Exam 2A - Chem1211 Spring 2012 (CHAPTERS 4 AND 5)

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
1) According to the following balanced reaction, how many moles of NO are formed from 8.44
moles of NO
2
if there is plenty of water present?

3 NO
2
(g) + H
2
O(l) 2 HNO
3
(aq) + NO(g)

1) _______
A) 1.83 moles NO
B) 5.63 moles NO
C) 25.3 moles NO
D) 2.81 moles NO
E) 8.44 moles NO

2) Convert 1.25 atm to mm Hg. 2) _______
A) 1000 mm Hg
B) 875 mm Hg
C) 760 mm Hg
D) 1520 mm Hg
E) 950 mm Hg

3) Which of the following is NOT part of the kinetic theory of gases? 3) _______
A) Gas particles move faster when the temperature increases.
B) A gas is composed of very small particles.
C) There is very little empty space in a gas.
D) Gas particles do not attract or repel one another.
E) Gas particles move rapidly.

4) A tank contains helium gas at 490 mmHg, nitrogen gas at 0.75 atm, and neon at 520 torr. What is
the total pressure in atm?
4) _______
A) 1.5 atm
B) 0.55 atm
C) 1600 atm
D) 2.1 atm
E)
1.0 x atm

5) What volume will a balloon occupy at 1.0 atm, if the balloon has a volume of 7.6 L at 3.8 atm? 5) _______
A) 5.0 L B) 35 L C) 29 L D) 2.0 L E) 17 L

6) To what temperature must a balloon, initially at 25C and 2.00 L, be heated in order to have a
volume of 6.00 L?
6) _______
A) 75 K B) 655 K C) 403 K D) 894 K E) 993 K

7) What pressure will 14.0 g of CO exert in a 3.5 L container at 75C? 7) _______
A) 1.1 atm B) 4.1 atm C) 6.4 atm D) 2.3 atm E) 5.0 atm

8) Which of the following samples will have the greatest volume at STP? 8) _______
A) 22 g Cl
2
B) 22 g O
2
C) 22 g He
D) 22 g CO
E) All of these samples would have the same volume at STP.

9) In a container containing CO, H
2
, and O
2
, what is the mole fraction of CO if the H
2
mole fraction
is 0.22 and the O
2
mole fraction is 0.58?
9) _______
A) 0.20 B) 0.50 C) 0.10 D) 0.30

10) Give the definition for diffusion. 10) ______
A) gas molecules mix unequally
B) average distance between collisions
C) gas molecules spread out in a concentration gradient
D) gas molecules mix equally
E) gas molecules escape from a container into a vacuum through a small hole

11) How many grams of oxygen are formed when 6.21 moles of KOH are formed?

4 KO(s) + 2 H
2
O(l) 4 KOH(s) + O
2
(g)

11) ______
A) 19.9 g O
2
B) 27.9 g O
2
C) 11.7 g O
2
D) 3.59 g O
2
E) 49.7 g O
2

12) Determine the theoretical yield of H
2
S (in moles) if 4.0 mol Al
2
S
3
and 4.0 mol H
2
O are reacted
according to the following balanced reaction. A possibly useful molar mass is Al
2
S
3
= 150.17
g/mol.

Al
2
S
3
(s) + 6 H
2
O(l) 2 Al(OH)
3
(s) + 3 H
2
S(g)

12) ______
A) 2.0 mol H
2
S
B) 12 mol H
2
S
C) 18 mol H
2
S
D) 4.0 mol H
2
S
E) 6.0 mol H
2
S

13) Give the percent yield when 28.16 g of CO
2
are formed from the reaction of 4.000 moles of C
8
H
18

with 8.000 moles of O
2
.

