Académique Documents
Professionnel Documents
Culture Documents
Thermal
Physics
Daniel V. Schroeder
Weber State University
This collection of figures and tables is provided for the personal and classroom use of
students and instructors. Anyone is welcome to download this document and save
a personal copy for reference. Instructors are welcome to incorporate these figures
and tables, with attribution, into lecture slides and similar materials for classroom
presentation. Any other type of reproduction or redistribution, including re-posting
on any public Web site, is prohibited. All of this material is under copyright by the
publisher, except for figures that are attributed to other sources, which are under
copyright by those sources.
c
Copyright 2000,
Addison-Wesley Publishing Company
Pressure (atmospheres)
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
300
200
100
Temperature ( C)
100
Figure 1.3. Data from a student experiment measuring the pressure of a fixed
volume of gas at various temperatures (using the bulb apparatus shown in Figure 1.2). The three data sets are for three dierent amounts of gas (air) in the bulb.
Regardless of the amount of gas, the pressure is a linear function of temperature
that extrapolates to zero at approximately 280 C. (More precise measurements
show that the zero-point does depend slightly on the amount of gas, but has a
well-defined limit of 273.15 C as the density of the gas goes to zero.) Copyright
c
2000,
Addison-Wesley.
Piston area = A
vx
!v
Length = L
Volume = V = LA
Figure 1.5. A diatomic molecule can rotate about two independent axes, perpendicular to each other. Rotation about the third axis, down the length of the
c
molecule, is not allowed. Copyright 2000,
Addison-Wesley.
U = Q + W
W
Q
Figure 1.8. When the piston moves inward, the volume of the gas changes by
V (a negative amount) and
the work done on the gas
(assuming quasistatic compression) is P V . Copyc
right 2000,
Addison-Wesley.
Piston area = A
Force = F
V = A x
x
Pressure
Pressure
Area =
Area = P (Vf Vi )
P dV
Vi
Vf
Volume
Vi
Vf
Volume
Figure 1.9. When the volume of a gas changes and its pressure is constant, the
work done on the gas is minus the area under the graph of pressure vs. volume. The
c
same is true even when the pressure is not constant. Copyright 2000,
AddisonWesley.
(b)
B
A
Volume
Pressure
Pressure
(a)
P2
A
P1
D
V1
V2
Volume
c
Figure 1.10. P V diagrams for Problems 1.33 and 1.34. Copyright 2000,
Addison-Wesley.
Pressure
Isotherm
Vf
Vi
Volume
Adiabat
Pressure
Tf
Ti
Vf
Vi
Volume
7
2R
Vibration
5
2R
Rotation
CV
3
2R
Translation
10
100
1000
T (K)
Figure 1.13. Heat capacity at constant volume of one mole of hydrogen (H2 ) gas.
Note that the temperature scale is logarithmic. Below about 100 K only the three
translational degrees of freedom are active. Around room temperature the two
rotational degrees of freedom are active as well. Above 1000 K the two vibrational
degrees of freedom also become active. At atmospheric pressure, hydrogen liquefies
at 20 K and begins to dissociate at about 2000 K. Data from Woolley et al. (1948).
c
Copyright 2000,
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25
20
3R
Lead
Aluminum
15
10
Diamond
100
200
300
400
T (K)
Figure 1.14. Measured heat capacities at constant pressure (data points) for
one mole each of three dierent elemental solids. The solid curves show the heat
capacity at constant volume predicted by the model used in Section 7.5, with the
horizontal scale chosen to best fit the data for each substance. At suciently high
temperatures, CV for each material approaches the value 3R predicted by the
equipartition theorem. The discrepancies between the data and the solid curves
at high T are mostly due to the dierences between CP and CV . At T = 0 all
degrees of freedom are frozen out, so both CP and CV go to zero. Data from Y. S.
Touloukian, ed., Thermophysical Properties of Matter (Plenum, New York, 1970).
c
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Figure 1.15. To create a rabbit out of nothing and place it on the table, the
magician must summon up not only the energy U of the rabbit, but also some
additional energy, equal to P V , to push the atmosphere out of the way to make
room. The total energy required is the enthalpy, H = U + P V . Drawing by
c
Karen Thurber. Copyright 2000,
Addison-Wesley.
Area = A
Outside
T1
Inside
T2
!
2r
2r
2r
Figure 1.17. A collision between molecules occurs when their centers are separated by twice the molecular radius r. The same would be true if one molecule
had radius 2r and the other were a point. When a sphere of radius 2r moves in a
straight line of length , it sweeps out a cylinder whose volume is 4r2 . Copyright
c
2000,
Addison-Wesley.
Box 1
Box 2
Area = A
0.10
kt (W/mK)
Helium
0.08
Neon
0.06
Air
0.04
Krypton
0.02
10
15
T ( K)
20
25
Fluid
ux
Area = A
Figure 1.20. The simplest arrangement for demonstrating viscosity: two parallel
surfaces sliding past each other, separated by a narrow gap containing a fluid. If
the motion is slow enough and the gap narrow enough, the fluid flow is laminar:
At the macroscopic scale the fluid moves only horizontally, with no turbulence.
c
Copyright 2000,
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Figure 1.21. When the concentration of a certain type of molecule increases from left to right,
there will be diffusion, a net flow of molecules,
c
from right to left. Copyright 2000,
AddisonWesley.
J!
Penny
Nickel
Dime
H
H
T
H
T
H
T
H
H
H
T
T
T
H
T
T
T
H
Table 2.1. A list of all possible microstates of a set of three coins (where H
is for heads and T is for tails). Copyright
c
2000,
Addison-Wesley.
!
B
Energy
hf
1
Figure 2.2. In quantum mechanics, any system with a quadratic potential energy
function has evenly spaced energy levels separated in energy by hf , where f is the
classical oscillation frequency. An Einstein solid is a collection of N such oscillators,
c
all with the same frequency. Copyright 2000,
Addison-Wesley.
Oscillator: #1
Energy:
#2
#3
1
0
0
0
1
0
0
0
1
2
0
0
1
1
0
0
2
0
1
0
1
0
0
2
0
1
1
Oscillator: #1
Energy:
3
0
0
2
2
1
0
1
0
1
#2
#3
0
3
0
1
0
2
2
0
1
1
0
0
3
0
1
0
1
2
2
1
Table 2.2. Microstates of a small Einstein solid consisting of only three oscillators,
c
containing a total of zero, one, two, or three units of energy. Copyright 2000,
Addison-Wesley.
Solid A
NA , qA
Energy
Solid B
NB , qB
Figure 2.3. Two Einstein solids that can exchange energy with each other, isoc
lated from the rest of the universe. Copyright 2000,
Addison-Wesley.
A
1
3
6
10
15
21
28
qB
6
5
4
3
2
1
0
B
28
21
15
10
6
3
1
total = A B
28
63
90
100
90
63
28
462 = 6+61
6
100
80
total
qA
0
1
2
3
4
5
6
60
40
20
0
3 4
qA
qB
1
100 2.8 1081
300
99 9.3 1080
45150
98 3.1 1080
4545100 97 1.0 1080
3.4 108 96 3.3 1079
..
..
..
.
.
.
59 2.2 1068 41 3.1 1046
60 1.3 1069 40 5.3 1045
61 7.7 1069 39 8.8 1044
..
