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Product identity :
0870000000
Product type :
thinner
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
8 October 2014
14 January 2013.
Mixture
R10
Xn; R20/21
Xi; R38
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Warning
Hazard statements :
Precautionary statements :
Prevention :
Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response :
IF ON SKIN: Wash with plenty of soap and water. In case of fire: Use alcohol-resistant foam to
extinguish.
Storage :
Keep cool.
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0870000000
1-methoxy-2-propanol
xylene
Not applicable.
Not applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
1-methoxy-2-propanol
xylene
ethylbenzene
2-methoxypropanol
<0.3
R10
R67
Classification
Regulation (EC) No.
1272/2008 [CLP]
Flam. Liq. 3, H226
STOT SE 3, H336
(Narcotic effects)
R10
Xn; R20/21
Xi; R38
Type
[1] [2]
[1] [2]
[1] [2]
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 5
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
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0870000000
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness.
Skin contact :
Ingestion :
Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact :
Inhalation :
Skin contact :
Ingestion :
No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments :
No specific treatment.
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
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0870000000
xylene
ethylbenzene
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0870000000
Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Hand protection :
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
May be used: nitrile rubber, neoprene rubber, butyl rubber, natural rubber (latex)
Recommended: Silver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton
Not recommended: polyvinyl chloride (PVC)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. Be sure to use an approved/certified respirator or
equivalent.
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0870000000
Liquid.
Odor :
Solvent-like
pH :
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Vapor pressure :
1.13 kPa This is based on data for the following ingredient: 1-methoxy-2-propanol
Vapor density :
Relative density :
0.894 g/cm
Solubility(ies) :
Very slightly soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Decomposition temperature :
Viscosity :
Explosive properties :
Highly explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
Water % by weight :
Weighted average: 0 %
VOC content :
894 g/l
TOC Content :
Solvent Gas :
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0870000000
ethylbenzene
Result
Species
LD50 Dermal
LD50 Oral
LC50 Inhalation Gas.
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
Dose
Rabbit
Rat
Rat
Rat
Rabbit
Rat
Rabbit
Rat
Exposure
13 g/kg
6600 mg/kg
5000 ppm
6350 ppm
>2000 mg/kg
4300 mg/kg
>5000 mg/kg
3500 mg/kg
4 hours
4 hours
-
ATE value
Dermal
Inhalation (gases)
Inhalation (vapors)
2682.9 mg/kg
12195.1 ppm
122.2 mg/l
Irritation/Corrosion
Product/ingredient name
1-methoxy-2-propanol
xylene
ethylbenzene
Result
Species
Score
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Exposure
24 hours 500 milligrams
24 hours 5 milligrams
24 hours 500 milligrams
24 hours 15 milligrams
-
Category
1-methoxy-2-propanol
2-methoxypropanol
Category 3
Category 3
Route of exposure
Target organs
Not applicable.
Not applicable.
Narcotic effects
Respiratory tract irritation
Category
ethylbenzene
Category 2
Route of exposure
Target organs
Not determined
ears
Aspiration hazard
Product/ingredient name
Result
ethylbenzene
Carcinogenic effects
Mutagenic effects
Developmental effects
Fertility effects
2-methoxypropanol
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0870000000
Result
1-methoxy-2-propanol
Species
ethylbenzene
Exposure
48 hours
96 hours
96 hours
Test
Result
Product/ingredient name
xylene
ethylbenzene
Dose
Photolysis
Inoculum
-
Biodegradability
Readily
Readily
LogPow
1-methoxy-2-propanol
xylene
ethylbenzene
<1
3.12
3.6
BCF
8.1 to 25.9
-
Potential
low
low
low
Mobility :
Not applicable.
vPvB :
Not applicable.
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0870000000
ADR/RID
Class
14.1
UN no.
14.2
Proper shipping name
14.3
Transport hazard class(es)
UN1263
14.4
PG*
14.5
Env* Additional information
III
No.
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG
Class
UN1263
IATA
Class
UN1263
III
No.
Emergency schedules
(EmS)
F-E, S-E
III
No.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
C6: Flammable (R10)
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0870000000
F - Highly flammable
Repr. Cat. 2 - Toxic to reproduction category 2
Xn - Harmful
Xi - Irritant
H225
H226
H304
H312 (dermal)
H315
H318
H332 (inhalation)
H335 (Respiratory
tract irritation)
H336 (Narcotic
effects)
H360D (Unborn
child)
H373 (ears)
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
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