4

4
0
T = 40 10
8
T
4
8110
8
= 40 10
8
T
4
= 121 10
8
T 330 K
10. A point source S is placed at the bottom of a transparent block of height 10 mm and refractive index 2.72. It is
immersed in a lower refractive index liquid as shown in the figure. It is found that the light emerging from the
block to the liquid forms a circular bright spot of diameter 11.54 mm on the top of the block. The refractive index
of the liquid is
) l+ ii i n (S) ) 10 mm +i; (i iii n- i li nr ii ni r | n- i ( ni 2.72
r | n - i ) - (n i (i ( - +i i ini r , i li - ii i ni r | n - l ( - i
(ii ii, n - i + nr 11.54 mm i i ) in ( -i(spot) +ini r | ( i (n i r
(A) 1.21 (B) 1.30 (C) 1.36 (D) 1.42
Ans. (C)
Sol. Sin i
C
=
2 2
h r
r

B
n
n
=
2 2
h r
r
n =
72 . 2
h r
r
2 2
=
72 . 2
54 . 11
77 . 5
= 1.36
Page || 11
PHYSICS
SECTION-2 : Comprehension Type (Only One options correct)
=r= 2 : -e +r (+ + |+- =;|)
This section contains 3 paragraphs, each describing theory, experiments, data etc. Six questions
relate to the three paragraphs with two questions on each paragraph. Each question has only one
correct answer among the four given options (A), (B), (C) and (D)
; i - l,i ni , i ni i i i il i ii (i 3 -e r | i i s i + lin r r , l-
r s i r | li ii s - r i l(- (A), (B), (C) i (D) r , l- + +
;| =;| r |
Paragraph For Questions 11 to 12
= =r 11 r 12 + | -e
The figure shows a circular loop of radius a with two long parallel wires (numbered 1 and 2) all in the plane of
the paper. The distance of each wire from the centre of the loop is d. The loop and the wires are carrying the
same current . The current in the loop is in the counterclockwise direction if seen from above.
li - ii n a lii (ii ( -ii ii (loop) nii i -in ni ln 1 nii 2 ii - n - r | i i ni
(-ii ii d i r | (-ii ii nii i i nii - )-i iii (ilrn r | + i (-ii
ii - iii i lii (i-i(n r |
11. When d a but wires are not touching the loop, it is found that the net magnetic filed on the axis of the loop
is zero at a height h above the loop. In that case
(A) current in wire 1 and wire 2 is the direction PQ and RS, respectively and h a
(B) current in wire 1 and wire 2 is the direction PQ and SR, respectively and h a
(C) current in wire 1 and wire 2 is the direction PQ and SR, respectively and h 1.2 a
(D) current in wire 1 and wire 2 is the direction PQ and RS, resepectively and h 1.2 a
+ d a l ni ii i -i ri r r n+ ( -ii ii i h + i; lii-i +i i i i l-
i l-iln -
(A) ni 1 nii ni 2 - iii i lii -i PQ nii RS r i h a
(B) ni 1 nii ni 2 - iii i lii -i PQ nii SR r i h a
(C) ni 1 nii ni 2 - iii i lii -i PQ nii SR r i h 1.2 a
(D) ni 1 nii ni 2 - iii i lii -i PQ nii RS r i h 1.2 a
Ans. (C)
Page || 12
PHYSICS
Sol. B B
R
due to ring
B B
1
due to wire - 1
B B
2
due to wire -2
In magnitudes B
1
= B
2
=
r 2
I
0
Resultant of B
1
and B
2
= 2B
1
cos =
2
0
r
a
B
R
=
3
2
r
a I
4
2
0
For zero magnetic field at P
2
0
r
a
=
3
2
r
a I
4
o 2

a 2 . 1 h
Hindi B B
R
( ii
B B
1
ni - 1 ii
B B
2
ni - 2 ii
l-ii - B
1
= B
2
=
r 2
I
0
B
1
nii B
2
i lii-i= 2B
1
cos =
2
0
r
a
B
R
=
3
2
r
a I
4
2
0
P i +i i i l)
2
0
r
a
=
3
2
r
a I
4
o 2

a 2 . 1 h
12. Consider d >> a, and the loop is rotated about its diameter parallel to the wires by 30 from the position shown
in the figure. If the currents in the wires are in the opposite directions, the torque on the loop at its new position
will be (assume that the net field due to the wires is constant over the loop)
-i il) d >> a nii ii i li - lii; n; (-ii nii -in nii ii i ln 30 i -ii
ini r | l nii - l(nn iii i lii ) l(in lii - ri ni ii i ; (-ii - n (ii +
ii i (torque) ri ni (-i il) l nii ii ( -ii ii +i i i l-i r |)
(A)
d
a
2 2
0
(B)
d 2
a
2 2
0
(C)
d
a 3
2 2
0
(D)
d 2
a 3
2 2
0
Ans. (B)
Page || 13
PHYSICS
Sol. Magnetic field at mid point of two wires =
d
I
0
Magnetic moment of loop =
2
a I
Torque on loop = M B sin 150
=
d 2
a
2 2
0
I
i nii - l+ +i i i =
d
I
0
+i ii i =
2
a I
+ii i = M B sin 150
=
d 2
a
2 2
0
I
Paragraph For Questions 13 to 14
= =r 13 r 14 + | -e
In the figure a container is shown to have a movable (without friction) piston on top. The container and the
piston are all made of perfectly insulating material allowing no heat transfer between outside and inside the
container. The container is divided into two compartments by a rigid partition made of a thermally conducting
material that allows slow transfer of heat. The lower compartment of the container is filled with 2 moles of an
ideal monatomic gas at 700 K and the upper compartment is filled with 2 moles of an ideal diatomic gas at 400
K. The heat capacities per mole of an ideal monatomic gas are C
V
=
2
3
R, C
P
=
2
5
R, and those for an ideal
diatomic gas are C
V
=
2
5
R, C
P
=
2
7
R.
li - lii) n) ii - + i i ) ii ilrn l-- ni r| ii nii l-- ii ni (i ii ii ll- n
r , l ii nii +ir +i i ii i i( ri r | ii i ) +-i i ii + r ) l(ii
- ,ii i iini - +i -i ni r l +-i i iii (ir i( r | ii i li iin ) ii ).-il(
(monatomic) n 2 -i , li ni 700 K r, ii ri r| ii i +i iin ) l,-iil( n (diatomic)
2 -i , li ni-i 400 K r , ii r i r | n i ln-i +-i iilni ii )-iil( n l)
-i C
V
=
2
3
R, C
P
=
2
5
R nii ii l,-iil( n l) -i C
V
=
2
5
R, C
P
=
2
7
R r |
Page || 14
PHYSICS
13. Consider the partition to be rigidly fixed so that it does not move. When equilibrium is achieved, the final
temperature of the gases will be :
l l(ii - ii ni i r , n+ ii(-ii - i n i i lnni-i ri ni|
(A) 550 K (B) 525 K (C) 513 K (D) 490 K
Ans. (D)
Sol. Let final temperature of gases is T
Heat rejected by gas in lower compartment (nC
v
T) = ) T 700 ( R
2
3
2
Heat received by gas in above compartment (nC
P
T) = ) 400 T ( R
2
7
2
Equating above
2100 3T = 7T 2800
T = 490 K
-ii n i lnni-i T r |
l iin - n ,ii -ini n; +-i (nC
v
T) = ) T 700 ( R
2
3
2
+i iin - n ,ii (ii lin +-i (nC
P
T) = ) 400 T ( R
2
7
2
i i i +i+
2100 3T = 7T 2800
T = 490 K
14. Now consider the partition to be free to move without friction so that the pressure of gases in both compart-
ments is the same. Then total work done by the gases till the time they achieve equilibrium will be :
+ -i il) l l(ii - ii iri nln l) -(n i r , l i i iini - n i +i( -i r | n i ,ii
ii(-ii - r n li ni i ri ni|
(A) 250 R (B) 200 R (C) 100 R (D) 100 R
Ans. (D)
Sol. W
1
+ U
1
= Q
1
W
2
+ U
2
= Q
2
Q
1
+ Q
2
= 0
R
2
7
(T 400) = R
2
5
(700 T)
T =
12
6300
= 525 K
So n W
1
+ W
2
= 2 . R. (525 400) + 2R(525 700)
= + 250R 350 R
= 100R
Page || 15
PHYSICS
Paragraph for Question 15 to 16
= =r 15 r 16 + | -e
A spray gun is shown in the figure where a piston pushes air out of a nozzle. A thin tube of uniform cross
section is connected to the nozzle. The other end of the tube is in a small liquid container. As the piston
pushes air through the nozzle, the liquid from the container rises into the nozzle and is sprayed out. For the
spray gun shown, the radii of the piston and the nozzle are 20 mm and 1mm respectively. The upper end of the
container is open to the atmosphere.
li - lii; n; lii - ) l-- (i i ) (nozzle) ,ii +ir i ni r | -i )-i -i
i- (ii ni i ni r | i i i li ( i ) si - ii - r | + l-- (i i +ir i ni
r , n+ ii - ( - - i ini r | i ri - +ir lni r | li - lii; n; lii - l--
nii i lii) -i 20mm nii 1 mm r | ii i +i iin (ini(i (atmosphere) - i i r |
15. If the piston is pushed at a speed of 5mms
1
, the air comes out of the nozzle with a speed of
l-- i 5mms
1
i nln i +ir (ii (i i nln r |
(A) 0.1ms
1
(B) 1ms
1
(C) 2ms
1
(D) 8ms
1
Ans. (C)
Sol. A
1
V
1
= A
2
V
2
A
1
= 400 A
2
400 (5 10
3
) = V
2
s / m 2
2
V (C)
16. If the density of air is
a
and that of the liquid , then for a given piston speed the rate (volume per unit time)
at which the liquid is sprayed will be proportional to
(i nii ( i i-( -i
a
i -il | l-- i ) ln nln ( i ii (in ln -) ri
ri ni r | (r i l n l(-i - l -i ini r `
(A)
a
(B)
a
(C)
a
(D)
Ans. (A)
Sol. Pressure at A and B will be same
A nii B i+ -i ri ni
gh v
2
1
P v
2
1
P
2
0
2
a a 0
gh 2 v v
a
a
Page || 16
PHYSICS
SECTION-3 : Matching List Tpype (Only One options correct)
This section contains four questions, each having two matching lists. Choices for the correct
combination of elements from List-I and List-II are given as options (A), (B), (C) and (D) out of which
one is correct
=r= -3 = = = | +r (+ + |+- =;|)
; i - 4 +rl(- r | - - i - li r | li l) - l(- (A), (B), (C) i (D)
r l- ( ) ri r |
17. A person in a lift is holding a water jar, which has a small hole at the lower end of its side. When the lift is at
rest, the water jet coming out of the hole hits the floor of the lift at a distance d of 1.2 m from the person. In the
following, state of the lift's motion is given in List - I and the distance where the water jet hits the floor of the lift
is given in List - II. Match the statements from List - I with those in List- II and select the correct answer using
the code given below the lists.
List -I List -II
P. Lift is accelerating vertically up. 1. d = 1.2 m
Q. Lift is accelerating vertically down 2. d > 1.2m
with an accelerating less than the
gravitational acceleration.
R. List is moving vertically up with constant 3. d < 1.2 m
Speed
S. Lift is falling freely. 4. No water leaks out of the jar
Code :
(A) P-2, Q-3, R-2, S-4
(B) P-2, Q-3, R-1, S-4
(C) P-1, Q-1, R-1, S-4
(D) P-2, Q-3, R-1, S-1
) ln ii ) ii l- - i i r | ii i i; l n - ) ls r | + l- l(i-i(-ii
- r , n+ ls +ir i (i i iii ln 1.2 m, d l- i lnni r | l- i nln i l(lii
(-ii i -I - i n; r , nii (r i ri i iii i lnni r, i-II - i n; r| i-I i, i -II -ln
il) nii li i l) n) i i i n ri -i l)
= | -I = | -II
P. l- + i lii - -(ln nln 1. d = 1.2 m
nlnii r |
Q. l- -(ln nln i i i nlnii 2. d > 1.2m
r i -(i i -i n -(i -(i
- r |
R. l- + i i )-i i
nln-i r | 3. d < 1.2 m
S. l- -(n i ln ri r | 4. ii +ir ri i)ni|
Page || 17
PHYSICS
+r = :
(A) P-2, Q-3, R-2, S-4
(B) P-2, Q-3, R-1, S-4
(C) P-1, Q-1, R-1, S-4
(D) P-2, Q-3, R-1, S-1
Ans. (C)
Sol. Match the column i - i l-i il)
When lift is at rest: + l- l(i-i(-ii - r |
(P) g
eff
> g d =
2 1
h h 4 = 1.2 m
(Q) g
eff
< g d =
2 1
h h 4 = 1.2 m
(R) g
eff
= g d =
2 1
h h 4 = 1.2 m
(S) g
eff
= o No water leaks out of the jar. i i ; ii +ir ri l ni
Ans. (C) P1 Q1 R1 S4
18. Four charge Q
1
,Q
2
,Q
3
, and Q
4
,of same magnitude are fixed along the x axis at x = 2a a, +a and +2a,
respectively. A positive charge q is placed on the positive y axis at a distance b > 0. Four options of the signs
of these charges are given in List-I . The direction of the forces on the charge q is given in List- II Match List-
1 with List-II and select the correct answer using the code given below the lists.