..
..
..
.
.
.
.
1
100 1.7 1096 0
0
1
2
3
4
..
.
total
2.8 1081
2.8 1083
1.4 1085
4.6 1086
1.1 1088
..
.
6.8 10114
6.9 10114
6.8 10114
..
.
1.7 1096
9.3 10115
7
6
total (10114 )
qA
5
4
3
2
1
0
20
40
60
80
qA
100
Multiplicity
N , q few thousand
Multiplicity
N , q few hundred
qA
Figure 2.6. Typical multiplicity graphs for two interacting Einstein solids, containing a few hundred oscillators and energy units (left) and a few thousand (right).
As the size of the system increases, the peak becomes very narrow relative to the
full horizontal scale. For N q 1020 , the peak is much too sharp to draw.
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Copyright 2000,
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qA
N
1
10
100
N!
1
3628800
9 10157
NNe
2 N
.922
3598696
9 10157
N
Error
7.7%
.83%
.083%
ln N !
0
15.1
364
N ln N
N
1
13.0
360
Error
13.8%
.89%
max
Width = q/ N
qA
Figure 2.7. Multiplicity of a system of two large Einstein solids with many
energy units per oscillator (high-temperature limit). Only a tiny fraction of the
c
full horizontal scale is shown. Copyright 2000,
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pz
Radius =
2mU
py
px
Position space
Momentum space
px
x
L
px
Lp
=
2
2
1
UA , VA , N
UB , VB , N
Figure 2.11. Two ideal gases, each confined to a fixed volume, separated by a
partition that allows energy to pass through. The total energy of the two gases is
c
fixed. Copyright 2000,
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total
UA
VA
c
Figure 2.13. A very unlikely arrangement of gas molecules. Copyright 2000,
Addison-Wesley.
Vacuum
Figure 2.14. Free expansion of a gas into a vacuum. Because the gas neither does
work nor absorbs heat, its energy is unchanged. The entropy of the gas increases,
c
however. Copyright 2000,
Addison-Wesley.
Figure 2.15. Two dierent gases, separated by a partition. When the partition
is removed, each gas expands to fill the whole container, mixing with the other
c
and creating entropy. Copyright 2000,
Addison-Wesley.
qA
SA /k
qB
187.5
186.4
185.3
..
.
2.8 1081
2.8 1083
1.4 1085
..
.
187.5
192.1
196.0
..
.
175.1
173.9
172.7
..
.
5.9 1095
4.7 1096
3.5 1097
..
.
220.5
222.6
224.6
..
.
SB /k
total
Stotal /k
0
1
2
..
.
1
300
45150
..
.
0
5.7
10.7
..
.
11
12
13
..
.
5.3 1019
1.4 1021
3.3 1022
..
.
45.4
48.7
51.9
..
.
59
60
61
..
.
2.2 1068
1.3 1069
7.7 1069
..
.
157.4
159.1
160.9
..
.
41
40
39
..
.
3.1 1046
5.3 1045
8.8 1044
..
.
107.0
105.3
103.5
..
.
6.7 10114
6.9 10114
6.8 10114
..
.
264.4
264.4
264.4
..
.
221.6
1.7 1096
221.6
qB
300
80
60
40
20
Stotal
250
Entropy (units of k)
200
SA
150
100
SB
50
0
20
40
60
80
100
qA
Energy
Enlightened
Entropy
Miserly
Entropy
Entropy
Normal
Energy
Energy
Figure 3.2. Graphs of entropy vs. energy (or happiness vs. money) for a normal
system that becomes hotter (more generous) as it gains energy; a miserly system
that becomes colder (less generous) as it gains energy; and an enlightened system
c
that doesnt want to gain energy at all. Copyright 2000,
Addison-Wesley.
SA
SB
UA,initial
UA
UB,initial
UB
Figure 3.3. Graphs of entropy vs. energy for two objects. Copyright
c
2000,
Addison-Wesley.
1500 J
500 K
300 K
SA = 3 J/K
SB = +5 J/K
Figure 3.4. When 1500 J of heat leaves a 500 K object, its entropy decreases by
3 J/K. When this same heat enters a 300 K object, its entropy increases by 5 J/K.
c
Copyright 2000,
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Q
S
Q
S
Q
S
Q
S
Q
S
Figure 3.5. Each unit of heat energy (Q) that leaves a hot object is required to
carry some entropy (Q/T ) with it. When it enters a cooler object, the amount of
c
entropy has increased. Copyright 2000,
Addison-Wesley.
!
B
Energy
+B
Down
0
B
Up
U/B
M/N
S/k
kT /B
100
99
98
97
..
.
100
98
96
94
..
.
1.00
.98
.96
.94
..
.
52
51
50
49
48
..
.
4
2
0
2
4
..
.
1
0
98
100
C/N k
1
100
4950
1.6 105
..
.
0
4.61
8.51
11.99
..
.
0
.47
.54
.60
..
.
.074
.310
.365
..
.
.04
.02
0
.02
.04
..
.
9.3 1028
9.9 1028
1.0 1029
9.9 1028
9.3 1028
..
.
66.70
66.76
66.78
66.76
66.70
..
.
25.2
50.5
50.5
25.2
..
.
.001
.001
..
.
.98
1.00
100
1
4.61
0
.47
0
.074
S/k
60
40
20
100
50
50
100
U/B
kT /B
20
10
U/N B
1
1
10
20
M/N
1
C/N k
0.5
0.4
0.3
10
0.2
5
5
10
kT /B
0.1
1
3
kT /B
7
1
tanh x
1
Figure 3.11. The hyperbolic tangent function. In the formulas for the energy
and magnetization of a two-state paramagnet, the argument x of the hyperbolic
c
tangent is B/kT . Copyright 2000,
Addison-Wesley.
0.8
Curies law
0.6
M
N
0.4
tanh(B/kT )
0.2
0.1
0.2
0.3
0.4
1/T (K1 )
0.5
0.6
UA , VA , SA
UB , VB , SB
Figure 3.13. Two systems that can exchange both energy and volume with each
c
other. The total energy and total volume are fixed. Copyright 2000,
AddisonWesley.
Stotal
UA
VA
Figure 3.14. A graph of entropy vs. UA and VA for the system shown in Figure 3.13. The equilibrium values of UA and VA are where the graph reaches its
c
highest point. Copyright 2000,
Addison-Wesley.
Step 2
Step 1
Figure 3.16. Two types of non-quasistatic volume changes: very fast compression
that creates internal disequilibrium, and free expansion into a vacuum. Copyright
c
2000,
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N links
Figure 3.17. A crude model of a rubber band as a chain in which each link can
c
only point left or right. Copyright 2000,
Addison-Wesley.
UA , NA , SA
UB , NB , SB
Figure 3.18. Two systems that can exchange both energy and particles. Copyc
right 2000,
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0
A
Particles
B
N = 3, q = 3, = 10
N = 4, q = 2, = 10
Figure 3.20. In order to add an oscillator (represented by a box) to this very small
Einstein solid while holding the entropy (or multiplicity) fixed, we must remove
c
one unit of energy (represented by a dot). Copyright 2000,
Addison-Wesley.
