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FLUOR
Solkane 134a
Thermodynamics
SOLVAY FLUOR
Technical Service - Refrigerants PRODUCT BULLETIN NO.: T/09.04/01/E
Phone
Fax
E-Mail
Internet:
+49/511/857-2653
+49/511/857-2166
refrigerants@solvay.com
www.solvay-fluor.com
SOLVAY FLUOR
Solkane134a Thermodynamics
Release 1.05
CONTENTS
1 UNITS AND SYMBOLS.................................................................................................. 2
2
INTRODUCTION....................................................................................................... 3
2.1 DEFINITION OF ISOMERS ............................................................................................ 4
REFRIGERANT OILS................................................................................................ 18
FLAMMABILITY ..................................................................................................... 19
TOXICITY ............................................................................................................... 19
SFD-AK T/09.04/01/E
Solkane134a Thermodynamics
Release 1.05
Unit
A, B
C
D
[-]
[-]
[kJ/(kg K)]
E, F, G
H
J
L
K
M
R
b
c
e
h
k
p
r
s
t
T
v
Meaning/Definition
Indices
c
R
i
u
p
v
0
SFD-AK T/09.04/01/E
liquid
vapour
critical value
reduced value
run index
ambient conditions
isobar
isochor
ideal gas
SOLVAY FLUOR
Solkane134a Thermodynamics
Release 1.05
Introduction
1
2
SFD-AK T/09.04/01/E
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
R 134
R 134a
The difference in the position of the fluorine and hydrogen atoms on the two carbon
atom centres can be seen in the structural formulae above.
SFD-AK T/09.04/01/E
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
Thermophysical Values
[-]
1,1,1,2-tetrafluoroethane
Chemical formula
[-]
CH2FCF3
Chemical structure
[-]
CAS No.
[-]
F
H
FCCF
F
H
811-97-2
Molecular weight
[kg/kmol]
102.0
Boiling point1
[C]
-26.06
Freezing point1
[C]
-101
Critical temperature
[C]
101.1
Critical pressure
[bar]
40.59
[kg/m3]
1206
[kg/m3]
32.35
Vapour pressure1,2
[bar]
6.654
Enthalpy of vaporization2
[kJ/kg]
177.5
[W/m K]
83.51E-3
[W/m K]
13.97E-3
[N/m]
[kJ/(kgK)]
1.425
[kJ/(kgK)]
1.011
Liquid viscosity2
[Pa s]
0.1974E-3
[Pa s]
0.01193E-3
[Vol.-%]
8.02E-3
none3
at 1.013 bar
at 25oC
3 according to DIN 51649 and UL 2128
2
SFD-AK T/09.04/01/E
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
ln p R = A1 (1 TR ) + A2 (1 TR ) 1 + A3 (1 TR ) 2 + A4 (1 TR ) 3 + A5 (1 TR ) B4 + A6 TR
where TR =
(1)
p
T
and p R =
pc
Tc
was chosen to describe the vapour pressure. The constants and values for the critical
pressure pc and the critical pressure Tc are as follows:
A1
A2
A3
A4
A5
A6
[-]
[-]
[-]
[-]
[-]
[-]
B1
B2
B3
B4
Tc
pc
-7.7069E+00
2.4932E+00
-2.9212E+00
-3.8684E+00
4.6898E-01
-8.3360E-05
[-]
[-]
[-]
[-]
[K]
[bar]
1.5158
1.9907
4.3798
1.7461
374.21
40.59
R = 1 + C1 (1 TR ) 3 + C2 (1 TR ) 3 + C3 (1 TR ) + C4 (1 TR )
1
where R =
(2)
The constants and the value for the critical density are:
C1
C2
C3
[-]
[-]
[-]
1.732277
1.348322
-1.251446
C4
c
[-]
[kg/m3]
1.056144
511.90
The specific heat capacity under ideal gas conditions is represented by the equation
c p 0 = D1 + D2T + D3T 2 + D4T 3 + D5 T
(3)
[kJ/(kg K)]
[kJ/(kg K2)]
[kJ/kg]
SFD-AK T/09.04/01/E
2.49202E-01 D3
2.45251E-03 D4
-6.96764E+00
[kJ/(kg K3)]
[kJ/kg]
-1.65650E-06
8.91048E-10
SOLVAY FLUOR
Solkane134a Thermodynamics
Release 1.05
p=
(4)
where z = v b
and is a good representation of the pvT relationship for Solkane 134a. The
coefficients of the equation are:
E1
[-]
-1.40114E-03
F2 [-] -2.78860E-09
E2
[-]
2.19433E-06
F4 [-] 1.02574E-14
E3
[-]
-6.73580E-10
G1 [-] -2.69555E-02
E4
[-]
-4.66800E-12
G2 [-] 2.67772E-05
F1
[-]
1.63714E-06
G4 [-] 1.69513E-10
3
b
[m /kg]
2.99628E-04
K
[-] 5.475
3
R
[bar m /(kg K)] 8.14892E-04
The equation for specific heat capacity under ideal gas conditions (3) and the thermal
equation of state (4) form the basis of the specific enthalpy and entropy calculation.
Applying generally valid thermodynamic relationships the equation is transformed to
T2
T3
E
E
E
E
+ D3
+ D4 ln T + 1 + 22 + 33 + 44
z 2z
2
3
3z
4z
G
G
G
(1 + k TR ) 1 + 22 + 44
z 2z
4z
h = h0 + ( pv - RT ) + D1T + D2
+e-k TR
(5)
and
T 2 D4
zp1
s = s0 + R ln
+ D1 ln T + D2 T + D3
RT
T
2
G
G
F
F k
F
G
- 1 + 22 + 44 + e-k TR 1 + 22 + 44
z 2z
z 2z
4 z Tc
4z
(6)
(7)
dp
T (v ''-v ')
dT
SFD-AK T/09.04/01/E
(8)
SOLVAY FLUOR
Solkane134a Thermodynamics
Release 1.05
295.57 kJ/kg
-0.2037 kJ/(kg K)
If neither the kinetic nor the potential energies are taken into account, the specific
exergy may be found by the following equation:
e = h hu Tu ( s su )
(9)
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Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
(10)
H0 =
H1 =
-1.29909
-0.0129286
H2 =
H3 =
[Pa s]
[Pa s/K]
4.9223 x10-6
-1.9860 x10-7
[Pa s/K2]
[Pa s/K3]
0,3
0,2
0,1
0
-50
-40
-30
-20
-10
10
20
30
40
50
60
Temperature t in C
Figure 1:
SFD-AK T/09.04/01/E
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
= 0 +
(11)
with
1
0 = 2.6696 10
2
(MT )2
T
2
T* =
kT
and
2.2
R
zc =
pcVc
RTc
[ln(1.65 + )]
0.8
R0
and
1.6
R0 =
1 0.78 r 0
e Tc 1( F z c ) 1
0
and F = 1 for R134a as a light polar agent.