List-I List-II
P. Q
1
,Q
2
,Q
3
, Q
4
, all positive 1. +x
Q. Q
1
,Q
2
positive Q
3
,Q
4
negative 2. x
R. Q
1
,Q
4
positive Q
2
, Q
3
negative 3. +y
S. Q
1
,Q
3
positive Q
2
, Q
4
negative 4. y
Code :
(A) P-3, Q-1, R-4,S-2 (B) P-4, Q-2, R-3, S-1
(C) P-3, Q-1, R-2,S-4 (D) P-4, Q-2, R-1, S-3
Page || 18
PHYSICS
i i( i Q
1
,Q
2
,Q
3
, nii Q
4
,li -i -i r , x i li -i x = 2a, a, +a nii +2a i r | )
ii( i q, + y i b > 0 i ii r | i( ii l, (sign) i l(- i-I - l) r | i( i q
n (i +i i lii i-II - i n; r | i-I i i-II - ln il) nii li i l n) i i i n
ri l(- l)
= |-I = | -II
P. Q
1
,Q
2
,Q
3
, Q
4
, ii ii( i r | 1. +x
Q. Q
1
,Q
2
ii( i r Q
3
,Q
4
~ii( i r | 2. x
R. Q
1
,Q
4
ii(i r Q
2
, Q
3
~ii( i r | 3. +y
S. Q
1
,Q
3
ii(i r Q
2
, Q
4
~ii( i r | 4. y
+r = :
(A) P-3, Q-1, R-4,S-2 (B) P-4, Q-2, R-3, S-1
(C) P-3, Q-1, R-2,S-4 (D) P-4, Q-2, R-1, S-3
Ans. (A)
Sol. (P)
Component of forces along x-axis will vanish. Net force along +ve y-axis
x-i li +i i- l-n ri i n | n + ii-- y- i li ri ni
(Q)
Component of forces along y-axis will vanish. Net force along +ve x-axis
y-i li +i i- l-n ri i n | n + ii-- x- i li ri ni
Page || 19
PHYSICS
(R)
Component of forces along x-axis will vanish. Net force along -ve y-axis.
x-i li +i i- l-n ri i n | n + ~ii-- y- i li ri ni
(S)
F
4
F
3
F
2
F
1
+Q - Q +Q - Q
+q
Component of forces along y-axis will vanish. Net force along -ve x-axis.
y-i li +i i- l-n ri i n | n + ~ii-- x- i li ri ni
Ans. (A) P3, Q1, R4, S2
19. Four combinations of two thin lenses are given in List-I. The radius of curvature of all curved surface is r and the
refractive index of all lenses is 1.5. Match lens combinations in List-I with their focal length in List-II and select
the correct answer using the code given below the lists.
i n i i i i-I - l) r | - (i - i (ni lii r nii (n i (r.i) 1.5 r |
i-I - l(lii i l) r nii i-II - i i i i r ; r | i-I i i-II - ln il) nii
li i l) n) i i i n ri -i l)
List-I List-II
= |-I = | -II
P. 1. 2r
Q. 2. r/2
R. 3. r
S. 4. r
Page || 20
PHYSICS
Code :
+r = :
(A) P-1, Q-2, R-3,S-4 (B) P-2, Q-4, R-3, S-1
(C) P-4-,Q-1, R-2,S-3 (D) P-2, Q-1, R-3, S-4
Ans. (B)
Sol. (P)
r
1
r
1
r
1
1
2
3
f
1
f = r

eq
f
1
=
f
1
+
f
1
=
r
2
f
eq
=
2
r
(Q)
f
1
=
r
1
1
2
3
f = 2r
f
1
+
f
1
=
f
2

r
1
f
eq
= r
(R)
f
1
=
r
1
1
2
3
=
r 2
1
f = 2r
eq
f
1
=
f
1
+
f
1
=
r 2
2
f
eq
= r
(S)
r 2
1
r 2
1
r
1
f
1
eq
f
eq
= 2r
Ans. (B) P2 Q 4 R3 S 1
Page || 21
PHYSICS
20. A block of mass m
1
= 1 kg another mass m
2
= 2 kg , are placed together (see figure) on an inclined plane with
angle of inclination . Various values of are given in List I. The coefficient of friction between the block m
1
and
the plane is always zero. The coefficient of static and dynamic friction between the block m
2
and the plane are
equal to = 0.3. In List II expression for the friction on block m
2
given. Match the correct expression of the
friction in List II with the angles given in List I, and choose the correct option. The acceleration due to gravity
is denoted by g.
[Useful information : tan(5.5) 0.1 ; tan (11.5) 0.2 ; tan(16.5 0.3)]
) in n , li in i i r , -i m
1
= 1 kg nii -i m
2
= 2 kg i i i - -i i
n) r | ( i l li - liii ni r) i i l(li -i i I - l) n) r | i m
1
nii in n +i ii i
n ii ( i r | i m
2
nii in n +i -i ln nii nln iii n ii = 0.3 -i r | i II - i m
2
n (i ii i + l) r | i II - ln il) nii li i l) n) ii i i n ri
-i l)| n -(i -(i g ln r |
[r+ r += : tan(5.5) 0.1 ; tan (11.5) 0.2 ; tan(16.5 0.3)]
List-I List-II
i-I i-II
P. = 5 1. m
2
g sin
Q. = 10 2. (m
1
+ m
2
)g sin
R. = 15 3. m
2
g cos
S. = 20 4. (m
1
+ m
2
)g cos
Code :
(A) P-1, Q-1, R-1,S-3
(B) P-2, Q-2, R-2,S-3
(C) P-2, Q-2, R-2,S-4
(D) P-2, Q-2, R-3,S-3
Ans. (D)
Page || 22
PHYSICS
Sol. Block will not slip if
(m
1
+ m
2
) g sin m
2
g cos
3 sin
10
3
(2) cos
tan
5
1
5 . 11
(P) = 5 friction is static f = (m
1
+ m
2
)g sin
(Q) = 10 friction is static f = (m
1
+ m
2
)g sin
(R) = 15 friction is kinetic f = m
2
g cos
(S) = 20 friction is kinetic f = m
2
g cos
Ans. (D) P2 Q 2 R3 S 3
i ri l ni l
(m
1
+ m
2
) g sin m
2
g cos
3 sin
10
3
(2) cos
tan
5
1
5 . 11
(P) = 5 -iln iii f = (m
1
+ m
2
)g sin
(Q) = 10 -iln iii f = (m
1
+ m
2
)g sin
(R) = 15 nln ii i f = m
2
g cos
(S) = 20 nln ii i f = m
2
g cos
Ans. (D) P2 Q 2 R3 S 3
Page || 23
JEE-ADVANCED-2014 | DATE: 25-05-2014 | PAPER-2 | CODE-2 CHEMISTRY
PART II : CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27,
Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As =
75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION 1 : (Only One option correct Type)
=r= 1 : (+ + =;| |+- +r)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
;= =r= = 10 ; |+- ; | - + = r |+- (A), (B), (C) r (D) ; , |= = + + =;| ; |
21. Assuming 2s-2p mixing is NOT operative, the paramagnetic species among the following is :
r -in r ) l 2s-2p i l-i liii (operative) ri r , l - +i (paramagnetic) ((
(species) r
(A) Be
2
(B) B
2
(C) C
2
(D) N
2
Ans. (C)
Sol. If 2s-2p mixing is not operative, the increasing order of Molecular orbitals will be :
1s
2
, *1s
2
, 2s
2
, *2s
2
,
1
2 y
x 1
z
2p
2P
2p
Considering this Be
2
& B
2
become diamagnetic, so does N
2
. Only C
2
would be paramagnatic with
electronic configuration as above
; l 2s-2p l-i lil(n ri ri ni r , ni iil( ii i ii ri - l ri ni
1s
2
, *1s
2
, 2s
2
, *2s
2
,
1
2 y
x 1
z
2p
2P
2p
Be
2
( B
2
ln +i r , ) i ri N
2
ii ri ni r | ( i n ; - i l l(i ii C
2
+i ri ni|
22. For the process
H
2
O( ) H
2
O(g)
at T = 100 C and 1 atmosphere pressure, the correct choice is :
(A) S
system
> 0 and S
surroundings
> 0 (B) S
system
> 0 and S
surroundings
< 0
(C) S
system
< 0 and S
surroundings
> 0 (D) S
system
< 0 and S
surroundings
< 0
ni-i T = 100 C nii 1 (i - i i+ - H
2
O( ) H
2
O(g) l) ri l(- r
(A) S
iii
> 0 i S
l( i
> 0 (B) S
iii
> 0 i S
l( i
< 0
(C) S
iii
< 0 i S
l( i
> 0 (D) S
iii
< 0 i S
l( i
< 0
Ans. (B)
Sol. For H
2
O( ) H
2
O(g) at T = 100C, 1atm
equilibrium exists. G = 0, H T S = 0
H = T S > 0 for system, since evaporation is endothermic
( S)
system
> 0, also ( S)
surrounding
=
surr
surr
T
q
Heat gained by system = heat lost by surroundings
q
surr.
< 0 ( S)
surr.
< 0
Page || 24
; T = 100, 1 atm
H
2
O( ) H
2
O(g) l i -iiln ri ni r G = 0, H T S = 0
ni l) H = T S > 0, l (i +-iii ii ri ni r |
( S)
n i
> 0, ii ri ( S)
l( i
=
i l(
i l(
T
q
n i ,ii in +-i = l( i ,ii ,iln +-i
q
l( i
< 0 ( S)
l( i
< 0
23. For the elementary reaction M N, the rate of disappearance of M increases by a factor of 8 upon
doubling the concentration of M. The order of the reaction with respect to M is :
lili M N l), M i i ni i n i M i l(i (rate of disappearance) 8 n i
+ ini r | M i i lili i i l- (order of the reaction) r |
(A) 4 (B) 3 (C) 2 (D) 1
Ans. (B)
Sol. M N
r = K [M]
x
as [M] is doubled, rate increases by a factor of 8.
i.e. 8 r = K [2M]
x
8 = (2)
x
x = 3
Sol. M N
r = K [M]
x
[M] n i ri n ri n ii - 8 ( l, ri ini r |
iin 8 r = K [2M]
x
8 = (2)
x
x = 3
24. For the identification of -naphthol using dye test, it is necesary to use :
(A) dichloromethane solution of -naphthol. (B) acidic solution of -naphthol.
(C) neutral solution of -naphthol. (D) alkaline solution of -naphthol.
i; - -- - - ii i ri l) i n i i( r
(A) - ii i i;i i l-i l( (B) - ii i i l(
(C) - ii i ii l( (D) - ii i iii l(
Ans. (D)
Sol. In dye test, phenolic OH is converted to , which activates the ring towards EAS. This is possible
only in alkaline solution. Hence (D).
;. iii - , li l OH - r - l(ln n ri ini r i ( i EAS ln l ni r |
r ( iii l( - ri i( r | n -i (D) ri ni|
25. Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the
figure.
[Figure]

