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2.0 WATER POLLUTION

2.1 The types of water pollution:
a. point sources:
discharge pollutants at specific locations through pipes, ditches, or
sewers into bodies of surface water
Easily identified, monitored, & regulated

b. non-point sources:
Nonpoint sourcessources that cannot be traced to a single site of discharge
Large areas of land that pollute water by runoff or atmospheric deposition
Agricultural runoff includes sediments, inorganic fertilizers, manure, salts from
irrigation waters, & pesticides.
Responsible for an estimated 64% of all water pollution in US


2.2 The sources of water pollution and its effects on aquatic life:

2.2.1 Infectious agents:
o Examples include bacteria, viruses, protozoa, & parasitic worms
o Major human sourceshuman & animal wastes
o Effectsdiseases (Typhoid fever, Cholera, Dysentary, Giardiasis, Hepatitis)
o Good indicator of water quality in terms of infectious agents is the number of
colonies of coliform bacteria present in a 100-mL sample of water
WHO & EPA recommend 0 colonies/100-mL for drinking water & maximum level of
200 colonies for swimming

2.2.2 Oxygen-demanding wastes:
o Examples include decomposition of animal & plant matter by aerobic bacteria
o Major human sourcessewage, animal feed lots, paper mills
o Effectsdepletion of dissolved oxygen leading to death of aquatic organisms
o Biological Oxygen Demand (BOD)amount of dissolved oxygen needed by
aerobic decomposers to break down the organic matter in a certain volume
of water in a 5-day incubation period at 20
o
C.

2.2.3 Inorganic chemicals:
o Examples include acids, toxic metals (Pb, As, Se), & salts (NaCl, Fl-)
o Major human sourcessurface runoff, industrial effluents, household
cleansers
o Effectsdamage human systems (cancers), harm aquatic life, lower crop
yields, accelerate corrosion, make water non-potable
o Chemical water analysis is used to determine presence of inorganics in water

2.2.4 Organic chemicals:
o Examplesgasoline, oil, plastics, pesticides, detergents
o Major human sourcesindustrial effluents, household cleansers, surface
runoff from farms & yards
o Effectsthreaten human health & harm wildlife
o Chemical water analysis & use of indicator species used to determine
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presence & concentration
Filter-feeding mollusks.

2.2.5 Sediment:
o Examplessoil & silt
o Major human sourcesland erosion
o Harmful effectsreduce photosynthesis, disrupt aquatic food webs, destroy
spawning grounds of benthic species, clog harbors & lakes
2.2.2 Explain the causes of soil erosion.
2.2.3 Describe the effects of soil erosion on environment.
2.2.4 Identify the ways to control soil erosion.

2.2.6 Heat (Thermal pollution)
o Examples include excessive heat
o Major sourceswater cooling of electric power plants
o Lowers DO levels & causes thermal shock in species


2.3 Pollution of Streams & Lakes
2.3.1 The process of self-purification in river.
Streams & rivers have potential to rapidly recover from degradable wastes & excess
heat
o Depends on volume, flow rate, temperature, & pH
o Developing nations deploy about 95% of all sewage directly into rivers & streams

2.3.2 Dilution limits using mass balance equation.

2.3.3 Explain dissolved oxygen profile in river (graph of dissolved
oxygen against time).



2.4 The phenomena of eutrophication.

2.4.1 The eutrophication process occurred in a lake and its effects.
Lakes are more vulnerable to pollution
o Often stratified with little vertical mixing
o Have little flow

Eutrophicationnatural nutrient enrichment of lakes leading to excessive algal growth
o Human activities accelerate eutrophication (sewage treatment plants, runoff of
fertilizers, & accelerated erosion of topsoil)cultural eutrophication
o Accumulation of nitrates can lead to nitrate poisoning as nitrates bind to hemoglobin
reducing the capacity for oxygen transport (amphibians)

o Leads to a potential algal bloom
Decreases light penetration
Decreases DO levels due to the action of decomposers
Disrupts nitrogen & phosphorus cycles