c
(12 d-f)
= 8314
= 515.30
[J kmol-1 K-1]
[kg/m3]
[kg/m3]
= 374.205
[K]
=
=
/k =
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10
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
10-6
Pa s
16
14
12
10
8
6
4
2
0
-50
-40
-30
-20
-10
10
20
30
40
50
60
Temperature t in C
Figure 2:
SFD-AK T/09.04/01/E
11
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
= J 0 + J 1t
(13)
J0 =
[10-3W/(m K)]
94.21
J1 =
100
80
60
40
20
0
-50
-40
-30
-20
-10
10
20
30
40
50
60
Temperature t in C
Figure 3:
SFD-AK T/09.04/01/E
12
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
= L0 + L1t + L2 t 2
(14)
where t is in C und in 10-3 W/(m K). The coefficients of the equation are as
follows:
L0 =
L1 =
L2 =
11.804
0.0805
1.33741 x10-4
15
10
0
-50
-40
-30
-20
-10
10
20
30
40
50
60
Temperature t in C
Figure 4:
SFD-AK T/09.04/01/E
13
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
= K 0 + K1t + K 2 t 2 + K 3 t 3
(15)
15
10
0
-50
-40
-30
-20
-10
10
20
30
40
50
60
Temperature t in C
Figure 5:
Surface tension
SFD-AK T/09.04/01/E
14
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
c p = M 0 + M 1 (1 TR )
where TR =
19
+ M 2 (1 TR )
29
+ M 3 (1 TR )
39
+ M 4 (1 TR )
69
(16)
T
, c p is in kJ/(kg K) and T is in K. The coefficients of the equation are as
Tc
follows:
M0 =
M1 =
M2 =
M3 =
M4 =
Tc =
1,5
0,5
0
-50
-40
-30
-20
-10
10
20
30
40
50
60
Temperature t in C
Figure 6:
SFD-AK T/09.04/01/E
15
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
Compatibility of Materials
4.1 Elastomeres
The compatibility of materials with Solkane134a was checked according to DIN 8944
using various selected elastomers. The extraction tests, which were carried out on the
elastomers usually used in refrigeration technology CR, NBR and H-NBR, showed only
slight swelling and yielded negligible amounts of extract. Fluorinated rubbers (types
FKM and FPM) are not recommended because of their considerable swelling and
blistering when used with Solkane134a. Ethylenepropylenediene rubber is only to be
recommended where the presence of mineral oil in the refrigeration cycle can be
excluded. The effect of the lubricant which is used must not be ignored.
Recommendations made by the lubricant and compressor manufacturers must be
followed.
Table 1:
Elastomer
IIR
EPDM
HNBR
CR
NBR
NR
FKM
Change
in weight [%]
butyl rubber
ethylenepropylenediene rubber
hydrated acrylonitrilebutadiene rubber
chlorobutadiene rubber (Neoprene)
acrylonitrilebutadiene rubber
natural rubber
fluoro rubber
-1.1
-0.4
-0.11
-0.15
-0.29
-0.6
+7.3
Extract [%]
0
0
0
0
0
0
0.1
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16
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
4.2 Thermoplastics
Experience with CFC and H-CFC has shown that only a limited number of plastics are
resistant to fluorinated refrigerants. Various plastics used in refrigeration technology
were stored for 50 days at room temperature. It is vital to take the possible
additional effect of the lubricants into account. The following table of values can only
be used to give an idea of the effects to be expected.
Tabelle 2:
Thermoplast
Change in weight /%
Drying time:
Hostaform S 27076
Hostaform S 9064
Hostaform C 9021 GV
Fortron 6165 A4 natural
Fortron 1140 L4 natural
Hostalit Z
Polyethylene GM 7746
Polyethylene GA 7260
Polystyrene 4000
Polystyrene 6600
Vectra A 130 + 30% Glass fibres
Vectra C 130 + 30% Glass fibres
Vectra A 530 + 30% Mineral content
Vectra C 810
Vectra C 510
Polypropylene PPX 4207
Polypropylene PPW 1752
Polypropylene PPN 1060
10.3
2.7
0.8
0
-0.1
-0.1
0.6
0.5
0.5
0.8
-0.1
-0.1
-0.1
0
0
0.9
0.7
0.5
1h
9.5
2.5
0.8
0
-0.1
-0.1
0.5
0.4
0.3
0.7
-0.1
-0.1
-0.1
0
0
0.9
0.7
0.4
Optical
changes1
24 h
6.1
1.6
0.4
0
-0.1
-0.1
0.3
0.2
0.1
0.4
-0.1
-0.1
-0.1
0
0
0.5
0.4
0.3
0
0
0
0
0
0
0
++
+
0
0
0
0
0
0
0
0
0
SFD-AK T/09.04/01/E
17
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
4.3 Metals
Solkane134a is generally used in conjunction with lubricants (Ester oils, PAG-oils) in
refrigeration technology. The combination of both these materials is compatible with
the metals and joints usually found in machines and apparatus. Only zinc,
magnesium, lead and aluminium alloys with more than 2% magnesium by mass
should be avoided. The water content of refrigeration oil depending on oil type
should especially be taken into account. Values of not more than 50 ppm are to be
aimed at.
Refrigerant Oils
Like all fluorinated hydrocarbons, Solkane134a is immiscible with mineral oils. Ester
oil, and in automotive airconditioning systems, fully synthetic polyglycols (PAG) are
used as lubricants. The solubility of these oils in Solkane134a is a function of
temperature and composition. The following diagram shows the solubility properties
of various lubricants with Solkane134a. Highly viscous lubricants tend to give large
miscibility gaps.
The precise miscibility gaps of the individual oils can be obtained from the lubricant
manufacturers.
Temperature
Miscibility gaps
PAG oils
Miscibility gaps
ester oils
Oil concentration in
refrigerants
Figure 7:
SFD-AK T/09.04/01/E
18
SOLVAY FLUOR
Solkane134a Thermodynamics
Release 1.05
Thermal Stability
Solkane134a demonstrates a better thermal stability than the CFCs which have been
used up to now. No fluoride ions were found by the Phillip test in accordance with
DIN 51 593 (refrigerant + mineral oil in a U-tube for 96 h at 250C). The product has
therefore passed the Phillip test.
Flammability
Toxicity
The toxicity of Solkane134a was extensively tested between 1987 and 1994 within
the scope of the PAFT programme (Programme for Alternative Fluorocarbon Toxicity
Testing). The tests showed that the safety for Solkane134a with regard to toxicity
was at least as high as that for R12. The results showed that the product can be
safely used in domestic, commercial and industrial refrigeration and in air
conditioning technology. The usual measures which are recommended for work
safety must be followed. Solvay recommends a TLV of 1000 ppm.