The correct order of their boiling point is
(A) I > II > III (B) III > II > I (C) II > III > I (D) III > I > II
CHEMISTRY
Page || 25
r -i((i (Isomers) i iiiii iii i ii li i ii ln ni li (ni - l(iiln
li i ni r |

(ii (boiling point) i ri - r
(A) I > II > III (B) III > II > I (C) II > III > I (D) III > I > II
Ans. (B)
Sol. Greater the extent of branching, lesser is the boiling point of hydrocarbon.
Hence III > II > I
;. ri; i i+ - lni ii i ri ni, ri; i i+ i (ii l+ ni ri - ri ni|
n III > II > I
26. The acidic hydrolysis of ether (X) shown below is fastest when :
[Figure]
(A) one phenyl group is replaced by a methyl group.
(B) one phenyl group is replaced by a para-methoxyphenyl group.
(C) two phenyl groups are replaced by two para-methoxyphenyl groups.
(D) no structural change is made to X.
i l ; i (X) i i i- (hydrolysis) ni( n- r +
(A) ) l - r i ) - li - r ,ii ln-iiln li ni ri |
(B) ) l - r i ) il-iii l - r ,ii ln-iiln li ni ri |
(C) i l - r i i il-iii l - r ,ii ln-iiln li ni ri |
(D) X - i ; i-- +i( li ni ri |
Ans. (C)
CHEMISTRY
Page || 26
Sol. Ph
3
CCO
2
H
H O
Ph
3
COH + ROH
The reaction proceeds by S
N
1 Mechanism :
Ph
3
COR + H Ph
3
COHR Ph
3
C + ROH
H O
2
Ph
3
COH
H
Ph
3
C
2 OH
Greater the electron releasing effect of the attached groups greater is the stability of intermediate carbocation,
& faster is the rate of reaction.
If two ph groups are replaced by MeO groups , strong +M effect of MeO groups stablize, the
carbocation better there by making the reaction faster.
;. Ph
3
CCR
2
H
H O
Ph
3
COH + ROH
i n lili S
N
1 lil(li ,ii rini r |
Ph
3
COR + H Ph
3
C
OHR
Ph
3
C
H O
2
Ph
3
COH
H
Ph
3
C
2 OH
- r i lni ii ; - i lnii ii( ri ni, -(ni i+ ii i -iil-( ni ri ii ri ni nii
lili i ii ni( ri ni|
l i ph - r i MeO - r ,ii ln-iiln li i , MeO + +M i+ ii i s i
-iiii ni r | l iii--( lili ni( ri ni|
27. Hydrogen peroxide in its reaction with KIO
4
and NH
2
OH respectively, is acting as a
(A) reducing agent, oxidising agent (B) reducing agent, reducing agent
(C) oxidising agent, oxidising agent (D) oxidising agent, reducing agent
ri; i ii; i -i KIO
4
)( NH
2
OH lili - , r i ri r
(A) i (reducing agent) i nr, i ii (oxidising agent) i nr
(B) i i nr, i i nr
(C) i ii i nr, i ii i nr
(D) i ii i nr, i i nr
Ans. (A)
Sol. KlO
4
+ H
2
O
2
KlO
3
+ H
2
O + O
2
H
2
O
2
acts as a reductant
2NH
2
OH + H
2
O
2
N
2
+ 4H
2
O
H
2
O
2
acts as an oxidant.
Sol. KlO
4
+ H
2
O
2
KlO
3
+ H
2
O + O
2
H
2
O
2
i i nr i ni r |
2NH
2
OH + H
2
O
2
N
2
+ 4H
2
O
H
2
O
2
i ii i nr i ni r |
CHEMISTRY
Page || 27
28. The major product in the following reaction is :
[Figure]
(A) (B)
(C) (D)
l lili - - -i r
(A) (B)
(C) (D)
Ans. (D)
Sol. Cl
O
CH
3
CHMgBr/ether
3
0C

Cl
CH
3
CH
3
O
O
+Cl
CHEMISTRY
Page || 28
29. Under ambient conditions, the total number of gases released as products in the final step of the reaction
scheme shown below is :
(A) 0 (B) 1 (C) 2 (D) 3
l( ii (-ii (ambient conditions) i ii lili iii ilii i - -i - l- n
n i i i i r
(A) 0 (B) 1 (C) 2 (D) 3
Ans. (C)
Sol. XeF
6

Complete
Hydrolysis

Page || 29
;. XeF
6

i
i-
30. The product formed in the reaction of SOCl
2
with white phosphorous is :
SOCl
2
i i-i i lili +i -i r
(A) PCl
3
(B) SO
2
Cl
2
(C) SCl
2
(D) POCl
3
Ans. (A)
Sol. P
4
+ 8SOCl
2
4PCl
3
+4SO
2
S
2
Cl
2
(NCERT Reaction) (NCERT lili)
SECTION 2 : Comprehension Type (Only One Option Correct)
=r= 2 : -e +r (+ + |+- =;|)
This section contains 3 paragraphs each describing theory, experiment, data etc. Six questions
relate to three paragraphs with two questions on each paragraph. Each question has only one
correct answer among the four given options (A), (B), (C) and (D).
;= =r= = |=qr nr , r nr r r += r r| +r rr r 3 -e ; | n|r -e r = = |=rn e: ; , |=
= ; -e r ; | |+=| -r| -e = ; + r |+- (A), (B), (C) r (D) ; , |= = +
+ ;| =;| ; |
Paragraph for questions 31 and 32
X and Y are two volatile liquids with molar weights of 10 g mol
1
and 40 g mol
1
respectively. Two cotton
plugs, one soaked in X and the other soaked in Y, are simultaneously placed at the ends of a tube of
length L = 24 cm, as shown in the figure. The tube is filled with an inert gas at 1 atmosphere pressure
and a temperature of 300 K. Vapours of X and Y react to form a product which is first observed at a
distance d cm from the plug soaked in X. Take X and Y to have equal molecular diameters and assume
ideal behaviour for the inert gas and the two vapours.
= 24 cm L
d
Cotton wool
soaked in X
Cotton wool
soaked in Y
Initial formation of
the product
= =r 31 r 32 + | -e
X i Y, -i 10 g -i
1
)( 40 g -i
1
(iii ( r | i ; n, ) X - lini r ) nii i Y
- lini r ), li - ii i 24 cm +i ) - + i i si i i n r | - + - ) l n
1 (i -i +i( (atmosphere pressure) nii 300 K niii r | X i Y i (i li n ri
) -i +ini r i X - iin n d cm i i r lini r | X i Y il( i (molecular
diameters) -i il) nii l n )( i i (ii i ii ii (ideal behaviour) -il)|
Page || 30
X - lini r )
ri lin -i
Y - lini r )
= 24 cm L
d
31. The value of d in cm (shown in the figure), as estimated from Grahams law, is :
n ir- l- i ln d i -i (lii li - ) cm - r
(A) 8 (B) 12 (C) 16 (D) 20
Ans. (C)
Sol. According to Grhams law, if all conditions are identical,
M
1
r
As in this question, all conditions are identical for X and Y, it will be followed
Hence
x
y
y
x
M
M
r
r
10
40
d 24
d
d 24
d
= 2
d = 48 2d
3d = 48
d = 16 cm.
r n ir- l-i i, l ii ll-ini -i ri ni r ,
M
1
r
- X ( Y l) ii ll-ilni -i ri ni r , r l i i ni r
n
x
y
y
x
M
M
r
r
10
40
d 24
d
d 24
d
= 2
d = 48 2d
3d = 48
d = 16 cm.
Page || 31
32. The experimental value of d is found to be smaller than the estimate obtained using Grahams law. This
is due to :
(A) larger mean free path for X as compared to that of Y.
(B) larger mean free path for Y as compared to that of X.
(C) increased collision frequency of Y with the inert gas as compared to that of X with the inert gas.
(D) increased collision frequency of X with the inert gas as compared to that of Y with the inert gas.
n ir- l- i ni l- i (extimate) i ii d i ii ln -i - ii ni| ;i ii r
(A) Y i ii X i li -i - n i (mean free path)|
(B) X i ii Y i li -i - n i (mean free path)|
(C) X i ii Y i l n ii + i i; i( l-i (collision frequency)|
(D) Y i ii X i l n ii + i i; i( l-i (collision frequency)|
Ans. (D)
Sol. The general formula of mean free path ( ) is
P N d 2
RT
A
2
(d = diameter of molecule
p = pressure inside the vessel).
d & p are same for both gases, ideally their are same. Hence it must be the higher drift speed of X
due to which it is seeing more collisions per second, with the inert gas in comparison to gas Y. So X see
comparably more resistance from noble gas than Y and hence covers lesser distance than that predicted
by Graham's Law.
;. -i - n i ( ) i i-i i
P N d 2
RT
A
2
(d = i i i
p = ii i+ ).
i i n i l) d ( p -i ri n r , ;l) -i ri ni r |
n X l) (iri ( n ri i ilr) l ii Y i ii l n ii ln li -
i i l-ni r | ;l) ri X - Y i n i - - - n li lni i ii ni r ( ;l) n ir- l-
,ii +nii ni i i n i - - i n ini r |
Paragraph for questions 33 and 34
Schemes 1 and 2 describe sequential transformation of alkynes M and N. Consider only the major
products formed in each step for both the schemes.
HO
H
1. NaNH (excess)
2
2. CHCH (1 equivalent)
3 2
I
3. CH (1 equivalent)
3
I
4. H, Lindlar's catalyst
2
M
X Scheme-1
Y Scheme-2
Page || 32
= =r 33 r 34 + | -e
i i) 1 nii 2 )-i;i M )( N l- ini (sequential transformation) i ii ni r | i i
i ii - l) ( - -i l(i il)|
HO
H
1. NaNH
2
(lini - )
2. CHCH
3 2
I (-i-iii)
3. CH
3
I (-i-iii)
4. H,
(Lindlar's catalyst)
2
li -
M
X r r-1
Y r r-2
33. The product X is :
-i X r
(A)
H CO
3
H H
(B)
(C)
CH CH O
3 2
H H
(D)
H
H
CH CH O
3 2
Ans. (A)
Sol.
Page || 33
34. The correct statement with respect to product Y is :
(A) It gives a positive Tollens test and is a functional isomer of X.
(B) It gives a positive Tollens test and is a geometrical isomer of X.
(C) It gives a positive iodoform test and is a functional isomer of X.
(D) It gives a positive iodoform test and is a geometrical isomer of X.
-i Y + i - - i r
(A) r ii-- -i - -- ni r nii X i li-- -i(( (functional isomer) r |
(B) r ii-- -i - -- ni r nii X i il-ni -i(( (geometrical isomer) r |
(C) r ii-- ii i i- - -- ni r nii X i li-- -i(( r |
(D) r ii-- ii i i- - -- ni r nii X i il-ni -i(( r |
Ans. (C)
Sol.
(Y) can answer iodoform test (but not Tollen's test and it is a functional isomer of (X)
(Y) ii i i - iii ni r ( l -i iii ri ni r nii r (X) i ) li-- -i((i r |)
Paragraph For question 35 to 36
An aqueous solution of metal ion M1 reacts separately with reagents Q and R in excess to give tetrahedral
and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms
tetrahedral complexes with these reagents. Aqueous solution of M2 on reaction with reagent S gives
white precipitate which dissolves in excess of S. The reactions are summarized in the scheme given
below :
SCHEME:
Tetrahedral
Q
excess
M1
R
excess
Square planar
Tetrahedral
Q
excess
M2
R
excess
Tetrahedral
S, stoichiometric amount
White precipitate
S
excess
precipitate dissolves
Page || 34
= =r 35 r 36 + | -e
) iin i M1 i i l( nn Q nii R li- i i lini - lili -i
n i )( (n -ni +in r | iin i M2 i i l( i i li- i ii lili
r- ii n i +ini r | M2 i i l( li- S lili (i ni
r i S i lini - i ini r | lili) i i n; i i - ii i n; r |
r r :
ni
(Tetrahedral)

