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January 1999
1. Consider the reaction:
Ca (s) + 2H2O (l) Ca(OH)2 (aq) + H2 (g)
At a certain temperature, 2.50 g Ca reacts completely in 30.0 seconds.
The rate of consumption of Ca is
A. 0.00208 mol/min
B. 0.0833 mol/min
C. 0.125 mol/min
D. 5.00 mol/min
2. The minimum amount of energy required to overcome the energy barrier in a chemical
reaction is the
A. heat of reaction.
B. activation energy.
C. KE of the reactants.
D. enthalpy of the products.
3. An activated complex is a chemical species that is
A. stable and has low PE.
B. stable and has high PE.
C. unstable and has low PE.
D. unstable and has high PE.
4. A certain reaction is able to proceed by various mechanisms. Each mechanism has a
different Ea and results in a different overall rate. Which of the following best describes
the relationship between the Ea values and the rates?
In this reaction, H2 is a
A. product.
B. catalyst.
C. reactant.
D. reaction intermediate.
April 1999
1. The slowest of the following reactions is
A. Ag+ (aq) + Cl- (aq) AgCl (s)
B. H3O+ (aq) + OH- (aq) 2H2O (l)
C. 3Ba 2+ (aq) + 2PO43- (aq) Ba3(PO4)2 (s)
D. Cu(s) + 2Ag+ (aq) Cu2+ (aq) + 2Ag(s)
2. The rate of a chemical reaction is equal to the slope of a graph with the axes labeled
6. A substance that increases the rate of a chemical reaction and may be recovered
unchanged at the end of the reaction is a(n)
A. product.
B. catalyst.
C. activated complex.
D. reaction intermediate.
7. Consider the following PE diagram for a reversible reaction:
June 1999
1. Which of the following can be used to represent the rate of a reaction?
5. Which graph shows the relationship between activation energy (Ea) and temperature?
January 2000
1. Which of the following is most likely to have the greatest reaction rate at room
temperature?
A. 2H2(g) + O2(g) 2H2O(l)
B. 2Ag+ (aq) + CrO4 2- (aq) Ag2CrO4(s)
C. Pb(s) + 2HCl(aq) PbCl2(aq) + H2(g)
D. CH4 (g) + 2O2(g) CO2(g) + 2H2O(g)
2. Consider the following reaction involving 1 0. g of powdered zinc:
Zn (s) + 2HCl (aq) ZnCl2 (aq) + H2 (g)
Which of the following represents the heat of reaction, H, for the forward reaction?
A. I
B. II
C. III
D. IV
A. II only
B. I and II only
C. II and III only
D. I, II and III
6. Consider the following mechanism for a reaction:
Step 1.
HBr + O2 HOOBr
Step 2.
HBr + HOOBr 2HOBr
Step 3.
2HBr + 2HOBr 2H2O + 2Br2
Which of the following statements is correct?
A. Br2 is a reactant.
B. HBr is a product.
C. HOBr is a catalyst.
D. HOOBr is a reaction intermediate.
June 2000
1. Which of the following reactions will be slowest at 25C?
A. Cu (s) + S(s) CuS(s)
B. H+ (aq) + OH- (aq) H2O(l)
C. Pb 2+ (aq) + 2Cl- (aq) PbCl2(s)
D. 2NaOCl(aq) 2NaCl (aq) + O2(g)
2. Which of the following could be used as the units for rate of a reaction?
I.
mL/s
II.
g/min
III.
M/min
A. I only.
B. I and II only.
C. II and III only.
D. I, II and III.
4. Consider the following experiments, each involving equal masses of zinc and 10.0 mL
of acid:
Balance
Pressure gauge
pH meter
A. I and II only.
B. I and III only.
C. II and III only.
D. I, II and III.
3. Which of the following changes occur when the temperature of a reaction is increased?
I.
of the reaction increases
II.
Frequency of the collisions increases
III.
