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INTRODUCTION
By using industrial residues as secondary raw materials,
the concrete industry can play an important role in sustainable
development. Ground blast-furnace slag is used as an admixture
in concrete or as an additive in the manufacture of portland slag
cements in countries where large amounts of blast-furnace slag
is available as a by-product.1 Numerous studies on the properties
of cement and concrete, including ground blast-furnace slag as
an admixture, were carried out to investigate the fresh
and hardened concrete properties. Much research has been
conducted to date on the hydraulic binding properties of ground
blast furnace slag.2-5 Also, durability characteristics of concrete
containing blast-furnace slag have been investigated by many
researchers. Alkali-silica reactivity, resistance to chloride
penetration, freezing, and deicing salt resistance can be shown as
examples of such characteristics.6-10
It is reported by Stutterheim11 that blast-furnace slag first
became an industrial product; the ground-granulated blastfurnace slag (GGBFS) was used as a partial replacement to
portland cement between 1947 and 1952. The research on
this subject led to the production of the concrete containing
GGBFS as binding material.12 It was established that an
improvement in the compressive and flexural strength of the
concrete was achieved by adding mineral filler.13
The strength of concrete containing GGBFS depends on
the fineness of slag, activity index, and slag/cement ratio in
mixtures.14 Neville15 has stated that workability of concrete
increases with the decrease in water absorption ratio and
bleeding using slightly ground blast-furnace slag in concrete.
Corrosion occurs more slowly in slag concrete than in
fly-ash concrete and its dry unit weight decreases by
approximately 5%. 16
ACI Materials Journal/May-June 2006
203
named C1, the second one, C2. Only a single type of sand (0
to 7 mm [0 to 0.276 in.]) was used and replaced with
NGGBFS in C1 as fine aggregate. Two different types of
fine aggregates in 0 to 3 mm (0 to 0.118 in.) and 0 to 7 mm
(0 to 0.276 in.) sizes were used in the C2 group. In this group,
NGGBFS replaced only subtype aggregate in 0 to 7 mm
(0 to 0.276 in.) sizes. Table 3 gives the mixture proportions of
concrete in this study. The extent of this study is limited with
C25/30 concrete class, which is classified in TS-EN 206-1.19
The 0 to 7 mm (0 to 0.276 in.) sand was replaced by
NGGBFS in five steps in terms of volume percentages,
which are 0, 25, 50, 75, and 100% (full replacement) in both
groups. The NGGBFS/sand ratio represents the volumetric
percentage of NGGBFS in the mixture with respect to
volume of 0 to 7 mm (0 to 0.275 in.) sand. A modified
polymer-based chemical admixture was added to the both
groups by 0.6% of cement content by weight.
Ninety specimens were prepared and cast into 150 x 150 x
150 mm (5.906 x 5.906 x 5.906 in.) molds for compressive
strength tests. Thirty specimens were produced for flexural
strength tests using 100 x 100 x 500 mm (3.93 x 3.93 x
9.69 in.) prism molds. They were demolded after 24 hours
and kept immersed in water for an additional 27 days. The
specimens for the 360-day test were stored in a room of the
laboratory with a temperature of 20 C (68 F) and a relative
humidity of 90% for 24 hours. The compressive strength test
was conducted on Day 7, 28, and 360. Flexural strength
values were measured only on the 28th day. The flexural
S
0.66
MnO TiO2
0.83
0.68
Fe
P2 O 3
0.70
0.37
C2
204
Cement, kg (lb)
350 (772)
Water,
L (gal.)