lini -
Q
M1
lini -
R
(n -ni
(Square planar)
ni
(Tetrahedral)

lini -
Q
M2
lini -
R

ni
(Tetrahedral)
S, -iii -iii (stoichiometric amount)
(i
(White precipitate)

lini -
S

i ini r
(precipitate dissolves)
35. M1, Q and R, respectively are :
(A) Zn
2+
, KCN and HCl (B) Ni
2+
, HCl and KCN
(C) Cd
2+
, KCN and HCl (D) Co
2+
, HCl and KCN
M1, Q i R, -i r
(A) Zn
2+
, KCN nii HCl (B) Ni
2+
, HCl nii KCN
(C) Cd
2+
, KCN nii HCl (D) Co
2+
, HCl nii KCN
Ans. (B)
36. Reagent S is :
li- S r
(A) K
4
[Fe(CN)
6
] (B) Na
2
HPO
4
(C) K
2
CrO
4
(D) KOH
Ans. (D)
(35 & 36)
Page || 35
Reaction with (S) indicates amphoteric nature of M2 . Amongst the options mentioned for (S) in Q.36,
only KOH can give a complexing agent OH

; which is its answer.
[Note : M2 may be Zn
2+
, which (a) is amphoteric (b) has cordination number 4 and (c) always from
tetrahedral complexes. It may be noted that Be
2+
will also qualify with these characterstics]
Let us consider the possiblities of M1 . M1 should be able to form square planner complex (dsp
2
hybridisation) as well as tetrahedral (sp
3
). This rules out Zn
2+
& Cd
2+
[ d
10
configuration will not allow
dsp
2
hybridization]
Ni
2+
is most suitable
Ni
2+
(aq.) + 4CN
(excess) Ni
2
4
) CN ( (square planner)
Ni
2+
(aq.) + Cl
(excess) NiCl
4
2
(tetrahedral)
[Note : Co
2+
+ 6CN
(excess) Co
4
6
) CN ( , an octahedral compelex]
r
Q ( ) ili
ni
(n -ni
R ( ) ili
( ) iin i
M2 ( ) i
S
(n (i i ii (S)
ni
(n -ni
R ( ) ili
Q ( ) ili
ili -
M1 ( ) i
(S) iiii lili M2 i ii-i ln i ; lnn ni r | l(-i - 36 - (S) l) (li n
( KOH ri ) li- OH

ni r i l ;i -i r |
[r c : M2 , Zn
2+
ri ni r l- l (a) ii-i r (b) -( i 4 ini r ( (c) r- ii n i
+ini r | r i i r l Be
2+
ii ; liiii ii ) i ni r |
+ r- M1 i ii(ii i in r | M1 (n -ni (dsp
2
i) +i iiii n i (sp
3
)
+i i i-ni ii ini r | r Zn
2+
( Cd
2+
i ini r | [ d
10
l(i dsp
2
i i in ri ni r |]
Ni
2+
+ n r |
Ni
2+
(i) + 4CN
(ili) Ni
2
4
) CN ( ((n -ni)
Ni
2+
(i) + Cl
(ili) NiCl
4
2
(n i)
[r c: Co
2+
+ 6CN
(ili) Co
4
6
) CN ( , ) -i ]
Page || 36
SECTION 3 : Matching List Type (One One Option Correct)
=r= 3 : = = = | +r (+ + |+- =;|)
This section contains four questions, each having two matching lists. Choices for the correct
combination of elements from List-I and List-II are given as option (A), (B), (C) and (D) out of which
one is correct.
;= =r= = 4 ; |+- ; | - + = r = = = |r ; | = |r + | + c + |+- (A), (B), (C) nrr
(D) ; , |= = + |= + =;| ; |
37. Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and
select the correct answer using the code given below the lists.
{en = H
2
NCH
2
CH
2
NH
2
; atomic numbers : Ti = 22; Cr = 24; Cp = 27; Pt = 78}
List-I List-II
P. [Cr(NH
3
)
4
Cl
2
)Cl] 1. Paramagnetic and exhibits ionisation isomerism
Q. [Ti(H
2
O)
5
Cl](NO
3
)
2
2. Diamagentic and exhibits cis-trans isomerism
R. [Pt(en)(NH
3
)Cl]NO
3
3. Paramagentic and exhibits cis-trans isomerism
S. [Co(NH
3
)
4
(NO
3
)
2
]NO
3
4. Diamagentic and exhibits ionisation isomerism
Code :
P Q R S
(A) 4 2 3 1
(B) 3 1 4 2
(C) 2 1 3 4
(D) 1 3 4 2
i-I - r i i ln (coordination compound) i i-II i n l(i inii i i i
- ln il) nii li i l i i i n ri -i l
{en = H
2
NCH
2
CH
2
NH
2
; -ii i : Ti = 22; Cr = 24; Cp = 27; Pt = 78}
= |-I = |-II
P. [Cr(NH
3
)
4
Cl
2
)Cl] 1. +i (Paramagnetic) nii i -i((ni
(ionisation isomerism) ii ni r |
Q. [Ti(H
2
O)
5
Cl](NO
3
)
2
2. ln +i (Diamagentic) nii -il(i (cis-trans) -i((ni
ii ni r |
R. [Pt(en)(NH
3
)Cl]NO
3
3. +i nii -il(i -i((ni ii ni r |
S. [Co(NH
3
)
4
(NO
3
)
2
]NO
3
4. ln +i nii i -i((ni ii ni r |
i :
P Q R S
(A) 4 2 3 1
(B) 3 1 4 2
(C) 2 1 3 4
(D) 1 3 4 2
Ans. (B)
Sol. (P) [Cr(NH
3
)
4
Cl
2
]Cl Cr
+3
is d
3
. It is paramagnetic and it shows cis-trans isomerism.
(Q) [Ti(H
2
O)
5
Cl](NO
3
)
2
Ti
+3
is d
1
. It is paramagnetic and it show ionisation isomerism.
(R) [Pt(en)(NH
3
)Cl]NO
3
Pt
+2
is d
8
. But this complex is square planar and all electron are paired. So
it is diamagnatic. It exhibit ionisation isomerism.
(S) [Co(NH
3
)
4
(NO
3
)
2
]NO
3
Co
+3
is d
6
. Since ligands are strong, so electron are paired. it is diamagnetic.
It exhibit cis-trans isomerism.
Ans. is (B).
CHEMISTRY
Page || 37
Sol. (P) [Cr(NH
3
)
4
Cl
2
]Cl Cr
+3
d
3
r | r +i r ( r -il(i -i((ni ii ni r |
(Q) [Ti(H
2
O)
5
Cl](NO
3
)
2
Ti
+3
d
1
r | r +i r ( r i -i((ni ii ni r |
(R) [Pt(en)(NH
3
)Cl]NO
3
Pt
+2
d
8
r | l r (n -ni r ( ii ; - i l-n ri in r |
;l) r ln +i r | r i -i((ni li n ni r |
(S) [Co(NH
3
)
4
(NO
3
)
2
]NO
3
Co
+3
d
6
r | l ln + ri n r ;l) ; - i l-n ri in r | r
ln +i r | r -i l(i -i((ni li n ni r |
-i (B) r |
38. Match the orbital overlap figures shown in List-I with the description given in List-II and select the correct
answer using the code given below the lists.
List-I List-II
P. 1. pd antibonding
Q. 2. dd bonding
R. 3. pd bonding
S. 4. dd antibonding
Code :
P Q R S
(A) 2 1 3 4
(B) 4 3 1 2
(C) 2 3 1 4
(D) 4 1 3 2
i-I - ii ii lni (orbital overlap) i ln i i-II - ii (i - il) nii li
i l i i i n ri -i l
= |-I = |-II
P. 1. pd lni+i (antibonding)
Q. 2. dd i+i (bonding)
R. 3. pd i+i (bonding)
S. 4. dd lni+i (antibonding)
i :
P Q R S
(A) 2 1 3 4
(B) 4 3 1 2
(C) 2 3 1 4
(D) 4 1 3 2
Page || 38
Ans. (C)
Sol. It is dd axial overlap in same phase, so dd bonding.
It is p & d lateral overlap in same phase, so it is pd bonding.
It is p and d lateral overlap in opposite phase, so it is pd antibonding.
It is dd axial overlap in opposite phase, so it is dd antibonding.
;. r -i i(-ii - dd ii lni in r , ;l) dd +i in r |
r -i i(-ii - p ( d -il( lni in r , ;l) pd +i in r |
r l(in i(-ii - p ( d -ili( ln(i in r , ;l) pd ln+lin in
r |
r l(in i(-ii - dd ii lni in r , ;l) r dd ln+lin in r |
39. Different possible thermal decomposition pathways for peroxyesters are shwon below. Match each
pathway from List I with an appropriate structure from List II and select the correct answer using the
code given below the lists.

