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ACKNOWLEDGEMENT
The Most Gracious and Most Merciful, finally we manage to complete our first
assignment on this particular subject, Organic and Instrumental Chemistry for Engineers
(CBE422). We wish to express our gratitude to all those who had taking part in the making of
this assignment.
Our special thanks to Miss Julia Tan regarding her valuable guidance and advice
about this assignment. We also would like to thank her for showing us some example that
related to the topic of our assignment. We were really grateful to have her as our lecturer for
this subject.
Not to forget, we would also like to thank to our families and friends for their
understandings and supports on us in order to complete this assignment. Without the help of
the particular people mentioned above, we would face many difficulties while doing this
assignment. Thank you to all of you once again.
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Contents
ACKNOWLEDGEMENT ............................................................................................................................. 1
Contents .................................................................................................................................................. 2
1.0
Introduction ................................................................................................................................ 3
References ............................................................................................................................................ 17
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1.0 Introduction
1.1 History
Nylon was introduced in 1940, is the
first all-synthetic fibre made commercially and
opened up the entire field. Wallace H.
Carothers was the person who discovered
polyamides
in
year
1931.
Commercial
1938.
First,
polyamides
were
powders
began
commercial
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Nylon 6, 6 is the product resulting from the polymerization reaction of adipic acid and
hexamethylene diamine because each of the raw material chains contains six carbon atoms.
Nylon 6 is the homopolymer of caprolactam, and the newly developed aramid fibre, Kevlar,
an aromatic polyamide, poly-p-phenylene terephthalamide.
Nylon is a family of plastics. The common grades of nylon is Nylon 6 and Nylon 6,6
(the number refers to the number of methyl groups). In condition where the separation of
amide group increase, the polarity of the amide group decreases, thus the moisture
absorbance decreases. Due to more flexibility and mobility in the methyl unit sections of the
chain, the resistance to thermal deformation is lowered.
Comparison the Nylon 6 and Nylon 6, 6 properties are not that different. But we can
see the relationship when comparing the Nylon 6, 6 and Nylon 6, 12. Nylon 6, 12 has lower
modulus, longer elongation, lower strength, lower thermal distortion temperature, lower
hardness and lower melting point than Nylon 6, 6. However, Nylon 6/12 can absorb half as
much water on Nylon 6/6. Thus the property of Nylon 6, 6 is better in dry condition. While,
Nylon 6,12 is much more consistent when it is used in applications in which water may be
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In general, Nylon has very good physical properties. But moisture gives significant
effect on the properties. It was very good heat resistance, chemical resistance, and wear
resistance. Its price is between moderate to high price and it is fair to easy processing.
Physical
Value
2
Tensile Strength:
90 - 185 N/mm
80 x 10
Melting Point:
45 C (113 F)
Density:
-6
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1. Composition: The nylons are polyamides with recurring amide groups. They contain
carbon, oxygen, nitrogen and hydrogen elements.
2. Strength: Nylon has good tenacity and the strength is not lost with age. Nylon has a high
strength to weight ratio. It is one of the lightest textile fibres is at the same time also one of
the strongest. It is one of the fibres which are added at the points of wear such as knees and
seats of jeans and toes and heels of socks. The strength of the nylon fabric is lost when wet.
Nylon has excellent abrasion resistance.
3. Elasticity: Nylon has good elasticity which makes it much suitable for the apparel
purposes. The excellent elasticity would mean that the nylon materials return to their original
length and shreds the wrinkles or creases. Nylon like other fibres has its own limit of
elasticity. If stretched too much, it will not completely recover its shape. The high elongation
and excellent elastic recovery of nylon contributes to the outstanding performance in hosiery.
Nylon hosiery recovers to its original shape at knees and ankles instead of bagging.
4. Resilience: Nylon fabrics have excellent resilience. Nylon fabrics retain their smooth
appearance and the wrinkles from the usual daily activities can be removed easily.
5. Drapability: Fabrics of nylon filament yarn have excellent draping qualities. The drape of
the fabrics made from nylon can be varied depending on the yarn size. The light weight sheer
fabrics of nylon night gowns have high-draping quality. The medium-weight dress fabrics
can drape very nicely.
6. Heat Conductivity: The heat conductivity of the nylon fabrics vary depending upon the
fabric construction, the type of nylon (staple/filament) used in the construction etc. For
instance, the filament nylon used in the open construction would be cooler when compared to
the same filament used in a closed construction. In a closed or tight construction the air
circulation through the fabric is limited. The heat and moisture of the body will not readily
pass the fabric construction, which makes the wearer feel very warm. Such fabrics are good
for winter apparel, such as wind-breakers, but are not suitable for summer garments. On the
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7. Absorbency: Nylon fabrics have low absorbency. The low absorbency of the fabrics tends
to be advantageous and also disadvantageous. The main advantage of the nylons low
absorbency is that the water remains on the surface of the fabrics and runs off the smooth
fabric and hence dries quickly. This property makes the nylon fabrics suitable for raincoats
and shower curtains. Nylons low absorbency has a disadvantage in that the fabric feels
clammy and uncomfortable in warm, humid weather.