Kinetic energy of the reactants increases
A. I and II only.
B. I and III only.
A. I
B. II
C. III
D. IV
January 2001
1. Which of the following units could be used to express reaction rate?
A. mL/s
B. mL/g
C. g/mL
D. mL/mol
2. Consider the reaction:
Zn (s) + 2HCl (aq) ZnCl2(aq) + H2(g)
The rate of production of ZnCl2 , can be increased by
A. decreasing the [HCl].
B. increasing the temperature.
C. increasing the volume of H2.
6. A substance that increases the rate of a reaction without appearing in the equation
for the overall reaction is a(n)
A. product.
B. catalyst.
C. reactant.
D. intermediate.
April 2001
1. Which of the following reactions occurs most rapidly at standard conditions?
A. 2Fe (s) + O2(g) 2FeO(s)
B. CaO(s) + 3C(s) CaC2(s) + CO(g)
C. SnO2(s) + 2CO(g) Sn(s) + 2CO2(g)
D. 2AgNO3(aq) + Na2CrO4(aq) Ag2CrO4(s) + 2NaNO3(aq)
2. Consider the following reaction:
CaO (s) + 2HCl (aq) CaCl2 (aq) + H2O (l)
Which of the following could be used to measure the rate of this reaction?
A. change in acidity
B. change in volume
C. change in pressure
D. change in total mass
3. In order for a collision between reactant particles to be successful
A. H must be positive.
B. the system must be closed.
C. there must be sufficient KE.
D. the change in KE must be less than the change in PE.
4. Consider the following PE diagram:
5. What is the relationship between the activation energy and the rate of a reaction?
A. When the activation energy is high, the rate of reaction is fast.
B. When the activation energy is low, the rate of reaction is slow.
C. When the activation energy is high, the rate of reaction is slow.
D. There is no relationship between activation energy and rate of reaction.
6. Consider the following reaction mechanism:
Step 1.
OCl- + H2O HOCl + OHStep 2.
I- + HOCl HOI + ClStep 3.
HOI + OH- H2O + OHWhich of the following is correct for the overall reaction?
A. HOI is a product.
B. H2O is a reactant.
C. HOCl is a catalyst.
D. OH- is a reaction intermediate.
June 2001
1. Which of the following reactions is slowest at room temperature?
A. NH3(g) + HCl(g) NH4Cl (s)
B. MgCl2(s) + Ca(s) Mg(s) + CaCl2(s)
C. HCl(aq) + NaOH(aq) NaCl (aq) + H2O(l)
D. Ba(NO3)2 (aq) + Na2SO4(aq) BaSO4(s) + 2NaNO3(aq)
2. Consider the following reaction:
COCl2(g) CO(g) + Cl2(g)
Which of the following could be used to determine reaction rate in a closed system?
A. a decrease in gas pressure
B. an increase in gas pressure
C. a decrease in the mass of the system
D. an increase in the mass of the system
3. Activation energy is defined as the
A. H
B. average kinetic energy.
C. energy of a particles motion.
D. minimum energy needed for a successful collision.
H3O+ + I- HI + H2O
H2O2 + HI H2O + HOI
HOI + H3O+ + I- 2H2O + I2
I2 + I- I3-
In the above mechanism, which of the following is true for the overall reaction?
A. HI is a catalyst
B. H3O+ is a product
C. H2O2 is a reactant
D. H2O is an intermediate
August 2001
1. Consider the following reaction:
N2H4(l) + 2H2O2(l) N2(g) + 4H2O(l)
In 5.0seconds, 0.015mol of H2O2 is consumed. The rate of production of N2 is
B. -30 kJ
C. +30 kJ
D. +120 kJ
6. A substance that is produced in one step in a reaction mechanism and consumed
in a subsequent step, without appearing in the overall reaction, is a(n)
A. catalyst.
B. product.
C. reactant.
D. intermediate.
January 2002
1. Which of the following has the greatest reaction rate?
A. C(s) + O2(g) CO2(g)
B. 2H2O2 (l) 2H2O (l) + O2 (g)
C. 2Al (s) + 3CuCl2(aq) 2AlCl3(aq) + 3Cu(s)
D. NaCl(aq) + AgNO3(aq) AgCl(s) + NaNO3(aq)
2. Which factor explains why potassium generally reacts faster than sodium?
A. surface area
B. temperature
C. concentration
D. nature of reactants
3. What happens to the PE and KE of the reactants particles as the activated complex is
formed?