190 (50.2)
Crushed stone
Sand (0 to 3 mm), Sand (0 to 7 mm),
Chemical
(4 to 22 mm), kg (lb)
kg (lb)
kg (lb)
GBFS, kg (lb) admixture, %
835 (1841)
927 (2044)
0.6
25
350 (772)
190 (50.2)
835 (1841)
695 (1532)
183 (403)
50
350 (772)
190 (50.2)
835 (1841)
464 (1023)
365 (805)
0.6
75
100
350 (772)
350 (772)
190 (50.2)
190 (50.2)
835 (1841)
835 (1841)
232 (511)
548 (1208)
730 (1609)
0.6
0.6
0
25
350 (772)
350 (772)
190 (50.2)
190 (50.2)
835 (1841)
835 (1841)
377 (831)
377 (831)
570 (1257)
428 (944)
112 (247)
0.6
0.6
50
75
350 (772)
350 (772)
190 (50.2)
190 (50.2)
835 (1841)
835 (1841)
377 (831)
377 (831)
285 (628)
143 (315)
225 (496)
337 (743)
0.6
0.6
100
350 (772)
190 (50.2)
835 (1841)
377 (831)
449 (990)
0.6
0.6
28 days
360 days
15.47 (2.24)
14.83 (2.15)
33.19 (4.81)
31.54 (4.57)
44.07 (6.39)
41.57 (6.03)
5.15 (0.75)
4.71 (0.68)
12.0 (1.86)
12.7 (1.97)
5.81
6.25
2.42 (0.151)
2.36 (0.147)
50
75
12.24 (1.78)
10.92 (1.58)
26.86 (3.90)
24.01 (3.48)
35.45 (5.14)
31.76 (4.61)
4.29 (0.62)
3.98 (0.58)
13.8 (2.14)
16.8 (2.60)
6.88
7.65
2.25 (0.140)
2.20 (0.137)
100
0
9.66 (1.40)
15.57 (2.26)
20.45 (2.97)
32.47 (4.71)
27.04 (3.92)
43.65 (6.33)
3.56 (0.52)
5.16 (0.75)
18.6 (2.88)
8.59 (1.33)
9.15
5.54
2.19 (0.137)
2.44 (0.152)
25
50
14.79 (2.15)
14.30 (2.07)
32.06 (4.65)
31.19 (4.52)
42.96 (6.23)
42.15 (6.11)
5.05 (0.73)
4.92 (0.71)
10.9 (1.69)
9.28 (1.44)
5.16
5.75
2.41 (0.150)
2.38 (0.149)
75
100
13.78 (2.00)
12.83 (1.86)
30.24 (4.39)
26.71 (3.87)
40.59 (5.89)
35.99 (5.22)
4.75 (0.69)
4.42 (0.64)
9.45 (1.46)
10.7 (1.66)
6.48
7.68
2.34 (0.146)
2.32 (0.145)
C2
Average compressive
strength after burning,
MPa (ksi)
0
25
40.4 (5.86)
40.2 (5.83)
31.2 (4.53)
24.2 (3.51)
50
75
31.3 (4.54)
24.4 (3.54)
26.6 (3.86)
18.5 (2.68)
100
0
25.2 (3.65)
39.7 (5.76)
13.7 (1.99)
34.1 (4.95)
25
50
37.5 (5.44)
37.6 (5.45)
34.1 (4.95)
36.2 (5.25)
75
100
35.9 (5.21)
33.3 (4.83)
33.7 (4.89)
29.8 (4.32)
Concrete GBFS/sand
type
ratio, %
C2
Saturated unit
weight,
kg/m3 (lb/ft3)
0
25
C1
C1
GBFS/sand ratio,
%
Compressive strength,
MPa (ksi)
Before
After
freezingfreezingGBFS/
Loss in
Concrete sand and-thawing and-thawing strength,
cycle
cycle
ratio, %
MPa (ksi)
type
0
32.07 (4.74) 34.93 (5.07) 2.86 (0.41)
C1
C2
Variation
(% of
control
sample)
8.19
25
1.88
50
17.89
75
0
51.90
7.86
25
50
4.92
1.31
75
2.56
Qav /(Coulomb)
Chloride permeability
0
25
2016.27
1319.94
Moderate
Low
50
1347.03
Low
Coarse
Fine
aggregate aggregate
(4 to
(0 to
22 mm) GBFS
7 mm)
Property
Unit
kg/m3
(lb/ft3)
1612
(100.6)
1660
(103.6)
1052
(65.7)
kg/m3
(lb/ft3)
1835
(114.5)
1786
(111.5)
1236
(77.2)
Specific gravity
2.64
2.68
2.08
%
%
7.5
7
3.8
0.24
10
Other impurities
Color
5.2
9.4
Primrose
yellow
5
207
REFERENCES
1. ACI Committee 233, Ground Granulated Blast-Furnace Slag as a
Cementitious Grout in Concrete (ACI 233R-95), American Concrete Institute,
Farmington Hills, Mich., 1995, 18 pp.
2. Smolczyk, H. G., The Effect of Chemistry of Slag on the Strength of
Blast Furnace Slag Cements, Zement-Kalk-Gips, V. 31, No. 6, 1978,
pp. 294-296.
3. Mantel, D. G., Investigation into the Hydraulic Activity of Five
Granulated Blast Furnace Slags with Eight Different Portland Cements,
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Ankara, Turkey, 1992, 19 pp. (in Turkish)
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