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HIGH-TEMPERATURE
SUPERCONDUCTORS
T
he discovery of high-temother factor, that will deterOur understanding of vortex matter in mine
perature superconducthe success of these
superconductors has grown dramatically technological applications in
tors1 has stimulated dramatic
growth
in
our
in the last decade, creating new horizons the long term. Many of the
understanding of the physics
potential applications dein fundamental science and potential
of quantized vortex lines.
mand high current densities
commercial applications.
These superconductors exwith minimal energy dissiclude magnetic fields weaker
pation, a requirement that
than a lower critical field
necessitates the immobiGeorge W. Crabtree and David R. Nelson lization, or pinning, of vorHcl < 10"2 tesla. Stronger
fields penetrate as an array
tices against the driving
of vortices, each consisting of
Lorentz forces induced by
exactly one quantum of flux
current flow. In earlier
(<o = hc/2e) surrounded in the plane perpendicular to the days, the knowledge needed to improve the performance
field by circulating supercurrents that extend radially a
of superconductors was generated primarily by materials
few hundred nanometers. The behavior of vortices domiscientists and engineers working empirically on specific
nates many physical properties of high-temperature suproblems. Now, a much more fundamental and compreperconductors up to the upper critical field Hc2 ~ 102 tesla,
hensive picture of vortex physics has emerged, to the point
where superconductivity gives way to normal metallic
where general principles developed in the last few years
behavior and magnetic fields penetrate uniformly.
can be used to understand and control vortex behavior.
Encompassing both fundamental science and commerWe know, for example, that vortex pinning is inticial technology, the behavior of vortices promises to permately linked to the layered structure of high-Tc cuprates
manently alter the way we think about superconductivity
(illustrated in the upper right of figure 2). The double
and its potential applications. Of all the new physics
copper oxide (CuO2) planes that contain most of the
generated by high-temperature superconductors, vortex
superelectrons and define the vortex properties are sepabehavior with its richness and complexity is perhaps the
rated by "blocking layers" of normal metallic or insulating
most unexpected and the most rapidly advancing.
material, which act as potential barriers against the tunVortices in superconductors provide a highly accessineling of superelectrons between planes. If the coupling
ble example of flexible one-dimensional objects interacting
between layers is weak compared to thermal energies, the
through a simple potential in the presence of controlled
vortex lines behave more like sheets of "pancake vortices"
disorder. These wandering lines of magnetic flux display
that interact strongly within each layer but only weakly with
complex equilibrium behavior reflecting liquid, crystalline
neighboring layers. Pancake vortices are difficult to pin
and glassy phases. In addition, they can be subjected to
because mobile pancakes in one layer can slip past pinned
an external driving force through the application of a
pancakes in adjacent layers. Thus, a key element in
transport current, allowing steady states of driven vortex
improving superconducting performance is strengthening
motion to be established and explored. Like the equilibthe vortex coupling between adjacent CuO2 double layers.
rium phases, these dynamic phases display remarkable
Ways of implementing this strategy include reducing the
complexity and subtlety, including several types of plastic
CuO2 layer separation, metallizing the blocking layers by
and elastic motion separated by novel dynamical phase
chemical substitution and introducing extended "columnar
transitions.
defects" that pin vortex lines across many superconducting
Technology has embraced the potential of high-templanes.
perature superconductors, with more than 15 companies
actively involved in developing products that range from
Equilibrium vortex phases
high-current bulk wires and tapes (see figure 1) to thin
The richly detailed equilibrium behavior of vortex phases
film devices. It is materials performance, more than any
in high-temperature superconductors arises from the competition of four energies:
D> Thermal energy favors a vortex liquid of lines or panGEORGE CRABTREE is a senior scientist in the materials science
cakes.
division ofArgonne National Laboratory in Argonne, Illinois,
D> Vortex interaction energy favors a perfect vortex lattice.
and theme leader for vortices and critical currents in the NSF
O
Pinning energy favors an amorphous or glassy solid.
Science and Technology Center for Superconductivity.
O Coupling energy between layers controls the formation
DAVID NELSON is Mallinckrodt Professor ofPlrysics and a
of vortex lines from weakly interacting pancake vortices
professor of applied physics at Harvard University in
in adjacent layers.
Cambridge, Massachusetts.
Remarkably, all four energies can be the same order
38
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PHYSICS TODAY
FIGURE 1. FLEXIBLE MULTIFILAMENT SUPERCONDUCTING WIRE made from Bi2Sr2CaCu2O8 (BSCCO) superconductor in silver
sheathing. The wire is made by the powder-in-tube process, in which superconducting powder is put into an array of holes in
a silver rod (shown in the center of the picture), which is then rolled and heat treated to produce a flat, flexible wire with hundreds or thousands of filaments. (Photo courtesy of American Superconductor Corp.)
of magnitude in high-temperature superconductors, leading to an unprecedented variety of liquid and solid phases
and transitions among them. The term "vortex matter"
emphasizes that vortices are comparable in complexity
and diversity to conventional atomic or molecular matter.
Vortex matter provides an excellent laboratory for
exploring general phase-transformation behavior. Experimentally, all the relevant parameters can be varied over
wide ranges: the areal vortex density over many orders
of magnitude by changing the magnetic field; thermal
fluctuations through the temperature; the pinning disorder through controlled irradiation; and the coupling energy
between CuO2 planes through the choice of material.
Furthermore, vortex interactions with each other and with
an external driving current are known rather precisely,
allowing one to do analytical theory and numerical simulations with essentially no uncontrolled approximations.
