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Clinical Implications
This study showed that heat-pressed lithium disilicate can be reused up to 4
times. Routine mechanical strength tests revealed no adverse consequences
for lithium disilicate when it is reused and that dental laboratories may be
routinely and unnecessarily discarding excess material.
Heat pressing of glass ceramic materials for dental applications is a
proven method of fabricating xed
prosthodontic restorations.1-20 These
restorations are translucent because of
the absence of a metal substructure
Assistant Professor, Division of Restorative Dentistry and Periodontology, Dublin Dental University School and Hospital.
Graduate student, Department of Restorative Dentistry, University Dental School and Hospital, University College Cork.
c
Graduate student, School of Mechanical and Materials Engineering, University College Dublin.
d
Senior Lecturer, School of Mechanical and Materials Engineering, University College Dublin.
b
Gorman et al
December 2014
extends its recommended use to short
span partial xed dental prostheses. IPS
e.max Press material has now replaced
IPS Empress 2; it has improved mechanical properties and has signicantly higher translucency (Ivoclar
Vivadent, IPS e.max Press Scientic
Documentation, 2011). The microstructure consists of 70% lithium disilicate crystals embedded in a glassy
matrix. These crystals are acicular in
morphology and measure 3 to 6 mm in
length. Recommendations for its clinical use remain unchanged. IPS e.max
Press is available in 4 different levels of
opacity and/or translucency, the selection of which is determined by the requirements of the individual clinical
treatment. It is supplied for heat
pressing in 2 sizes, a small ingot that
weighs 3.2 g or a larger ingot that
weighs 6.1 g. It is more economical to
press several restorations from 1 ingot
at the same time. However, this often is
not possible and may result in a
considerable amount of leftover material. The issue is thereby raised whether
the leftover material should be discarded or reused. Concerns as to the
mechanical properties of the reused
material for clinical use are valid.
Extensive research into the mechanical properties and clinical performance
of heat-pressed glass ceramics has been
carried out over the past 2 decades.1-20
In spite of this, only 2 studies that
examined the mechanical and microstructural properties of re-pressed ceramics were identied by the present
authors.19,20 In the rst of these
studies, the re-pressing of both IPS
Empress and IPS Empress 2 was evaluated.19 The biaxial exural strength
(BFS) of the pressed and re-pressed
materials was unchanged, although a
higher scatter of the data was reported
for the re-pressed material. Weibull
analysis of the data indicated that there
was less reliability when the material
was re-pressed. X-ray diffraction (XRD)
revealed no differences in crystalline
phase assemblage or x-ray reection
intensities with re-pressing. Scanning
electron microscopy (SEM) revealed
larger crystals for the re-pressed IPS
Gorman et al
1371
Empress 2; this was attributed to Ostwald ripening, whereby larger crystals
grow at the expense of smaller ones.
The conclusion was that re-pressing the
material did not result in lower mechanical properties; however, the
greater scatter may predict a reduction
in reliability for the materials. In the
second study, a signicant difference in
BFS was observed for re-pressed IPS
Empress 2.20 These studies show
promising results and give good insight
into re-pressed materials. However,
studies have only tested a single reuse
of the material, whereas, in practice, it
could be reused several times, depending on the amount of material left over.
The null hypothesis of the present study
is that IPS e.max Press can be reused
without adversely affecting its mechanical properties.
1372
Table I.
BFS, MPa
Hardness, Hv/5
KIc, MPa.m
0.5a
Group 0
Group 1
Group 2
Group 3
Group 4
10
n/a
243.4 45.9
252.7 23.7
225.06 35.3
214.8 45.9
.137
585.2 6.42
548.8 28.68
559.4 8.68
526.4 49.13
547.6 13.39
.99
0.29 0
1.13 0.02
1.01 0.13
1.05 0.04
1.09 0.05
<.001
n/a, not available; BFS, biaxial exural strength; Hv, Vickers hardness; KIc, fracture toughness.
a
If group 0 is omitted, then there was no statistically signicant variation in fracture toughness (P>.05).