Type of
interaction
Exchanged
quantity
Governing
variable
thermal
energy
temperature
1
T
mechanical
volume
pressure
P
T
diusive
particles
chemical potential
Formula
S
=
U V,N
S
=
V U,N
S
=
N U,V
Table 3.3. Summary of the three types of interactions considered in this chapter,
c
and the associated variables and partial-derivative relations. Copyright 2000,
Addison-Wesley.
Hot reservoir, Th
Qh
Engine
W
Qc
Cold reservoir, Tc
(a)
(d)
Qh
(b)
(c)
Qc
Figure 4.2. The four steps of a Carnot cycle: (a) isothermal expansion at Th
while absorbing heat; (b) adiabatic expansion to Tc ; (c) isothermal compression
at Tc while expelling heat; and (d) adiabatic compression back to Th . The system
must be put in thermal contact with the hot reservoir during step (a) and with
c
the cold reservoir during step (c). Copyright 2000,
Addison-Wesley.
Pressure
Th isotherm
Adiabat
Adiabat
Tc isotherm
Volume
Hot reservoir, Th
Qh
Refrigerator
W
Qc
Cold reservoir, Tc
Ignition
Power
2
4
Compression
V2
Exhaust
1
V1
Injection/ignition
V2
V3
V1
Hot
reservoir
Th
Cold
reservoir
Tc
Qh
Regenerator
Figure 4.7. A Stirling engine, shown during the power stroke when the hot piston
is moving outward and the cold piston is at rest. (For simplicity, the linkages
c
between the two pistons are not shown.) Copyright 2000,
Addison-Wesley.
Hot reservoir
Qh
(Water)
Boiler
Pressure
Pump
Turbine
Qc
(Steam)
Turbine
Pump
1
Condenser
Boiler
Condenser
4
(Water + steam)
Volume
Cold reservoir
Figure 4.8. Schematic diagram of a steam engine and the associated P V cycle
(not to scale), called the Rankine cycle. The dashed lines show where the fluid
is liquid water, where it is steam, and where it is part water and part steam.
c
Copyright 2000,
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T
( C)
P
(bar)
Hwater
(kJ)
Hsteam
(kJ)
Swater
(kJ/K)
Ssteam
(kJ/K)
0
10
20
30
50
100
0.006
0.012
0.023
0.042
0.123
1.013
0
42
84
126
209
419
2501
2520
2538
2556
2592
2676
0
0.151
0.297
0.437
0.704
1.307
9.156
8.901
8.667
8.453
8.076
7.355
P (bar)
200
Temperature ( C)
300
400
500
600
1.0
H (kJ)
S (kJ/K)
2875
7.834
3074
8.216
3278
8.544
3488
8.834
3705
9.098
3.0
H (kJ)
S (kJ/K)
2866
7.312
3069
7.702
3275
8.033
3486
8.325
3703
8.589
10
H (kJ)
S (kJ/K)
2828
6.694
3051
7.123
3264
7.465
3479
7.762
3698
8.029
30
H (kJ)
S (kJ/K)
2994
6.539
3231
6.921
3457
7.234
3682
7.509
100
H (kJ)
S (kJ/K)
3097
6.212
3374
6.597
3625
6.903
300
H (kJ)
S (kJ/K)
2151
4.473
3081
5.791
3444
6.233
Table 4.2. Properties of superheated steam. All values are for 1 kg of fluid, and
are measured relative to liquid water at the triple point. Excerpted from Keenan
c
et al. (1978). Copyright 2000,
Addison-Wesley.
Hot reservoir
id)
Qh
Throttle
(Liqu
Throttle
Evaporator
Evaporator
(Gas)
Condenser
Pressure
Compressor
Condenser
Compressor
(Liquid + gas)
Qc
Cold reservoir
Volume
Figure 4.9. A schematic drawing and P V diagram (not to scale) of the standard
refrigeration cycle. The dashed lines indicate where the refrigerant is liquid, gas,
c
and a combination of the two. Copyright 2000,
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Pi
Pf
Figure 4.10. The throttling process, in which a fluid is pushed through a porous
c
plug and then expands into a region of lower pressure. Copyright 2000,
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P
(bar)
1.0
1.4
2.0
4.0
6.0
8.0
10.0
12.0
T Hliquid
( C)
(kJ)
26.4
18.8
10.1
8.9
21.6
31.3
39.4
46.3
16
26
37
62
79
93
105
116
Hgas
(kJ)
Sliquid
(kJ/K)
Sgas
(kJ/K)
231
236
241
252
259
264
268
271
0.068
0.106
0.148
0.240
0.300
0.346
0.384
0.416
0.940
0.932
0.925
0.915
0.910
0.907
0.904
0.902
Table 4.3. Properties of the refrigerant HFC-134a under saturated conditions (at
its boiling point for each pressure). All values are for 1 kg of fluid, and are measured
relative to an arbitrarily chosen reference state, the saturated liquid at 40 C.
c
Excerpted from Moran and Shapiro (1995). Copyright 2000,
Addison-Wesley.
Temperature ( C)
40
50
60
P (bar)
8.0
H (kJ)
S (kJ/K)
274
0.937
284
0.971
295
1.003
10.0
H (kJ)
S (kJ/K)
269
0.907
280
0.943
291
0.977
12.0
H (kJ)
S (kJ/K)
276
0.916
287
0.953
Compressor
Throttle
Heat Exchanger
Liquid
Figure 4.11. Schematic diagram of the Hampson-Linde cycle for gas liquefaction.
Compressed gas is first cooled (to room temperature is sucient if it is nitrogen
or oxygen) and then passed through a heat exchanger on its way to a throttling
valve. The gas cools upon throttling and returns through the heat exchanger to
further cool the incoming gas. Eventually the incoming gas becomes cold enough
to partially liquefy upon throttling. From then on, new gas must be added at the
c
compressor to replace what is liquefied. Copyright 2000,
Addison-Wesley.
200
150
T (K)
100
50
50
100
P (bar)
150
200
77 (liq.) 77 (gas)
1 bar
100 bar
3407
2161
100
2856
1946
Temperature (K)
200
300
5800
4442
8717
8174
400
500
600
11,635
11,392
14,573
14,492
17,554
17,575
Table 4.5. Molar enthalpy of nitrogen (in joules) at 1 bar and 100 bars.
c
Excerpted from Lide (1994). Copyright 2000,
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(300 K)
Compressor
He bath
(1 K)
Constriction
Still
(0.7 K)
Heat Exchanger
Mixing
chamber
(few mK)
He
Entropy
Low B
1
High B
Temperature
Figure 4.14. Entropy as a function of temperature for an ideal two-state paramagnet, at two dierent values of the magnetic field strength. (These curves were
plotted from the formula derived in Problem 3.23.) The magnetic cooling process
consists of an isothermal increase in the field strength (step 1), followed by an
c
adiabatic decrease (step 2). Copyright 2000,
Addison-Wesley.
Laser
Figure 4.15. An atom that continually absorbs and reemits laser light feels a
force from the direction of the laser, because the absorbed photons all come from
the same direction while the emitted photons come out in all directions. Copyright
c
2000,
Addison-Wesley.
Figure 5.1. To create a rabbit out of nothing and place it on the table, the
magician need not summon up the entire enthalpy, H = U + P V . Some energy,
equal to T S, can flow in spontaneously as heat; the magician must provide only
the dierence, G = H T S, as work. Drawing by Karen Thurber. Copyright
c
2000,
Addison-Wesley.
