Académique Documents
Professionnel Documents
Culture Documents
TW TEST
TOPICS:ATOMIC STRUCTURE
MARKS: 65
DATE: 26/08/12
SECTION-I
This section contains 10multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONLY ONE is correct.
(+3, - 1)
1.
2.
3.
4.
For which of the following electron distributions in ground state, the Paulis exclusion principle is
violated?
5.
6.
7.
The ionisation potential of hydrogen atom is 13.6 eV. The energy required to remove an electron in
the n 2 state of the hydrogen atom is
(a) 3.4 eV
(b) 6.8eV
(c) 13.6 eV
(d) 27.2 eV
8.
9.
The total spin and magnetic moment for the atom with atomic number 24 are:
3
3
(a) 3, 48 BM
(b) 3, 35 BM
(c) , 48 BM
(d) , 35 BM
2
2
10.
The important principles that do not help in assigning electronic configuration to atoms are
(a) Aufbau rule
(b) Hunds rule
(c) Heisenberg uncertainty principle
(d) Paulis exclusion principle
SECTION-II
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONE OR MORE is/are correct.
(+3, 0)
11.
The isotone(s) of
(a)
12.
77
32
Ge
76
32
Ge is/are
(b)
77
33
As
(c)
77
34
As
(c) Electrons
(d)
78
34
Se
(d) Photons
13.
14.
The energy of an electron in the first energy level of H atom is 13.6eV . The possible energy value
(s) of the excited state (s) for the electron in He is (are).
(a) 54.4 eV
(b) 13.6 eV
(c) 3.4eV
(d) 6.4eV
15.
A hydrogen-like species in ground state absorbs n photons having the same energy and its emits
exactly n photons when electrons transition take placed. Then, the energy of the absorbed photon
may be
(a) 91.8eV
(b) 40.8eV
(c) 48.4 eV
(d) 54.4 eV
16.
An electron has spin quantum number (s) 1 2 and magnetic quantum number is 1 . It can be
present in
(a) s orbital
(b) d orbital
(c) p orbital
(d) f orbital
17.
SECTION-III
(Paragraph Type)
This section contains 2 groups of questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
(+3, -1)
o
The characteristic X-ray wavelength for the lines of K series in elements X and Y are 9.87 A and
o
18.
19.
(c) 12
(d) 16
(c) 8
(d) 12
SECTION-IV
This section contains 2 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled. (+4, 0)
20.
21.
h
. Into how many
2
DATE: 26/08/12
1. a
2. c
3. a
4. c
5. b
6. a
7. a
8. b
9. a
10. c
11. b,d
12. a,b
13. a,c
14. b,c
15. a,b
16. b,c,d
17. a,b,c,d
18. c
19. a
20. 1
21. 5
(c)
l = 1 , therefore p orbitals
3.
(a)
(b)
wave function
9.
(a)
Atomic number 24
Configuration is [Ar] 3d 5 , 4s1 , n = 6
1
Total spin 6 3
2
Magnetic moment n n 2 6 6 2
48 BM
11.
(b, d)
Species having the same number of neutrons are called isotones.
76
32
Neutrons
Ge
34
77
33
As
34
12.
(a, b)
The atomic nucleus contains protons and neutrons.
14.
(b, c)
78
34
Se
34
13.6 4
n2
n 2, 3, 4... for excited state
E He
15.
(a, b)
Li He
2
19.
(a)
v
0.75
4.9 10 7
[You will get to know about this]
v 4.9 107 Z 0.75 Z
For 9.87 A v
Zx
0.3 1018
0.75 12
4.9 107
o
For 14.6 A v
Zy
20.
c
3 108
0.3 1018
10
9.87 10
3 108
0.2 1018
10
14.6 10
0.2 108
0.75 10
4.9 107
1
He 1s 2 ; n 1; l = 0; m = 0;s = 1 2, 1 2
1 1
Sum 1 1
2 2