SFD-AK T/09.04/01/E
19
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
9
[C]
-50
-49
-48
-47
-46
-45
-44
-43
-42
-41
p
v
v
3
3
3
[bar] [dm /kg] [dm /kg] [kg/dm ] [kg/m3]
0.29
0.691
606.17
1.447
1.65
0.31
0.692
574.14
1.444
1.74
0.33
0.694
544.11
1.441
1.84
0.35
0.695
515.95
1.438
1.94
0.37
0.697
489.51
1.436
2.04
0.39
0.698
464.68
1.433
2.15
0.41
0.699
441.35
1.430
2.27
0.44
0.701
419.41
1.427
2.38
0.46
0.702
398.76
1.424
2.51
0.49
0.704
379.33
1.421
2.64
h
[kJ/kg]
135.75
136.99
138.24
139.49
140.73
141.98
143.22
144.47
145.71
146.96
h
[kJ/kg]
367.70
368.33
368.96
369.60
370.23
370.86
371.50
372.13
372.76
373.39
r
s
s
[kJ/kg] [kJ/kgK] [kJ/kgK]
231.95 0.7409 1.7808
231.34 0.7463 1.7790
230.73 0.7518 1.7772
230.11 0.7572 1.7755
229.50 0.7626 1.7738
228.89 0.7681 1.7722
228.27 0.7735 1.7706
227.66 0.7789 1.7690
227.05 0.7842 1.7674
226.43 0.7896 1.7659
-40
-39
-38
-37
-36
-35
-34
-33
-32
-31
0.51
0.54
0.57
0.60
0.63
0.66
0.70
0.73
0.77
0.80
0.705
0.706
0.708
0.709
0.711
0.712
0.714
0.715
0.717
0.718
361.01
343.76
327.49
312.13
297.64
283.95
271.01
258.78
247.20
236.25
1.418
1.415
1.413
1.410
1.407
1.404
1.401
1.398
1.395
1.392
2.77
2.91
3.05
3.20
3.36
3.52
3.69
3.86
4.05
4.23
148.21
149.46
150.71
151.96
153.21
154.47
155.73
156.98
158.24
159.51
374.02
374.66
375.29
375.92
376.54
377.17
377.80
378.43
379.06
379.68
225.81
225.20
224.58
223.95
223.33
222.70
222.08
221.45
220.81
220.18
0.7950
0.8003
0.8057
0.8110
0.8163
0.8217
0.8270
0.8322
0.8375
0.8428
1.7645
1.7630
1.7616
1.7602
1.7589
1.7576
1.7563
1.7551
1.7538
1.7526
-30
-29
-28
-27
-26
-25
-24
-23
-22
-21
0.84
0.88
0.93
0.97
1.02
1.06
1.11
1.16
1.22
1.27
0.720
0.721
0.723
0.725
0.726
0.728
0.729
0.731
0.733
0.734
225.88
216.05
206.73
197.90
189.51
181.56
174.00
166.82
160.00
153.51
1.389
1.386
1.383
1.380
1.377
1.374
1.371
1.368
1.365
1.362
4.43
4.63
4.84
5.05
5.28
5.51
5.75
5.99
6.25
6.51
160.77
162.04
163.31
164.58
165.85
167.13
168.41
169.69
170.98
172.27
380.31
380.93
381.56
382.18
382.80
383.42
384.04
384.66
385.28
385.89
219.54
218.89
218.25
217.60
216.94
216.29
215.63
214.96
214.30
213.62
0.8480
0.8533
0.8585
0.8637
0.8689
0.8741
0.8793
0.8845
0.8896
0.8948
1.7515
1.7503
1.7492
1.7481
1.7471
1.7460
1.7450
1.7440
1.7431
1.7421
-20
-19
-18
-17
-16
-15
-14
-13
-12
-11
1.33
1.39
1.45
1.51
1.57
1.64
1.71
1.78
1.85
1.93
0.736
0.738
0.739
0.741
0.743
0.744
0.746
0.748
0.750
0.752
147.33
141.46
135.86
130.54
125.46
120.62
116.00
111.60
107.39
103.38
1.359
1.356
1.353
1.349
1.346
1.343
1.340
1.337
1.334
1.331
6.79
7.07
7.36
7.66
7.97
8.29
8.62
8.96
9.31
9.67
173.56
174.85
176.15
177.45
178.75
180.06
181.36
182.68
183.99
185.31
386.51
387.12
387.73
388.34
388.95
389.56
390.17
390.77
391.38
391.98
212.95
212.27
211.58
210.90
210.20
209.51
208.81
208.10
207.39
206.67
0.8999
0.9050
0.9101
0.9152
0.9203
0.9254
0.9304
0.9355
0.9405
0.9455
1.7412
1.7403
1.7394
1.7385
1.7377
1.7369
1.7361
1.7353
1.7346
1.7338
SFD-AK T/09.04/01/E
20
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
v
v
3
[dm /kg] [dm3/kg] [kg/dm3] [kg/m3]
0.753
99.54
1.327
10.05
0.755
95.88
1.324
10.43
0.757
92.38
1.321
10.82
0.759
89.03
1.318
11.23
0.761
85.83
1.315
11.65
0.763
82.76
1.311
12.08
0.765
79.83
1.308
12.53
0.766
77.02
1.305
12.98
0.768
74.33
1.301
13.45
0.770
71.75
1.298
13.94
Solkane134a
[C]
-10
-9
-8
-7
-6
-5
-4
-3
-2
-1
p
[bar]
2.01
2.09
2.17
2.25
2.34
2.43
2.53
2.62
2.72
2.82
0
1
2
3
4
5
6
7
8
9
2.93
3.04
3.15
3.26
3.38
3.50
3.62
3.75
3.88
4.01
0.772
0.774
0.776
0.778
0.780
0.782
0.785
0.787
0.789
0.791
69.28
66.91
64.64
62.46
60.36
58.35
56.42
54.57
52.79
51.08
1.295
1.291
1.288
1.285
1.281
1.278
1.275
1.271
1.268
1.264
14.43
14.95
15.47
16.01
16.57
17.14
17.72
18.33
18.94
19.58
200.00
201.35
202.70
204.06
205.42
206.79
208.15
209.52
210.90
212.27
398.49
399.07
399.65
400.22
400.80
401.37
401.94
402.50
403.07
403.63
198.49
197.72
196.95
196.16
195.38
194.58
193.78
192.98
192.17
191.36
1.0000
1.0049
1.0098
1.0146
1.0195
1.0243
1.0292
1.0340
1.0388
1.0436
1.7267
1.7262
1.7256
1.7251
1.7246
1.7241
1.7236
1.7231
1.7226
1.7221
10
11
12
13
14
15
16
17
18
19
4.15
4.29
4.43
4.58
4.73
4.88
5.04
5.21
5.37
5.54
0.793
0.795
0.798
0.800
0.802
0.804
0.807
0.809
0.811
0.814
49.43
47.84
46.32
44.85
43.44
42.08
40.77
39.51
38.30
37.12
1.261
1.257
1.254
1.250
1.247
1.243
1.240
1.236
1.232
1.229
20.23
20.90
21.59
22.29
23.02
23.76
24.53
25.31
26.11
26.94
213.65
215.03
216.42
217.80
219.19
220.58
221.98
223.38
224.78
226.18
404.19
404.74
405.30
405.85
406.39
406.94
407.48
408.02
408.55
409.08
190.54
189.71
188.88
188.04
187.20
186.35
185.50
184.64
183.77
182.90
1.0484
1.0532
1.0580
1.0627
1.0675
1.0723
1.0770
1.0818
1.0865
1.0912
1.7217
1.7212
1.7208
1.7204
1.7200
1.7196
1.7192
1.7188
1.7184
1.7180
20
21
22
23
24
25
26
27
28
29
5.72
5.90
6.08
6.27
6.46
6.65
6.85
7.06
7.27
7.48
0.816
0.819
0.821
0.824
0.826
0.829
0.832
0.834
0.837
0.840
35.99
34.91
33.85
32.84
31.86
30.91
30.00
29.12
28.27
27.44
1.225
1.221
1.218
1.214
1.210
1.206
1.202
1.199
1.195
1.191
27.78
28.65
29.54
30.45
31.39
32.35
33.33
34.34
35.38
36.44
227.59
229.00
230.41
231.83
233.25
234.67
236.09
237.52
238.96
240.39
409.61
410.14
410.66
411.18
411.69
412.20
412.71
413.21
413.71
414.20
182.02
181.14
180.25
179.35
178.44
177.53
176.61
175.69
174.75
173.81
1.0960
1.1007
1.1054
1.1101
1.1148
1.1195
1.1242
1.1289
1.1336
1.1383
1.7176
1.7172
1.7169
1.7165
1.7162
1.7158
1.7155
1.7151
1.7148
1.7144
SFD-AK T/09.04/01/E
h
[kJ/kg]
186.63
187.95
189.28
190.61
191.94
193.27
