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Because red and ox idasi uksi occur at the same time, the above reaction is called
redox reactions.
Oxidation
and
reduction
in
terms
of
hydrogen
transfer
Definitions of oxidation and reduction in terms of hydrogen transfer has been long
and is now not much used.
Oxidation is loss of hydrogen, reduction is gain of hydrogen.
Note that what happens is the opposite of the oxygen definitions.
For example, ethanol can be oxidized to ethanal:
This definition is very important to remember. There is an easy way to help you
remember this definition. In the case of electron transfer:
A simple example
Redox
reactions
in
terms
of
electron
transfer:
Copper (II) oxide and magnesium oxide are both ionic. Being in the form of nonmetal ions. If this reaction is rewritten as an ionic equation, it turns oxide ions are
spectator ions (ions audience).
If you look at the equation above, magnesium is reducing the copper (II) by giving
electrons to neutralize the charge of copper (II).
It
can
be
said:
magnesium
is
reducing
agent
(reductant).
In contrast, the copper ions (II) electron transfer from magnesium to produce
magnesium ions. Thus, copper ions (II) acts as the oxidizing agent (oxidant).
It is rather confusing to study the oxidation and reduction in terms of electron
transfer, and learn the definition of oxidising and reducing agents in terms of
electron transfer.
Can be summarized as follows, oxidiser what role in electron transfer:
Because red and ox idasi uksi occur at the same time, the above reaction is called
redox reactions.
A simple example
Redox
reactions
in
terms
of
electron
transfer:
Copper (II) oxide and magnesium oxide are both ionic. Being in the form of nonmetal ions. If this reaction is rewritten as an ionic equation, it io n oxide is the
spectator ions (ions audience).
If you look at the equation above, magnesium is reducing the copper (II) by giving
electrons to neutralize the charge of copper (II).
It
can
be
said:
magnesium
is
reducing
agent
(reductant).
In contrast, the copper ions (II) electron transfer from magnesium to produce
magnesium ions. Thus, copper ions (II) acts as the oxidizing agent (oxidant).
It is rather confusing to study the oxidation and reduction in terms of electron
transfer, and learn the definition of oxidising and reducing agents in terms of
electron transfer.
Can be summarized as follows, oxidiser what role in electron transfer:
Example:
- The reaction between Na and Cl 2 to form NaCl
In this reaction Na release one electron which is then received by Cl
2Na + Cl2? 2NaCl or Na + Cl2? NaCl
OXIDATION NUMBERS
The oxidation number (bilok or bo) is a number that indicates the charge
contributed by the atoms of the element in the formation of molecules or ions. For
example, the NaCl formed through ionic bonds, the oxidation number of Na is +1
and the oxidation number of Cl is -1. To compound HCl formed by covalent bonds,
more electropositive H has oxidation number +1, while the more electronegative
Cl has oxidation number -1.
In general, for two bonded atoms are ionic or covalent apply:
- Atomic elements with larger electronegativity will have a negative oxidation
number.
- Atomic elements with smaller electronegativity (more electropositive) have a
positive oxidation number.
The following rules and keeping that can help determine the oxidation number of
an atom.
Rule 1:
Oxidation numbers of atoms in an element is equal to 0 (zero)
Example: bilok atoms on the elements Fe, Na, Cu, H2, Cl2, Br2, I2, O2 = 0
Rule 2:
Monoatom ion oxidation number equal to the charge on the ion.
Example - bilok Fe2 + = +2
- Bilok Na + = +1
- Bilok ion Cl = -1
- Bilok S2- ion = -2
Rule 3:
The oxidation number of IA group metal (Li, Na, K, Rb, Cs) in the compound =
+1
The oxidation number of group IIA metal (Be, Mg, Ca, Sr, Ba, Ra) in the
compound = + 2
Example - bilok Na in NaOH = +1
- Bilok K in KCl = +1
- Bilok Mg in MgO = +2
- Bilok Ca in CaCl2 = -2
Rule 4:
The oxidation number of H in the compound generally = +1
Numbers oksdasi H in a metal hydride compound = -1
Example - bilok H in HCl, H2O, NH3 = +1
- Bilok H in NaH, CaH2 = -1
Rule 5:
The oxidation number of oxygen (O) in the compound generally = -2 (oxides)
Numbers okidasi oxygen (O) in a peroxide compound = -1
The oxidation number of oxygen (O) in a peroxide compound = -
The oxidation number of oxygen (O) in a binary compound of fluoride = +2
Rule 6:
The amount of oxidation numbers in a neutral compound = 0
The amount of oxidation numbers in a polyatomic ion = charge on the ion
Example - in the compound H2SO4
2 x bilok bilok H + S + 4 x bilok O = 0
in ion Cr2O7
2 x bilok Cr + 7 x bilok O = -2
By understanding the rules above we can determine the oxidation number of an
atom in a compound or ion.
