Cooling Water Treatment Program

Shipboard Log Sheet, 309

Owner
Type
Makeup
Product

Ship Name
Diesel Engine Manufacturer
Year

Month
Jacket

Capacity,
tons:

Date
1-3
> or = 2700
Nitrite as ppm
2520
NO2
2340
2160
Normal Level
1980
1500 - 2400ppm
1800
1620
1440
1260
1080
900
< or = 720
Chloride
ppm Cl
Normal Level
max 50ppm

HT
4-7

8-11 12-15 16-19 20-23 24-27 28-31

> or = 100
80
60
40
20
0

Piston
Date
1-3
> or = 2700
Nitrite as ppm
2520
NO2
2340
2160
Normal Level
1980
1500 - 2400ppm
1800
1620
1440
1260
1080
900
< or = 720
Chloride
ppm Cl
Normal Level
max 50ppm

Chloride
ppm Cl
Normal Level
max 50ppm

> or = 100
80
60
40
20
0

pH
Dieselguard NB kg
Rocor NB Liquid ltr
Makeup ltr
Comments:

4-7

8-11 12-15 16-19 20-23 24-27 28-31

> or = 100
80
60
40
20
0

pH
Dieselguard NB kg
Rocor NB Liquid ltr
Makeup ltr

Fuel Valves
Date
1-3
> or = 2700
Nitrite as ppm
2520
NO2
2340
2160
Normal Level
1980
1500 - 2400ppm
1800
1620
1440
1260
1080
900
< or = 720

LT

Capacity,
tons:

pH
Dieselguard NB kg
Rocor NB Liquid ltr
Makeup ltr

Capacity,
tons:

IMO/Lloyds No.
Shore
Distilled
Mixed
Dieselguard NB
Rocor NB Liquid

Others
4-7

8-11 12-15 16-19 20-23 24-27 28-31

Aux. Generators
Capacity,
tons:

Date
1-3
> or = 2700
Nitrite as ppm
2520
NO2
2340
2160
Normal Level
1980
1500 - 2400ppm
1800
1620
1440
1260
1080
900
< or = 720
Chloride
ppm Cl
Normal Level
max 50ppm

> or = 100
80
60
40
20
0

pH
Dieselguard NB kg
Rocor NB Liquid ltr
Makeup ltr

4-7

Combined with Main Eng.

8-11 12-15 16-19 20-23 24-27 28-31

Boiler Water Treatment Program

Shipboard Log Sheet 310- for Combined Boiler Water Treatment with Liquitreat & Condensate Control
Ship Name

Owner

Boiler Maker
Evaporation rate-kg/h
Year

Type

Pressure, bar

Month

Make up

Boiler Identification:

Liquitreat
P. Alkalinity
ppm as CaCO3
100 - 300

Day 1
> or = 350
330
310
290
270
250
230
210
190
170
150
130
110
90
< or = 70

Boiler pH

Over 11.0
9.5 - 11.0
Below 9.5

Sample appearance

Cloudy
Clear
Coloured

Condensate pH
Limits
8.3 - 9.0
"Condensate Control"
Dosage in Liter

Condensate Chloride
Usually below 20 ppm
Should be kept as
low as possible

Hotwell
Temp oC

Comments:

Shore

Distilled

Ton
Mixed

Eg: Aux. Boiler / Exh. Gas Boiler / Boiler 1

Dosage in Liter

Boiler Chlorides
Max 200 ppm as Cl
Should be kept as
low as possible
(Usually below 50)
Blowdown Bottom/Top

Water volume

> or = 260
220 - 240
180 - 200
140 - 160
100 - 120
60 -80
0 - 40

> or = 9.2
8.8 - 9.0
8.3 - 8.6
7.0 - 8.0
< or = 6.0

> 80
60-80
40-60
20-40
0 - 20
> or = 90
81 - 90
70 - 80
61 - 69
< or = 60

10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

Boiler Water Treatment Program

Shipboard Log Sheet 311/312- for Coordinated Boiler Water Treatment with Oxygen Control or Oxygen Scavenger Plus
Ship Name

