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INSTITUTE OF TECHNOLOGY
Name_______________________________
Course/Section:_______________________
Q5-SET UNO
Multiple choice.
Choose the letter of the best answer to the question. For problem solving, write your solution in GIVEN,
REQUIRED and SOLUTION format. Finalize your answer on the 1stsheet of your test booklet. (3 pts each)
________1.
________2.
________3.
________4.
1.
11.
21.
2.
12.
22.
3.
13.
23.
4.
14.
24.
5.
15.
25.
6.
16.
26.
7.
17.
27.
8.
18.
28.
9.
19.
29.
10.
20.
30.
________6.
the universe.
none of these.
+297 kJ
-297 kJ
Page 1 of 3
MAPA
INSTITUTE OF TECHNOLOGY
For nos. 10 and 11,
Given the thermochemical equation 2SO2(g) + O2(g) 2SO3(g), Hrxn= 198 kJ/mol
_______10. What is the heat of reaction (Hrxn) per mole of SO2 reacted?
a.
99 kJ/mol
c.
198 kJ/mol
b.
396 kJ/mol
d.
+198 kJ/mol
_______11. How much heat is evolved when 600. g of SO2 is burned?
2
a.
5.46 x 10 kJ
c.
59,400 kJ
3
b.
928 kJ
d.
1.85 x 10 kJ
For nos. 12 to 16,
Solid sodium peroxide (Na2O2) reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas.
(Given: Hf[Na2O2(s)] = 510.9 kJ/mol; Hf[NaOH(aq)] = 469.2 kJ/mol; Hf[H2O(l)] = 285.8 kJ/mol)
_______12. What is the heat of reaction per mole O2?
a.
283.4 kJ/mol
c.
+141.7 kJ/mol
b.
141.7 kJ/mol
d.
+327.5 kJ/mol
_______13. Calculate the amount of oxygen gas (in moles) produced given that 250 L of O 2 was liberated from the
reaction of sodium peroxide and water if the reaction is carried out in an open container at 1.000 atm
pressure and 25C. (5 pts.)
a.
0.100 moles
c.
10.2 moles
b.
122 moles
d.
6.8 moles
_______14. In problem 13, How much heat is released during the process? (5 pts.)
a.
35,400 kJ
c.
3330 kJ
b.
1740 kJ
d.
2900 kJ
_______15. Based on the heat of formation of substances given above, what is the heat of reaction of the equation
8NaOH(aq) + 2O2(g) 4Na2O2(s) + 4H2O(l)
a.
+566.8 kJ/mol
c.
283.4 kJ/mol
b.
+283.4 kJ/mol
d.
655.0 kJ/mol
_______16. Given the thermochemical equation, 4Na2O2(s) + 4H2O(g) 8NaOH(aq) + 2O2(g) Hrxn= 729.6
kJ/mol, Calculate the heat of vaporization of water, H2O(l) H2O(g).
a.
111.6 kJ/mol
c.
40.70 kJ/mol
b.
253.3 kJ/mol
d.
346.2 kJ/mol
For nos. 17 to 20,
The enthalpy change when a strong acid is neutralized by strong base is 56.1 kJ/mol. In a bomb calorimeter, 12.0 mL
of 6.00 M HBr at 21.30C is mixed with 300. mL of 0.250 M NaOH, also at 21.30C. The neutralization reaction is
HBr + NaOH NaBr + H2O
_______17. Calculate the total mass of the solution. (Assume that the density of the final solution is that of water.)
a.
288 g
c.
8.825 g
b.
312 g
d.
5.825 g
o
_______18. Calculate the heat capacity of the solution in J/ C (Assume that the specific heat of the final solution is
4.18 J/gC)
a.
1204
c.
36.89
b.
1304
d.
24.35
_______19. Calculate the amount of heat generated (in kJ) during the reaction.
a.
0.168
c.
4.21
b.
8.25
d.
4.04
_______20. What will be the maximum temperature reached by the resulting solution? (Assume that there is no heat
loss to the container)
o
o
a.
27.6 C
c.
25.8 C
o
o
b.
25.9 C
d.
24.7 C
_______21. The bond enthalpy of the BrCl bond is equal to H for the reaction
BrCl(g) Br(g) + Cl(g).
Use the following data to find the bond enthalpy of the BrCl bond. (5 pts.)
Br2(l) Br2(g)
H = 30.91 kJ/mol
Br2(g) 2Br(g)
H = 192.9 kJ/mol
Cl2(g) 2Cl(g)
H = 243.4 kJ/mol
Br2(l) + Cl2(g) 2BrCl(g)
H = 29.2 kJ/mol
a.
219.0 kJ/mol
c.
14.6 kJ/mol
b.
203.5 kJ/mol
d.
438.0 kJ/mol
_______22. Potential energy is
a.
the energy stored within the structural units of chemical substances.
b.
the energy associated with the random motion of atoms and molecules.
c.
solar energy, i.e. energy that comes from the sun.
d.
energy available by virtue of an object's position.
Page 2 of 3
MAPA
INSTITUTE OF TECHNOLOGY
For nos. 23 and 24,
A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the
1.000 kg of water contained therein rose from 20.22C to 22.82C. The heat capacity of the calorimeter is 2.21 kJ/C.
The heat capacity of water = 4.184 J/gC.
_______23. Calculate the amount of heat generated during combustion (in kJ). (5 pts.)
a.
14.35
c.
9.47
b.
16.62
d.
4.18
_______24. What is the heat of combustion, in megajoules (MJ) per mole of pentane?
a.
3.02 MJ/mol
c.
3.50 MJ/mol
b.
1.99 MJ/mol
d.
0.879 MJ/mol
_______25. According to the first law of thermodynamics:
a.
Energy is neither created nor destroyed.
b.
Perpetual motion is possible.
c.
Energy is conserved in quality but not in quantity.
d.
Energy is being created as time passes. We have more energy in the universe now than when
time began.
_______26. It is the amount of heat required to raise the temperature of one gram of a substance by one degree
Celsius.
a.
Heat capacity
c.
Specific heat
b.
Calorie
d.
Energy
_______27. The enthalpy of reaction of combustion of C2H2 is described by
C2H2(g) + 5/2 O2(g) 2CO2(g) + H2O(l) Hrxn= 1299 kJ/mol
The reaction above is _________
a.
endothermic.
c.
exergic.
b.
exothermic.
d.
endogenic.
_______28. Enthalpy (H) is a thermodynamic quantity that is related to internal energy (U), pressure (P) and volume
(V). It is defined as
a.
U + PV
c.
V UP
b.
U PV
d.
V + UP
_______29. Chemical reactions in a bomb calorimeter occur at constant _______
a.
volume.
c.
moles of substances.
b.
temperature.
d.
pressure.
_______30. Given 2Al(s) + (3/2)O2(g) Al2O3(s), Hf = 1,670 kJ/mol for Al2O3 (s).
Determine H for the reaction 2Al2O3(s) 4Al(s) + 3O2(g).
a.
3,340 kJ/mol
c.
1,670 kJ/mol
b.
1,670 kJ/mol
d.
3,340 kJ/mol
Page 3 of 3