Example:
Determine the oxidation number of Cl in CaCl2
Bilok Ca = +2 (rule 3)
(Bilok Ca) + (2 x bilok Cl) = 0
2 + (2 x bilok Cl) = 0
bilok Cl = -1
Step 2
MnO4
- + 2Cl-? Mn2 + + Cl2
+7 2x (-1) +2 0
The change in oxidation state of Mn + 2 = 5 + 7 become
The change in oxidation state of Cl 2x (-1) to 0 = 2
Step 3
2MnO4
- + 10Cl- ?? 2Mn2 + + 5Cl2
The number of electrons received Mn = 5 and electrons are released Cl = 2. That
received the same number of electrons with the electrons removed, then Mn
multiplied by 2 and multiplied Cl 5.
Step 4
2MnO4
- + 10Cl- + 16H + ?? 2Mn2 + + 5Cl2 + 8H2O
On the left side there are eight oxygen atoms from 2MnO4
-, Add 8H2O in segment
right. As a result of the addition of H2O, in the right-hand side there are 16
hydrogen atoms
of 8H2O, add 16H + on the left.
In the oxidation reaction the amount of charge on the left = 2 and on the right side
= 3,
then on the right side plus 1e-.
Step 5
Cr2O7
2- + 14H + + 6e-? 2Cr3 + + 7H2O
6Fe2 +? 6Fe3 + + 6eCr2O7
2- + 14H + + 6Fe2 +? 2Cr3 + + 7H2O + 6Fe3 +
In the reduction reaction the number of electrons = 6 whereas the oxidation
reaction
number of electrons 1, then the oxidation reaction must be multiplied by six.
Now if you try to count the number of atoms and the number of charges,
whether the reaction is equivalent?
To equalize the redox reaction under alkaline conditions can
performed as described in oxidation number, which neutralizes H + with
OH-in the final stages.
Combustion Reaction
Substances around us there are that have a flammable nature, and nature is not
can burn. Any substance that can burn fuel will have a point each.
A substance will burn by itself when the agent reaches the point of fuel
due to heating. Burning substance actually involves a reaction between the
substance
with oxygen gas (O2).
Therefore, the combustion event can only happen because of the two
factors, namely materials (substances) that can be burned and the factor of oxygen
gas.
Thus, the combustion can be avoided by lowering the burning point
substances (flush with water or certain chemicals), or by blocking
Basic Concepts of Chemistry for PGSD 139
materials / substances come into contact with oxygen gas. Or vice versa, so that
the combustion occurs,
materials / substances to the point where the temperature is raised in the fuel gas
of sufficient oxygen.
Materials / substances that burn will result in the form of oxide compounds. Kind
oxide is dependent on the type of elements that make up the material / substance
concerned. Note Table 1.
The content of
ROHP
Elements of H
H2O vapor
Elements of C
Elements of S
Elements of P
Gas P2O5
Of N
NO2
Table 1
Oxide Formula Combustion (ROHP) of Material / Substance That Can Be Burned
Substances such as hydrogen gas (H2), phosphorus (P4), sulfur (S8), or carbon (C)
when burned
will produce the gases listed in Table 6.1. Materials / substances there are
contains several types of content listed, such as C and H. Example
This compound is methane (CH4), acetylene (C2H2), liquefied petroleum gas
when burned will
produce H2O vapor and CO2. On other occasions, there are materials / substances
oxidizing
(C) Na Na + + 1e- (oxidation)
(D) Ca 2+ + 2e (oxidation)
reductant
(E) Ca + O CaO (redox reaction)
(F) Fe + H2SO4 FeSO4 + H2 (redox reaction)
reducing agent oxidizer
Explanation:
Raising BO
+2 -2
Ca + O CaO
Decrease BO
0 +2 +2 0
Fe + H2SO4 FeSO4 + H2
reducing agent oxidizer
Basic Concepts of Chemistry for PGSD 148
Reducing agents = reducing agent.
