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Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem. 2004, 49(2), 764
Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem. 2004, 49(2), 765
Conclusions
The long-term automotive and aircraft related technological
benefits can be derived from fundamental understanding of fuel
thermal stability issues such as, free radical autoxidation mechanism,
establishing a global chemistry model, understanding of fuel-metal
surface interactions, and developing additive packages to increase the
thermal stability of gasoline, diesel, and jet fuels. Research and
development efforts in these areas will help eliminate the operational
problems associated with carbon deposit accumulation on various
components of fuel delivery and combustion systems in internal
combustion engines.
References
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3117-3122.
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R. W. Grosser, R. W., SAE Paper, 1999-01-3690.
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30
Gasoline
25
25
20
20
15
15
10
10
Jet
Diesel
0
0
10
12
14
16
18
20
22
24
26
Carbon Number
Sulfur Compounds
Initial Hydrocarbon
f.r.r.
+ Metal Surface
Lighter
hydrocarbons
Products
Metal sulfide formation
(Ni1-xS, Fe1-xS, Co1-xS, CrS)
(fast reaction)
Heavier hydrocarbons
f.r.r
Surface roughening
(sulfide crystals)
Cyclized intermediates
Polymerization
High molecular
weight
Surface
Condensation
f.r.r
Tar
Surface
carbon
Bulk particles
Metal dusting
(particle removal)
Surface carbon
(filamentous);
ordered
Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem. 2004, 49(2), 766
Volume Percent
30
Mass Percent