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Sub-topics
Diffusion
Diffusion processes in industry
NON-SPONTANEOUS PROCESSES
1.
2.
Q=activation energy
State 1
State 2
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DIFFUSION
As T of the system is increased, more and more molecules will attain the
activation energy level.
In statistical mechanics, Maxwell
Boltzmann statistics describes the
distribution of material particles
over various energy states and
probabilities to find a particle in
definite state:
Probability ~ exp(-E/RT)
R Boltzman constant = 1.38
x10 -23 J/atom K
WHAT IS DIFFUSION?
SELF-DIFFUSION
C
C
A
D
B
Concentration
of Ni [kg/m3]
Position, x
Concentration Profile, C(x): [kg/m3]
flux in x-dir.
[kg/m2-s]
dC
Jx = D
dx
concentration
gradient [kg/m4]
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STEADY-STATE DIFFUSION
o Diffusion is a time dependent process and the rate of mass transfer is
the diffusion flux (J).
o In a steady-state condition the concentration gradient is constant.
Steady state diffusion takes place at a constant rate - that is, once
the process starts the number of atoms crossing a given interface (the
flux) is constant with time.
This means that throughout the system dc/dx = constant and dc/dt = 0.
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CONCENTRATION GRADIENT
The concentration gradient shows how
the composition of the material varies
with distance:
c is the difference in concentration
over the distance x
atoms/m2 s
Kg/m2 s
Kg/m3
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DIFFUSIVITY
Diffusivity depends on
9 Type of diffusion : Whether the diffusion is
interstitial or substitutional.
9 Temperature: As the temperature increases
diffusivity increases.
9 Type of crystal structure: BCC crystal has lower
APF than FCC and hence has higher diffusivity.
9 Type of crystal imperfection: More open structures
(grain boundaries) increases diffusion.
9 The concentration of diffusing species: Higher
concentrations of diffusing solute atoms will affect
diffusivity.
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DIFFUSION COEFFICIENT
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SiO2
1. Deposit P rich
layers on surface.
silicon
2. Heat it.
3. Result: Doped
semiconductor
regions.
silicon
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TYPES OF DIFFUSION
In volume diffusion, the atoms move through the crystal
from one regular or interstitial site to another. Because of
the surrounding atoms, the activation energy is large and
the rate of diffusion is relatively slow.
Atoms can also diffuse along boundaries, interfaces, and
surfaces in the material. Atoms diffuse easily by grain
boundary diffusion, because the atom packing is
disordered and less dense in the grain boundaries.
Because atoms can more easily squeeze their way through
the grain boundary, the activation energy is low.
Surface diffusion is easier still because there is even less
constraint on the diffusing atoms at the surface.
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NONSTEADY-STATE DIFFUSION
Concentration of solute atoms at any point in metal changes with
time in this case.
Change of concentration of solute atoms with change in time in different planes
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Surface conc.,
Cs of Cu atoms
Cs
bar
pre-existing conc., C o of copper atoms
C(x,t)
t3
t2
to t1
Co
position, x
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SOLUTION
One practically important solution is for a semi-infinite solid in which the
surface concentration is held constant.
Frequently, the source of the diffusing species is a gas phase, the partial
pressure of which is maintained at a constant value.
Furthermore, the following assumptions are made:
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CARBURIZING
Diffusing carbon
atoms
Low
carbon
Steel part
Carbon Gradients
In Carburized metals
Result:
--hard to deform: C atoms
"lock" planes from shearing.
--hard to crack: C atoms put
the surface in compression.
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TIME COMPUTATION
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DESIGN PROBLEM
The wear resistance of a steel gear is to be improved by hardening its
surface. This is to be accomplished by increasing the carbon content
within an outer surface layer as a result of carbon diffusion into the
steel; the carbon is to be supplied from an external carbon-rich gaseous
atmosphere at an elevated and constant temperature.
The initial carbon content of the steel is 0.20 wt%, whereas the surface
concentration is to be maintained at 1.00 wt%. In order for this treatment
to be effective, a carbon content of 0.60 wt% must be established at a
position 0.75 mm below the surface.
Specify an appropriate heat treatment in terms of temperature and time
for temperatures between 900C and 1050 C. Use data in Table for the
diffusion of carbon in -iron. The gas const = 8.31 J/mol K
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SUMMARY:
STRUCTURE & DIFFUSION
Diffusion FASTER for... Diffusion SLOWER for...
open crystal structures
close-packed structures
materials w/secondary
bonding
materials w/covalent
bonding
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