List-I List-II
P. Pathway P 1.
Q. Pathway Q 2.
R. Pathway R 3.
Page || 39
S. Pathway S 4.
Code :
P Q R S
(A) 1 3 4 2
(B) 2 4 3 1
(C) 4 1 2 3
(D) 3 2 1 4
ii; -- l) l(li i( nii l(i- (thermal decomposition) i i ii n r | i-I -
i i i-II - llin ) n i - il) nii li i l i i i n ri
-i l

= |-I = |-II
P. i P 1.
Q. i Q 2.
R. i R 3.
S. i S 4.
+r = :
P Q R S
(A) 1 3 4 2
(B) 2 4 3 1
(C) 4 1 2 3
(D) 3 2 1 4
Ans. (A)
Page || 40
Sol. This is an excellent question, probably the best in the paper. Pyrolysis of peroxyesters is not conventionally
taught anywhere for IIT-JEE preparation, not even in any standard organic chemistry course. But the
question is throughly logical. It can be answered after a bit of reflection by anyone with good basics of
reaction mechanism.
Four pathways for reactions are given :
Note that first homolytic fission is expected to give + R'O . This is usually unstable (remember
kolbe's electrolysis) and decomposes to R + CO
2
. But is stable, since it is a difficult bond to
break. Hence in (1) & (3), which have PhCHCOOR
2
O
groups, PhCH
2
. will be formed ( benzyl
radical is stable) so P or Q are possible pothways for them. For PhCOOR
O
(2 & 4), R & S pathways
will be more likely.
1: P or Q 2 : R or S
2: P or Q 4 : R or S
Now consider R'O . If it is CH
3
O , It cannot splite.
But 3
C CH
|
O
|
CH
3
PhCH
2
PhCH
2
+ C
CH
3
CH
3 O
can occur. Hence carbonyl compound will be formed
with 3 & 4, but not with 1 & 2.
1 : P or S 3 : Q or R
2 : P or S 4 : Q or R
combining these options gives
1: P , 2 : S, 3 : Q , 4 : R
I cannot but help commenting that such questions are those which make IIT-JEE what it is. A good
motivation for students to keep thinking while studying .
Sol. r ; i i + si r | IIT-JEE n ii l) li ii nr i i) --i nii i-
i - ri ii ini r , ri n l li -ni i+ l i i -ni - ii ri li ni
r | l r ri +r n ri n nn r | ; i -i lili lil(i i - i n l,in iii
li ,ii li i ni r |
Page || 41
lilii l) i i l n r
i i l + r -i i l(i ,ii + R'O in ri n r | r i-ini -iii r (i -+
( n n i-i lili i i - i ) nii R + CO
2
- il-n ri in r | l -iii ri ni r ,
;i + i l-i; ( - -ni r |
n (1) ( (3) - l- PhCH COOR
2
O
- r l-in r , PhCH
2
+ini r ( + l - -iii ri ni r )
;l) P i Q ; iil(n i r | PhCOOR
O
l) (2 ( 4), R ( S i li i( r |
1: P i Q 2 : R i S
2: P i Q 4 : R i S
+ R'O l(i , l r CH
3
O r , ni r l(iln ri ri ni r |
l 3
C CH
|
O
|
CH
3
PhCH
2
PhCH
2
+ C
CH
3
CH
3 O
ii ini r | n 3 ( 4 ii i+i l i ln +ni
r l 1 ( 2 - ri +ni r |
1 : P i S 3 : Q i R
2 : P i S 4 : Q i R
; l(-i i ,
1: P , 2 : S, 3 : Q , 4 : R
- ; i ; n ri ni r i IIT-JEE ; i i +ii r | r l(niii l(iiii
i + i i ) si -ii n r |
40. Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes
(I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.
List-I List-II
P. 1. Scheme I
Page || 42
Q. 2. Scheme II
R. 3. Scheme III
S. 4. Scheme IV
Code :
P Q R S
(A) 1 4 2 3
(B) 3 1 4 2
(C) 3 4 2 1
(D) 4 1 3 2
i-I - llin i li iii (P, Q, R, S) i i-II - llin lili i ii (Scheme)
(I, II, III, IV) - il) nii li i l i i i n ri -i l
= |-I = |-II
P. 1. r r I
CHEMISTRY
Page || 43
Q. 2. r r II
R. 3. r r III
S. 4. r r IV
+r = :
P Q R S
(A) 1 4 2 3
(B) 3 1 4 2
(C) 3 4 2 1
(D) 4 1 3 2
Ans. (C)
Sol. P :
CHEMISTRY
Page || 44
P 3
Q :
Q 4
R :
R 2
S :
S 1
Hence the answer is (C) (n ri -n (C) r |)
Note : Verifying any two can easily give you the answer complete details are given for reference &
understanding.
r c : i -n i lri i ,ii iii -ili n r |
v ki d sfunsZ' k(reference) nii -n l) i l((i li ni r |
CHEMISTRY
Page || 45
MATHS
PART- III - MATHEMATICS
SECTION 1 : (Only One Option Correct Type)
=r= 1 : (+ + =;| |+- +r)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE option is correct.
; i - 10 ; |+- r | - - i l(- (A),(B),(C) i (D) r , l- + + ri r |
41. The quadratic equation p(x) = 0 with real coefficients has purely imaginary roots. Then the equation p(p(x))
= 0 has
(A) only purely imaginary roots (B) all real roots
(C) two real and two purely imaginary roots (D) neither real nor purely imaginary roots
(i-nl( n ii i (i l,iin -ii (quadratic equation) p(x) = 0 - i ni i-l r | n+ -ii
p(p(x)) = 0
(A) ( i ni i-l - r | (B) ii - (i-nl( r |
(C) i (i-nl( i i i ni i-l - r | (D) - ni (i-nl( r ri i ni i-l r |
Ans. (D)
Sol. p(x) will be of the form ax
2
+ c. Since it has purely imaginary roots only.
Since p(x) is zero at imaginary values while ax
2
+ c takes real value only at real 'x', no root is real.
Also p(p(x)) = 0
p(x) is purely imaginary
ax
2
+ c = purely imaginary
Hence x can not be purely imaginary since x
2
will be negative in that case and ax
2
+ c will be real.
Thus .(D) is correct.
Hindi p(x), ax
2
+ c i ri ni l r ( l(i , i-l - ini r |
l i-l -ii p(x) i r +l ax
2
+ c ( (i-nl( 'x' (i-nl( -i ni r | i; - (i-nl( ri
n p(p(x)) = 0
p(x) l(i, i-l
ax
2
+ c = l(i , i-l
n x l(i , i-l ri ri ni r l x
2
~ii-- ri ni ; l-iln - ax
2
+ c (i-nl( ri ni
n (D) ri r |
42. Three boys and two girls stand in a queue. The probability, that the number of boys ahead of every girl is
at least one more than the number of girls ahead of her, is
(A)
2
1
(B)
3
1
(C)
3
2
(D)
4
3
ni i i li ) l n - i r | (r ilni (probability), + r i in i ri (i
i i i in i i ri (ii li i i - - ) li ri , l r
(A)
2
1
(B)
3
1
(C)
3
2
(D)
4
3
Ans. (A)
Page || 46
MATHS
Sol. 3 Boys & 2 Girls..................
(1) B (2) B (3) B (4)
Girl can't occupy 4
th
position. Either girls can occupy 2 of 1, 2, 3 position or they can both be a position
(1) or (2).
Hence total number of ways in which girls can be seated is
3
C
2
2! 3! +
2
C
1
2! 3! = 36 + 24 = 60.
Number of ways in which 3 B & 2 A can be seated = 5 !
Hence required prob. =
60
5!
=
1
2
.
Hindi 3 i 2 li ..................
(1) B (2) B (3) B (4)
li 4
th
-ii ri ri ni r | i ni li 1, 2, 3 -ii 2 ri ni r i i i l-iln (1) i (2)
ri ni r .
n -i i i l- li + - ni r
3
C
2
2! 3! +
2
C
1
2! 3! = 36 + 24 = 60.
-i i i l- 3 B nii 2 A + - n r = 5 !
n ii- ilni =
60
5!
=
1
2
.
43. Six cards and six envelopes are numbered 1, 2, 3, 4, 5, 6 and cards are to be placed in envelopes so that
each envelope contains exactly one card and no card is placed in the envelope bearing the same number
and moreover the card numbered 1 is always placed in envelope numbered 2. Then the number of ways
it can be done is
(A) 264 (B) 265 (C) 53 (D) 67
s i i s li 1, 2, 3, 4, 5, 6 i i+, r | ii i lii - ; nr ii r l r li
- ( ) ri i ri , i ( li ln i -i ri nii i i 1 r- ii lii i 2 -
ri ri , ni ;i nii i i r
(A) 264 (B) 265 (C) 53 (D) 67
Ans. (C)
Sol.
Cards Envelopes
1
2
3
4
5
6
1
2
3
4
5
6
If '2' goes in '1' then it is dearrangement of 4 things which can be done in 4!
1 1 1
2! 3! 4!
= 9 ways.
If '2' doen't go in 1, it is dearrangement of 5 things which can be done in 44 ways. Hence total 53 ways.
Page || 47
MATHS
Hindi
i li
1
2
3
4
5
6
1
2
3
4
5
6
l '2', '1' - ini r n+ r 4 (-n i i (-ii r i 4!
1 1 1
2! 3! 4!
= 9 nii i ini r |
l '2' , 1, - ri ini r n+ 5 (-n i i -ii 44 nii i ini r n 53 ni
44. In a triangle the sum of two sides is x and the product of the same two sides is y. If x
2
c
2
= y, where c
is the third side of the triangle, then the ratio of the in-radius to the circum-radius of the triangle is
(A)
) c x ( x 2
y 3
(B)
) c x ( c 2
y 3
(C)
) c x ( x 4
y 3
(D)
) c x ( c 4
y 3
) lii i i i ii i i n x r nii ri i ii i n i y r | l x
2
c
2
= y, ri c lii i nii
i i r , n+ lii i nlii (in-radius) )( l( nlii (circum-radius) i in (ratio) r
(A)
) c x ( x 2
y 3
(B)
) c x ( c 2
y 3
(C)
) c x ( x 4
y 3
(D)
) c x ( c 4
y 3
Ans. (B)
Sol. a + b = x
a
C
b
A
c
B
ab = y
x
2
c
2
= y
(a + b)
2
c
2
= ab
a
2
+ b
2
+ ab = c
2
a
2
+ b
2
c
2
= ab
2 2 2
a b c
2ab
=
7
2
cosC =
1
2
C =
2
3
r 4
R s abc
=
2 2 2
1
4 a b sin C
4
a b c abc
=
3ab
4c x c
=
3y
4c x c
Page || 48
MATHS
45. The common tangents to the circle x
2
+ y
2
= 2 and the parabola y
2
= 8x touch the circle at the points P,
Q and the parabola at the points R, S. Then the area of the quadrilateral PQRS is
(A) 3 (B) 6 (C) 9 (D) 15
( -i x
2
+ y
2
= 2 nii ( (parabola) y
2
= 8x i il- -i ii (common tangents) ( -i i P, Q
nii ( i R, S -i ni r , n+ n i (quadrilateral) PQRS i i i r
(A) 3 (B) 6 (C) 9 (D) 15
Ans. (D)
Sol. y = mx +
2
m
If it is tangent to x
2
+ y
2
= 2
Then,
2
2
m
1 m
=
2