Y = substance. release electrons.
Y = substance. experienced an increase of BO
alkali (alkali metal, M) is the most powerful reducing agent; whereas the halogens
(X2)
is the most powerful oxidizer. Why?
Inter alkali metal (M) itself, the Li metal was the one most difficult to let go
valence electrons whereas Rb metal easiest release valence electrons.
Thus, Li metal is the weakest reducing agent; otherwise metal Rb
is the strongest reducing agent among the alkali metals.
Another case with a halogen (X2), then the most powerful electron binding ability
among group elements are elements of F2. Means the halogen group, an element
of F2
is the most powerful oxidizer, and the elements of I2 is the weakest oxidizing.
From the foregoing, it is clear that the elements between the two groups (alkali
and halogen) most easily react with each other to form ionic compounds.
Consider the two following redox reaction:
2 Li + Cl 2 2 LiCl
2 Na + Cl 2 2 NaCl
Which reaction will easily take place?
Due to the nature of the reductant metal is stronger than metal Na Li, the second
reaction
which would be easier to take place.
nomenclature
based
on
1. Ion Binary Compounds (IA and IIA Metal goi + nonmetal + ida)
KCl
oxides
=
Na2O
potassium
chloride
Sodium
Summary
The concept of redox reactions based on the incorporation and release of oxygen.
Oxidation is the combination of oxygen with an element or compound.
Reduction is the release of oxygen from compounds.
The concept of redox reactions based on the incorporation and release of electrons.
Oxidation is the release of electrons.
Reduction is the electron acceptance.
The concept of redox reactions by oxidation number changes.
Oxidation is increase in oxidation number.
Reduction is a decrease in oxidation number.
Substances atom of the element undergoes oxidation is called reducing agent,
whereas substance atom of the element is reduced is called an oxidizing.
Oxidants are substances that undergo reduction.
Reducing agents are substances that undergo oxidation.
The oxidation number (bilok or bo) is a number that indicates
charge contributed by the atoms of the element in a molecule or ions are formed.
There are two ways to balance a redox reaction equation, namely how oxidation
numbers and half-reaction method.
Fig. 1: Model of the reaction of metal atoms with nonmetal atoms by electron
transfer (1)
In these examples, the reactions can be explained by electron transfer from metal
atoms
Fig. 2: Photo of the reaction of an iron nail with copper sulfate solution, model
drawing of the particle view (1)
Fig. 3: Model drawing of the reaction of Cl2 molecules with I-(aq) ions, K+(aq)
ions remain as spectator ions (2)
transferred, nor O atoms change their partner. If the redox idea would only be
taught as an
electron transfer from one particle to another, then instruction and results should
improve
dramatically.
Historical redox idea. Since this idea is prescribed in all guidelines and school
books, one must
consider ways of instruction that are touching the extended redox idea as little as
possible.
There is first the historically evolved definition: teachers or students can refer
Stahls Phlogiston
theory from 1690 and its refutation by the Oxidation theory of Lavoisier in 1784.
Students can
understand that historically adapted theories have been rejected later and replaced
or extended by
new theories. In their own classes, they can accept that the extension of the
oxygen transfer to
the electron transfer is legitimate.
On the other hand, in the beginning one could instruct this subject without the word
redox and use it only in the extended sense. Since oxidation (metal + oxygen
metal oxide)
and reduction (silver oxide silver + oxygen) are initially defined separately, the
redox idea
appears dispensable; the notation for the copper oxide-iron reaction is sufficient in
this way: iron
is oxidized to iron oxide, copper oxide is reduced to copper. Then, if the reaction
is described
only in words, one cannot get into difficulties with "O atoms, O2 molecules or O2ions are
changing the partner". Choosing a model drawing to show the regrouping of
particles in the
copper oxide-carbon reaction for example, you can explain the "combination of
carbon particles
with the oxygen particles and the release of copper particles" (Fig. 4).