194.61
195.95
197.30
198.64
h
[kJ/kg]
392.58
393.18
393.78
394.37
394.97
395.56
396.15
396.74
397.32
397.91
r
s
s
[kJ/kg] [kJ/kgK] [kJ/kgK]
205.95 0.9505 1.7331
205.23 0.9555 1.7324
204.50 0.9605 1.7317
203.77 0.9655 1.7310
203.03 0.9705 1.7304
202.29 0.9754 1.7297
201.54 0.9804 1.7291
200.79 0.9853 1.7285
200.03 0.9902 1.7279
199.27 0.9951 1.7273
21
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
v
v
'
''
3
[dm /kg] [dm3/kg] [kg/dm3] [kg/m3]
0.842
26.65
1.187
37.53
0.845
25.88
1.183
38.64
0.848
25.13
1.179
39.79
0.851
24.41
1.175
40.96
0.854
23.72
1.171
42.16
0.857
23.04
1.167
43.40
0.860
22.39
1.163
44.66
0.863
21.76
1.159
45.96
0.866
21.15
1.155
47.29
0.869
20.55
1.150
48.66
Solkane134a
[C]
30
31
32
33
34
35
36
37
38
39
p
[bar]
7.70
7.93
8.15
8.39
8.63
8.87
9.12
9.37
9.63
9.90
40
41
42
43
44
45
46
47
48
49
10.17
10.44
10.72
11.01
11.30
11.60
11.90
12.21
12.53
12.85
0.872
0.876
0.879
0.882
0.886
0.889
0.893
0.896
0.900
0.904
19.98
19.42
18.88
18.36
17.85
17.36
16.88
16.41
15.96
15.53
1.146
1.142
1.138
1.133
1.129
1.125
1.120
1.116
1.111
1.107
50.06
51.49
52.97
54.48
56.03
57.62
59.25
60.92
62.64
64.40
256.43
257.91
259.40
260.90
262.40
263.90
265.41
266.93
268.45
269.98
419.33
419.76
420.19
420.61
421.03
421.44
421.84
422.24
422.63
423.01
162.90
161.85
160.79
159.72
158.63
157.54
156.43
155.31
154.17
153.02
1.1897
1.1944
1.1991
1.2038
1.2085
1.2132
1.2179
1.2226
1.2273
1.2320
1.7107
1.7104
1.7100
1.7097
1.7093
1.7090
1.7086
1.7082
1.7078
1.7075
50
51
52
53
54
55
56
57
58
59
13.18
13.51
13.85
14.20
14.55
14.92
15.28
15.66
16.04
16.42
0.908
0.911
0.915
0.919
0.923
0.928
0.932
0.936
0.941
0.945
15.10
14.69
14.29
13.90
13.52
13.15
12.80
12.45
12.11
11.78
1.102
1.097
1.093
1.088
1.083
1.078
1.073
1.068
1.063
1.058
66.21
68.07
69.98
71.94
73.95
76.02
78.15
80.34
82.59
84.90
271.52
273.07
274.62
276.18
277.74
279.32
280.90
282.49
284.10
285.71
423.38
423.75
424.10
424.45
424.79
425.12
425.44
425.76
426.06
426.35
151.86
150.68
149.49
148.28
147.05
145.81
144.54
143.26
141.96
140.64
1.2367
1.2415
1.2462
1.2510
1.2557
1.2605
1.2653
1.2701
1.2749
1.2797
1.7071
1.7066
1.7062
1.7058
1.7053
1.7049
1.7044
1.7039
1.7034
1.7029
60
61
62
63
64
65
66
67
68
69
16.82
17.22
17.63
18.04
18.47
18.90
19.34
19.78
20.24
20.70
0.950
0.955
0.960
0.965
0.970
0.975
0.980
0.986
0.992
0.998
11.46
11.15
10.84
10.54
10.26
9.97
9.70
9.43
9.17
8.91
1.053
1.047
1.042
1.037
1.031
1.026
1.020
1.014
1.008
1.002
87.28
89.72
92.24
94.84
97.51
100.27
103.11
106.04
109.06
112.19
287.33
288.96
290.60
292.26
293.92
295.60
297.29
298.99
300.71
302.44
426.63
426.90
427.15
427.40
427.63
427.84
428.05
428.24
428.41
428.57
139.30
137.94
136.55
135.14
133.71
132.25
130.76
129.25
127.70
126.13
1.2845
1.2894
1.2942
1.2991
1.3040
1.3089
1.3138
1.3188
1.3237
1.3287
1.7024
1.7018
1.7012
1.7006
1.7000
1.6994
1.6987
1.6980
1.6973
1.6965
SFD-AK T/09.04/01/E
h
[kJ/kg]
241.83
243.27
244.72
246.17
247.62
249.08
250.54
252.01
253.48
254.95
h
[kJ/kg]
414.69
415.18
415.66
416.14
416.61
417.07
417.54
417.99
418.44
418.89
r
s
s
[kJ/kg] [kJ/kgK] [kJ/kgK]
172.86 1.1429 1.7141
171.91 1.1476 1.7138
170.94 1.1523 1.7134
169.97 1.1570 1.7131
168.99 1.1616 1.7128
168.00 1.1663 1.7124
167.00 1.1710 1.7121
165.99 1.1757 1.7118
164.97 1.1804 1.7114
163.94 1.1850 1.7111
22
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
'
''
[C]
70
71
72
73
74
75
76
77
[bar]
21.17
21.65
22.13
22.63
23.13
23.64
24.16
24.69
1.004
1.010
1.016
1.023
1.030
1.037
1.044
1.052
8.66
8.42
8.18
7.95
7.72
7.50
7.28
7.07
0.996
0.990
0.984
0.978
0.971
0.964
0.958
0.951
115.41
118.75
122.20
125.77
129.47
133.30
137.28
141.42
78
79
80
81
82
83
84
85
86
87
25.23
25.78
26.33
26.90
27.47
28.06
28.65
29.26
29.87
30.50
1.060
1.068
1.077
1.086
1.095
1.105
1.116
1.127
1.138
1.151
6.86
6.66
6.46
6.26
6.07
5.88
5.69
5.51
5.33
5.15
0.944
0.936
0.929
0.921
0.913
0.905
0.896
0.888
0.879
0.869
88
89
90
91
92
93
94
95
96
97
31.14
31.78
32.44
33.11
33.79
34.49
35.19
35.91
36.64
37.39
1.164
1.178
1.193
1.210
1.228
1.248
1.270
1.295
1.324
1.358
4.97
4.80
4.63
4.45
4.28
4.11
3.94
3.76
3.59
3.40
0.859
0.849
0.838
0.827
0.814
0.801
0.788
0.772
0.755
0.736
SFD-AK T/09.04/01/E
Solkane134a
h
[kJ/kg]
304.18
305.94
307.72
309.51
311.32
313.14
314.99
316.85
428.71
428.83
428.93
429.01
429.07
429.11
429.13
429.12
124.52
122.88
121.21
119.50
117.76
115.97
114.14
112.27
1.3337
1.3387
1.3438
1.3489
1.3539
1.3590
1.3642
1.3693
1.6957
1.6949
1.6940
1.6931
1.6921
1.6911
1.6901
1.6890
145.71
150.19
154.85
159.71
164.79
170.11
175.69
181.54
187.71
194.22
318.73
320.64
322.56
324.50
326.47
328.46
330.47
332.51
334.57
336.66
429.08
429.02
428.93
428.80
428.64
428.44
428.19
427.91
427.57
427.19
110.35
108.38
106.37
104.30
102.17
99.98
97.72
95.40
93.01
90.53
1.3745
1.3797
1.3850
1.3903
1.3955
1.4009
1.4062
1.4116
1.4170
1.4225
1.6878
1.6866
1.6852
1.6839
1.6824
1.6809
1.6792
1.6775
1.6756
1.6736
201.11
208.42
216.21
224.56
233.54
243.26
253.90
265.66
278.91
294.32
338.77
340.91
343.08
345.28
347.52
349.78
352.07
354.40
356.76
359.16
426.74
426.23
425.64
424.97
424.20
423.33
422.31
421.13
419.73
417.99
87.97
85.31
82.56
79.69
76.69
73.55
70.24
66.73
62.96
58.84
1.4280
1.4335
1.4391
1.4447
1.4503
1.4560
1.4617
1.4675
1.4733
1.4791
1.6715
1.6692
1.6667
1.6641
1.6611
1.6579
1.6544
1.6504
1.6459
1.6405
23
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
10
0.293bar
-50C
dm3/kg
606.17
620.71
635.20
649.63
664.01
678.35
692.64
706.90
721.13
735.33
749.50
763.65
777.77
791.88
805.96
