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NATURAL GAS
NaturalGas
5/29/2012
Gasreservestoproduction(R/P)ratios
Distributionofprovedgasreserves
Source:BPStatisticalReviewofWorldEnergyJune2011
5/29/2012
Gasproduction/consumptionbyregion
Gasconsumptionpercapita
5/29/2012
Chartofgasprices
5/29/2012
Majorgastrademovements
Chartofnaturalgastrade
5/29/2012
NATURALGAS
Naturalgasesareclassifiedaccordingtotheirhydrocarbon
composition
Gascomposedofalmostmethaneisdrygas.
Iftheproportionofethane(C2H6)andheaviermolecules
propane,andbutaneexceedssomeofarbitralvalues(4
or5%),thegasiscalledwet gas.
Naturalgasesconsistinglargelyofmethanemayhaveany
one of three distinct origins
oneofthreedistinctorigins
Petroleumgas
Coalgas
Bacteriagas
FluidProperties:NaturalGas
Naturalgasismostly(60
80%)methane,CH4.Some
heaviergasesmakeupthe
rest.
Gascancontainimpurities
suchasHydrogenSulphide,
H2SandCarbonDioxide...
Impurities
CarbonDioxide(CO2):Volcanic
andorganicsources
d
i
Dilutehydrocarboncontent
Greenhouseproblem
Maybecommerciallyexploitable
HydrogenSulphide(H2S):Sour
gas
Poisonous
Corrosionproblem
Nitrogen
Nitrogen,Helium,Argon,
Helium Argon
Hydrogen
12
5/29/2012
HYDROCARBON GASES
Defined based on their occurrence
y
gas
g that exists in the gaseous
g
Free gas is a hydrocarbon
phase in a reservoir and remains in the gaseous phase
when produced.
Dissolved gas is defined as natural gas in solution in crude
oil in a reservoir. The reduction in pressure when oil is
produced from a reservoir often results in dissolved gas
being emitted from oil as free gas.
Associated gas is natural gas which occurs as a gas cap
which overlies and is in contact with crude oil within a
reservoir. Nonassociated gas is natural gas in reservoirs
that do not contain crude oil.
5/29/2012
LIQUIFIED GASES
NGL, natural gas liquids, are hydrocarbon liquids
separated from the produced gas stream.
C d
Condensates
t are an important
i
t t type
t
off natural
t l gas
liquid.
LPG, liquified petroleum gas, is comprised of
heavier hydrocarbon gases, usually propane and
butane, stored under pressure in a liquid form.
LNG, liquified natural gas, is natural gas,
commonly methane, which is compressed into
liquid for storage and transportation.
NaturalGasLiquid(NGL)
Classifiedinto
INORGANIC ORIGIN
Inert Gases
Helium
Argon
Krypton
Radon
Nitrogen
Also
Carbon dioxide
Hydrogen sulfide
ORGANIC ORIGIN
Hydrocarbon Gases
Methane (dry)
Ethane (wet)
Propane
Butane
5/29/2012
FluidProperties:WhatisOilandGas?
17
HydrocarbonClassification
Hydrocarbonsarealsodefinedbytheirweightandthe
Gas/Oilratio.Thetablegivessometypicalvalues:
Wetgas
Condensate
Volatileoil
Blackoil
Heavy oil
Heavyoil
Tar/bitumen
GOR(cf/bbl)
100,000
5100,000
3,000
1002,500
0
0
APIGravity
5070
5070
4050
3040
10 30
1030
<10
Thespecificgravityofanoilisdefinedas:
o
API =
141.5
131.5
or
141.5
API + 131.5
18
5/29/2012
FluidProperties
TypicalhydrocarbonshavethefollowingcompositioninMolFraction
HydrocarbonC1
C2
C3
C4
C5
C6+
Drygas
.88
.045
.045
.01
.01
.01
Condensate.72
.08
.04
.04
.04
.08
Volatileoil.6.65
.08
.05
.04
.03
.15.2
Blackoil
.03
.05
.05
.04
.42
.01
.01
.04
.8
.41
Heavyoil.11
.03
Tar/bitumen
1.0
The'C'numbersindicatedthenumberofcarbonatomsinthemolecular
chain.