TS
+ PV
Figure 5.3. To separate water into hydrogen and oxygen, just run an electric
current through it. In this home experiment the electrodes are mechanical pencil
leads (graphite). Bubbles of hydrogen (too small to see) form at the negative
electrode (left) while bubbles of oxygen form at the positive electrode (right).
c
Copyright 2000,
Addison-Wesley.
P V = 4 kJ (pushing
atmosphere away)
U = 282 kJ
G = 237 kJ
(electrical work)
System
T S = 49 kJ
(heat)
Figure 5.4. Energy-flow diagram for electrolysis of one mole of water. Under ideal
conditions, 49 kJ of energy enter as heat (T S), so the electrical work required is
only 237 kJ: G = H T S. The dierence between H and U is P V =
c
4 kJ, the work done to make room for the gases produced. Copyright 2000,
Addison-Wesley.
H2
O2
H2 O
U = 316 kJ
394 kJ
(electrical work)
78 kJ
(heat)
Figure 5.6. Energy-flow diagram for a lead-acid cell operating ideally. For each
mole that reacts, the systems energy decreases by 316 kJ and its entropy increases
by 260 J/K. Because of the entropy increase, the system can absorb 78 kJ of heat
from the environment; the maximum work performed is therefore 394 kJ. (Because
no gases are involved in this reaction, volume changes are negligible so U H
c
and F G.) Copyright 2000,
Addison-Wesley.
System
Environment (reservoir)
V , U , S, P, T
2V , 2U , 2S, P, T
Figure 5.9. Two rabbits have twice as much volume, energy, and entropy as
one rabbit, but not twice as much pressure or temperature. Drawing by Karen
c
Thurber. Copyright 2000,
Addison-Wesley.
System
T ( C)
Critical point
Pressure (bar)
221
Ice
Water
Steam
0.006
273
Triple point
0.01
374
Temperature ( C)
40
20
0
0.01
25
50
100
150
200
250
300
350
374
Pv (bar)
L (kJ/mol)
0.00013
0.00103
0.00611
0.00612
0.0317
0.1234
1.013
4.757
15.54
39.74
85.84
165.2
220.6
51.16
51.13
51.07
45.05
43.99
42.92
40.66
38.09
34.96
30.90
25.30
16.09
0.00
Figure 5.11. Phase diagram for H2 O (not to scale). The table gives the vapor
pressure and molar latent heat for the solid-gas transformation (first three entries)
and the liquid-gas transformation (remaining entries). Data from Keenan et al.
c
(1978) and Lide (1994). Copyright 2000,
Addison-Wesley.
Critical point
Pressure (bar)
73.8
Liquid
Solid
Gas
5.2
Triple point
56.6
31
Temperature ( C)
T ( C)
Pv (bar)
120
100
80
78.6
60
56.6
40
20
0
20
31
0.0124
0.135
0.889
1.000
4.11
5.18
10.07
19.72
34.85
57.2
73.8
Figure 5.12. Phase diagram for carbon dioxide (not to scale). The table gives the
vapor pressure along the solid-gas and liquid-gas equilibrium curves. Data from
c
Lide (1994) and Reynolds (1979). Copyright 2000,
Addison-Wesley.
He
Solid
P (bar)
P (bar)
He
Solid
34
25.3
Helium II
(superfluid)
Helium I
(normal liquid)
Gas
2.2
Liquid
1
Gas
3.2 3.3 T (K)
Ferromagnet
External magnetic field
Type-I Superconductor
Bc
Normal
Superconducting
Tc
Magnetized up
Critical point
T
Magnetized down
Figure 5.14. Left: Phase diagram for a typical type-I superconductor. For lead,
Tc = 7.2 K and Bc = 0.08 T. Right: Phase diagram for a ferromagnet, assuming
that the applied field and magnetization are always along a given axis. Copyright
c
2000,
Addison-Wesley.
Diamond
Graphite
2.9 kJ
5
10
15
20
P (kbar)
Figure 5.15. Molar Gibbs free energies of diamond and graphite as functions of
pressure, at room temperature. These straight-line graphs are extrapolated from
low pressures, neglecting the changes in volume as pressure increases. Copyright
c
2000,
Addison-Wesley.
dP
dT
100
P (kbar)
80
Diamond
60
Graphite
40
20
Liquid
0
Figure 5.18. Cumulus clouds form when rising air expands adiabatically
and cools to the dew point (Problem 5.44); the onset of condensation slows
the cooling, increasing the tendency of the air to rise further (Problem 5.45).
These clouds began to form in late morning, in a sky that was clear only
an hour before the photo was taken. By mid-afternoon they had developed
c
into thunderstorms. Copyright 2000,
Addison-Wesley.
Figure 5.19. When two molecules come very close together they repel each other
strongly. When they are a short distance apart they attract each other. Copyright
c
2000,
Addison-Wesley.
P/Pc
2
V /Vc
Figure 5.20. Isotherms (lines of constant temperature) for a van der Waals fluid.
From bottom to top, the lines are for 0.8, 0.9, 1.0, 1.1, and 1.2 times Tc , the
temperature at the critical point. The axes are labeled in units of the pressure
and volume at the critical point; in these units the minimum volume (N b) is 1/3.
c
Copyright 2000,
Addison-Wesley.
P/Pc
G
4
3
7
0.8
2,6
0.6
7
3
2
1
0.4
0.2
0.4
0.6
0.8 P/Pc
3 V /Vc
Figure 5.21. Gibbs free energy as a function of pressure for a van der Waals fluid
at T = 0.9Tc . The corresponding isotherm is shown at right. States in the range
c
2-3-4-5-6 are unstable. Copyright 2000,
Addison-Wesley.
V
2
4
5
B
6
P
1.2
1.2
1.0
1.0
0.8
0.8
0.6
0.6
0.4
0.4
0.2
0.2
1
4
V
Critical point
Liquid
Gas
0.2
0.4
0.6
0.8
1.0
Figure 5.23. Complete phase diagrams predicted by the van der Waals model.
The isotherms shown at left are for T /Tc ranging from 0.75 to 1.1 in increments
of 0.05. In the shaded region the stable state is a combination of gas and liquid.
The full vapor pressure curve is shown at right. All axes are labeled in units of
c
the critical values. Copyright 2000,
Addison-Wesley.
Mixed
Figure 5.24. A collection of two types of molecules, before and after mixing.
c
Copyright 2000,
Addison-Wesley.
GB
Smixing
No mixing
GA
Ideal mixing
0
Pure A
1
Pure B
0
Pure A
1
Pure B
Figure 5.25. Before mixing, the free energy of a collection of A and B molecules
is a linear function of x = NB /(NA + NB ). After mixing it is a more complicated
function; shown here is the case of an ideal mixture, whose entropy of mixing
is shown at right. Although it isnt obvious on this scale, the graphs of both
Smixing and G (after mixing) have vertical slopes at the endpoints. Copyright
c
2000,
Addison-Wesley.
G
T =0
Umixing
0
Pure A
1
Pure B
Highest T
0
Figure 5.26. Mixing A and B can often increase the energy of the system; shown
at left is the simple case where the mixing energy is a quadratic function (see
Problem 5.58). Shown at right is the free energy in this case, at four dierent
c
temperatures. Copyright 2000,
Addison-Wesley.