820.03
834.11
kJ/kg
367.70
371.27
374.88
378.54
382.24
385.98
389.76
393.59
397.46
401.38
405.33
409.34
413.38
417.47
421.60
425.77
429.98
kJ/kgK
1.7808
1.7966
1.8123
1.8278
1.8432
1.8584
1.8735
1.8885
1.9033
1.9181
1.9327
1.9472
1.9616
1.9759
1.9901
2.0042
2.0183
-50
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
0.39bar
-45C
dm3/kg
464.68
475.76
486.77
497.74
508.66
519.55
530.39
541.21
551.99
562.74
573.47
584.18
594.87
605.54
616.19
626.83
637.45
kJ/kg
370.86
374.50
378.18
381.90
385.66
389.47
393.31
397.20
401.13
405.10
409.12
413.17
417.27
421.41
425.59
429.81
434.08
kJ/kgK
1.7722
1.7879
1.8036
1.8190
1.8343
1.8495
1.8646
1.8795
1.8943
1.9089
1.9235
1.9379
1.9523
1.9665
1.9807
1.9947
2.0087
-45
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
0.512bar
-40C
dm3/kg
361.01
369.59
378.10
386.57
395.00
403.39
411.75
420.08
428.37
436.65
444.90
453.13
461.34
469.53
477.71
485.87
494.02
kJ/kg
374.02
377.73
381.48
385.27
389.10
392.97
396.87
400.82
404.81
408.84
412.91
417.02
421.17
425.37
429.60
433.88
438.19
kJ/kgK
1.7645
1.7802
1.7958
1.8112
1.8265
1.8416
1.8566
1.8715
1.8862
1.9008
1.9153
1.9297
1.9440
1.9582
1.9723
1.9862
2.0001
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
SFD-AK T/09.04/01/E
0.66bar
t
C
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
-35C
dm3/kg
283.95
290.68
297.36
304.00
310.61
317.17
323.70
330.21
336.69
343.15
349.58
356.00
362.40
368.78
375.15
381.50
387.84
kJ/kg
377.17
380.96
384.78
388.64
392.53
396.46
400.44
404.45
408.49
412.58
416.71
420.88
425.09
429.34
433.63
437.95
442.32
kJ/kgK
1.7576
1.7733
1.7889
1.8043
1.8195
1.8346
1.8495
1.8643
1.8790
1.8936
1.9081
1.9224
1.9366
1.9508
1.9648
1.9787
1.9926
0.843bar
t
C
-30
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
-30C
dm3/kg
225.88
231.24
236.55
241.83
247.07
252.28
257.46
262.61
267.74
272.85
277.94
283.01
288.06
293.10
298.12
303.13
308.14
kJ/kg
380.31
384.17
388.06
391.99
395.96
399.96
404.00
408.07
412.18
416.33
420.52
424.75
429.01
433.32
437.66
442.04
446.46
kJ/kgK
1.7515
1.7672
1.7827
1.7981
1.8133
1.8284
1.8433
1.8581
1.8727
1.8872
1.9017
1.9160
1.9301
1.9442
1.9582
1.9721
1.9859
0.927bar
t
C
-28
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
-28C
dm3/kg
206.73
209.68
214.57
219.42
224.23
229.00
233.75
238.47
243.17
247.85
252.50
257.14
261.76
266.36
270.96
275.54
280.10
kJ/kg
381.56
383.89
387.80
391.75
395.73
399.74
403.79
407.88
412.00
416.16
420.35
424.59
428.86
433.17
437.52
441.91
446.34
kJ/kgK
1.7492
1.7587
1.7743
1.7897
1.8050
1.8201
1.8351
1.8499
1.8646
1.8791
1.8936
1.9079
1.9221
1.9362
1.9502
1.9641
1.9779
1.016bar
t
C
-26
-25
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
-24
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
dm3/kg
189.51
190.42
194.92
199.39
203.81
208.20
212.57
216.90
221.21
225.50
229.77
234.02
238.26
242.47
246.68
250.87
255.05
kJ/kg
382.80
383.58
387.51
391.48
395.47
399.50
403.57
407.66
411.80
415.97
420.18
424.42
428.70
433.02
437.38
441.77
446.21
kJ/kgK
1.7471
1.7502
1.7659
1.7814
1.7967
1.8119
1.8269
1.8418
1.8565
1.8711
1.8856
1.9000
1.9142
1.9283
1.9424
1.9563
1.9701
-22
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
-24C
t
C
-20
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
dm3/kg
174.00
177.33
181.44
185.53
189.57
193.59
197.58
201.55
205.49
209.42
213.32
217.21
221.08
224.94
228.79
232.62
236.45
kJ/kg
384.04
387.20
391.19
395.20
399.25
403.33
407.44
411.58
415.77
419.98
424.24
428.53
432.86
437.22
441.62
446.07
450.54
kJ/kgK
1.7450
1.7576
1.7732
1.7886
1.8038
1.8189
1.8338
1.8486
1.8632
1.8777
1.8921
1.9064
1.9206
1.9346
1.9486
1.9624
1.9762
-22C
t
C
-18
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
dm3/kg
147.33
150.87
154.37
157.83
161.27
164.67
168.05
171.41
174.74
178.06
181.36
184.64
187.91
191.17
194.41
197.65
200.87
kJ/kg
386.51
390.53
394.59
398.67
402.78
406.93
411.10
415.31
419.55
423.83
428.14
432.49
436.87
441.29
445.75
450.24
454.77
kJ/kgK
1.7412
1.7569
1.7725
1.7879
1.8031
1.8181
1.8330
1.8477
1.8623
1.8768
1.8911
1.9053
1.9194
1.9334
1.9473
1.9611
1.9748
dm3/kg
160.00
161.53
165.35
169.12
172.86
176.57
180.25
183.91
187.54
191.15
194.75
198.33
201.89
205.44
208.98
212.50
216.01
kJ/kg
385.28
386.87
390.87
394.91
398.97
403.06
407.19
411.35
415.55
419.78
424.04
428.34
432.68
437.05
441.46
445.91
450.40
kJ/kgK
1.7431
1.7494
1.7650
1.7805
1.7958
1.8109
1.8259
1.8407
1.8554
1.8700
1.8844
1.8987
1.9129
1.9270
1.9409
1.9548
1.9686
t
C
-16
-15
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
-18C
dm3/kg
135.86
137.83
141.09
144.30
147.49
150.64
153.77
156.88
159.96
163.03
166.07
169.11
172.13
175.13
178.13
181.11
184.08
kJ/kg
387.73
390.17
394.25
398.35
402.48
406.64
410.83
415.06
419.31
423.60
427.92
432.28
436.67
441.10
445.57
450.07
454.61
kJ/kgK
1.7394
1.7489
1.7645
1.7800
1.7952
1.8103
1.8253
1.8401
1.8547
1.8692
1.8836
1.8979
1.9120
1.9260
1.9399
1.9538
1.9675
1.573bar
-20C
1.446bar
1.216bar
t
1.327bar
1.112bar
t
-26C
-18C
dm3/kg
125.46
126.07
129.10
132.09
135.05
137.98
140.89
143.77
146.63
149.47
152.29
155.10
157.89
160.67
163.44
166.19
168.94
kJ/kg
388.95
389.77
393.87
398.00
402.15
406.33
410.54
414.78
419.05
423.36
427.69
432.06
436.46
440.90
445.38
449.89
454.43
kJ/kgK
1.7377
1.7409
1.7566
1.7722
1.7875
1.8027
1.8177
1.8325
1.8472
1.8618
1.8762
1.8905
1.9046
1.9187
1.9327
1.9465
1.9603
24
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
-14C
dm3/kg
116.00
118.26
121.05
123.81
126.54
129.24
131.92
134.58
137.21