19
AVERAGECOMPARISIONOFCRUDEOIL,
NATURALGAS,ASPHALT
Element Crudeoil
Carbon
Hydrogen
Sulfur
Nitrogen
Oxygen
Asphalt
%Weight
%Weight
82.2 87.1
11.7 14.7
0.1 5.5
0.5 1.5
0.1 4.5
80 85
8.5 11
2 8
0 2
Naturalgas
%Weight
65 80
1 25
trace 0.2
1 15
10
5/29/2012
FluidProperties:Condensate
Veryoldandformedwith high temperature andpressure therefore
foundverydeep
Very lighthydrocarbonsthataregaseswhentheyarebelowground
butcondensewhenreducedintemperatureandpressure
Veryhighgravity(>60API),lightyellowandrunnylikewater
Premiumproduct
easytodistil
containlargeamountsofnaphthaforfuels and petrochemicals
21
FluidProperties:Colorofliquid
3rd/4th/5th flow initially light yellow and later dark brown
If cooled to 0 degC,
Some sticky part
appear
22
11
5/29/2012
FluidProperties:LightOil
Oldinageandformedwith muchheatandpressure thereforefound
atdeepdepths
HighgravityAPI>28API,colour blackcoffee,quiterunny like
milkshake
Highvalue product
Easierandlessexpensivetoextractbecauseitislessviscous andless
densethanheavyoil
Easierandlessexpensivetorefinebecauseitcontainslesssulphurand
morelightpetroleumdistillateslikegasoline,naphtha,keroseneand
dieseloilthanheavyoil
23
FluidProperties:ColorofLiquid
Colorofoil:DarkBrown
Oil
Oil
Emulsion
Mud
Mud
Solid
(barite)
Solid
((barite))
1st flow
1st flow
2nd flow
2nd flow
(4hrsafterwellopen)
(9hrsafter)
(4hrsafterwellopen)
(12hrsafter)
DrillingMud+Oil
BSW=80%
WHT=50degC
DrillingMud+Oil
BSW=10~25%
WHT=71degC
100%Oil
BSW=0%
WHT=46degC
100%Oil
BSW=0%
WHT=48degC
24
12
5/29/2012
HydrocarbonVolumes
Fluidsatbottomholeconditionsproducedifferentfluidsatsurface:
Oilbecomesoilplusgas.
GasusuallystaysasgasunlessitisaCondensate.
Waterstaysaswaterwithoccasionallysomedissolvedgas.
25
OilTerminologyandConversions
Barrel=42USgallons,159L
BOPD,BPD=BarrelsofOil
perDay
bbl/d=BlueBarrelsofOil
perDay
STB=StockTankBarrels(Oil
willchangeinvolumeasit
goesfromthereservoirinto
theStockTankasthegasis
removed
1bbloil=0.159kLoil
1kLoil=6.29bbloil
1bbl ofoilistheenergy
equivalentof6 MSCF of
naturalgas Barreloil
equivalent(BOE)
26
13
5/29/2012
GasTerminologyandConversions
MMCFD&MCFD=Million
CubicFeetofGasperDay(M
means Mille French for
meansMilleFrenchfor
1,000)
MMSCFD&MSCFD=Million
StandardCubicFeetperDay
TCF=TrillionCubicFeet(1012)
1m3 =35.3standardcubic
feet(SCF)
1tonneLNG=1,333m3 gas@
0o C
1milliontonnesofLNGper
year(mtpa)=1.333BCMpa=
47BCFpa
27
Th trngkh
Trnc s bocos 270/KVNNKK,ngy04
th 2 2010 T C T Kh (PV
thng2nm2010caTngCngTyKh(PV
Gas)trnhTponDuKhQucGiaVit
Namv viccnicungcukhkhuvc
NamB,tnhtonnguncungvnhucu
khcakhuvcnytronggiaion2011
2015.
Nguncungcpkhctnhtont:
14
5/29/2012
B CuLong(BchH,Rng,iMi,C
N Vng,ST,STV,STT,Rngng,Phng
Ng
V ST STV STT R
Ph
ng,HST,HS,TGicTrng,Khkh);
B NamCnSn(HiThch,McTinh,Lan
Ty,Lan,Rngi,ChimSo,Khkh);
B MalayTh Chu(PM3CAA&46CN,Hoa
Chu (PM3CAA & 46CN Hoa
Mai,LB48&52,Khkh).
Nhucukh bngtrnctnhchocc
T
Trungtmtiuth
t ti th NamB
N
B nh:
h
in mngNamb;
in mTyNamb.
15
5/29/2012
Natural gas
Proved reserves
Australia
Bangladesh
Brunei
China
India
Indonesia
Malaysia
M
Myanmar
Pakistan
Papua New Guinea
Thailand
Vietnam
Other Asia Pacific
Total Asia Pacific
Total World
At end 1990
Trillion
cubic
metres
0.9
0.7
0.3
1.0
0.7
2.9
1.6
03
0.3
0.6
0.2
0.2
0.3
9.9
125.7
At end 2000
Trillion
cubic
metres
2.2
0.3
0.4
1.4
0.8
2.7
2.3
03
0.3
0.7
0.4
0.4
0.2
0.3
12.3
154.3
At end 2010
At end 2009
Trillion
Trillion Trillion
cubic
cubic
cubic Share
metres
feet
metres of total
2.9 103.1
2.9 1.6%
0.4
12.9
0.4 0.2%
0.3
10.6
0.3 0.2%
2.8
99.2
2.8 1.5%
1.1
51.2
1.5 0.8%
3.0 108.4
3.1 1.6%
2.4
84.6
2.4 1.3%
03
0.3
11 8
11.8
0 3 0.2%
0.3
0 2%
0.8
29.1
0.8 0.4%
0.4
15.6
0.4 0.2%
0.3
11.0
0.3 0.2%
0.7
21.8
0.6 0.3%
0.4
12.4
0.4 0.2%
15.8
571.8
16.2 8.7%
186.6 6608.9
187.1 100.0%
R/P
ratio
58.0
18.3
24.7
29.0
28.5
37.4
36.1
2
27.5
20.9
*
8.6
66.0
20.4
32.8
58.6
16
5/29/2012
TheEnd
5/29/2012
33
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