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2.4.2 Explain the causes of eutrophication.
Soil retention
o Nutrients from human activities tend to accumulate in soils and remain
there for years. It has been shown that the amount of phosphorus lost to
surface waters increases linearly with the amount of phosphorus in the
soil. Thus much of the nutrient loading in soil eventually makes its way to
water. Nitrogen, similarly, has a turnover time of decades or more.
o
Runoff to surface water and leaching to groundwater
o Nutrients from human activities tend to travel from land to either surface
or ground water. Nitrogen in particular is removed through storm drains,
sewage pipes, and other forms of surface runoff. Nutrient losses in runoff
and leachate are often associated with agriculture. Modern agriculture
often involves the application of nutrients onto fields in order to maximise
production. However, farmers frequently apply more nutrients than are
taken up by crops or pastures. Regulations aimed at minimising nutrient
exports from agriculture are typically far less stringent than those placed
on sewage treatment plants and other point source polluters. It should be
also noted that lakes within forested land are also under surface runoff
influences. Runoff can wash out the mineral nitrogen and phosphorus
from detritus and in consequence supply the water bodies leading to
slow, natural eutrophication.
o
Atmospheric deposition
o Nitrogen is released into the air because of ammonia volatilization and
nitrous oxide production. The combustion of fossil fuels is a large human-
initiated contributor to atmospheric nitrogen pollution. Atmospheric
deposition (e.g., in the form of acid rain) can also affect nutrient
concentration in water especially in highly industrialized regions.
o
Other causes
o Any factor that causes increased nutrient concentrations can potentially
lead to eutrophication. In modeling eutrophication, the rate of water
renewal plays a critical role; stagnant water is allowed to collect more
nutrients than bodies with replenished water supplies. It has also been
shown that the drying of wetlands causes an increase in nutrient
concentration and subsequent eutrophication blooms.

2.4.3 Identify the methods of eutrophication control.
Planting vegetation along streambeds to slow erosion
Controlling application & timing of fertilizer
Controlling runoff from feedlots, golf courses, & fields
Use of biological control agents such as denitrification





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2.5 Pollution of Groundwater

2.5.1 The sources ground water pollution:
a. industrial waste
b. domestic waste
c. municipal landfill
d. petroleum waste and mining
e. agriculture
f. saltwater intrusion.

Groundwater supplies 75% of drinking water in Europe & 51% in US

Pollution sources include storage lagoons, septic tanks, landfills, hazardous waste
dumps, deep injection wells, and underground storage tanks filled with gasoline, oil, &
solvents.

EPA estimates that 4.5 trillion liters of contaminated water seep into US groundwater
each day.

Easily polluted because water in aquifers is renewed very slowly (recycling time is 1400
years compared to 16 days for rivers)
o Degradable wastes do not break down due to slow flow of water, cold temperatures, &
smaller populations of bacteria

Excessive pumping of groundwater leads to saltwater intrusion of an aquifer

Impossible to clean contamination so prevention is the only effective way to protect
groundwater resources
o Require leak detection devices for underground tanks
o Banning disposal of hazardous wastes in deep injection wells & landfills
o Storing hazardous wastes above ground


2.6 Sea / Ocean Pollution
2.6.1 The sources of sea pollution:
a. domestic and industrial waste
b. sludge disposal
c. oil spillage

Coastal areas (wetlands, estuaries, coral reefs, etc.)
o 40% of worlds population lives within 160 miles of the coast
o 14 of the 15 largest metropolitan cities are coastal

Dumping of untreated sewage directly into the ocean along SE Asia

Algal blooms (Red tides)
o Release toxins that kill marine life
o Poison seafood

Effects of oil on ocean ecosystems
o Operation of offshore wells, washing tankers, pipeline & storage tank leaks
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50% of oil pollution comes from oil dumped on land making its way to sewers
o VOCs in oil kill aquatic organisms immediately (especially larvae)
o Accumulation of tars on feathers & fur of marine birds & mammalsreduce natural
insulation
o Cleaning up oil spills

Floating booms to contain coil spill

Absorbent pads to soak up oil on beaches

Coagulating agents that cause oil to clump for easier pickup

Dispersing agents to break up oil slicks

Biological cleanupoil degrading microbes