Owner

Boiler Maker
Evaporation rate-Kg/h
Year

Type

Pressure, bar

Month

Make up

Boiler Identification:

Hardness Control
Phosphate
ppm as PO4
Limits 20 to 50

100 - 150

40
30
20
10
0

> or = 170
150
130
110
90
< or = 70

Dosage in ml
M. Alkalinity

Boiler pH

Oxygen Control
Hydrazine ppm N2H4
limits 0.10 - 0.20

Over 2xP.Alk
Below 2xP.Alk
Over 11.0
9.5 - 11.0
Below 9.5
> or = 0.25
0.20
0.15
0.10
< or = 0.05

Dosage in Liter

(Alternative to Ox. Ctrl)

Oxygen Scavenger +
(Diethylhydroxylamine)
DEHA
limits: 0.08 - 0.30 ppm

> or = 0.40
0.35
0.30
0.25
0.20
0.16
0.12
0.08
< or = 0.04

Dosage in Liter

Boiler Chlorides
Max 200 ppm as Cl
Should be kept as
low as possible
(Usually below 50)
Blowdown Bottom/Top

Condensate pH
Limits
8.3 - 9.0
Condensate Control
Dosage in Liter

Condensate Chloride
Usually below 20 ppm
Should be kept as
low as possible

Hotwell
Temp oC
The higher the better

Comments:

Shore

Distilled

Ton
Mixed

Eg: Aux. Boiler / Exh. Gas Boiler / Boiler 1

Day 1
> or = 70
60
50

Dosage in grammes

Alkalinity Control
P. Alkalinity
ppm as CaCO3

Water volume

> or = 260
220 - 240
180 - 200
140 - 160
100 - 120
60 -80
0 - 40

> or = 9.2
8.8 - 9.0
8.3 - 8.6
8.2
< or = 8.0

> 80
60-80
40-60
20-40
0 - 20
> or = 90
81 - 90
70 - 80
61 - 69
< or = 60

10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

Boiler Water Treatment Program

Shipboard Log Sheet 311/312- for Coordinated Boiler Water Treatment with Oxygen Control or Oxygen Scavenger Plus
Ship Name

Owner

Boiler Maker
Evaporation rate-Kg/h
Year

Type

Pressure, bar

Month

Make up

Boiler Identification:

Hardness Control
Phosphate
ppm as PO4
Limits 20 to 50

100 - 150

Day 1
> or = 70
60
50
40
30
20
10
0

> or = 170
150
130
110
90
< or = 70

Dosage in ml
M. Alkalinity

Boiler pH

Oxygen Control
Hydrazine ppm N2H4
limits 0.10 - 0.20

Over 2xP.Alk
Below 2xP.Alk
Over 11.0
9.5 - 11.0
Below 9.5
> or = 0.25
0.20
0.15
0.10
< or = 0.05

Dosage in Liter

(Alternative to Ox. Ctrl)

Oxygen Scavenger +
(Diethylhydroxylamine)
DEHA
limits: 0.08 - 0.30 ppm

> or = 0.40
0.35
0.30
0.25
0.20
0.16
0.12
0.08
< or = 0.04

Dosage in Liter

Boiler Chlorides
Max 200 ppm as Cl
Should be kept as
low as possible
(Usually below 50)
Blowdown Bottom/Top

Condensate pH
Limits
8.3 - 9.0
Condensate Control
Dosage in Liter

Condensate Chloride
Usually below 20 ppm
Should be kept as
low as possible

Hotwell
Temp oC
The higher the better

Comments:

Shore

Distilled

Ton
Mixed

Eg: Aux. Boiler / Exh. Gas Boiler / Boiler 1

Dosage in grammes

Alkalinity Control
P. Alkalinity
ppm as CaCO3

Water volume

> or = 260
220 - 240
180 - 200
140 - 160
100 - 120
60 -80
0 - 40

> or = 9.2
8.8 - 9.0
8.3 - 8.6
8.2
< or = 8.0

> 80
60-80
40-60
20-40
0 - 20
> or = 90
81 - 90
70 - 80
61 - 69
< or = 60

10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

Boiler Water Treatment Program

Shipboard Log Sheet 315+313- for Combined Boiler Water Treatment with Autotreat & Oxygen Scavenger Plus
Ship Name