Homogeneous
mixture
Unmixed
a and b
0
xa
xb
70
Homogeneous mixture
60
50
T
40
30
20
10
0
Pure A
1
Pure B
0
Water
1
Phenol
Figure 5.28. Left: Phase diagram for the simple model system whose mixing
energy is plotted in Figure 5.26. Right: Experimental data for a real system, water
+ phenol, that shows qualitatively similar behavior. Adapted with permission from
Alan N. Campbell and A. Jean R. Campbell, Journal of the American Chemical
Society 59, 2481 (1937). Copyright 1937 American Chemical Society. Copyright
c
2000,
Addison-Wesley.
xa
xb 1
G
T > TB
T3
Liquid
Gas
T = TB
T2
TA < T < TB
T1
T = TA
TB
T3
Gas
T2
T < TA
Liquid
T1
TA
0
Pure A
1
Pure B
0
Pure A
1
Pure B
Figure 5.30. The five graphs at left show the liquid and gas free energies of an
ideal mixture at temperatures above, below, at, and between the boiling points
TA and TB . Three graphs at intermediate temperatures are shown at right, along
c
with the construction of the phase diagram. Copyright 2000,
Addison-Wesley.
92
90
Gas
88
T (K)
86
84
82
Liquid
80
78
76
0
Pure N2
0.2
0.4
0.6
x
0.8
1.0
Pure O2
Figure 5.31. Experimental phase diagram for nitrogen and oxygen at atmospheric
pressure. Data from International Critical Tables (volume 3), with endpoints adc
justed to values in Lide (1994). Copyright 2000,
Addison-Wesley.
1600
1500
Liquid
T ( C)
1400
1300
1200
Solid
1100
0.0
Albite
0.2
0.4
x
0.6
0.8
1.0
Anorthite
T3
Liquid
T2
TB
T
TA
T2
T1
Liquid
T3
+ liquid
+ liq.
Eutectic
T2
T1
G
T1
0
Pure A
1
Pure B
Figure 5.33. Construction of the phase diagram of a eutectic system from free
c
energy graphs. Copyright 2000,
Addison-Wesley.
10
300
T ( C)
Liquid
200
+ liquid
+ liq.
100
0
Sn
10
20
30 40 50 60 70
Weight percent lead
80
90
100
Pb
Figure 5.34. Phase diagram for mixtures of tin and lead. From Thaddeus B.
Massalski, ed., Binary Alloy Phase Diagrams, second edition (ASM International,
c
Materials Park, OH, 1990). Copyright 2000,
Addison-Wesley.
Liquid
Liquid
Figure 5.35. Free energy diagrams for Problems 5.71 and 5.72. Copyright
c
2000,
Addison-Wesley.
Semipermeable
membrane
Pure solvent
Solution
P1
P2
Without
mixing
With
mixing
0
Reactants
Equilibrium
1
Products
Figure 5.42. The dissolution of a gas in a liquid, such as oxygen in water, can be treated as a
chemical reaction with its own equilibrium conc
stant. Copyright 2000,
Addison-Wesley.
Boltzmann Statistics
Reservoir
Energy = UR
Temperature = T
System
Energy = E
Energy
1.5 eV
3.4 eV
s2
s1
13.6 eV
Figure 6.2. Energy level diagram for a hydrogen atom, showing the three lowest
energy levels. There are four independent states with energy 3.4 eV, and nine
c
independent states with energy 1.5 eV. Copyright 2000,
Addison-Wesley.
Probability, P(s)
kT
2kT
3kT
E(s)
Figure 6.3. Bar graph of the relative probabilities of the states of a hypothetical
system. The horizontal axis is energy. The smooth curve represents the Boltzmann
distribution, equation 6.8, for one particular temperature. At lower temperatures
it would fall o more suddenly, while at higher temperatures it would fall o more
c
gradually. Copyright 2000,
Addison-Wesley.
H Ca H Fe H
Ca Fe H
Mg
16 Cyg A
5800 K
UMa
9500 K
380
400
420
440
Wavelength (nm)
460
480
Figure 6.4. Photographs of the spectra of two stars. The upper spectrum is of
a sunlike star (in the constellation Cygnus) with a surface temperature of about
5800 K; notice that the hydrogen absorption lines are clearly visible among a
number of lines from other elements. The lower spectrum is of a hotter star (in Ursa
Major, the Big Dipper), with a surface temperature of 9500 K. At this temperature
a much larger fraction of the hydrogen atoms are in their first excited states, so
the hydrogen lines are much more prominent than any others. Reproduced with
permission from Helmut A. Abt et al., An Atlas of Low-Dispersion Grating Stellar
c
Spectra (Kitt Peak National Observatory, Tucson, AZ, 1968). Copyright 2000,
Addison-Wesley.
Energy
7 eV
4 eV
Energy
12!
j=3
6!
2!
0
j=2
j=1
j=0
kT /! = 30
kT /! = 3
10
12
14
Figure 6.7. Bar-graph representations of the partition sum 6.30, for two dierent
temperatures. At high temperatures the sum can be approximated as the area
c
under a smooth curve. Copyright 2000,
Addison-Wesley.
q
q
Figure 6.8. To count states over a continuous variable q, pretend that theyre
c
discretely spaced, separated by q. Copyright 2000,
Addison-Wesley.
Figure 6.9. The partition function is the area under a bar graph whose height
2
is the Boltzmann factor, e cq . To calculate this area, we pretend that the bar
c
graph is a smooth curve. Copyright 2000,
Addison-Wesley.
u(x)
D(v)
Probability = area
v1
v2
Figure 6.11. A graph of the relative probabilities for a gas molecule to have
various speeds. More precisely, the vertical scale is defined so that the area under
the graph within any interval equals the probability of the molecule having a speed
c
in that interval. Copyright 2000,
Addison-Wesley.
vz
Area = 4v 2
vy
vx
D(v)
Dies exponentially
Parabolic
v
vmax v
vrms
U fixed
T fixed
S = k ln
F = kT ln Z
Figure 6.14. For an isolated system (left), S tends to increase. For a system at
constant temperature (right), F tends to decrease. Like S, F can be written as
c
the logarithm of a statistical quantity, in this case Z. Copyright 2000,
AddisonWesley.
=
2
2
1
3 =
2L
3
2 =
2L
2
1 = 2L
L
Quantum Statistics
Reservoir
UR , NR
T,
System
E, N
Figure 7.1. A system in thermal and diusive contact with a much larger reservoir, whose temperature and chemical potential are eectively constant. Copyright
c
2000,
Addison-Wesley.
Fe2+
Fe2+
Fe2+
E=0
E = 0.7 eV
E = 0.85 eV
Figure 7.2. A single heme site can be unoccupied, occupied by oxygen, or occupied by carbon monoxide. (The energy values are only approximate.) Copyright
c
2000,
Addison-Wesley.
Normal gas, V /N ! vQ
Quantum gas, V /N vQ
Figure 7.4. In a normal gas, the space between particles is much greater than the
typical size of a particles wavefunction. When the wavefunctions begin to touch
c
and overlap, we call it a quantum gas. Copyright 2000,
Addison-Wesley.
