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Rock phosphate is the raw material used in the manufacture of most commercial phosphate
fertilizers on the market. In the past, ground rock phosphate itself has been used as a source
of P for acid soils. However, due to low availability of P in this native material, high
transportation costs, and small crop responses, very little rock phosphate is currently used in
agriculture.
solution (28-0-0) to form 7-21-7 and related grades. The P in these products is present in both
the orthophosphate and polyphosphate form.
When ammonia is added to the phosphoric acid that has not been heated, monoammonium
phosphate (11-52-0) or diammonium phosphate (18-46-0) is produced depending on the ratio
of the mixture. The P present in these two fertilizers is present in the orthophosphate form.
The cost of converting rock phosphate to the individual phosphate fertilizers varies with the
process used. More importantly, the processes used have no effect on the availability of P to
plants.
Reference:
http://www.extension.umn.edu/distribution/cropsystems/DC6288.html