This combination of accessibility, diversity of phases and
simplicity of interaction is difficult to find in conventional
matter composed of atoms and molecules. Qualitatively
new physics arises, moreover, because the basic degrees
of freedom can be lines instead of points.
Figure 2 is a generic phase diagram for single-crystal
cuprate materials in the absence of pinning. The basic
layered structure of the cuprates is illustrated in the upper
right. For simplicity, we assume a field oriented along
the c-axis, perpendicular to the CuO2 planes, which contain the a and b directions. The magnetic induction B,
which is proportional to the vortex density in the ab plane,
is plotted because demagnetizing corrections in the usual
platelet crystals ensure that B (rather than the magnetic
field H) is held fixed in most experiments. The famous
Abrikosov vortex lattice, which exists at all temperatures
PHYSICS TODAY
39
FIGURE 2. EQUILIBRIUM
z
o
y
_J
Q
Z
U
w
Z
TEMPERATURE 7
APRIL 1997
PHYSICS TODAY
65
70
75
80
85
TEMPERATURE (kelvin)
90
95
[r(z)] =
b
0.3
NORMLAJLIZED RESIS
Ji (**W ] i
(1)
Pre-irradiation
hharmonic
i
fii potential
il k
confining
k ~dd2V/dr
0.2 -
0.1 -
^Post-irradiation
\.
Post-anneal
S\
n
0.89
0.94
0.90
0.91
0.92
0.93
NORMALIZED TEMPERATURE T/Tc
358.9
Ur,
w h e r e aQ =
ao
358.5
43.15
43.20
43.25
43.30
TEMPERATURE (kelvin)
43.35
1/2
Note that the slope of the melting curve Tm(B) predicted by the
Lindemann formula (equation 2) is indeed negative: At higher
fields the spatial fluctuations required for melting are reduced.
The soft, long-range nature of the logarithmic repulsion between
vortex lines is crucial: For potentials of the form V(r) \/rn,
a conventional melting curve with dTm/dB > 0 (and a denser
crystal phase) appears whenever n > 2.
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PHYSICS TODAY
41
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PHYSICS TODAY
where H w = - 5 X ;
XA>)
Z ( l i / l )
nBli3
DOUBLE-SIDED
TRIANGULATION of
PHYSICS TODAY
43
Solid
Liquid
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PHYSICS TODAY
Elastic
motion
m
j
0
MH
Plastic motion
TEMPERATURE
presence of twin boundaries. 2 Wandering vortex lines
have many other important consequences that can be
explored with an analogy between vortex trajectories and
the world lines of quantum mechanical bosons, as sketched
in box 2 on page 43.
ROWER AMPLIFIERS
References
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2. G. Blatter, M. V. Feigel'man, V. B. Geshkenbein, A. I. Larkin,
V. M. Vinokur, Rev. Mod. Phys. 66, 1125 (1994).
3. V. B. Geshkenbein, M. V. Feigel'man, A. I. Larkin, Physica C
167, 177 (1990). E. Frey, D. R. Nelson, D. S. Fisher, Phys. Rev.
B 49, 9723(1994).
4. E. Br6zin, D. R. Nelson, A. Thiaville, Phys. Rev. B 31, 7124
(1985).
5. H. Safar et al, Phys. Rev. Lett. 69, 3370 (1992).
6. W. K Kwok et ai, Phys. Rev. Lett. 72, 1092 (1994).
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V. M. Vinokur, Nature 375, 373 (1995).
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(1996). U. Welp, J. A. Fendrich, W. K. Kwok, G. W. Crabtree,
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Righi, G. Nieva, F. de la Cruz, Phys. Rev. Lett. 76, 4034 (1996).
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T. Giamarchi, P. Le Doussal, Phys. Rev. Lett. 76, 3408 (1996).
15. F. Nori, Science 271, 1373 (1996). M. J. Higgins, S. Bhattacharya, Physica C 257, 232 (1996).
16. P. Thorel, R. Kahn, Y. Simon, D. Cribier, J. Physique 34, 447
(1973). U. Yaron et al, Nature 376, 753 (1995).
17. D. R. Nelson, H. S. Seung, Phys. Rev. B 39, 9153 (1989).
18. S. Yoon, Z. Yao, H. Dai, C. M. Lieber, Science 270, 270 (1995).
APPLICATION
Uhrasound/EMI
RF Power Source
Plasma / Heating
NMR / MRI
FREQUENCY [Hz]
20k-400 M
50 k ~ 800 M
13.65/27.12/40.86 M
5 M - 800 M
POWER |\VJ
10-3 k
100 - 10 k
100-5 k
50-3 k
3022AA
100k~400M
1 W
30 dB
0.5dB
-20dB
+ 5 dB MAX
4029A
100k~350M
10W
40 dB
ldB
-20dB
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4749A
1M-250M
50 W
47 dB
1.5dB
- 2 0 dB
+ 5dBMAX
5059A
5M-220M
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50 dB
I.5dB
-20dB
+ 5dBMAX
CW / Pulse Operation
Stable for Any Load
Wide Band
Low Distortion
Compact Design
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MAGNETIC FIELD
MEASUREMENT
3 Axis Fluxgate Magnetometers
Measure magnetic fields from
2 x l O n T t o 10 4 T
Highly stable - offset drift
less than 1 0 9 T / C
Small probe size - 3 orthogonal
axes in probe size of r f xl"x2.625"
Simultaneous analog outputs
for all axes
Offset Capability:
The APS520A also has
precision 3 axis offset
capability with a full
scale range of + l x l 0 4 T
APS520A
APS520
415-965-0500
Fax 415-965-0404
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45