Reservoir
System
Figure 7.5. To treat a quantum gas using Gibbs factors, we consider a system
consisting of one single-particle state (or wavefunction). The reservoir consists
c
of all the other possible single-particle states. Copyright 2000,
Addison-Wesley.
1
nFD = occupancy
Low T
High T
0
Figure 7.6. The Fermi-Dirac distribution goes to 1 for very low-energy states
and to zero for very high-energy states. It equals 1/2 for a state with energy ,
falling o suddenly for low T and gradually for high T . (Although is fixed on
this graph, in the next section well see that normally varies with temperature.)
c
Copyright 2000,
Addison-Wesley.
Boltzmann
Bose-Einstein
1
Fermi-Dirac
+ kT
Figure 7.7. Comparison of the Fermi-Dirac, Bose-Einstein, and Boltzmann distributions, all for the same value of . When ( )/kT 1, the three distributions
c
become equal. Copyright 2000,
Addison-Wesley.
Energy
q=0
q=1
q=2
q=3
nFD
1
= !F
Figure 7.9. At T = 0, the Fermi-Dirac distribution equals 1 for all states with
c
< and equals 0 for all states with > . Copyright 2000,
Addison-Wesley.
nz
nmax ny
nx
nz
dn
n=
n d
n sin d
ny
nx
Figure 7.12. The double star system Sirius A and B. Sirius A (greatly overexposed
in the photo) is the brightest star in our
night sky. Its companion, Sirius B, is hotter but very faint, indicating that it must
be extremely smalla white dwarf. From
the orbital motion of the pair we know
that Sirius B has about the same mass as
our sun. (UCO/Lick Observatory photo.)
c
Copyright 2000,
Addison-Wesley.
g(!)
!F
g(!)
g(!)nFD (!)
!F
Figure 7.14. At nonzero T , the number of fermions per unit energy is given by
the density of states times the Fermi-Dirac distribution. Because increasing the
temperature does not change the total number of fermions, the two lightly shaded
areas must be equal. Since g() is greater above F than below, this means that the
chemical potential decreases as T increases. This graph is drawn for T /TF = 0.1; at
c
this temperature is about 1% less than F . Copyright 2000,
Addison-Wesley.
d nFD
d!
5kT
/!F
1
kT /!F
1
2
g(!)
Gap
Valence
band
Conduction
band
!v
!F
!c
Figure 7.17. The periodic potential of a crystal lattice results in a densityof-states function consisting of bands (with many states) and gaps
(with no states). For an insulator or a semiconductor, the Fermi energy
lies in the middle of a gap so that at T = 0, the valence band is completely
c
full while the conduction band is completely empty. Copyright 2000,
Addison-Wesley.
E = kT
E = kT
Total energy = kT
E = kT
1.4
1.2
1.0
x3
0.8
1
0.6
ex
0.4
0.2
2
6
x = !/kT
10
12
Figure 7.19. The Planck spectrum, plotted in terms of the dimensionless variable
x = /kT = hf /kT . The area under any portion of this graph, multiplied by
8(kT )4 /(hc)3 , equals the energy density of electromagnetic radiation within the
corresponding frequency (or photon energy) range; see equation 7.85. Copyright
c
2000,
Addison-Wesley.
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0
3
11
f (10
4
s
R d
R
c dt
Figure 7.23. The photons that escape now were once somewhere within a hemispherical shell inside the box. From a given point in this shell, the probability of
c
escape depends on the distance from the hole and the angle . Copyright 2000,
Addison-Wesley.
Box of photons
Blackbody
Sunlight
Atmosphere
Ground
n=
n=3
n=2
n=1
nz
nmax ny
nx
Figure 7.27. The sum in equation 7.106 is technically over a cube in n-space
whose width is 3 N . As an approximation, we instead sum over an eighth-sphere
c
with the same total volume. Copyright 2000,
Addison-Wesley.
C/T (mJ/K2 )
8
6
Gold
Silver
Copper
8 10 12 14 16 18
T 2 (K2 )
1.0
0.8
CV
3N k
0.6
Debye model
0.4
Einstein model
0.2
0.2
0.4
0.6
0.8
1.0
T /TD
Figure 7.29. The Debye prediction for the heat capacity of a solid, with the
prediction of the Einstein model plotted for comparison. The constant in the
Einstein model has been chosen to obtain the best agreement with the Debye
model at high temperatures. Note that the Einstein curve is much flatter than the
c
Debye curve at low temperatures. Copyright 2000,
Addison-Wesley.
Ground
state:
Spin
wave:
Wavelength
Density of states
Bose-Einstein
distribution
g(!)
Particle distribution
nBE (!)
kT
kT
N
N0
Nexcited
Tc
Figure 7.32. Number of atoms in the ground state (N0 ) and in excited states,
for an ideal Bose gas in a three-dimensional box. Below Tc the number of atoms
c
in excited states is proportional to T 3/2 . Copyright 2000,
Addison-Wesley.
/kTc
Tc
T
0.4
0.8
Single-particle states
!0
!
(for T < Tc )
kTc
Figure 7.34. Schematic representation of the energy scales involved in BoseEinstein condensation. The short vertical lines mark the energies of various singleparticle states. (Aside from growing closer together (on average) with increasing
energy, the locations of these lines are not quantitatively accurate.) The condensation temperature (times k) is many times larger than the spacing between the
lowest energy levels, while the chemical potential, when T < Tc , is only a tiny
c
amount below the ground-state energy. Copyright 2000,
Addison-Wesley.
T = 200 nK
T = 100 nK
T 0
Distinguishable particles
Identical bosons
Excited states
(E kT )
Ground state
(E = 0)
Figure 7.36. When most particles are in excited states, the Boltzmann factor for
the entire system is always very small (of order e N ). For distinguishable particles,
the number of arrangements among these states is so large that system states of
this type are still very probable. For identical bosons, however, the number of
c
arrangements is much smaller. Copyright 2000,
Addison-Wesley.
2.0
1.5
CV
Nk
1.0
0.5
0.5
1.0
1.5
2.0
2.5
3.0
T /Tc
f (r)
u(r)
kT = 0.5u0
kT = u0
r0
kT = 2u0
2r0
r
u0
r0
2r0
2
0
2
B(T )
r03
, u0 = 0.00057 eV)
He (r0 = 2.97 A
Ne (r0 = 3.10
A, u0 = 0.00315 eV)
, u0 = 0.0105 eV)
Ar (r0 = 3.86 A
6
8
A, u0 = 0.0027 eV)
H2 (r0 = 3.29
, u0 = 0.0185 eV)
CO2 (r0 = 4.35 A
10
A, u0 = 0.0127 eV)
CH4 (r0 = 4.36
12
1
10
kT /u0
100
Figure 8.2. Measurements of the second virial coecients of selected gases, compared to the prediction of equation 8.36 with u(r) given by the Lennard-Jones
function. Note that the horizontal axis is logarithmic. The constants r0 and u0
have been chosen separately for each gas to give the best fit. For carbon dioxide, the poor fit is due to the asymmetric shape of the molecules. For hydrogen
and helium, the discrepancies at low temperatures are due to quantum eects.