Owner

Boiler Maker
Evaporation rate-kg/h
Year

Type

Pressure, bar

Month

Make up

Boiler Identification:

Autotreat
P. Alkalinity
ppm as CaCO3
100 - 300

Sample appearance

Oxygen Scavenger +
(Diethylhydroxylamine)
DEHA
limits: 0.08 - 0.30 ppm

Day 1
> or = 350
330
310
290
270
250
230
210
190
170
150
130
110
90
< or = 70

Over 11.0
9.5 - 11.0
Below 9.5
Cloudy
Clear
Coloured
> or = 0.40
0.35
0.30
0.25
0.20
0.16
0.12
0.08
< or = 0.04

Dosage in Liter

Boiler Chlorides
Max 200 ppm as Cl
Should be kept as
low as possible
(Usually below 50)
Blowdown Bottom/Top

Condensate pH
Limits
8.3 - 9.0

Condensate Chloride
Usually below 20 ppm
Should be kept as
low as possible

Hotwell
Temp oC
The higher the better

Comments:

Shore

Distilled

Ton
Mixed

Eg: Aux. Boiler / Exh. Gas Boiler / Boiler 1

Dosage in Liter

Boiler pH

Water volume

> or = 260
220 - 240
180 - 200
140 - 160
100 - 120
60 -80
0 - 40

> or = 9.2
8.8 - 9.0
8.3 - 8.6
7.0 - 8.0
< or =6.0
> 80
60-80
40-60
20-40
0 - 20
> or = 90
81 - 90
70 - 80
61 - 69
< or = 60

10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

GENERAL RECOMMENDATIONS
TAKE THE SAMPLES ALWAYS FROM SAME PLACE AND LEAVE A FEW SECONDS TO DRAIN TO COLLECT A VALID SAMPLE.(FILTER IF TOO CLOUDY)
(BOILER: FROM MID OR BOTTOM - CONDENSATE: FROM HOTWELL, INSPECTION TK OR CONDENSER- COOLING: FROM RUNNING CIRCUIT.NOT FROM TK!)
COOL DOWN THE SAMPLES AS SOON AS POSSIBLE AND TEST IN THE NEXT 15-30 MINUTES, SAMPLES BELOW 21C !!!
USE DISTILLED WATER AS MAKE UP ONLY... USING A FEED WTR >50 PPM CHLORIDE WILL REDUCE TREATMENT EFFICIENCY DRASTICALLY.
TEST AT LEAST TWICE A WEEK AND FOR MEDDIUM PRESSURE BOILER... ANALYZE EVERYDAY
IF ANY REAGENT TABLET SHOW SPOT CONTAMINATION. THROW IT AWAY ...
ON ANY BOILER: CARRY OUT DAILY FLASH (INTENSE-FULL OPEN & BRIEF) BOTTOM BLOWDOWNS TO ELIMINATE SOLIDS PRECIPITATED BY CHEMICALS
THE TEMPERATURE OF HOTWELL TANK SHOULD BE THE HIGHEST POSSIBLE(95) TO REDUCE OXYGEN ABSORPTION (BY PASS CONDENSER IF NEEDED)
SEND THE LOGS REGULARY TO UNITOR FOR A PROPER TRACKING & ADVISE
PH PAPER STRIPS SHOULD BE IMMERSED FOR 20-30 SECONDS. USE REAGENT FOR BOILER & CONDENSATE SAMPLES
PH VALUES SHOULD BE RIGHT WHEN THE CHEMICAL RESERVE IS WITHIN LIMITS. IN CASE OF EXTERNAL CONTAMINATION CAN BE LOWER
IF PH IS LOWER THAN MINIMUN AND CHEMICAL RESERVE IS OK, ADD 50 ML PER TON OF ALKALINITY CTRL TO RESTORE THE NORMAL VALUES
IN THE COMMENTS CELL: PLS WRITE DOWN WHEN THE CHEMICAL PRODUCTS RUN OUT OF STOCK. TO UNDERSTAND LOW READINGS
THERE IS NO TREATMENT FOR HIGH CHLORIDE: CHANGE THE WATER AND FILL UP WITH PURE DISTILLED IS THE ONLY SOLUTION
IN THE COMMENTS CELL, PLS ADVISE THE FOLLOWING INFO:
WHEN A SUDDEN CHANGE OF NORMAL RUNNING CONDITION (IE. DRAIN DUE TO REPAIRS,MAINTENANCE, INSPECTION, BIG LEAKS, ETC)
IF AN OIL OR SEAWATER CONTAMINATION HAPPENS
IF A BOILER IS KEPT ON LAID-UP FOR SOME WEEKS, OR WHICH ONE WORKS AS MASTER OR SLAVE
PLS MENTION WHEN A BOILER RUNS AT FULL OUTPUT (TANKERSHIPS WHEN USING STEAM CARGO PUMPS)...ADD MORE CHEMICALS THAT DAY

