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Article history:
Received 9 November 2009
Received in revised form 23 August 2010
Accepted 4 October 2010
Available online 30 October 2010
Keywords:
Biomass
Empty fruit bunch
Gasication
Hydrogen
Yield
Energy source
a b s t r a c t
A study on gasication of empty fruit bunch (EFB), a waste of the palm oil industry, was investigated. The
composition and particle size distribution of feedstock were determined and the thermal degradation
behaviour was analysed by a thermogravimetric analysis (TGA). Then uidized bed bench scale gasication unit was used to investigate the effect of the operating parameters on EFB air gasication namely
reactor temperature in the range of 7001000 C, feedstock particle size in the range of 0.31.0 mm
and equivalence ratio (ER) in the range of 0.150.35. The main gas species generated, as identied by
a gas chromatography (GC), were H2, CO, CO2 and CH4. With temperature increasing from 700 C to
1000 C, the total gas yield was enhanced greatly and reached the maximum value (92 wt.%, on the
raw biomass sample basis) at 1000 C with big portions of H2 (38.02 vol.%) and CO (36.36 vol.%). Feedstock particle size showed an inuence on the upgrading of H2, CO and CH4 yields. The feedstock particle
size of 0.30.5 mm, was found to obtain a higher H2 yield (33.93 vol.%), and higher LHV of gas product
(15.26 MJ/m3). Equivalence ratio (ER) showed a signicant inuence on the upgrading of hydrogen production and product distribution. The optimum ER (0.25) was found to attain a higher H2 yield
(27.31 vol.%) at 850 C. Due to the low efciency of bench scale gasication unit the system needs to
be scaling-up. The cost analysis for scale-up EFB gasication unit showed that the hydrogen supply cost
is RM 6.70/kg EFB ($2.11/kg = $0.18/Nm3).
2010 Elsevier Ltd. All rights reserved.
1. Introduction
Dependence on fossil fuels as the main energy sources has led
to serious energy crisis and environmental problems. Therefore,
due to the environmental considerations as well as the increasing
demand for energy in the world, more attention has been paid to
develop new energy sources [1]. Owing to that, there has been
interest in the utilization of biomass for production of environmental friendly biofuels. As known, biomass is a CO2 neutral resource in
the life cycle, while CO2 is a primary contributor to the global
greenhouse effect. Hence, increasing attention is being paid to biomass as a substitute for fossil fuel to reduce the global greenhouse
effect, particularly under the commitment of the Kyoto Protocol.
Biomass used as an energy resource can be efciently achieved
by thermo-chemical conversion technology: pyrolysis, gasication
or combustion. Gasication process is one of the most promising
thermo-chemical conversion routes to recover energy from biomass. During gasication process, biomass is thermal decomposed
to small quantities of char and ash, liquid oil and high production
of gaseous products under limited presence of oxygen following
Eq. (1). The yields of end products of gasication and the composition of gases are dependent on several parameters including temperature, biomass species, particle size, heating rate, operating
pressure and reactor conguration [2].
1556
Currently, oil palm biomass (shell, ber and EFB) can be converted to the high-value products via thermo-chemical conversion processes. Yang et al. [21] have investigated the use of the
palm oil wastes as a feedstock to produce hydrogen-rich gas via
pyrolysis process in xed bed reactor. The authors reported that
the palm oil wastes could be ideal biomass sources for biofuels
production The total gas yield was enhanced by increasing reactor
temperature with the maximum 70 wt.% of gas yield achieved
per raw biomass sample with good portions of H2 (33.49 vol.%).
Kelly-Yong et al. [29] have studied the thermodynamic analysis
of hydrogen production from oil palm biomass in gasication
reaction using supercritical water (SCW) technology. The authors
reported that the utilization of SCW medium in biomass gasication can directly deal with high moisture content of biomass
(>50%). Therefore, preliminary treatment such as biomass drying
could be avoided which will automatically reduce the operating
cost of the process. In addition, the feasibility study of obtaining
hydrogen from palm oil biomass (0.117 kg H2 kg1 biomass) was
obtained. Abdullah et al. [30] investigated the fast pyrolysis of
EFB using 150 g/h uidized-bed reactor to produce bio-oil. The results showed that the maximum bio-oil production was 55.1 wt.%
at 450 C at only 1.03 s vapor residence time.