PE
A. increases
B. increases
C. decreases
D. decreases
KE
.
decreases
increases
decreases
increases
What are the values of H and activation energy (Ea) for the forward reaction?
D. CHCl3
April 2002
1. Which of the following could be used to describe the rate of a reaction?
A. change in time
change in mass
B. change in mass
change in volume
C. change in volume
change in time
D. change in volume
change in mass
Which of the following describes the type of reaction and H for the reverse reaction?
June 2002
1. Which of the following has the lowest rate of reaction?
A. Pb(s) + CuCl2(aq) Cu(s) + PbCl2(aq)
B. HCl(aq) + NaOH(aq) H2O(l) + NaCl(aq)
C. H2SO4(aq) + Ba(OH)2(aq) 2H2O(l) + BaSO4(s)
D. Pb(NO3)2(aq) + 2NaI(aq) PbI2(s) + 2NaNO3(aq)
2. Which of the following affects the rate of heterogeneous reactions, but does not affect
the rate of homogeneous reactions?
A. catalyst
B. temperature
C. surface area
D. concentration
3. As reactant particles approach each other, what changes occur in KE and PE?
A.
B.
C.
D.
KE
increases
increases
decreases
decreases
PE
increases
decreases
increases
decreases
What is the minimum potential energy required to change reactants to the activated
complex?
A. 200 KJ
B. 300 KJ
C. 400 KJ
D. 500 KJ
5. Consider the following reaction mechanism:
Step 1
2NO2 NO3 + NO
Step 2
A.
B.
C.
D.
Reverse
Reaction
uncatalyzed
catalyzed
uncatalyzed
catalyzed
Activation
Energy (kJ)
300
300
400
400
H
(kJ)
-100
-100
+100
+100
August 2002
1. Which of the following could be used to describe the rate of a reaction?
A.
B.
C.
D.
Bonds
form
form
break
break
PE
increases
decreases
increases
decreases
Which of the following describes H and the type of reaction in the forward direction?
A.
B.
C.
D.
H
(kJ)
-50
-50
+50
+50
Type of
Reaction
exothermic
endothermic
exothermic
endothermic
catalyzed
uncatalyzed
catalyzed
uncatalyzed
Activation
Energy (kJ)
300
300
400
400
H
(kJ)
-100
-100
+100
+100
NOCl NO + Cl
Step 2
NOCl + Cl NO + Cl2
small
small
large
large
Activated
Complex
unstable
stable
unstable
stable
5. How does the addition of a catalyst increase the reaction rate of an endothermic
reaction?
A. It reduces the H of the reaction.
B. It increases the H of the reaction.
C. It reduces the required activation energy.
D. It causes the reaction to become exothermic.
6. Consider the following PE diagram:
April 2003
1. Consider the following reaction occurring in an open container:
CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)
The reaction rate could be calculated by using which of the following?
A. a change in [Cl-]
B. a decrease in pH value
C. a change in gas pressure
D. a decrease in the mass of the system
2. Which of the following does not affect both homogeneous and heterogeneous
reaction rates?
A. addition of a catalyst
B. change in temperature
C. change in surface area
D. change in concentration
3. How do KE and PE change as reactant particles collide with each other?
A.
B.
C.
KE
increases
increases
decreases
PE
increases
decreases
increases
D.
decreases
decreases
4. Under which of the following conditions will the reaction rate decrease for a
reaction which goes to completion?
A. A catalyst is removed.
B. Products are removed.
C. Temperature is increased.
D. Solid reactants are ground into powders.
5. Consider the following potential energy diagram for a reaction:
A.
B.
C.
D.