Data from J. H. Dymond and E. B. Smith, The Virial Coefficients of Pure Gases
and Mixtures: A Critical Compilation (Oxford University Press, Oxford, 1980).
c
Copyright 2000,
Addison-Wesley.
i=1
si = 1
"n < 1
s
tanh("ns)
"n > 1
Stable
s
Stable solution
Stable
s
Unstable
Figure 8.7. Graphical solution of equation 8.50. The slope of the tanh function
at the origin is n. When this quantity is less than 1, there is only one solution,
at s = 0; when this quantity is greater than 1, the s = 0 solution is unstable but
c
there are also two nontrivial stable solutions. Copyright 2000,
Addison-Wesley.
program ising
size = 10
T = 2.5
initialize
for iteration = 1 to 100*size^2 do
i = int(rand*size+1)
j = int(rand*size+1)
deltaU(i,j,Ediff)
if Ediff <= 0 then
s(i,j) = -s(i,j)
colorsquare(i,j)
else
if rand < exp(-Ediff/T) then
s(i,j) = -s(i,j)
colorsquare(i,j)
end if
end if
next iteration
end program
subroutine deltaU(i,j,Ediff)
T = 10
T = 5
T = 4
T = 3
T = 2.5
T = 2
T = 1.5
T = 1
Figure 8.9. Graphical output from eight runs of the ising program, at successively lower temperatures. Each black square represents an up dipole and each
white square represents a down dipole. The variable T is the temperature in
c
units of /k. Copyright 2000,
Addison-Wesley.
Figure 8.10. A typical state generated by the ising program after a few billion
iterations on a 400 400 lattice at T = 2.27 (the critical temperature). Notice that
there are clusters of all possible sizes, from individual dipoles up to the size of the
c
lattice itself. Copyright 2000,
Addison-Wesley.
++++++++
Voltmeter
Ammeter
Figure A.1. Two experiments to study the photoelectric eect. When an ideal
voltmeter (with essentially infinite resistance) is connected to the circuit, electrons
accumulate on the anode and repel other electrons; the voltmeter measures the
energy (per unit charge) that an electron needs in order to cross. When an ammeter
is connected, it measures the number of electrons (per unit time) that collect on the
c
anode and then circulate back to the cathode. Copyright 2000,
Addison-Wesley.
Laser
Figure A.3. These images were produced using the beam of an electron microscope. A positively charged wire was placed in the path of the beam, causing the
electrons to bend around either side and interfere as if they had passed through
a double slit. The current in the electron beam increases from one image to the
next, showing that the interference pattern is built up from the statistically distributed light flashes of individual electrons. From P. G. Merli, G. F. Missiroli,
c
and G. Pozzi, American Journal of Physics 44, 306 (1976). Copyright 2000,
Addison-Wesley.
(x)
(x)
x=a
x=b
Figure A.4. Wavefunctions for states in which a particles position is well defined (at x = a and x = b, respectively). When a particle is in such a state, its
c
momentum is completely undefined. Copyright 2000,
Addison-Wesley.
(x)
(x)
x
(x)
Real part
Imaginary part
(x)
(x)
Figure A.7. Other possible wavefunctions for which neither the position nor the
c
momentum of the particle is well defined. Copyright 2000,
Addison-Wesley.
(x)
Real part
Imaginary part
Figure A.8. A wavepacket, for which both x and px are defined approximately
but not precisely. The width of the wavepacket is quantified by x, technically
the standard deviation of the square of the wavefunction. (As you can see, x is
c
actually a few times smaller than the full width.) Copyright 2000,
AddisonWesley.
V (x)
3 (x)
E4
2 (x)
E3
1 (x)
E2
x
E1
0
Figure A.9. A few of the lowest energy levels and corresponding definite-energy
c
wavefunctions for a particle in a one-dimensional box. Copyright 2000,
AddisonWesley.
V (x)
2 (x)
x
E5
E4
1 (x)
E3
E2
E1
0 (x)
E0
x
Figure A.10. A few of the lowest energy levels and corresponding wavefunctions
c
for a one-dimensional quantum harmonic oscillator. Copyright 2000,
AddisonWesley.
300
310
320
Wavelength (nm)
330
340
350
360
4
3
2
1
0
7
6
5
4
3
2
1
0
V (r)
Continuum
E3 = 1.5 eV
9 states
E2 = 3.4 eV
E1 = 13.6 eV
4 states
1 state
Figure A.12. Energy level diagram for a hydrogen atom. The heavy curve is
the potential energy function, proportional to 1/r. In addition to the discretely
spaced negative-energy states, there is a continuum of positive-energy (ionized)
c
states. Copyright 2000,
Addison-Wesley.
Lz = 2
h
z
Lz =
h
Lz =
h
Lz = 0
! =
|L|
Lz = 0
h
Lz =
h
Lz =
2h
! =
|L|
h
Lz = 2
6h
Mathematical Results
ex
Area =
1
x2
to is
dr
r
+ d
r d
(n)
6
4
2
2
4
6
Figure B.3. The gamma function, (n). For positive integer arguments, (n) =
(n 1)!. For positive nonintegers, (n) can be computed from equation B.12, while
for negative nonintegers, (n) can be computed from equation B.14. Copyright
c
2000,
Addison-Wesley.
ln x
10
Figure B.4. The area under the bar graph, up to any integer n, equals ln n!.
When n is large, this area can be approximated by the area under the smooth
c
curve of the logarithm function. Copyright 2000,
Addison-Wesley.
xn ex
nn en
Gaussian
approximation
Figure B.5. The function xn e x (solid curve), plotted for n = 50. The area
under this curve is n!. The dashed curve shows the best Gaussian fit, whose area
c
gives Stirlings approximation to n!. Copyright 2000,
Addison-Wesley.
r sin
rd
f (x)
Figure B.7. A square-wave function with period 2 and amplitude /4. The
Fourier series for this function yields values of (n) when n is an even integer.
c
Copyright 2000,
Addison-Wesley.
Reference Data
Physical Constants
k = 1.381 10
= 8.617 10
23
5
J/K
eV/K
NA = 6.022 10
23
R = 8.315 J/molK
h = 6.626 10
34
Js
= 4.136 10
15
eVs
G = 6.673 10
11
Nm2 /kg2
e = 1.602 10
19
me = 9.109 10
31
kg
mp = 1.673 10
27
kg
c = 2.998 10 m/s
8
Unit Conversions
1 atm = 1.013 bar = 1.013 105 N/m2
= 14.7 lb/in2 = 760 mm Hg
(T in C) = (T in K)
(T in F) =
1 R=
9
5 (T
5
9 K
273.15
in C) + 32
1 cal = 4.186 J
1 Btu = 1054 J
1 eV = 1.602 10
1 u = 1.661 10
19
27
kg
The atomic number (top left) is the number of protons in the nucleus. The atomic mass (bottom) is weighted by isotopic abundances in the earths
surface. Atomic masses are relative to the mass of the carbon-12 isotope, defined to be exactly 12 unified atomic mass units (u). Uncertainties range
from 1 to 9 in the last digit quoted. Relative isotopic abundances often vary considerably, both in natural and commercial samples. A number in
parentheses is the mass of the longest-lived isotope of that elementno stable isotope exists. However, although Th, Pa, and U have no stable isotopes,
they do have characteristic terrestrial compositions, and meaningful weighted masses can be given. For elements 110112, the mass numbers of known
isotopes are given. From the Review of Particle Physics by the Particle Data Group, The European Physical Journal C3, 73 (1998).