Fig. 4: Model drawing for the reaction of copper oxide with carbon (1)
Given the decrease in mass, a sensible name for the process was made: reduction.
In what world does it make sense to call a process where electrons are gained
reduction ?
The answer from my high school chemistry teacher was , well, youre reducing
the oxidation state making it more negative. Which was a very clever answer,
completely jettisoning the inconvenient historical definition in favor of a simplistic
mathematical one. Fortunately for him, I wasnt fast or clever enough to counter
with then why isnt oxidation called addition? (Feel free to use this yourself,
however).
Result: I just memorized that reduction meant adding electrons and
oxidation meant removing electrons.
At first glance, this seems a long way away from the Gen chem definition of
oxidation being loss of electrons and reduction a gain of electrons.
But if you go back to the concept of the oxidation state, it might make some more
sense. If you just pay attention to whats happening to the oxidation state of the
carbons, you can follow along to see if its an oxidation or reduction. If the
oxidation state is becoming more negative, its a reduction (gaining electrons). If
the oxidation state is becoming more positive, its an oxidation (losing electrons).
Lets look at those examples again (putting in an extra example for fun), paying
attention to the change in oxidation state.
So is there a quick way to figure out if a carbon is being oxidized or reduced? Why
yes there is.
A reduction will result in a net increase in the number of C-H bonds, or a net
decrease in the number of C-O bonds (or equivalent, such as C-Cl, C-Br, etc).
An oxidation will result in a net decrease in the number of C-H bonds, or a net
increase in the number of C-O bonds (or equivalent).
All of these events affect the oxidation state of the carbon, and this ties back to
the concept of oxidation that I originally learned in high school: keeping track of
the gaining (and losing) of electrons.
When I finally understood this I was happy to note that the term oxidation finally
made sense again.
Reduction still didnt, but I learned to live with it and moved on. You will too.
PHOTOSYNTHSIS
Photosynthesis is a word derived from the Greek, ie photos and synthesis. Photo
itself is defined as a light while synthesis is a meaningful word combining or
merging. The word is often used in scope photosynthesis study biological sciences.
What exactly is photosynthesis? Simply put, it can be defined as the process of
making food that is made by green plants involving sunlight in it. In addition to
the sun, photosynthesis process also involves several enzymes. The process of
photosynthesis is usually carried out by plants, algae and some kinds of bacteria in
order to produce the energy that will be used in a variety of activities. The energy
is
also
called
nutrients.
The leaves on the plant has a primary function as the site of photosynthesis.
Actually, not only important for the photosynthesis of plants but also for all the
living creatures that inhabit the earth. Why? Because the oxygen that is in the earth
is mostly produced by plants. This is what makes trees often nicknamed lungs of
the planet earth. Organisms that perform photosynthesis known as Phototroph.
Photosynthesis is actually one way of carbon assimilation because in the process
of
photosynthesis,
carbon-free
and
then
tied
that
into
sugar.
The process of photosynthesis in green plants found in nature that autotrophs can
prepare their own food. Through the leaves, plants absorb carbon dioxide
molecules are also water in order to produce sugar and oxygen. Both of these
compounds will then be used as a backstop growing. The equation reaction that
occur
in
the
6H2O
6CO2
process
light
of
photosynthesis
C6H12O6
is
as
(glucose)
follows:
6O2
Plants that perform photosynthesis requires sunlight assistance. They are able to
absorb the light because they have a green substance or chlorophyll. Chlorophyll
itself is in organelles called chloroplasts section. On the leaves of plants, there are
two layers of cells called mesophyll denegan. in this section there are
approximately half a million chloroplasts scattered in every square millimeter.
Sunlight will then pass through the epidermal layer of colorless then drove towards
the mesophyll. In this section most of the photosynthetic activity takes place.
The process of photosynthesis itself is quite complex and is still in the research to
some experts. There are still many things that have not been successfully
expressed. Why this complex process? Because it involves almost all branches of
science, for example bilologi, chemistry and physics. The main organ where
photosynthesis is exactly in the stomata of the leaves or leaf mouth. The process
of photosynthesis consists of two series of reactions that the light reaction and a
dark reaction. Named because the light reaction process takes light. While it is a
dark photosynthesis reaction process that no longer involves the light but only
carbon
dioxide.
molecules and then collected at the reaction centers. Photosynthesis begins when
light begin to ionize molecules of chlorophyll and then the release of electrons.