Forward Catalyzed
Ea
40 kJ
80 kJ
100 kJ
100 kJ
Reverse Uncatalyzed
Ea
140 kJ
40 kJ
80 kJ
160 kJ
H = -114 kJ
August 2003
1. Which of the following reactions would be slowest at room temperature?
A. Zn(s) + S(s) ZnS(s)
B. Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s)
C. Pb(NO3)2(aq)+ 2KI(aq) PbI2(s) + 2KNO3(aq)
D. HC2H3O2(aq) + KOH(aq) KC2H3O2(aq) + H2O(l)
2. Consider the following reaction:
2BaCrO4(s) + 2H+(aq) 2Ba2+(aq) + H2O(l) + Cr2O72-(aq)
(yellow)
(orange)
The progress of the reaction could be followed by observing the rate of
A. mass loss.
B. decrease in pH.
C. precipitate formation.
D. formation of orange colour in the solution.
3. What happens to the activation energy as the temperature in a reacting system
increases?
A. the activation energy increases
B. the activation energy decreases
C. the activation energy stays the same
Which of the following describes the reaction type and enthalpy change for the
forward reaction?
A.
B.
C.
D.
Reaction Type
exothermic
exothermic
endothermic
endothermic
H Value
-10 kJ
+10 kJ
-10 kJ
+10 kJ
Reactants
Temperature
Concentration
Rates
Experiment 1
Fe2+(aq) + MnO4-(aq)
20
0.5 M solutions
Fast
Experiment 2
MnO4 -(aq) + H2C2O4(aq)
40
1.0 M solutions
Slow
Which factor would account for the faster reaction rate in Experiment 1?
A. temperature
B. surface area
C. nature of reactants
D. solution concentration
6. Consider the reaction:
C5H12(g) + 8O2(g) 5CO2(g) + 6H2O(g)
Which of the following explains, in terms of collision theory, why this reaction
occurs in more than one step?
A. a low C5H12(g) concentration
B. low temperature of reactant mixture
C. low probability of a multi-particle collision
D. particles collide with insufficient kinetic energy
January 2004
1. Which of the following factors only affects the rate of heterogeneous reactions?
A. nature of reactants
B. presence of a catalyst
C. temperature of reactants
D. surface area of reactants
2. Consider the following reactions in open systems:
I.
II.
III.
IV.
Reaction
A.
B.
C.
D.
catalyzed
uncatalyzed
catalyzed
uncatalyzed
PE of Activated
Complex (kJ)
100
300
250
150
H
(kJ)
-50
-50
+50
-50
January 1999
1
C
2
B
3
D
4
C
5
A
6
C
April 1999
1
D
2
D
3
D
4
A
5
C
6
B
June 1999
1
D
2
A
3
B
4
C
5
A
6
D
August 1999
1
B
2
B
3
C
4
A
5
D
6
B
January 2000
1
B
2
C
3
D
4
A
5
B
6
D
April 2000
1
B
2
A
3
B
4
D
5
A
6
D
June 2000
1
A
2
D
3
C
4
C
5
B
6
B
August 2000
1
C
2
B
3
C
4
D
5
B
6
D
January 2001
1
A
2
B
3
B
4
A
5
A
April 2001
1
D
2
A
3
C
4
B
5
C
June 2001
1
B
2
B
3
D
4
D
5
B
August 2001
1
A
2
C
3
D
4
C
5
B
January 2002
1
D
2
D
3
A
4
A
5
D
6
A
April 2002
1
C
2
D
3
D
4
B
5
A
6
D
June 2002
1
A
2
C
3
C
4
B
5
B
6
C
August 2002
1
C
2
B
3
D
4
D
5
D
6
A
January 2003
1
C
2
B
3
D
4
A
5
C
6
D
April 2003
1
D
2
C
3
C
4
A
5
A
6
C
June 2003
1
C
2
D
3
C
4
C
5
B
6
B
August 2003
1
A
2
D
3
C
4
A
5
C
6
C
January 2004
1
D
2
B
3
D
4
B
5
D
6
D