2 C
8
H
18
+ 25 O
2
16 CO
2
+ 18 H
2
O

13) ______
A) 25.00% B) 20.00% C) 50.00% D) 12.50%

14) How many milliliters of a 0.184 M NaNO
3
solution contain 0.113 moles of NaNO
3
? 14) ______
A) 543 mL B) 163 mL C) 326 mL D) 885 mL E) 614 mL

15) Determine the molarity of a solution formed by dissolving 97.7 g LiBr in enough water to yield
750.0 mL of solution.
15) ______
A) 1.50 M B) 0.768 M C) 1.18 M D) 0.130 M E) 2.30 M

16) How many molecules of sucrose (C
12
H
22
O
11
, molar mass = 342.30 g/mol) are contained in 14.3
mL of 0.140 M sucrose solution?
16) ______
A)
5.90

10
24
molecules C
12
H
22
O
11
B)
1.21 10
21
molecules C
12
H
22
O
11
C)
8.29 10
22
molecules C
12
H
22
O
11
D)
1.63 10
23
molecules C
12
H
22
O
11
E)
6.15 10
22
molecules C
12
H
22
O
11

17) Which of the following is considered a STRONG electrolyte? 17) ______
A) C
12
H
22
O
11
B) CH
3
OH
C) PbCl
2
D) HC
2
H
3
O
2
E) NH
4
NO
3

18) Which of the following is a precipitation reaction? 18) ______
A) 2 LiI(aq) + Hg
2
(NO
3
)
2
(aq) Hg
2
I
2
(s) + 2 LiNO
3
(aq)
B) Zn(s) + 2 AgNO
3
(aq) 2 Ag(s) + Zn(NO
3
)
2
(aq)
C) HCl(aq) + KOH(aq) KCl(aq) + H
2
O(l)
D) NaCl(aq) + LiI(aq) NaI(aq) + LiCl(aq)
E) None of the above are precipitation reactions.

19) Give the net ionic equation for the reaction (if any) that occurs when aqueous solutions of K
2
S
and Fe(NO
3
)
2
are mixed.
19) ______
A)
K
+
(aq) + NO
3
-
(aq) KNO
3
(s)
B)
Fe
2+
(aq) + S
2-
(aq) + 2 K
+
(aq) + 2 NO
3
-
(aq) Fe
2+
(aq) + S
2-
(aq) + 2 KNO
3
(s)
C)
Fe
2+
(aq) + S
2-
(aq) FeS(s)
D)
Fe
2+
(aq) + S
2-
(aq) + 2 K
+
(aq) + 2 NO
3
-
(aq) FeS(s) + 2 K
+
(aq) + 2 NO
3
-
(aq)
E) No reaction occurs.

20) Determine the oxidation state of Sn in Sn(SO
4
)
2
. 20) ______
A) +2 B) -2 C) +4 D) +6 E) 0

21) Determine the reducing agent in the following reaction.

2 Li(s) + Fe(C
2
H
3
O
2
)
2
(aq) 2 LiC
2
H
3
O
2
(aq) + Fe(s)

21) ______
A) C B) Li C) Fe D) H E) O

22) How many milliliters of a 0.266 M LiNO
3
solution are required to make 150.0 mL of 0.075 M
LiNO
3
solution?
22) ______
A) 42.3 mL B) 35.1 mL C) 18.8 mL D) 23.6 mL E) 53.2 mL

23) Which of the following gas samples would be most likely to behave ideally under the stated
conditions?
23) ______
A) CO at 200 atm and 25C
B) SO
2
at 2 atm and 0 K
C) Ne at STP
D) O
2
at 400 atm and 25C
E) N
2
at 1 atm and -70C

24) Which of the following statements is TRUE? 24) ______
A) The smaller a gas particle, the slower it will effuse
B) The higher the temperature, the lower the average kinetic energy of the sample.
C) At a given temperature, lighter gas particles travel more slowly than heavier gas particles.
D) At low temperatures, intermolecular forces become important and the pressure of a gas will
be lower than predicted by the ideal gas law.
E) None of the above statements are true.

25) Which of the following is an acid base reaction? 25) ______
A) C(s) + O
2
(g) CO
2
(g)
B) 2 HClO
4
(aq) + Ca(OH)
2
(aq) 2 H
2
O(l) + Ca(ClO
4
)
2
(aq)
C) MgSO
4
(aq) + Ba(NO
3
)
2
(aq) Mg(NO
3
)
2
(aq) + BaSO
4
(s)
D) Fe(s) + 2 AgNO
3
(aq) 2 Ag(s) + Fe(NO
3
)
2
(aq)
E) None of the above are acid base reactions.

1) D
2) E
3) C
4) D
5) C
6) D
7) B
8) C
9) A
10) C
11) E
12) A
13) D
14) E
15) A
16) B
17) E
18) A
19) C
20) C
21) B
22) A
23) C
24) D
25) B