COOLING SYSTEMS: SPECTRAPAK 309 TEST KIT

There are -2- identical treatment products: Dieselguard NB & Rocor NB (The difference is the second one is Liquid & a little less concentrated)
Dieselguard NB...it should be diluted in a ratio 1 kg in 10 ltr of warm water before pouring into the tank
NB means Nitrite (Passivated protection layer by hard oxide) & Borate (a PH buffer to maintain alkalinity always within recommended limits)
Working range should be between 1200-2400 ppm NO2 (Nitrite)... But there is no risk when overdose...just an economical limit. If less 1.000 ppm corrosion can appear
In case of Chloride a little higher than 50 ppm cl- (maximun limit) as a temporary solution goto to 3.000 ppm NO2...water should be changed by distilled wtr asap
Do not use these chemicals to treat circuits with Aluminium compounds(ie.cylinder heads)... Use our specific treatment "CoolTreat AL" for these cases.
If you notice an abnormal chemical consumption with no leaks could be due to a bacteria contamination (eating nitrate...):Carry out a bacteria analysis (kit 568568)
LOW PRESSURE BOILERS (7 BAR) OR (16/25 BAR) WITH LESS THAN 10.000 KG/HR STEAM PRODUCTION
We call it: Combined treatment...You have -2- options.
1.- Traditional with Liquitreat & Condensate Control: SPECTRAPAK 310 TEST KIT.
Liquitreat is a one shot treatment for alkalinity reserve, oxygen scavenger, phosphate & sludge conditioner. Condensate Ctrl avoid acidity in the condensate circuit
Liquitreat concentration should be between 100-300 ppm CaCO3. Condensate Ctrl is a continuous product use 0,75 ltr per Day for a 10 ton boiler
Condensate PH should be between 8,3 & 9,0. Inject the product, into the hotwell, one meter below the wtr surface; to avoid contact with atmospheric oxygen
2.- Enviromentaly friendly range, with Autotreat & Oxygen Scavenger Plus: SPECTRAPAK 313+315 TEST KIT
Autotreat is a new generation one shot blr treatment with volatile compound...we can say it works as Liquitreat & Condensate Ctrl at a time, but has no Oxygen Scavngr.
Oxygen Scavenger Plus is a hydrazine free volatile compound of new amine called DEHA. Its should be dosed continuously (with a dosing pump):1 ltr/day +/Working range for Autotreat is like Liquitreat (100-300 ppm CaCO3). Oxygen Scavenger Plus, should be in concentration between (0.08-0.30 ppm DEHA)
LOW PRESSURE BOILERS WITH > 10.000 KG/H STEAM PRODUCTION & MEDIUM PRESSURE BOILERS:SPECTRAPAK 311/312 TEST KIT.
We call it : Co-ordinated blr treatment... You will need to use: -4- products for better and accurate parameter control
Hardness Control: A phosphate reserve will precipitate calcium hardness in a non adherent sludge. Working range between 20-50 ppm PO4.
Alkalinity Control: A concentrated alkaline reserve to prevent acid corrosion & assists the precipitation of other salts. Working range between: 100-150 ppm CaCo3.
Oxygen Control: Hydrazine compound to avoid oxygen pitting and maintain the magnetite layer. Working range between: 0.10-0.20 ppm N2H4
Oxygen Ctrl should be used continuously by metering pump around 1 ltr/day. Increase dosage(2-3 ltr/day) when the steam demand is higher (Cargo pumps running)
Alternatively Oxygen Ctrl can be replaced by Oxygen Scavenger Plus (less toxic) in a similar way. (Use 315 Spectrapak test kit for this purpose)
Condensate Control: Our neutralizing agent to avoid corrosion in the condensate lines. Best used continuously with a metering pump around 0.75 ltr/day (10 T system)