2 2
4
m (1 m )
= 2 m = 1.
P
Q
(2,0)
R
S
Hence equation of tangent is y = x + 2 & y = x 2.
Chord of contact PQ is 2x = 2 x = 1
Chord of contanct RS is y. 0 = 4 (x 2) x = 2
Hence co-ordinates of P, Q, R, S are (1, 1) ; (1, 1) ; (2, 4) & (2, 4)
Area of trapezium is =
1
2
(PQ + RS) Height =
1
2
(10) 3 = 15
Hindi y = mx +
2
m
l r x
2
+ y
2
= 2 i -i ii r |
n+,
2
2
m
1 m
=
2

2 2
4
m (1 m )
= 2 m = 1.
P
Q
(2,0)
R
S
n -i ii i -ii y = x + 2 & y = x 2 r |
-i i(i PQ, 2x = 2 x = 1 r |
-i i(i RS y. 0 = 4 (x 2) x = 2
n P, Q, R, S l ii (1, 1) ; (1, 1) ; (2, 4) & (2,4)
-+ n i i i i =
1
2
(PQ + RS) + i; =
1
2
(10) 3 = 15
Page || 49
MATHS
46. The function y = f(x) is the solution of the differential equation
2
4
2
x 1
x 2 x
1 x
xy
dx
dy
in (1, 1) satisfying
f(0) = 0. Then
2
3
2
3
dx ) x ( f is
y = f(x) l (i -ii (differential equation)
2
4
2
x 1
x 2 x
1 x
xy
dx
dy
i ni (1, 1) - r r )(- f(0) = 0 i -i - ni r | n+
2
3
2
3
dx ) x ( f i -i r
(A)
2
3
3
(B)
4
3
3
(C)
4
3
6
(D)
2
3
6
Ans. (B)
Sol. I.F. = 2
x
dx
x 1
e
= 2
1 2x
dx
2 x 1
e
=
2
1
n|x 1|
2
e
=
2
1
n(1 x )
2
e
=
2
1 x
2
y 1 x
=
4
2 2
2
x 2x
1 x dx c
1 x
5
2 2 2
x
y 1 x x c
5
x = 0, y = 0 c = 0
y =
5
2
2
x
x
5
1 x
=
5 5 3
2 2
2
2 2
0
x x
x x
5 5
dx
1 x 1 x
=
3
2
2
2
0
x
2 dx
1 x
x = sin
dx = cos d =
3
2
0
sin cos
2 d
cos
=
3
0
(1 cos2 )d =
3
0
1
sin2
2
=
1 2
sin
3 2 3
=
1 3 3
3 2 2 3 4
Page || 50
MATHS
47. Let f : [0, 2] R be a function which is continuous on [0, 2] and is differentiable on (0, 2) with f(0) = 1.
Let
2
x
0
dt ) t ( f ) x ( F for x [0, 2]. If F'(x) = f'(x) for all x (0, 2), then F(2) equals
-ii f : [0, 2] R ) ) i r i [0, 2] nn (continuous) r )(- (0, 2) (i (differentiable)
r nii f(0) = 1 r | -ii l ii x [0, 2] l
2
x
0
dt ) t ( f ) x ( F r | l ii x (0, 2) l
F'(x) = f'(x) r , n+ F(2) i -i r
(A) e
2
1 (B) e
4
1 (C) e 1 (D) e
4
Ans. (B)
Sol. f'(x) = 2x f(x)
f '(x)
f(x)
= 2x
n(f(x)) = x
2
+ c
x = 0, f(0) = 1
c = 0
n(f(x)) = x
2
f(x) =
2
x
e
F(x) = f(x) + c
F(x) =
2
x
e
+ c
F(0) = 0
c = 1
f(x) =
2
x
e 1
f(2) = e
4
1
48. Coefficient of x
11
in the expansion of (1 + x
2
)
4
(1 + x
3
)
7
(1 + x
4
)
12
is
(1 + x
2
)
4
(1 + x
3
)
7
(1 + x
4
)
12
l(-ni - (expansion) x
11
i n ii (coefficient) r
(A) 1051 (B) 1106 (C) 1113 (D) 1120
Ans. (C)
Sol. Coefficent of x
11

4 2
4 2 12 4 7 3 4 2
) x 1 (
) x 1 ( ) x 1 ( ) x 1 ( ) x 1 (
Coefficent of x
11
(1 x
8
)
4
(1 + x
4
)
8
(1 + x
3
)
7
(1 x
2
)
4
= (1 4x
8
) (1 + x
4
)
8
(7x
3
+ 35x
9
) (1 x
2
)
4
= (7x
3
+ 35x
9
28x
11
) (1 + x
4
)
8
(1 x
2
)
4
Coefficent of x
8
= (7x + 35x
6
28x
8
) (1 + 8x
4
+ 28x
8
) (1 x
2
)
4
= (7 + 35x
6
28x
8
+ 56x
4
+ 196x
8
) (1 x
2
)
4
Coefficent of t
4
(7 + 56t
2
+ 35t
3
+ 168t
4
) (1 t)
4
= 7
7
C
3
+ 56
5
C
3
+ 35
4
C
3
+ 168
= 245 + 700 + 168 = 1113.
Page || 51
MATHS
Hindi
4 2
4 2 12 4 7 3 4 2
) x 1 (
) x 1 ( ) x 1 ( ) x 1 ( ) x 1 (
- x
11 1
i n ii
1 x
8
)
4
(1 + x
4
)
8
(1 + x
3
)
7
(1 x
2
)
4
- x
11
i n ii
= (1 4x
8
) (1 + x
4
)
8
(7x
3
+ 35x
9
) (1 x
2
)
4
= (7x
3
+ 35x
9
28x
11
) (1 + x
4
)
8
(1 x
2
)
4
(7x + 35x
6
28x
8
) (1 + 8x
4
+ 28x
8
) (1 x
2
)
4
- x
8
i n ii
= (7 + 35x
6
28x
8
+ 56x
4
+ 196x
8
) (1 x
2
)
4
(7 + 56t
2
+ 35t
3
+ 168t
4
) (1 t)
4
- t
4
i n ii
= 7
7
C
3
+ 56
5
C
3
+ 35
4
C
3
+ 168
= 245 + 700 + 168 = 1113.
Alterantive : ( l- r
2x + 3y + 4z = 11
(x, y, z) = (0, 1, 2)
4
C
0

7
C
1

12
C
2
(1, 3, 0)
4
C
1

7
C
3
(2, 1, 1)
4
C
2

7
C
1

12
C
1
(4, 1, 0)
7
C
1
coefficient of x
11
i n ii = 66 7 + 35 4 + 42 12 + 7
= 1113. Ans.
49. For x (0, ), the equation sinx + 2 sin 2x sin 3x = 3 has
(A) infinitely many solutions (B) three solutions
(C) one solution (D) no solution
x (0, ) l -ii sinx + 2 sin 2x sin 3x = 3
(A) n (infinitely many) r r | (B) ni (three) r |
(C) ) (one) r r | (D) i ; r ri r (no solution)
Ans. (D)
Sol. sin x + 2 sin2x sin 3x = 3.
sin x (1 + 2 cos x 3 + 4 sin
2
x) = 3.
(4 sin
2
x + 2 cos x 2) =
x sin
3
2 4 cos
2
x + 2 cos x =
x sin
3
4
9

2
2
1
x cos 2
=
x sin
3
.
L.H.S.
4
9
R.H.S. 3.
No solution. i ; r ri |
Page || 52
MATHS
50. The following integral
2
4
17
dx cosecx) (2 is equal to
l -i (integral)
2
4
17
dx cosecx) (2 i l n l(-i - l -i r ?
(A)
) 2 1 log(
0
16 u u
du ) e e ( 2
(B)
) 2 1 log(
0
17 u u
du ) e e (
(C)
) 2 1 log(
0
17 u u
du ) e e (
(D)
) 2 1 log(
0
16 u u
du ) e e ( 2
Ans. (A)
Sol. =
2
17
4
(2cosecx) dx
Put n tan x/2 = t i tan
t
x
e
2
sinx =
t
2t
2e
1 e
cosec

