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+ RT ln{i}
!G
F, i
=
lree energy change of Lhe formauon of specles !, k!/mol, aL
sLandard condluons
8 = unlversal gas law consLanL, 8.314 x 10
-3
k!/mol k
1 = absoluLe LemperaLure, k
[l} = acuvlLy of specles l
Iree Lnergy of Iormanon
A+
b
a
B !
c
a
C +
d
a
D
Lxerclse: calculaLe Lhe free energy change of reacuon for Lhe followlng reacuon
Iree Lnergy of keacnon
Iree Lnergy at Lqu|||br|um
1emperature Dependence of Iree Lnergy Change
1emperature Dependence of Iree Lnergy Change
Lxerc|se 1
CalculaLe Lhe pP of neuLrallLy and free-energy change of
Lhe reacuon aL 10 degree Celslus assumlng LhaL Lhe
enLhalpy of reacuon does noL change wlLh LemperaLure
Lxerc|se 2
Can M18L be degraded anaerob|ca||y (|.e., |n
groundwater) |n the presence of n|trate?
Lnergy Lqulvalences
SLandard unlLs for expresslng Lhls energy lnpuL are:
LlecLron volLs,
Cell poLenual,
WavelengLh of llghL
8and gap
Lnergy = ev = L ! number of electrons transfer
-19
-19
1.60!10 coulomb Joule
1eV=1electron! !1Volt !
electron coulombvolt
=1.60!10 Joules
Energy
where
wavelength
h
c
!
"
!
=
=
-34
10
-19
6.26!10 Jsec
3.0 10 cm/sec
Energy 1.60!10 J
1172
c h
c
nm
!
"
= = # = # #
=
WhaL ls Lhe equlvalenL
wavelengLh for Lhls energy?