SPRING 2013, CHM 1120, SECTION 004, EXAM I, PAGE 1 of 6

CHM 1120 EXAM I SECTION 004 02/13/13

Name:__________________________________________ Score:_______/ 100
(please write your NAME above AND on the last page of this exam!!!)

Be sure to show all of your work clearly (partial credit) and circle your final answers.
Dont forget to label your answers with the correct units when appropriate.

Use the following information to answer questions 1-5.







1) What is the molality of the solution shown above? (3 pts.)






2) What is the osmolarity of the solution shown above? (3 pts.)






3) Compared to a 2.55 M CaCl
2
aq. solution, the aq. solution above will have a freezing point that is: (3 pts.)

a) lower than that of the CaCl
2
aq. solution
b) higher than that of the CaCl
2
aq. solution
c) that same as that of the CaCl
2
aq. solution
d) not enough information provided to answer

4) Compared to a 2.55 M CaCl
2
aq. solution, the aq. solution above will have a boiling point that is: (3 pts.)

a) lower than that of the CaCl
2
aq. solution
b) higher than that of the CaCl
2
aq. solution
c) that same as that of the CaCl
2
aq. solution
d) not enough information provided to answer

5) If a human red blood cell (~ 0.3 osmol) was placed in the NaCl aq. solution above: (3 pts.)

a) cell lysis would occur
b) we would consider the NaCl aq. solution to be hypotonic
c) we would consider the NaCl aq. solution to be isotonic
d) cell crenation would occur
e) none of the above
2.0 L of 2.55 M NaCl aqueous solution

density of solution = 1.08 g/mL
SPRING 2013, CHM 1120, SECTION 004, EXAM I, PAGE 2 of 6
Use the following four molecules to answer questions 6-8.



6) What is the strongest intermolecular force that exists between molecules C and D? (3 pts.)



7) What is the strongest intermolecular force that exists between molecules B and C? (3 pts.)



8) What is the strongest intermolecular force that exists between molecules A and B? (3 pts.)




Use the following information to answer questions 9-10.

NO(g) + O
3
(g) NO
2
(g) + O
2
(g)

frequency factor (A) = 8.7 x 10
12
s
-1

activation energy (E
a
) = 63 kJ/mol

9) At what temperature (in
o
C) would the rate constant (k) be 3.0 x 10
3
s
-1
? (6 pts.)










10) What is the rate constant (k) when the reaction is run at 100
o
C? (6 pts.)










SPRING 2013, CHM 1120, SECTION 004, EXAM I, PAGE 3 of 6
Use the following information to answer questions 11-17.

A + 2 B 3 C + D

Experiment [A] M [B] M Initial Rate (M/s) Time (s) [A] M
1 0.12 0.010 2.2 x 10
-3
0 0.120
2 0.36 0.010 1.98 x 10
-2
15 0.094
3 0.12 0.020 2.2 x 10
-3
30 0.077

11) Write the rate expressions with respect to all four species involved in the reaction shown above. (8 pts.)





12) What is the rate of the reaction shown above over the second 15 seconds? (6 pts.)






13) Write the rate law for the reaction shown above. (4 pts.)




14) What is the overall reaction order for the reaction shown above? (3 pts.)



15) What is the value of the rate constant (k) for the reaction shown above? (6 pts.)






16) How long will it take for the concentration of A to be reduced to 0.06 M? (6 pts.)






17) How long will it take for the concentration of A to be reduced to 0.03 M? (6 pts.)







SPRING 2013, CHM 1120, SECTION 004, EXAM I, PAGE 4 of 6
Use the following information to answer questions 18-21.

H
2
(g) + I
2
(g) 2 HI(g)

Concentrations after 10 seconds: [H
2
] = 0.1 [I
2
] = 0.1 [HI] = 0.4 K
c
= 54.3 at 430
o
C

18) Write the equilibrium expression for the reaction shown above. (4 pts.)





19) What is the value of the reaction quotient (Q
c
) after the reaction above has proceeded 10 seconds? (6 pts.)





20) Based on your calculated value of Q
c
, which direction will the reversible reaction proceed? (3 pts.)



21) What are the equilibrium concentrations of all three species involved in the reaction above? (12 pts.)


























[H
2
]
eq
= _______________ [I
2
]
eq
= _______________ [HI]
eq
= _______________


SPRING 2013, CHM 1120, SECTION 004, EXAM I, PAGE 5 of 6
SCRATCH PAPER
SPRING 2013, CHM 1120, SECTION 004, EXAM I, PAGE 6 of 6



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