139.83
142.44
145.02
147.60
150.16
152.71
155.26
157.79
kJ/kg
390.17
393.48
397.63
401.80
406.00
410.23
414.49
418.77
423.09
427.44
431.82
436.24
440.69
445.17
449.69
454.25
458.84
kJ/kgK
1.7361
1.7488
1.7644
1.7798
1.7951
1.8101
1.8250
1.8398
1.8544
1.8688
1.8832
1.8974
1.9115
1.9255
1.9394
1.9531
1.9668
-14
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
1.852bar
-12C
dm3/kg
107.39
108.45
111.06
113.64
116.18
118.70
121.20
123.67
126.12
128.56
130.98
133.38
135.77
138.15
140.52
142.87
145.22
kJ/kg
391.38
393.05
397.22
401.42
405.65
409.90
414.17
418.48
422.81
427.17
431.57
436.00
440.46
444.95
449.48
454.05
458.65
kJ/kgK
1.7346
1.7409
1.7566
1.7722
1.7875
1.8026
1.8176
1.8324
1.8471
1.8616
1.8760
1.8902
1.9043
1.9184
1.9323
1.9461
1.9598
-12
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
2.006bar
-10C
dm3/kg
99.54
101.99
104.41
106.79
109.14
111.47
113.78
116.07
118.33
120.59
122.82
125.05
127.26
129.46
131.64
133.82
136.00
kJ/kg
392.58
396.79
401.02
405.27
409.54
413.83
418.16
422.51
426.89
431.30
435.74
440.21
444.72
449.26
453.84
458.44
463.09
kJ/kgK
1.7331
1.7489
1.7646
1.7800
1.7952
1.8102
1.8251
1.8398
1.8544
1.8688
1.8831
1.8973
1.9113
1.9253
1.9391
1.9529
1.9665
-10
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
SFD-AK T/09.04/01/E
2.169bar
t
C
-8
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
-8C
h
dm3/kg
92.38
93.76
96.02
98.26
100.46
102.64
104.80
106.93
109.05
111.15
113.24
115.31
117.37
119.41
121.45
123.48
125.50
kJ/kg
393.78
396.33
400.58
404.86
409.15
413.47
417.82
422.19
426.58
431.01
435.47
439.95
444.47
449.02
453.61
458.23
462.88
kJ/kgK
1.7317
1.7412
1.7570
1.7725
1.7878
1.8029
1.8179
1.8326
1.8473
1.8617
1.8761
1.8903
1.9044
1.9184
1.9322
1.9460
1.9597
2.343bar
t
C
-6
-5
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
-6C
-4
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
t
C
-2
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
dm3/kg
85.83
86.26
88.39
90.49
92.56
94.60
96.63
98.62
100.60
102.57
104.52
106.45
108.37
110.28
112.18
114.07
115.95
kJ/kg
394.97
395.82
400.11
404.42
408.74
413.08
417.45
421.84
426.26
430.70
435.17
439.67
444.21
448.77
453.37
458.00
462.66
kJ/kgK
1.7304
1.7336
1.7494
1.7650
1.7804
1.7956
1.8107
1.8255
1.8402
1.8547
1.8691
1.8834
1.8975
1.9115
1.9254
1.9392
1.9529
-4C
t
C
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
dm3/kg
79.83
81.44
83.41
85.36
87.28
89.18
91.06
92.91
94.75
96.57
98.38
100.18
101.96
103.73
105.50
107.25
109.00
kJ/kg
396.15
399.61
403.95
408.30
412.67
417.06
421.47
425.91
430.37
434.86
439.37
443.92
448.50
453.11
457.75
462.42
467.13
kJ/kgK
1.7291
1.7419
1.7576
1.7731
1.7884
1.8035
1.8184
1.8332
1.8478
1.8622
1.8765
1.8907
1.9048
1.9187
1.9325
1.9463
1.9599
t
C
2
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
3.377bar
dm3/kg
74.33
75.09
76.96
78.79
80.60
82.39
84.15
85.89
87.62
89.33
91.02
92.70
94.37
96.03
97.68
99.32
100.95
kJ/kg
397.32
399.07
403.44
407.83
412.22
416.64
421.08
425.53
430.01
434.52
439.06
443.62
448.21
452.83
457.49
462.17
466.89
kJ/kgK
1.7279
1.7343
1.7502
1.7658
1.7812
1.7964
1.8114
1.8262
1.8409
1.8554
1.8697
1.8840
1.8981
1.9120
1.9259
1.9397
1.9533
0C
t
C
4
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
dm3/kg
69.28
71.05
72.79
74.49
76.18
77.84
79.48
81.10
82.70
84.30
85.87
87.44
88.99
90.54
92.07
93.60
95.12
kJ/kg
398.49
402.90
407.32
411.75
416.19
420.65
425.13
429.64
434.16
438.72
443.30
447.90
452.54
457.21
461.90
466.63
471.39
kJ/kgK
1.7267
1.7427
1.7585
1.7740
1.7893
1.8044
1.8193
1.8340
1.8486
1.8630
1.8773
1.8914
1.9054
1.9193
1.9331
1.9468
1.9604
2C
t
C
6
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
dm3/kg
60.36
60.68
62.24
63.78
65.28
66.77
68.23
69.67
71.10
72.50
73.90
75.28
76.66
78.02
79.37
80.71
82.05
kJ/kg
400.80
401.70
406.19
410.69
415.20
419.72
424.26
428.81
433.38
437.97
442.59
447.23
451.90
456.59
461.32
466.07
470.86
kJ/kgK
1.7246
1.7278
1.7438
1.7596
1.7751
1.7904
1.8055
1.8204
1.8351
1.8496
1.8640
1.8783
1.8924
1.9064
1.9203
1.9340
1.9477
dm3/kg
64.64
65.64
67.29
68.90
70.49
72.06
73.61
75.14
76.65
78.14
79.62
81.09
82.55
84.00
85.44
86.87
88.30
kJ/kg
399.65
402.32
406.78
411.24
415.71
420.20
424.71
429.24
433.78
438.36
442.95
447.58
452.23
456.91
461.62
466.36
471.13
kJ/kgK
1.7256
1.7353
1.7512
1.7668
1.7822
1.7974
1.8124
1.8272
1.8418
1.8563
1.8706
1.8848
1.8989
1.9128
1.9267
1.9404
1.9540
t
C
8
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
6C
dm3/kg
56.42
57.61
59.07
60.50
61.91
63.29
64.65
66.00
67.33
68.65
69.95
71.24
72.53
73.80
75.06
76.32
77.56
kJ/kg
401.94
405.57
410.11
414.66
419.21
423.77
428.35
432.95
437.56
442.20
446.86
451.55
456.26
461.00
465.77
470.57
475.39
kJ/kgK
1.7236
1.7365
1.7524
1.7680
1.7834
1.7986
1.8136
1.8284
1.8430
1.8575
1.8718
1.8860
1.9000
1.9139
1.9277
1.9414
1.9550
3.876bar
4C
3.620bar
3.146bar
-2C
2.928bar
2.527bar
t
2.722bar
Solkane134a
8C
dm3/kg
52.79
53.35
54.74
56.10
57.44
58.75
60.05
61.32
62.58
63.82
65.05
66.27
67.48
68.68
69.87
71.05
72.23
kJ/kg
403.07
404.90
409.49
414.07
418.66
423.26
427.87
432.49
437.13
441.79
446.47
451.18
455.90
460.66
465.44
470.25
475.10
kJ/kgK
1.7226
1.7291
1.7452
1.7609
1.7765
1.7918
1.8068
1.8217
1.8364
1.8509
1.8653
1.8795
1.8936
1.9076
1.9214
1.9352
1.9488
25
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
10C
dm3/kg
49.43
50.76
52.06
53.33
54.58
55.80
57.01
58.21
59.38
60.55
61.70
62.84
63.97
65.10
66.21
67.32
68.42
kJ/kg
404.19
408.82
413.45
418.08
422.71
427.35
432.00