This study focuses on using EFB, a waste from the palm oil
industry as a feedstock material using air gasication process in
bench scale uidized bed gasier. Different operation conditions
namely reactor temperature, feedstock particle size and equivalence ratio will be investigated to achieve an improved performance of EFB conversion to energy with a high yield of
hydrogen-rich gas.
Table 1
Particle size distribution of EFB.
Feed particle size (mm)
Mass fraction
22
50
28
Measured (wt.%)
Cellulose
Hemicellulose
Lignin
Asha
Extractivesa
22.24
20.58
30.45
8.28
18.45
Elemental analysis
C
H
N
S
Ob
46.62
6.45
1.21
0.035
45.66
Proximate analysis
Mad
Vad
Ad
FCad
Caloric value (MJ/kg)
5.18
82.58
3.45
8.79
17.02
3. Experimental procedure
A uidized bed bench scale gasication unit operating at atmospheric pressure was employed for all runs. Fig. 1 shows a schematic diagram of this unit, which consists of three main systems:
reactor (gasication reactor and heating furnace), condenser and
purication (condenser, glass wool lter and dryer) and gas storage
(gasbags). The reactor is a cylindrical conguration made of stainless steel with a length of 600 mm and a diameter of 40 mm. Three
thermocouples were inserted in the middle of the heating furnace,
middle of the reactor tube and bottom of the reactor tube, respectively. Biomass was fed into the reactor by a feeder on the top of
the reactor, which were continuously carried out at a constant ow
1557
Fig. 1. Schematic diagram of biomass air gasication in a uidized bed: (1) lab-scale gratier, (2) electric furnace, (3) air pump, (4) biomass feeder, (5) ange, (6)
thermocouples, (7) air distributor, (8) temperature recorder, (9) gas discharge, (10) water cooler, (11) ice trap, (12) cooling water supply, (13) glass wool lter, (14) fuel gas
sampling point, and (15) gas ow meter.
1558
ture content, followed by big peaks around 300 C, which are indicative to the decomposition of cellulose and hemicellulose, while
the humps apparent around 450 C are indicative to the decomposition of lignin. Similar weight loss rate was observed in other researches [32,33]. The distinction between hemicellulose and
cellulose breakdowns was not fully understood but it had been
established that hemicellulose broke down at lower temperature
compared to cellulose [34].
C O2 ! CO2
C 1=2O2 ! CO
C CO2 ! 2CO
C H2 Og ! CO H2
C 2H2 ! CH4
CO H2 O ! CO2 H2
CH4 H2 Og ! CO 3H2
Tar H2 Og ! CO H2 O CH4 H2 Cm Hn
10
11
1559
The lower heating value (LHV, MJ/m ) of the gas products can be
calculated using the following equation [21,35].
12
CO, H2, CH4 and CnHm in the above equation are the molar ratio
of the CO, H2, CH4 and other hydrocarbon (C2H2 and C2H6) in the
gas product. As shown in Fig. 3a, the heating value of total gas
products increase steadily as the temperature increases. At
1000 C, LHV of gas products reached 15.55 MJ/m3, which belongs
to be medium level of heat values for gas fuels that can be directly
used for gas engine, gas turbine or boiler for power generation.
Also it can be used for the chemical formation of methanol and
methane [31].
4.3. Effect of feedstock particle size on product yields
The second series of experiment was performed to establish the
effect of feedstock particle size on the EFB gasication product
yields. In this study, the experiments were conducted by using
three different feedstock particle size ranges, namely <0.3 mm,
0.30.5 mm and 0.51.0 mm with constant reactor temperature
of 850 C. As shown in Fig. 4a, the smallest particle size of
<0.3 mm produced a gas yield of 74.79 wt.%, about 2% higher than
larger particle size of 0.51.0 mm, which produced a gas yield of
72.74 wt.%, while particles size of 0.30.5 produced a gas yield
73.33 wt.%. The total gas yield decreased with feedstock particle
size increased, while char and tar yields increased with increasing
of feedstock particle size. An increase in feedstock particle size
causes greater temperature gradient inside the particle so that at
a given time the core temperature is lower than of the surface,
which possibly gives rise to an increase in the char and liquids
yields and decrease in gases [37].
