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System : Homogeneous
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Disadvantages
Heat transfer and mixing become difficult as the viscosity of reaction
mass increases.
low molecular weight polymers are obtained.
Polymerization is highly exothermic.
Sometimes, uncontrolled chain reaction releases large quantities of
heat resulting in explosion
Solution Polymerization
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Advantages
Efficient heat control
Stirring is easy
Separation process is easy
Products obtained are highly pure
Since water is used as solvent this method is more economical.
Disadvantages
Reactor capital costs are higher than for solution polymerization
This method is applicable only for water insoluble monomers
Examples: polymers like Poly styrene, PMMA ,PVC can be prepared by
this method.
Applications
Polystyrene beads are used as ion exchangers
Emulsion Polymerization
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Disadvantages:
The process requires rapid agitation
Polymer needs purification
Surfactants and other polymerization reagents remain in the polymer
and are difficult to remove
For dry (isolated) polymers, water removal is an energy-intensive
process
Examples: preparation of Polyvinyl chloride, butadiene, PMMA.
Applications
The polymer can be used as such for making adhesives, water-soluble
emulsion paints, adhesives etc.
Also used for manufacturing tacky polymers like butadiene and
Chloroprene
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Polymerisation Techniques :
Polymerisation techniques used in the production of some commercial
polymers
Polymer
Polymerisation technique
Polyamides
Bulk
Polycarbonates
Bulk
Poly(ethylene terephthalate)
Suspension
Polysulphides
Solution
Bulk
Bulk, Suspension
Solution
Solution
Emulsion
Suspension
Solution
Emulsion
Solution
Bulk
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