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Processes
A Cost Effective Solution to Meet
Modern Gasoline Requirements
Barcelona 2010
UOP 2887-2
UOP Ownership
UOP was founded in Chicago in
1914
UOP now a wholly-owned subsidiary
of Honeywell International Inc.
Global Coverage
19 Offices
16 Countries
11 Manufacturing Facilities
4 Engineering Centers
UOP 4638-13
ST.PETERSBURG
KIRISHI
UKHTA
YAROSLAVL
MOSCOW
N-NOVGOROD
MAZEIKIAI
NOVOPOLOTSK
RIAZAN
SURGUT
NIZHNEVARTOVSK
B E LARUS
MOZYR
DROGOBYCH
NADVORNAYA SHEBELINKA
KREMENCHUG
U K ODESSA
R A I N E LISICHANSK
KHERSON
SARATOV
SYZRAN
PERM
NIZHNEKAMSK
TOBOLSK
TIUMEN
SAMARA
OMSK
ASTRAKHAN
SEA
KOMSOMOLSK
4. GEORGIA
5. ARMENIA
6. AZERBAIJAN
KHABAROVSK
K A Z A K H S T A N
ARAL
SEA
CHIMKENT
BUKHARA
BAKU
TURKMENBASHI
FERGANA
6
SHURTAN
CHARDZHOU
ANGARSK
TENGIZCHEVROIL
BATUMI
ATYRAU
KRASNODAR
TUAPSE
GROZNYI
ORSK KARACHAGANAK
PAVLODAR
BLACK
S
TOMSK
ACHINSK
UFA
NOVOKUIBYSHEVSK ORENBURG
VOLGOGRAD
PETROCHEMICAL PLANTS
REFINING PLANTS
GAS PROCESSING PLANTS
7. TADJIKISTAN
8. KIRGIZSTAN
Description
1. Merox
Mercaptan oxidation
2. Platforming
SR Catalytic reforming
No of Units
in FSU
1650
12
753
18
170
14
4. Unionfining
675
226
22
5. Isomerization
Hydrotreating
6. FCC
Catalytic cracking
212
7. Unicracking
Hydrocracking
126
105
BTX extraction
106
PX extraction
55
8. HF Alkylation
9. Sulfolane
10. Parex
No. of Units
Worldwide
Gasoline production
2005
2010
2015
2020
Year
2025
2030
2035
Sulphur
Olefins
Benzene
&
Aromatics
RVP
UOP 3144-03a
Gasoline Blending
Isomerate
FCC Naphtha
Reformate
Oxygenates
Alkylate
Gasoline
UOP 3144-04
10
What About
Fuel Oil?
Fuel Cells?
Hybrids?
Cetane?
Aromatics?
Distillation?
Grade
Segregation?
Off-Road
Diesel Specs?
Alternative
Diesel Fuels?
UOP 3300D-02
11
FSU
Future Gasoline Specifications
Class 2
Class 3
Class 4
Class 5
Euro II
Euro III
Euro IV
Euro V
Dec 2010
Dec 2011
Dec 2014
500
150
50
10
Aromatics,
max vol%
42
35
35
18
18
18
92
95
95
95
83
85
85
85
Sulfur content,
max ppm
Research octane
number, min
Motor octane
number, min
Source: IFQC 2009
since 2002
Units Commissioned
FSU
26%
14%
Americas
7%
Asia
Pacific
Europe
16%
Middle East
24%
7% 4%
India
Service
Unit
Recycle PenexTM
59
Once-through Penex
82
Penex Plus
6
Par-IsomTM
13
Zeolitic (OT+Recycle) 66
Africa
Total
226
- Saturate benzene
- Process benzene precursors
Naphtha
Isomerisation
Splitter
Light Naphtha
Isomerate
Gasoline Pool
Reforming
Reformate
Heavy Naphtha
14
UOP 5225-07
90
RONC
85
78-80
80
75
70
65
60
55
15
81-84
60-70
82-85
88-90
90-92
20
15
10-12
10
10-12
8-9
5-6.5
5
0
3-5
ParIsom
Penex
Penex
Once/ Molex
Through
Unit Type
of Units
Penex
1
Penex/DIH Units
6
DIH/Penex Units
1
DIP/Penex/DIH Units
3
DIP/Penex/Super DIH Units
4
DIP/Par-Isom/Super DIH Units 2
Once-through Par-Isom Units
1
Butamer units
4
Total Units
22
6.0
4.0
Equilibrium
2.0
Sulfated
Zirconia
PI-242TM
0.0
-2.0
-4.0
Zeolitic
HS-10TM
-6.0
-8.0
-10.0
100
120
140
160
180
200
220
240
260
280
300
Reactor Temperature, C
19
UOP T_5238E-26
20
Catalyst
Service
I-82
I-84
PI-242
PI-244
Penex
Penex
Par-Isom
Par-Isom
Pt Content
(wt%)
0.24
0.18
0.33
0.24
Operating
Severity
All Operations
Typical and Low
All Operations
Typical and Low
UOP 5225-16
Conclusions
Demand for high performance Isomerisation processes
will continue as gasoline regulations continue to
evolve
UOP provides a comprehensive range of Isomerisation
process options for refiners to meet modern gasoline
requirements
UOP Isomerisation catalysts allow refiners to maximize
profitability by optimizing precious metal inventory
with operating severity
21
UOP T_5238E-32
UOP 4824G-49
22