Fig. 4b showed that the smaller EFB particles produced more
CO, CH4 and less CO2 than the larger ones, while hydrogen yields
was almost the same (32.99 and 33.93 vol.%) for particles size of
<0.3 mm and 0.30.5 mm, respectively, then decreased to
21.57 vol.%. for particle size of 0.51.0 mm. However, in this study
it was observed that the smallest feedstock particle size of
<0.3 mm obtained maximum yield of gas product, while the feedstock particle size in range of 0.30.5 mm obtained the optimum
gas composition and highest LHV of gas product.
4.4. Effect of equivalence ratio (ER) on product yields
The equivalence ratio (ER) is dened as the ratio of oxygen (air)
required for gasication to oxygen (air) required for stoichiometric
combustion of a given amount of biomass [38]. In this work, ER
1560
(a)
Table 4
Basis of cost analysis.
Items
Data
Capacity
Capital
Operation
Electricity
(b)
H2
CO
CH4
Maintenance
5% of capital cost
Other
1% of capital cost
H2 product
cost
RM 6.7/kg = $2.11/
kg: $0.18/Nm3
RM 3119
RM5865
RM1746
RM10730
RM2592
RM3000/
y
RM1073/
y
RM536.5/
y
RM107.3/
y
RM50/t, including
collection and
transportation
RM0.28/kWh
CO2
50
Table 5
Hydrogen cost through different process.
40
Yield, Vol. %
Interest
Note
30
20
10
0
0.1
0.15
0.2
0.25
0.3
0.35
0.4
ER
Fig. 5. Effect of equivalence ratio (ER) on EFB gasication yield at temperature of
850 C and feedstock particle size of 0.30.5 mm: (a) effect of equivalence ratio (ER)
on product yield, (b) effect of equivalence ratio (ER) on product gas composition.
5. Cost analysis
Performance data of uidized bed biomass gasier system used
in this study is given in Table 3. Due to the low efciency of bench
scale gasication unit, the system needs to be scaling-up. The principal costs of H2 production from EFB biomass using uidized bed
gasier are estimated as follows: It is assumed that 6 kg/h (144 kg/
Table 3
Performance data on uidized bed EFB gasier.
Feed rate of EFB (kg/h)
Feed rate of air (Nm3/h)
Gasier temperature (C)
Gas composition (vol.%)
H2
CO
CH4
CO2
LHV of gas (MJ/m3)
6.0
7.2
850
26.70
33.36
16.04
26.11
12.84
H2 cost
Process
Reference
$10/kg
$4.28/kg
$1.69/kg
$2.11/kg
Electrolyzed hydrogen
Biomass pyrolysis with high-pressure
Biomass gasication with CO-shift
EFB air gasication
[42]
[43]
[44]
This study
d) of EFB would be the raw material for gasication process to produce 0.052 kg H2/kg EFB (7.48 kg H2/d = 84.13 Nm3/d). The capital
cost of this system covers uidized bed gasier, furnace and construction expenditure. Costs of operation, interest, maintenance
and other expenses are assumed as shown in Table 4.
Based on the operating parameters and data of capital cost, the
calculation result of H2 product cost from this system is RM 6.7 for
every kilograms of EFB which is equal to $2.11/kg EFB ($0.18/Nm3).
For comparison, Table 5 presents other researchers cost analysis on H2 through different processes.
6. Conclusions
In this study, air gasication of EFB, one of the most abundant
biomass found in Malaysia, was carried out in bench scale uidized
bed gasier. The operating parameters namely reactor temperature, biomass particle size and equivalence ratio were tested to
determine their effects on total products yields, product gas composition and LHV gas. The main products of EFB air gasication
were solid charcoal, liquid oil, tar and hydrogen-rich gas product.
Temperature was an important factor in this process. As the temperature increased from 700 to 1000 C the gas yield increased signicantly whilst solid, liquid and tar yields progressively
decreased. The gas products mainly consisted of H2, CO, CO2 and
CH4. High temperature is favorable for the increasing gas products
including H2, CO, CH4. The LHV gas increased with temperature and
reached to 15.55 MJ/m3 at 1000 C. The EFB particle size had an
inuence on the total gas yield and gas composition; smaller EFB
particle size produced more CH4, CO and less CO2. On top of that,
LHV gas increased with smaller EFB particle size. ER had complex
effect on the gasication products. The ER of 0.25 was found to
be optimum to yield a maximum H2 production of 27.31 vol.% at
1561
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