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TW TEST
TOPIC: ATOMIC STRUCTURE
MARKS: 69
DATE: 28/06/13
SECTION-I
This section contains 12 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct.
(+3, - 1)
1.
With increasing quantum number, the energy difference between adjacent orbits of hydrogen atom
(A) increases
(B) decreases
(C) remains constant
(D) first increases followed by a decrease
2.
A photon of 300 nm is absorbed by a gas and then emits two photons. One photon has a wavelength
496 nm then the wavelength of second photon is
(A) 757
(B) 857
(C) 957
(D) 657
3.
l (l 1)
h
2
5.
Photoelectric emission is observed from a surface for frequencies 1 and 2 of incident radiations (1
> 2). If the maximum kinetic energy of photoelectrons in the two cases are in the ratio of 2 : 1, then
threshold frequency v0 is given by
1
21 2
2 2 1
1
(A) 2
(B)
(C)
(D) 2
2 1
2 1
2 1
2
6.
The ratio of (E2 E1) to (E4 E3) for the hydrogen atom is approximately equal to
(A) 11
(B)12
(C)15
(D)10
7.
(B) 4 times
(C) 2 times
(D)
1
times
2
8.
An element with atomic number 20 will be placed in the period of the periodic table
(A) 5
(B) 4
(C) 3
(D) 2
9.
If electrons are excited to 4th shell in He+ ion, the number of wavelengths emitted by electrons during
deexcitation are
(A) 4
(B) 5
(C) 6
(D) 7
10.
11.
12.
(D) n and l
If the shortest wavelength of H atom in Lyman series is x, the longest wavelength in the Balmer
series of He+ would be
36x
x
5x
9x
(A)
(B)
(C)
(D)
4
9
5
4
SECTION-II
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct.
(+4, 1)
13.
(D) When sodium metal is dissolved in liquid NH3, blue solution is formed.
14.
(D) All
15.
16.
A sample of hydrogen like atoms in ground state absorbs n photons having the same energy and it
emits exactly n photons when electronic transition takes place. Then, the energy of the absorbed
photon may be
(A) 91.8 eV
(B) 40.8 ev
(C) 48.4 eV
(D) 54.4 eV
17.
18.
The electronic configuration of an element is 1s2, 2s22p6, 3s23p63d5,4s1. This represents its
SECTION-III
(Paragraph Type)
This section contains 3 groups of questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONLY ONE is correct.
(+3, -1)
The wave functions for any 1-electron system is given by = k ekr where k and k are constants.
19.
What is the ratio of finding the electron at the nucleus to the probability of finding the electron at a0
(A) e
(B) e2
(C) 1/e2
(D) Zero
20.
Which of the following is the correct representation of plot radial probability (4r2R2) in Y-axis vs
distance from the nucleus in X-axis for 1-elelectron of 4d-atomic orbital?
Y
(A)
(B)
2 2
4 r R
(C)
(D)
2 2
4 r R
21.
2 2
4 r R
2 2
4 r R
The distance from the nucleus of the radial node of 2s-electron of Li2+ ion is
(A) 0.67a0
(B) 2a0
(C) a0
(D) 0.5a0