1
18
IA
VIIIA
Hydrogen
1.00794
IIA
Li 4
13
IIIA
Be
Lithium
Beryllium
6.941
9.012182
11
Na 12 Mg
Magnesium
22.989770
24.3050
IIIB
K 20
Ca 21
Potassium
Calcium
39.0983
40.078
37
Rb 38
4
IVB
Sc 22
Y 40
Yttrium
85.4678
87.62
88.90585
Ba
VB
Ti 23
47.867
44.955910
Sr 39
Strontium
Cs 56
5771
91.224
Hafnium
132.90545
137.327
nides
178.49
Radium
Actinide
series
10
VIII
Fe 27
Co 28
57
La 58
138.9055
140.116
89
Ac 90
Ar
Aluminum
Silicon
Phosph.
Sulfur
Chlorine
Argon
IB
IIB
26.981538
28.0855
30.973761
32.066
35.4527
39.948
Cu 30
Zn 31
Ga 32
Ge 33
As 34
Se 35
Br 36
Kr
65.39
69.723
72.61
74.92160
78.96
79.904
83.80
Os 77
106.42
Ir 78
186.207
190.23
192.217
195.078
Hassium
Nd 61 Pm 62
Np 94
Cd 49
In 50
Sn 51
Silver
Cadmium
Indium
Tin
107.8682
112.411
114.818
118.710
Au 80
Gold
Tl 82
Te 53
Antimony Tellurium
121.760
Pb 83
Mercury
Thallium
Lead
200.59
204.3833
207.2
196.96655
111
Hg 81
Sb 52
127.60
Bi 84
Bismuth
Xenon
126.90447
131.29
At 86
Astatine
Sm 63
Eu 64
151.964
Gd 65
Thorium
Protactin.
(227.027747)
232.0381
231.03588
238.0289
Dy 67
Ho 68
Er 69 Tm 70
Yb 71
Lu
Gadolin.
Terbium
Dyspros.
Holmium
Erbium
Thulium
Ytterbium
Lutetium
157.25
158.92534
162.50
164.93032
167.26
168.93421
173.04
174.967
Pu 95 Am 96 Cm 97
Actinium
(277)
Tb 66
Curium
Bk 98
Berkelium
Cf 99
Californ.
Einstein.
Rn
Radon
112
(272)
Xe
Iodine
Po 85
Polonium
I 54
Meitner.
Samarium Europium
150.36
Ag 48
Pt 79
180.9479
U 93
20.1797
Cl 18
63.546
Platinum
Pa 92
18.9984032
S 17
12
Pd 47
Iridium
Th 91
15.9994
P 16
58.6934
Rh 46
102.90550
(144.912745)
14.00674
Si 15
58.933200
Ru 45
101.07
144.24
12.0107
Al 14
55.845
Osmium
140.90765
10.811
13
Krypton
Re 76
Prometh.
Neon
Bromine
(97.907215)
Pr 60
Fluorine
Selenium
95.94
Praseodym. Neodym.
Oxygen
Arsenic
Rhenium
Ce 59
Cerium
Nitrogen
German.
Lanthanum
Carbon
Gallium
Tc 44
Bohrium
Ne
Boron
Zinc
Rhodium Palladium
Seaborg.
4.002602
F 10
Copper
Tantalum Tungsten
VIIA
O 9
Nickel
Ruthen.
183.84
VIA
N 8
Helium
Cobalt
Technet.
W 75
VA
C 7
He
17
Iron
Molybd.
Ta 74
IVA
16
11
Ni 29
(223.019731) (226.025402)
Lanthanide
series
VIIB
51.9961 54.938049
92.90638
Hf 73
72
Lantha-
Francium
Cr 25 Mn 26
Nb 42 Mo 43
Zirconium Niobium
Barium
Fr 88
VIB
V 24
50.9415
Zr 41
Cesium
87
Rubidium
55
15
B 6
Sodium
19
14
Fermium
Mendelev.
Nobelium
Lr
Lawrenc.
(237.048166) (244.064197) (243.061372) (247.070346) (247.070298) (251.079579) (252.08297) (257.095096) (258.098427) (259.1011) (262.1098)
f G (kJ)
S (J/K)
CP (J/K)
V (cm3 )
0
2594.29
2590.27
2587.76
0
2443.88
2442.66
2440.99
28.33
83.81
93.22
96.11
24.35
121.71
122.72
124.52
9.99
44.09
51.53
49.90
154.84
20.79
C (graphite)
C (diamond)
CH4 (g)
C2 H6 (g)
C3 H8 (g)
C2 H5 OH (l)
C6 H12 O6 (glucose)
CO (g)
CO2 (g)
H2 CO3 (aq)
HCO3 (aq)
0
1.895
74.81
84.68
103.85
277.69
1273
110.53
393.51
699.65
691.99
0
2.900
50.72
32.82
23.49
174.78
910
137.17
394.36
623.08
586.77
5.74
2.38
186.26
229.60
269.91
160.7
212
197.67
213.74
187.4
91.2
8.53
6.11
35.31
52.63
73.5
111.46
115
29.14
37.11
5.30
3.42
Ca2+ (aq)
CaCO3 (calcite)
CaCO3 (aragonite)
CaCl2 (s)
542.83
1206.9
1207.1
795.8
553.58
1128.8
1127.8
748.1
53.1
92.9
88.7
104.6
81.88
81.25
72.59
36.93
34.15
51.6
Cl2 (g)
Cl (aq)
0
167.16
0
131.23
223.07
56.5
33.91
136.4
17.3
Cu (s)
33.150
24.44
7.12
Fe (s)
27.28
25.10
7.11
Substance (form)
Al (s)
Al2 SiO5 (kyanite)
Al2 SiO5 (andalusite)
Al2 SiO5 (sillimanite)
Ar (g)
58.4
Substance (form)
f H (kJ)
f G (kJ)
S (J/K)
CP (J/K)
0
217.97
0
285.83
241.82
0
203.25
0
237.13
228.57
130.68
114.71
0
69.91
188.83
28.82
20.78
0
75.29
33.58
He (g)
126.15
20.79
Hg (l)
76.02
27.98
0
46.11
0
16.45
191.61
192.45
29.12
35.06
240.12
411.15
3935.1
3030.9
261.91
384.14
3711.5
2852.1
59.0
72.13
207.40
133.5
46.4
50.50
205.10
160.0
146.33
20.79
O2 (g)
O2 (aq)
OH (aq)
0
11.7
229.99
0
16.4
157.24
205.14
110.9
10.75
29.38
Pb (s)
PbO2 (s)
PbSO4 (s)
0
277.4
920.0
0
217.33
813.0
64.81
68.6
148.5
26.44
64.64
103.2
SO24 (aq)
HSO4 (aq)
909.27
887.34
744.53
755.91
20.1
131.8
293
84
910.94
1449.36
856.64
1307.67
41.84
215.13
44.43
468.98
H2 (g)
H (g)
H+ (aq)
H2 O (l)
H2 O (g)
N2 (g)
NH3 (g)
Na+ (aq)
NaCl (s)
NaAlSi3 O8 (albite)
NaAlSi2 O6 (jadeite)
Ne (g)
SiO2 ( quartz)
H4 SiO4 (aq)
V (cm3 )
18.068
14.81
1.2
27.01
100.07
60.40
148.5
18.3
22.69