WATER TREATMENT DOSING CHART FOR COOLING SYSTEMS & LOW PRESSURE BOILERS
TABLETS NITRITE CHLORIDE P ALKALINITY ROCOR NB DIESELGUARD NB LIQUITREAT/AUTOTREAT COMBITREAT
1
180
0
10 13.6
3.2
3.1
0.45
2
360
20
30 12.1
2.9
2.7
0.35
3
540
40
50 10.6
2.5
2.4
0.30
4
720
60
70 9.0
2.1
2.1
0.25
5
900
80
90 7.5
1.7
1.8
0.20
6
1,080
100
110 OK
OK
OK
OK
7
1,260
120
130 OK
OK
OK
OK
8
1,440
140
150 OK
OK
OK
OK
9
1,620
160
170 OK
OK
OK
OK
10
1,800
180
190 OK
OK
OK
OK
11
1,980
200
210 OK
OK
OK
OK
12
2,160
220
230 OK
OK
OK
OK
13
2,340
240
250 OK
OK
OK
OK
14
2,520
260
270 --OK
OK
15
2,700
280
290 --OK
OK
16
2,880
300
310 ----DOSING QUANTITIES ARE ADVISED TO BE MULTIPLIED BY TON OF EACH CIRCUIT TOTAL CAPACITY
Nitrite reserve will reach 1.800 ppm NO2 & Alkalinity reserve will reach 200 ppm CaCO3
If chloride reading is higher than 50 ppm Cl- in cooling circuits. Change water by distilled or raise NO2 till 2.880 ppm as a temporary solution
For boiler systems carry out daily bottom flash blowdowns. Increase time if chloride exceeds 50 ppm

WATER TREATMENT PRODUCT CONCENTRATION

ROCOR NB: 2.1 LTR/TON WILL INCREASE BY 250 PPM DE NITRITE (NO2) RESERVE. INITIAL DOSAGE: 13.6 LTR/TON
DIESELGUARD NB: O.5 KG/TON WILL INCREASE BY 250 PPM NO2 RESERVE. INITIAL DOSAGE: 3.2 KG/TON
LIQUITREAT-AUTOTREAT: 0.8 LTR/TON WILL INCREASE BY 50 PPM P ALKALINITY (CaCO3). INITIAL DOSAGE: 3.1 LTR/TON
CONDENSATE CONTROL: CONTINOUS TREATMENT. FOR A 10 TON SYSTEM USE: 0.75 LTR/TON EVERY DAY
OXYGEN SCAVENGER PLUS: CONTINOUS TREATMENT. USE 1 LTR/DAY .MODIFY +/- 25% TO RESTORE WORKING RANGE.
HARDNESS CONTROL: 23 GRM/TON WILL INCREASE BY 20 PPM THE PHOSPHATE (PO4) RESERVE. INITIAL DOSAGE: 46 GRM/TON
ALKALINITY CONTROL: 0.18 LTR/TON WILL INCREASE BY 100 PPM (CaCO3) ALKALINITY RESERVE. INITIAL DOSAGE: 0.250 ML/TON
OXYGEN CONTROL: IT IS A CONTINUOUS TREATMENT. USE 1 LTR/DAY.MODIFY +/- 25% TO RESTORE WORKING RANGE. ON LAID-UP USE 1.25LTR/TON
BOILER COAGULANT: IT IS A SLUDGE & MINOR OIL REMOVER. USE BETWEEN 0.25 - 0.50 LTR PER DAY TO CLEAN THE WATER & IMPROVE BLOWDOWN