436.67
441.35
446.05
450.78
455.53
460.30
465.10
469.93
474.78
479.66
kJ/kgK
1.7217
1.7379
1.7538
1.7695
1.7849
1.8001
1.8151
1.8298
1.8444
1.8589
1.8732
1.8873
1.9013
1.9152
1.9290
1.9426
1.9562
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
4.430bar
12C
dm3/kg
46.32
47.08
48.32
49.54
50.73
51.90
53.05
54.18
55.30
56.40
57.49
58.57
59.64
60.70
61.75
62.80
63.83
kJ/kg
405.30
408.11
412.78
417.45
422.12
426.80
431.48
436.18
440.89
445.61
450.36
455.13
459.92
464.74
469.58
474.45
479.35
kJ/kgK
1.7208
1.7306
1.7467
1.7625
1.7780
1.7933
1.8084
1.8233
1.8380
1.8525
1.8668
1.8811
1.8951
1.9091
1.9229
1.9366
1.9501
12
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
4.729bar
14C
dm3/kg
43.44
43.68
44.88
46.04
47.18
48.29
49.39
50.46
51.52
52.57
53.61
54.63
55.64
56.65
57.64
58.63
59.61
kJ/kg
406.39
407.34
412.07
416.79
421.50
426.21
430.93
435.65
440.39
445.15
449.92
454.71
459.52
464.35
469.21
474.10
479.01
kJ/kgK
1.7200
1.7233
1.7395
1.7555
1.7712
1.7866
1.8018
1.8167
1.8315
1.8461
1.8605
1.8748
1.8889
1.9029
1.9168
1.9305
1.9441
14
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
SFD-AK T/09.04/01/E
5.043bar
t
C
16
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
16C
h
dm3/kg
40.77
41.69
42.80
43.89
44.96
46.00
47.03
48.04
49.04
50.02
50.99
51.95
52.90
53.85
54.78
55.71
56.63
kJ/kg
407.48
411.31
416.08
420.83
425.59
430.34
435.10
439.87
444.65
449.45
454.26
459.09
463.95
468.82
473.72
478.65
483.61
kJ/kgK
1.7192
1.7323
1.7484
1.7643
1.7798
1.7951
1.8102
1.8251
1.8397
1.8542
1.8686
1.8828
1.8968
1.9107
1.9245
1.9382
1.9517
5.372bar
t
C
18
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
18C
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
95
dm3/kg
22 33.85
25 34.45
30 35.42
35 36.37
40 37.29
45 38.19
50 39.07
55 39.94
60 40.79
65 41.63
70 42.46
75 43.28
80 44.09
85 44.89
90 45.68
95 46.46
100 47.24
6.458bar
dm3/kg
38.30
38.73
39.81
40.85
41.87
42.87
43.86
44.82
45.77
46.70
47.63
48.54
49.44
50.34
51.22
52.10
52.98
kJ/kg
408.55
410.49
415.31
420.12
424.92
429.72
434.51
439.31
444.12
448.95
453.78
458.64
463.52
468.41
473.33
478.28
483.25
kJ/kgK
1.7184
1.7250
1.7413
1.7573
1.7730
1.7884
1.8036
1.8186
1.8334
1.8480
1.8624
1.8766
1.8907
1.9047
1.9185
1.9323
1.9458
5.717bar
t
6.079bar
20C
dm3/kg
24 31.86
25 32.05
30 32.99
35 33.90
40 34.79
45 35.66
50 36.51
55 37.34
60 38.15
65 38.96
70 39.75
75 40.53
80 41.30
85 42.06
90 42.81
95 43.56
100 44.30
6.854bar
dm3/kg
35.99
37.03
38.04
39.02
39.98
40.92
41.84
42.74
43.64
44.52
45.38
46.24
47.09
47.93
48.77
49.60
49.60
kJ/kg
409.61
414.50
419.36
424.21
429.05
433.89
438.72
443.56
448.42
453.28
458.16
463.06
467.98
472.92
477.88
482.87
482.87
kJ/kgK
1.7176
1.7341
1.7503
1.7662
1.7818
1.7971
1.8122
1.8270
1.8417
1.8562
1.8705
1.8847
1.8987
1.9126
1.9264
1.9400
1.9400
t
C
dm3/kg
26 30.00
30 30.73
35 31.61
40 32.47
45 33.31
50 34.12
55 34.92
60 35.70
65 36.47
70 37.23
75 37.97
80 38.71
85 39.44
90 40.15
95 40.87
100 41.57
100 41.57
Solkane134a
22C
7.269bar
kJ/kg
410.66
413.63
418.55
423.46
428.34
433.22
438.10
442.97
447.86
452.75
457.66
462.58
467.52
472.48
477.46
482.46
487.49
kJ/kgK
1.7169
1.7269
1.7433
1.7593
1.7750
1.7905
1.8057
1.8207
1.8354
1.8500
1.8644
1.8787
1.8928
1.9067
1.9205
1.9342
1.9478
24C
dm3/kg
28 28.27
30 28.62
35 29.48
40 30.31
45 31.11
50 31.90
55 32.67
60 33.42
65 34.16
70 34.88
75 35.60
80 36.30
85 37.00
90 37.68
95 38.36
100 39.03
105 39.70
7.702bar
kJ/kg
411.69
412.69
417.69
422.65
427.59
432.51
437.43
442.35
447.26
452.19
457.12
462.07
467.04
472.02
477.02
482.04
487.09
kJ/kgK
1.7162
1.7195
1.7361
1.7524
1.7683
1.7839
1.7992
1.8143
1.8292
1.8439
1.8583
1.8727
1.8868
1.9008
1.9147
1.9284
1.9420
26C
dm3/kg
30 26.65
35 27.48
40 28.29
45 29.07
50 29.83
55 30.57
60 31.30
65 32.01
70 32.70
75 33.39
80 34.06
85 34.73
90 35.38
95 36.03
100 36.67
105 37.31
110 37.94
8.154bar
kJ/kg
412.71
416.76
421.79
426.78
431.76
436.72
441.68
446.63
451.59
456.56
461.54
466.52
471.53
476.55
481.60
486.66
486.66
kJ/kgK
1.7155
1.7289
1.7454
1.7614
1.7772
1.7927
1.8079
1.8229
1.8377
1.8522
1.8666
1.8809
1.8949
1.9089
1.9227
1.9363
1.9363
t
C
dm3/kg
32 25.13
35 25.62
40 26.41
45 27.17
50 27.90
55 28.62
60 29.32
65 30.00
70 30.67
75 31.33
80 31.97
85 32.61
90 33.24
95 33.86
100 34.47
105 35.08
110 35.68
28C
h
kJ/kg
413.71
415.76
420.86
425.92
430.96
435.97
440.97
445.97
450.96
455.96
460.97
465.99
471.02
476.06
481.13
486.21
491.31
kJ/kgK
1.7148
1.7216
1.7383
1.7546
1.7705
1.7861
1.8015
1.8166
1.8315
1.8462
1.8606
1.8749
1.8891
1.9031
1.9169
1.9306
1.9442
30C
h
kJ/kg
414.69
419.88
425.01
430.10
435.17
440.22
445.26
450.30
455.33
460.37
465.42
470.47
475.54
480.63
485.74
490.86
496.01
kJ/kgK
1.7141
1.7311
1.7476
1.7637
1.7795
1.7950
1.8103
1.8253
1.8401
1.8546
1.8690
1.8832
1.8973
1.9112
1.9250
1.9386
1.9522
32C
h
kJ/kg
415.66
418.82
424.03
429.19
434.32
439.43
444.51
449.59
454.66
459.74
464.81
469.90
475.00
480.11
485.24
490.38
495.55
kJ/kgK
1.7134
1.7237
1.7405
1.7569
1.7729
1.7885
1.8039
1.8190
1.8339
1.8486
1.8631
1.8774
1.8915
1.9055
1.9193
1.9330
1.9466
26
Solkane134a Thermodynamics
SOLVAY FLUOR
Release 1.05
dm3/kg
34 23.72
35 23.87
40 24.64
45 25.38
50 26.10
55 26.79
60 27.47
65 28.13
70 28.77
75 29.41
80 30.03
85 30.64
90 31.24
95 31.84
100 32.42
105 33.01
110 33.58
34C
h
kJ/kg
416.61
417.68
422.98
428.22
433.42
438.58
443.72
448.84
453.96
459.07
464.18
469.30
474.42
479.56
484.71
489.88
495.07
kJ/kgK
1.7128
1.7162
1.7333
1.7499
1.7661
1.7820
1.7975
1.8128
1.8278
1.8426
1.8572