x =
t t
e e
2
=
0
t t 16
n( 2 1)
2 (e e ) .dt
=
0
t t 16
n( 2 1)
2 (e e ) .dt
since(e
t
+ e
t
)
16
is an even function
l (e
t
+ e
t
)
16
) - r |
0 a
a 0
Hence n =
n( 2 1)
t t 16
0
2(e e ) dt
Page || 53
MATHS
SECTION 2 : Comprehension Type (Only One Option Correct)
=r= 2 : -e +r (+ + |+- =;|)
This section contains 3 paragraphs, each describing theory, experiments, data etc. Six questions relate to
the three paragraphs with two questions on each paragraph. Each question has only one correct answer
among the four given options (A),(B),(C) and (D).
; i - l,i ni , i ni i i i il i ii (i 3 -e r | nii si +lin e: r , l-
r s i r | li ii s - r i l(- (A), (B), (C) i (D) r , l- + + ;|
=;| r |
Paragraph For Questions 51 and 52 ( = =r 51 r 52 + | -e )
Box 1 contains three cards bearing numbers 1, 2, 3; box 2 contains five cards bearing numbers 1, 2, 3,
4, 5; and box 3 contains seven cards bearing numbers 1, 2, 3, 4, 5, 6, 7. A card is drawn from each of the
boxes. Let x
i
be the number on the card drawn from the i
th
box, i = 1, 2, 3.
-i 1 - ni i r i 1, 2, 3 i i+, r , -i 2 - i i r i 1, 2, 3, 4, 5 i i+, r nii
-i 3 - in i r i 1, 2, 3, 4, 5, 6, 7 i i+, r | r -i ) i lii ini r | -ii l i(i
-i (i
th
box) li n i x
i
(i = 1, 2, 3) r |
51. The probability that x
1
+ x
2
+ x
3
is odd, is
x
1
+ x
2
+ x
3
l(i- ri i ilni r
(A)
105
29
(B)
105
53
(C)
105
57
(D)
2
1
Ans. (B)
Sol. x
1
+ x
2
+ x
3
is odd if
all three are odd or 2 are even & one is odd
ri nii l(i- i i - i ) l(i-
(OOO) or (OEE) or (EOE) or (EEO)
2 3 4 2 2 3 1 3 3 1 2 4
3 5 7 3 5 7 3 5 7 3 5 7
=
24 12 9 8 53
105 105
52. The probability that x
1
, x
2
, x
3
are in an arithmetic progression, is
x
1
, x
2
, x
3
-in ii (arithmetic progression) - ri i ilni r
(A)
105
9
(B)
105
10
(C)
105
11
(D)
105
7
Ans. (C)
Sol. 2x
2
= x
1
+ x
3
If x
1
& x
3
both are odd 2 4 = 8 ways
x
1
& x
3
both are even 1 3 = 3 ways
Total = 11 ways
Total (x
1
x
2
x
3
) triplets are 3 5 7
P =
11
105
Page || 54
MATHS
Hindi. 2x
2
= x
1
+ x
3
l x
1
i x
3
i i l(i- r 2 4 = 8 ni
x
1
nii x
3
i i - r 1 3 = 3 ni
= 11 ni
(x
1
x
2
x
3
) li - 3 5 7
P =
11
105
Let a, r, s, t be nonzero real numbers. Let P(at
2
, 2at), Q, R (ar
2
, 2ar) and (as
2
, 2as) be distinct points on
the parabola y
2
= 4ax. Suppose that PQ is the focal chord and lines QR and PK are parallel, where K is the
point (2a, 0)
-ii l a, r, s, t i n (i-nl( i (nonzero real numbers) r P(at
2
, 2at), Q, R (ar
2
, 2ar) nii
(as
2
, 2as) ( y
2
= 4ax l-in l(li l+ r | -ii l PQ iii i(i (focal chord ) r )( ii QR nii
PK -iin r , ri K l+ (2a, 0) r |
53. The value of r is
r i -i r
(A)
t
1
(B)
t
1 t
2
(C)
t
1
(D)
t
1 t
2
Ans. (D)
Sol. m
PK
= m
QR
'
2 2 2
2at 0 2at 2ar
at 2a a(t ') ar
2 t
t
2
=
2 2
t' r
(t') r
t tr
2
= t rt
2
2t + 2r , tt = 1
t tr
2
= t + 2r rt
2
tr
2
+ r(t
2
2) + t + t = 0
=
2
2 2 2
2 t t 2 4 1 t
2t
=
2 4
2 t t
2t
=
2 2
2 t t
2t
r =
1
t
It is not possible as the R & Q will be one same.
r =
1
t
r i( ri r i l R nii Q ) -i ri n |
or i r =
2
t 1
t
Page || 55
MATHS
54. If st = 1, then the tangent at P and the normal at S to the parabola meet at a point whose ordinate is
l st = 1 r , ni ; ( l+ P -i ii nii l+ S li+ (normal) l l+ l-n r ,
i i l- (ordinate) r
(A)
2 2
3
(t 1)
2t
(B)
2 2
3
a(t 1)
2t
(C)
3
2 2
t
) 1 t ( a
(D)
3
2 2
t
) 2 t ( a
Ans. (B)
Sol. Tangent at P is ty = x + at
2
Normal at S is y + sx = 2as + as
2
P -i ii ty = x + at
2
S li+ y + sx = 2as + as
2
ty + x = 2a +
2
a
t
ty = 2a +
2
a
t
ty + at
2
2t
3
y = at
4
+ 2at
2
+ a
y =
2
2
3
a t 1
2t
Given that for each a (0, 1)
0 h
lim
h 1
h
1 a a
dt ) t 1 ( t
exists. Let this limit be g(a). In addition, it is given that the function g(a) is differentiable on (0, 1).
li ni r l - a (0, 1) l) i-i
0 h
lim
h 1
h
1 a a
dt ) t 1 ( t
(i-n( - r | -ii l r i-i g(a) r ; lnl- r ii li ni r l ni (interval) (0, 1) g(a)
(i r |
55. The value of g
2
1
is
g
2
1
i -i r
(A) (B) 2 (C)
2
(D)
4
Ans. (A)
Page || 56
MATHS
Sol. g '(a) =
1 h
a a 1
h
t (1 t) dt
a
=
1 h
a 1
a a 1 a
h
t (1 t) dt t 1 t dt = 0
g(a) = constant g(a) =
g(a) =
0 h
Lt
1 h
h
1
dt
t 1 t
=
h 1
h
2
4
1
2
1
t
dt
=
1 h
1
h
1
t
2
sin
1
2
= sin
1
(2t 1)
h 1
h
= sin
1
(1 2h) sin
1
(2h 1) =
56. The value of g
2
1
is
g
2
1
i -i r
(A)
2
(B) (C)
2
(D) 0
Ans. (D)
Sol. g(a) =
h 1
h
1 a a
0 h
dt ) t 1 ( t lim
g(1 a) =
h 1
h
1 ) a 1 ( ) a 1 (
0 h
dt ) t 1 ( t lim
=
1 h
a 1 a
h 0
h
lim t (1 t) dt
=
1 h
a 1 a
h 0
h
lim (1 t) (1 (1 t)) dt
b
a
b
a
dx ) x b a ( f dx ) x ( f by
=
h 1
h
a 1 a
0 h
dt t ) t 1 ( lim
g(1 a) = g(a)
g' (1 a) = g'(a)
at a =
2
1
, g '
2
1
= g '
2
1
g'
2
1
= 0.
Page || 57
MATHS
SECTION 3 : Matching List Type (Only One Option Correct)
=r= 3 : = = = | +r (+ + |+- =;|)
This section contains four questions, each having two matching lists. Choices for the correct combination of
elements from List-I and List-II are given as options (A),(B),(C) and (D), out of which ONE is correct.
; i - 4 +r l(- r | - - - li r | li l) - l(- (A), (B), (C) nii (D)
r , l- ( + =;| r |
57. List I List II
P. The number of polynomials f(x) with non-negative integer 1. 8
coefficients of degree 2, satisfying f(0) = 0 and
1 dx ) x ( f
1
0
, is
Q. The number of points in the interval
13 , 13
at which 2. 2
f(x) = sin(x
2
) + cos(x
2
) attains its maximum value, is
R.
2
2
x
2
) e 1 (
x 3
dx equals 3. 4
S.
2 / 1
0
2 / 1
2 / 1
dx
x 1
x 1
log x 2 cos
dx
x 1
x 1
log x 2 cos
equals 4. 0
= |- I = | - II
P. ~ii-- ii nii (non-negative integer) (i +r i (polynomials), 1. 8
f(x), li iin (degree) 2 r , nii i f(0) = 0 )(- 1 dx ) x ( f
1
0
i
n - ni r , i i r
Q. ni
13 , 13
- l-in l+ i i i l 2. 2
f(x) = sin(x
2
) + cos(x
2
) i -i lin- r , r
R.
2
2
x
2
) e 1 (
x 3
dx i -i r 3. 4
S.
2 / 1
0
2 / 1
2 / 1
dx
x 1
x 1
log x 2 cos
dx
x 1
x 1
log x 2 cos
i -i r 4. 0
Page || 58
MATHS
P Q R S
(A) 3 2 4 1
(B) 2 3 4 1
(C) 3 2 1 4
(D) 2 3 1 4
Ans. (D)
Sol. (P) Let f(x) = ax
2
+ bx, a, b W (as f(0) = 0)
1
2
0
a b
ax bc
3 2
= 1 2a + 3b = 6
(a, b) (3, 0), (0, 2)
Number of such polynomials = 2
(Q) f(x) =
2
2 sin x
4
x
2
+
4
= 2n +
2
if f(x) is maximum
x
2
= 2n +
4
for n = 0, 1 x
2
[0, 13]
(R)
2 2
2
2
x x x
2 0
3x 1 1
dx 3x dx
1 e 1 e 1 e
a a
a 0
f(x)dx f(x) f(x) dx
=
2 2
x
2
2 2 3
x x
0
0 0
1 e
3x dx 3x dx x
1 e 1 e
= 8
(S)
1/ 2
1/ 2
1 x
cos2x n dx
1 x
= 0 (as it is an odd function)
Hence P 2, Q 3, R 1, S 4
(D) Ans.
Hindi. (P) -ii f(x) = ax
2
+ bx, a, b W ( l f(0) = 0)
1
2
0
a b
ax bc
3 2
= 1 2a + 3b = 6
(a, b) (3, 0), (0, 2)
; i +r i i i = 2
(Q) f(x) =
2
2 sin x
4
x
2
+
4
= 2n +
2
l f(x) lin- r |
Page || 59
MATHS
x
2
= 2n +
4
n = 0, 1 l) x
2
[0, 13]
(R)
2 2
2
2
x x x
2 0
3x 1 1
dx 3x dx
1 e 1 e 1 e
a a
a 0
f(x)dx f(x) f(x) dx
=
2 2
x
2
2 2 3
x x
0
0 0
1 e
3x dx 3x dx x
1 e 1 e
= 8
(S)
1/ 2
1/ 2
1 x
cos2x n dx
1 x
= 0 ( l r ) l(i- r )
n P 2, Q 3, R 1, S 4
58. List I List II
P. Let y(x) = cos(3 cos
1
x), x [1, 1], x
2
3
. Then 1. 1
dx
) x ( dy
x
dx
) x ( y d
1 x
) x ( y
1
2
2
2
equals
Q. Let A
1
, A
2
,......, A
n
(n > 2) be the vertices of a regular polygon of n 2. 2
sides with its centre at the origin. Let
k
a be the position vector of
the point A
k
, k = 1, 2,...., n. If
1 n
1 k
1 k k
1 n
1 k
1 k k
) a . a ( ) a a ( , then
the minimum value of n is
R. If the normal from the point P(h, 1) on the ellipse 1
3
y
6
x
2 2
is 3. 8
perpendicular to the line x + y = 8, then the value of h is
S. Number of positive solutions satisfying the equation 4. 9
2
1 1 1
x
2
tan
1 x 4
1
tan
1 x 2
1
tan
is
Page || 60
MATHS
= |- I = | - II
P. -iil y(x) = cos(3 cos
1
x), x [1, 1], x
2
3
, ni 1. 1
dx
) x ( dy
x
dx
) x ( y d
1 x
) x ( y
1
2
2
2
i -i r
Q. -iil A
1
, A
2
,......, A
n
(n > 2) ) n i i -+r i (regular polygon) 2. 2
iii (vertices) r li - l+ - r | -ii l
k
a l+
A
k
, k = 1, 2,...., n i l-iln li (position vector) r | l
1 n
1 k
1 k k
1 n
1 k
1 k k
) a . a ( ) a a (
r , n+ n i n- -i r
R. l ii ( -i (ellipse) 1
3
y
6
x
2 2
l+ P(h, 1) ii i ni 3. 8
li+ ii x + y = 8 +(n r , ni h i -i r
S. -ii
2
1 1 1
x
2
tan
1 x 4
1
tan
1 x 2
1
tan
i n - (i 4. 9
ii-- ri i i r
P Q R S
(A) 4 3 2 1
(B) 2 4 3 1
(C) 4 3 1 2
(D) 2 4 1 3
Ans. (A)
Sol. (P) y = 4x
3
3x where cos = x
dy
dx
= 12x
2
3
2
2
d y dy
x
dx
dx
= (x
2
1) . 24x + x(12x
2
3) = 36x
3
27x = 9(4x
3
3x) = 9y
Hence
2
2
2
1 d y dy
x 1 x
y dx dx
= 9
(Q)
1 2 2 3 n1 n
a a a a . . . a a =
1 2 2 3 n1 n
a . a a . a . . . a .a
Let
1 2
a a = . . . . . =
n
a = (as centre is origin)
More over angle between 2 consecutive
i
a ' s is
2
n
Page || 61
MATHS
Hence given equation reduces to
(n 1)
2
sin
2
n
= (n 1)
2
cos
2
n
tan
2
n
= 1
2
n 4
n = 8
(R) Equation of normal
6x 3y
h 1
= 3
2 2
2 2
1 1
a x b y
Equation of normal is a b
x y
slope =
6
3h
= 1 (as it is perpendicular to z + y = 1) h = 2
(S) tan
1
1
2x 1
+ tan
1
1
4x 1
+ tan
1
2
2
x
2
1 1
2
2x 1 4x 1
1
x
1
2x 1 4x 1
2 2
6x 2 2
8x 6x x
3x
3
+ x
2
= 8x
2
+ 6x 3x
3
7x
2
6x = 0
3x
2
7x + 6 = 0 (as x 0)
(x 3) (3x + 2) = 0 x =
2
3
, 3
rejected is
3
2
Hindi. (P) y = 4x
3
3x ri cos = x
dy
dx
= 12x
2
3
2
2
d y dy
x
dx
dx
= (x
2
1) . 24x + x(12x
2
3)
= 36x
3
27x = 9(4x
3
3x) = 9y
n
2
2
2
1 d y dy
x 1 x
y dx dx
= 9
(Q)
1 2 2 3 n1 n
a a a a . . . a a
=
1 2 2 3 n1 n
a . a a . a . . . a .a
-ii
1 2
a a = . . . . . =
n
a = ( l , - l+ r)
i -inn
i
a ' s - i i
2
n
r
n l) n) -ii ri ni r
Page || 62
MATHS
(n 1)
2
sin
2
n
= (n 1)
2
cos
2
n
tan
2
n
= 1
2
n 4
n = 8
(R) li+ i -ii
6x 3y
h 1
= 3
2 2
2 2
1 1
a x b y
Equation of normal is a b
x y
(ini =
6
3h
= 1 ( l r z + y = 1 +(n r ) h = 2
(S) tan
1
1
2x 1
+ tan
1
1
4x 1
+ tan
1
2
2
x
2
1 1
2
2x 1 4x 1
1
x
1
2x 1 4x 1
2 2
6x 2 2
8x 6x x
3x
3
+ x
2
= 8x
2
+ 6x 3x
3
7x
2
6x = 0
3x
2
7x + 6 = 0 ( l x 0)
(x 3) (3x + 2) = 0 x =
2
3
, 3
rejected is
3
2
59. Let f
1
: R R, f
2
: [0, ) R,f
3
: R R and f
4
: R [0, ) be defined by
f
1
(x) =
; 0 x if e
, 0 x if | x |
x
f
2
(x) = x
2
;
f
3
(x) =
sinx if x 0,
x if x 0
and
f
4
(x) =
0 x if 1 )) x ( f ( f
, 0 x if )) x ( f ( f
1 2
1 2
List I List II
P. f
4
is 1. onto but not one-one
Q. f
3
is 2. neither continuous nor one-one
R. f
2
o f
1
is 3. differentiable but not one-one
S. f
2
is 4. continuous and one-one
Page || 63
MATHS
-iil f
1
: R R, f
2
: [0, ) R,f
3
: R R i f
4
: R [0, ) li i
f
1
(x) =
x
| x | x 0,
e x 0;
l
l
f
2
(x) = x
2
;
f
3
(x) =
sinx x 0,
x x 0
l
l
nii
f
4
(x) =
2 1
2 1
f (f (x)) x 0,
f (f (x)) 1 x 0
l
l
liilin r |
= |- I = | - II
P. f
4
1. isi (onto) r n ) i (one-one) ri r |
Q. f
3
2. nn (continuous) r ri ) i r |
R. f
2
o f
1
3. (i (differentiable) r n ) i ri r |
S. f
2
4. nn (continuous) i ) i r |
P Q R S
(A) 3 1 4 2
(B) 1 3 4 2
(C) 3 1 2 4
(D) 1 3 2 4
Ans. (D)
Sol. f
2
(f
1
(x)) = (f
1
(x))
2