8. Cleanliness and Wash ability: Nylon fabrics are easy care garments. Nylon fabrics are
smooth, non-absorbent and dry quickly. Dirt doesnt cling to this smooth fibre, which can be
washed easily or can be even cleaned by using a damp cloth. Nylon whites are commonly
referred as colour scavengers and should be washed separately to avoid greying. They easily
pick up colour and dirt from the wash water. Nylons, washed with other fabrics pick up
colour (even from the palest pastels) and develop a dingy grey appearance that is extremely
difficult to remove. In addition to retaining their appearance during wear, garments made
from nylon fabrics retain their appearance and shape after washing. Hot water should be
avoided during washing as the hot water may cause wrinkling in some fabric constructions.
1. Effect of Bleaches: The nylon fabrics are white and generally do not require bleaching.
The nylon fabrics which pick up colour or develop greying should be bleached with oxidising
bleaches such as hydrogen peroxide.
2. Shrinkage: Nylon fabrics retain their shape and appearance after washing. It has good
stability and does not shrink.
3. Effect of Heat: Nylon should always be ironed at low temperatures. Using hot iron will
result in glazing and then melting of the fabric.
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7. Reaction to Alkalis: Nylon has excellent resistance to alkali's but the frequent and
prolonged exposures to alkalis will weaken the nylon fabrics.
8. Reaction to Acids: Nylon is less resilient to the action of acids and is damaged by strong
acids.
9. Affinity for Dyes: Nylon can be easily dyed with a wider range of dyes. The dyed fabrics
retain their colour and have good resistance to fading.
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solution.
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temperature.
6. The polymerization takes place by combining the two chemicals into polymers which
4.1 Advantages
1. One of the very strong fibers. Extremely resistant to abrasion and flexing.
2. The specific gravity is 1.14 Very light, i.e., 80% of that of silk fibers, and 70% of that
of cotton fibers.
3. Since nylon fibers absorb little water even though they are wetted., they dry fast and
simple in laundering.
4. Excellent in elasticity and resistant to wrinkle.
5. If properly set, nylon textiles little shrink/ extend or little deform their shape due to
thermo plasticity.
6. Resistant to chemicals and oil. Non-attackable by sea water.
7. Non-attackable by molds and insects.
8. Used in many military applications.
4.2 Disadvantages
Some of the disadvantage of nylon includes that:
1. It has a tendency to fade easily and stain. It is also highly sensitive to light and heat.
2. Good quality nylon fiber is much more expensive than some other types of material.
3. Nylon is famous of its properties that is easy to dye with bright color is the major
factor of it prone to staining. Permanent stains are result from food stain that mainly
contains oil and grease. Cleaning product that contain bleach or acid that are created
to remove stains from fabrics.
4. Prolonged exposure to direct sunlight also causes the nylon to fade and wear out.
5. Nylon fibers melt if exposed to extreme temperature.
6. Cheap nylon is also available. However it tends to lose its bounce, brightness and
color very quickly.
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7. It has high moisture pick-up with related dimensional stability and require UV
stabilization.
8. It has high shrinkage and molded sections.
9. Apart from that it has high moisture absorptivity degrades electrical and mechanical
properties.
10. It is also easily attack by oxidizing and strong acid or base.
11. It also has high notch sensitivity.
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5.2
Figure 12 Toothbrush
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References
Benefits of Nylon.
http://benefitof.net/benefits-of-nylon/
Bhishm Khanna (May 2013). What are the uses of Nylon?
http:// www.preservearticles.com/201101032306/uses-of-nylon.html
Mazharul Islam Kiron (August 2011). Characteristics of Nylon Fabrics | Physical and
Chemical Properties Nylon Fabrics.
http://textilelearner.blogspot.com/2011/08/characteristics-of-nylon-fabrics_745.ht
KqRMwGzB ml#ixzz3
Draw a flow chart and explain the manufacturing process of Nylon 6.
https://bookstreet.in/questions/draw-a-flow-chart-and-explain-the-manufacturing-process-ofnylon-6-10-marks-1602
Dr. Plotkin, J. S. (2009). PERP Program - Nylon 6 And Nylon 6,6. Retrieved from
http://www.chemsystems.com/about/cs/news/items/PERP%200708S6_Nylon%206.cfm
Fry, Bill. Working with Nylon -Speaking of Plastics Manufacturing Series
(Society of Manufacturing Engineers (SME), 1999)
George T. Austin. Shreves Chemical Process Industries
(McGraw-Hill Book Company, 1984)
Hoelderich, W. F., & Dahlhoff, G. (February, 2001). DEVELOPING TECHNOLOGY.
Retrieved from http://pubs.acs.org/subscribe/archive/ci/31/i02/html/02dahlhoff.html
Jim Clark. (2004). Polyamides - nylon and Kevlar.
http://www.chemguide.co.uk/organicprops/amides/polyamides.html
Nylon (Polyamide).
http://www.bpf.co.uk/plastipedia/polymers/polyamides.aspx
Polymer Technology & Services, LLC. A GUIDE TO NYLON
ptsllc.com/intro/nylon_intro.aspx.
Sambhar Pati. Flow sheet manufacturing diagram of Nylon 6, 6.
http://blog.oureducation.in/flow-sheet-manufacturing-diagram-of-nylon-66/
Steve Dashew. Materials used for Ropes: Nylon (polyamide)
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