1.8715
1.8858
1.8998
1.9137
1.9275
1.9411
9.118bar
36C
dm3/kg
22.39
22.99
23.71
24.41
25.09
25.74
26.38
27.00
27.61
28.21
28.80
29.38
29.95
30.51
31.07
31.62
32.16
kJ/kg
417.54
421.85
427.18
432.45
437.68
442.87
448.05
453.21
458.36
463.51
468.66
473.82
478.98
484.16
489.35
494.56
499.79
kJ/kgK
1.7121
1.7260
1.7428
1.7593
1.7753
1.7910
1.8065
1.8216
1.8365
1.8512
1.8657
1.8800
1.8941
1.9081
1.9219
1.9356
1.9491
36
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
9.632bar
36C
dm3/kg
21.15
21.44
22.15
22.83
23.49
24.12
24.74
25.34
25.93
26.51
27.08
27.64
28.18
28.73
29.26
29.79
30.31
kJ/kg
418.44
420.64
426.06
431.42
436.72
441.98
447.21
452.42
457.61
462.80
467.99
473.18
478.38
483.58
488.80
494.03
499.28
kJ/kgK
1.7114
1.7184
1.7356
1.7523
1.7686
1.7845
1.8001
1.8154
1.8304
1.8452
1.8598
1.8742
1.8884
1.9025
1.9163
1.9301
1.9437
38
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
SFD-AK T/09.04/01/E
10.166bar
t
C
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
40C
h
dm3/kg
19.98
20.68
21.35
21.99
22.61
23.21
23.79
24.36
24.92
25.47
26.01
26.53
27.05
27.57
28.07
28.57
29.07
kJ/kg
419.33
424.87
430.31
435.69
441.02
446.31
451.58
456.82
462.06
467.28
472.51
477.74
482.97
488.21
493.47
498.74
504.03
kJ/kgK
1.7107
1.7283
1.7453
1.7618
1.7779
1.7937
1.8091
1.8243
1.8392
1.8539
1.8684
1.8827
1.8968
1.9108
1.9246
1.9383
1.9518
10.722bar
t
C
42
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
42C
44
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
t
C
46
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
dm3/kg
18.88
19.29
19.95
20.58
21.19
21.77
22.34
22.89
23.43
23.96
24.48
24.99
25.49
25.98
26.47
26.95
27.43
kJ/kg
420.19
423.58
429.13
434.60
440.01
445.37
450.69
455.99
461.27
466.54
471.80
477.06
482.33
487.60
492.88
498.18
503.49
kJ/kgK
1.7100
1.7207
1.7381
1.7549
1.7712
1.7872
1.8028
1.8181
1.8332
1.8480
1.8626
1.8770
1.8912
1.9052
1.9191
1.9328
1.9464
42C
t
C
48
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
dm3/kg
17.85
17.98
18.63
19.25
19.85
20.42
20.98
21.51
22.04
22.55
23.05
23.54
24.03
24.50
24.97
25.43
25.89
kJ/kg
421.03
422.18
427.86
433.43
438.92
444.36
449.75
455.10
460.43
465.75
471.05
476.35
481.65
486.96
492.27
497.59
502.93
kJ/kgK
1.7093
1.7130
1.7307
1.7478
1.7644
1.7806
1.7964
1.8119
1.8271
1.8420
1.8567
1.8712
1.8855
1.8997
1.9136
1.9274
1.9411
t
C
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
13.854bar
dm3/kg
16.88
17.39
18.01
18.59
19.15
19.69
20.22
20.73
21.22
21.71
22.19
22.65
23.11
23.56
24.01
24.45
24.88
kJ/kg
421.84
426.48
432.17
437.76
443.28
448.74
454.16
459.55
464.91
470.26
475.60
480.94
486.28
491.62
496.97
502.33
507.71
kJ/kgK
1.7086
1.7231
1.7405
1.7574
1.7739
1.7899
1.8056
1.8209
1.8360
1.8509
1.8655
1.8799
1.8941
1.9081
1.9220
1.9357
1.9493
48C
t
C
52
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
dm3/kg
15.96
16.22
16.83
17.40
17.96
18.49
19.00
19.50
19.98
20.45
20.91
21.36
21.81
22.24
22.67
23.10
23.51
kJ/kg
422.63
425.00
430.82
436.52
442.13
447.68
453.16
458.61
464.03
469.43
474.82
480.19
485.57
490.94
496.32
501.71
507.11
kJ/kgK
1.7078
1.7152
1.7331
1.7503
1.7670
1.7833
1.7992
1.8147
1.8300
1.8449
1.8597
1.8742
1.8885
1.9026
1.9166
1.9304
1.9440
48C
t
C
54
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
dm3/kg
14.29
14.65
15.22
15.76
16.28
16.77
17.24
17.70
18.15
18.59
19.01
19.43
19.84
20.24
20.63
21.02
21.41
kJ/kg
424.10
427.78
433.75
439.59
445.33
450.98
456.57
462.12
467.63
473.11
478.57
484.03
489.48
494.92
500.37
505.83
511.30
kJ/kgK
1.7062
1.7175
1.7355
1.7529
1.7698
1.7861
1.8021
1.8177
1.8329
1.8479
1.8627
1.8772
1.8915
1.9056
1.9196
1.9334
1.9470
dm3/kg
15.10
15.71
16.28
16.83
17.35
17.85
18.34
18.81
19.27
19.71
20.15
20.58
21.00
21.42
21.83
22.23
22.63
kJ/kg
423.38
429.36
435.19
440.91
446.54
452.11
457.62
463.10
468.55
473.99
479.41
484.82
490.23
495.64
501.06
506.49
511.92
kJ/kgK
1.7071
1.7254
1.7430
1.7601
1.7766
1.7927
1.8085
1.8239
1.8390
1.8538
1.8685
1.8829
1.8971
1.9111
1.9250
1.9387
1.9523
t
C
56
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
54C
dm3/kg
13.52
13.64
14.21
14.75
15.26
15.75
16.21
16.66
17.10
17.52
17.94
18.34
18.74
19.13
19.51
19.89
20.26
kJ/kg
424.79
426.05
432.20
438.18
444.03
449.78
455.45
461.07
466.64
472.18
477.70
483.20
488.69
494.17
499.66
505.14
510.64
kJ/kgK
1.7053
1.7092
1.7278
1.7456
1.7628
1.7794
1.7956
1.8114
1.8268
1.8420
1.8569
1.8715
1.8859
1.9002
1.9142
1.9281
1.9418
15.282bar
52C
14.555bar
13.179bar
46C
12.529bar
11.301bar
t
11.903bar
Solkane134a
54C
dm3/kg
12.80
13.25
13.79
14.30
14.78
15.24
15.68
16.11
16.52
16.93
17.32
17.70
18.08
18.45
18.82
19.17
19.53
kJ/kg
425.44
430.51
436.65
442.63
448.50
454.26
459.96
465.60
471.21
476.78
482.33
487.86
493.38
498.90
504.42
509.95
515.48
kJ/kgK
1.7044
1.7197
1.7380
1.7556
1.7725
1.7890
1.8050
1.8207
1.8360
1.8510
1.8658
1.8803
1.8946
1.9088
1.9227
1.9365
1.9501
27
SOLVAY FLUOR
Solkane134a Thermodynamics
Release 1.05
Disclaimer:
All statements, information and data given herein are believed to be accurate and
reliable but are presented without guarantee, warranty or responsibility of any kind,
express or implied. Statements or suggestions concerning possible use of our products
are made without representation or warranty that any such use is free of patent
infringement, and are not recommendations to infringe any patent. The user should
not assume that all safety measures are indicated, or that other measures may not be
required.
SFD-AK T/09.04/01/E
28