0 x e
0 x x
x 2
2
f
4
(x)
0 x 1 e
0 x x
x 2
2
f (x)
1
x
f (x)
2
x
f (x)
3
x
x
2
e
2x 1
f (x)
4
Page || 64
MATHS
f
4
(x) is many-one onto, continuous and non-derivable
f
3
(x) is many-one, into, continuous and derivable
f
2
(x) is one-one, into, differentiable
f
4
(x) +r ) i isi, nn i (i ri
f
3
(x) +r) i, ni i, nn, (i
f
2
(x) ) i, n i i, (i
Hence n R 2
so n (D)
p 1, q 3, R 2, S 4
60. Let z
k
= cos 9 ,... 2 , 1 k ;
10
k 2
sin i
10
k 2
.
List I List II
P. For each z
k
there exists a z
j
such that z
k
. z
j
= 1 1. True
Q. There exists a k {1,2,....,9} such that z
1.
. z = z
k
has 2. False
no solution z in the set of complex numbers.
R.
10
| z 1 | ..... | z 1 || z 1 |
9 2 1
equals 3. 1
S. 1
9
1 k
10
k 2
cos
equals 4. 2
-iil z
k
= cos
9 ,... 2 , 1 k ;
10
k 2
sin i
10
k 2
.
= |-I = |-II
P. - z
k
l) ) ) i z
j
r l l z
k
. z
j
= 1 1. -
Q. {1,2,....,9} - ) ) i k r l z
1.
. z = z
k
i i ; r 2. -
z l- ii (complex numbers) - ri r
R.
10
| z 1 | ..... | z 1 || z 1 |
9 2 1
i -i r 3. 1
S. 1
9
1 k
10
k 2
cos
i -i r 4. 2
Page || 65
MATHS
P Q R S
(A) 1 2 4 3
(B) 2 1 3 4
(C) 1 2 3 4
(D) 2 1 4 3
Ans. (C)
Sol. (P) z
k
z
j
= 1 z
j
= z
10 k
Hence for each k {1, 2, 3, . . . . , 9} there exists z
j
such that z
k
. z
j
= 1 True
(Q) z
1
. z = z
k
z = z
k1
for k = 2, 3, 4, . . . , 9 &
z = 1 for k = 1 False
(R) z
1
, z
2
, . . . . , z
9
are roots of the equation z
10
= 1 other then unity, hence
10
z 1
z 1
= 1 + z + . . . + z
9
= (z z
1
)(z z
2
) . . . . (z z
9
)
Substituting z = 1, we get
1 2 9
1 z 1 z . . . . 1 z
10
10 10
= 1
(S) 1
9
k 1
2k
cos
10
= 1 {sum of real parts of roots of z
10
= 1 except 1}
= 1 (1) = 2
(as 1 + z
1
+ z
2
+ . . . . + z
9
= 0)
k
Re z 1 = 0
Hindi. (P) z
k
z
j
= 1 z
j
= z
10 k
n - k l) {1, 2, 3, . . . . , 9} ; i l(n-i z
j
; i r l z
k
. z
j
= 1 -
(Q) z
1
. z = z
k
z = z
k1
k = 2, 3, 4, . . . , 9 & l) nii
z = 1, k = 1 l) nn
(R) z
1
, z
2
, . . . . , z
9
-ii z
10
= 1 - r n
10
z 1
z 1
= 1 + z + . . . + z
9
= (z z
1
)(z z
2
) . . . . (z z
9
)
z = 1 ln-ii
1 2 9
1 z 1 z . . . . 1 z
10
10 10
= 1
(S) 1
9
k 1
2k
cos
10
= 1 {1 i si z
10
= 1 - i (i-nl( iini i i n}
= 1 (1) = 2
( l 1 + z
1
+ z
2
+ . . . . + z
9
= 0)
k
Re z 1 0
Page || 66
Appropriate way of darkening the bubble for your answer to be evaluated :
Figure-1 : Correct way of bubbling for valid answer and a few examples of invalid answer.
Any other form of partial marking such as ticking or crossing the bubble will be considered invalid.
Figure-2 : Correct way of Bubbling your Roll Number on the ORS. (Example Roll Number : 5045231)
|>r r.r.=. -2 : ORS ( : 5045231) ( .) i i + ++ i i i ri nii iri i +
a
a
a a
a
a
The one and the only one acceptable
Part darkening
Darkening the rim
Cancelling after darkening and
darkening another bubble
Attempt to Erase after darkening
Answer will not
be evaluated
no marks, no
negative marks
Name of the Candidate
iiiii i i-
Roll Number
i +
I have read all instructions and shall abide
by them.
- ii l ii i li r i - i
( i ni,ni|
I have verified all the information filled by
the candidate.
iiiii ,ii ii n; ii iii i
- i li r|
Signature of the Candidate
iiiii r-nii
Signature of the Invigilator
ii r-nii
r+ =-r + =-r + + | +r +rr + +r = n n|+r :
) i ( ) -(ii
i li ii i
l- ii i
ii +i i|
ii +i l--ii
-i i - -i
ri ri ni
i ; ri , i;
~ii-- ri
li-1 : o =-r + | r -r +r =;| n|+r r o =-rr + + e =r;r|
r|r+ + + - n|+ = +r |c+ +r r +r= +r nn ;rnr|

JEE Advanced 2014 Solution Paper 2

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