Application of Redox Reactions in Everyday Life Redox
1. metal reaction in Processing concentrating are from the rock either physics or
chemistry then concentrated into a concentrated ore. The concentrated ore is
reduced with a reducing agent most appropriate.
3C (S) + 4Al3 + (l) + 6O-2 (l) --> 4AL (l) + 3CO2
reduction reaction
Redox 2.Reaksi In BesiRel Splicing-thermite welded rail with the process. A
mixture of aluminum and iron oxide for redox reactions ignited to heat and can
melt the surface generated rel.Reaksi:
2AL (s) + Fe2O3 (S) --> 2Fe (s) + Al2O3 (s)
Redox 3.Reaksi On Cell Battery
Pb (s) + PbO2 (aq) + 2HSO4-2 (aq) + 2H + (aq) --> 2PbSO4 (S) + 2H2O (l)
At 4.Reaksi redox battery (cell Leclanche)
Zn (s) + 2NH4 + (aq) + 2MnO2 (S) --> Zn 2+ (aq) + Mn2O3 (s) + 2NH3 (aq) +
H2O (l)
Redox 5.Reaksi In Wastewater Treatment
Electrolytes concept a.Penerapan Waste containing heavy metal (Hg + 2, Pb + 2,
Cd + 2, and Ca 2+) were reacted denganelektrolit mengndung anion (SO4-2) which
can precipitate the metal ions so that the waste water is free from water limbahPb
+ 2 (aq) + SO4-2 (aq) PbSO4 --> (S)
b.Ph Libahan LuurAkTi Luurakti teriaerb teribak containing tub that serves as
inorganic oksidatorbah terarut without the use of oxygen in the water so that the
price can be in kurangi.Zat atorganik BOD in menjadiCO2 oxidation, H2O, NH4
+ and new cell biomass. Lumpurakt process takes place in the aeration tank. In that
pool lasts oxidation of organic wastes (carbohydrate, protein, oil). Results organi
oxidation compounds are CO2, H2O, sulfate, nitrate, and phosphate. Oxygen is
obtained for olsidasi obtained from the photosynthesis process algae that live
ditangki aeration
Redox 6.Reaksi On Cell Volta (Cells Galvani) electro-chemical cells where
oxidation - reduction occurs spontaneously and produces a potential difference dI
called galvanic cell. In a galvanic cell chemical energy is converted into electrical
energy. Selgalvani also often called Volta cells. Examples baterai.Energi galvanic
cell is a cell that is in the release can be used to turn on the radio to connect a wire
from the electrode to the radio. Whole-cell copper-magnesium reaction is a redox
reaction.
Mg (s) + Cu 2+ (aq) Mg2 + (aq) + Cu (s)
Is the function of the salt bridge? When the half-reaction continues, magnesium
ions released into the solution at the anode, and copper ions move to the cathode.
Ions should be able to move both electrodes equal freedom to neutralize the
positive charge (cation Mg 2+) generated at the anode and the negative charge
(anions) are left at the cathode. Solution of the ions in the salt bridge can neutralize
the positive and negative charges in solution and prevent excess charge on the
electrode. The same redox reaction occurs when magnesium metal is put directly
in the solution of copper sulfate, the reaction is
Mg + Cu 2+ Cu ++ -->Mg2.
However, this is not because the galvanic cell electrons flow through the circuit
luar.Elektron not move directly from magnesium metal ions to the copper, forming
copper metal. This is how to make copper metal from copper ions, but not for the
generation of electricity.
Redox Reaction In Natural Gas If natural gas is burned, it will establish the
following reaction
CH4 (g) + 2O2 (g) CO2 (g) + 2H2O (g)
Redox reaction in Biological cells, for example, is the oxidation of glucose
(C6H12O6) into CO2 and oxygen to water reduction. Concise equation of cell
respiration is: C6H12O6 + 6 CO2 + 6 O2 6 H2O