250
Biaxial Flexural
Strength (MPa)
Hv
300
2F sin 136e
F
2
z1:854 2 ;
d
d2
200
150
100
50
0
Press Number
1 Biaxial exural strength for IPS e.max Press groups 0-4
with 95% condence intervals.
dried and sputter coated with gold.
SEM (Quanta 3D FEG DualBeam) was
used to examine the surface topography
of the specimens; it also served as a
means of assessing a change in the
grain width or length within the specimens after re-pressing. Grains were
arbitrarily selected (n10) from 1
micrograph for each pressing, and the
width and length of each selected grain
was recorded.25 Optical microscopy
(Leica DFC320) also was performed to
assess indentations on the specimens.
Differential scanning calorimetry
(Stanton-Redcroft STA 1500; Rheometric Scientic) was carried out for
each group in a owing nitrogen atmosphere; the specimens were placed
in matched platinum-rhodium crucibles
and heated to 1200 C at 10 C/min
and cooled at 10 C/min until a temperature of 25 C was reached. Where
applicable, the results were statistically
analyzed with 1-way ANOVA (a.05).
RESULTS
The results of mechanical testing
are presented in Table I. No BFS
Gorman et al
December 2014
1373
mm mean length and 0.19 mm mean
Fracture Toughness
(MPa.m0.5)
1.4
1.2
1
0.8
0.6
0.4
0.2
0
Press 1
Press 2
Press 3
Press 4
Press Number
Hardness (Hv/5)
DISCUSSION
200
100
0
Group Number
Intensity (arb.)
10
20
30
40
50
60
70
Degrees 2
4 X-ray diffraction data for groups 0-4 exhibiting peaks at
2q values of 24.19 degrees, 24.74 degrees and 46.54 degrees. Note difference between group 0 and that of other
groups.
phase. The dominant peaks present for
groups 1 to 4 are shown in Figure 4.
The major peaks for lithium disilicate
(Li2Si2O5) were observed at 2q values of
24.74 degrees, 24.19 degrees, and
46.54 degrees. The dominant peak was
at 24.74 degrees, which corresponds to
the (040) crystallographic plane of this
monoclinic phase. The XRD data
Gorman et al
1374
5 Scanning electron microscopy images for IPS e.max Press. A, Group 0. B, Group 1. C, Group 2. D, Group 3. E, Group 4.
Growth in grain size is evident from group 0 to group 4. F, Shows group 2 with increased magnication. Note increase in
secondary crystals present. This is due to partial dissolution of crystals at 960 C.
Gorman et al
December 2014
1375
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
500
600
700
800
900
1000
Temperature (degrees C)
6 Representative differential scanning calorimetry for
IPS e.max Press group 3 showing dissolution at 960 C.
comparative purposes only. Because of
the indentation method selected to
measure this property, comparing the
results with absolute values determined
by other means in the literature is
inadvisable.
XRD revealed that lithium disilicate
was present in all the groups, and no
difference existed among the patterns for
each group. Observations of the scanning electron micrographs indicated an
increase in crystal grain growth at the
expense of smaller crystals. This nding
is in agreement with another study,
which found that Ostwald ripening
occurred when the material was reused
once.19 The current study indicated that
grain growth occurs and has an
approximately linear relationship with
an increased number of pressings.
SEM revealed not only the expected
primary lithium disilicate crystals (as
conrmed by XRD) but also secondary
crystals, which appeared in greater
numbers with an increased number of
press cycles. In other systems, such secondary crystals may be due to the
nucleation of polymorphs of the primary
crystal type.29 In the present study, no
additional phases were seen with
increased pressings from XRD, whereas
the number of secondary crystals did
appear to increase with the number of
pressings. Therefore, the secondary
crystals are likely to be due to recrystallization of the crystals after they either
partially melt or partially dissolve in the
residual glass phase during the process
cycle. The DSC trace (Fig. 6) showed
that the melting endotherm begins at
Gorman et al
CONCLUSIONS
The optimum properties for IPS
e.max Press are probably obtained with
the rst pressing. However, no material
mechanical properties appear to vary
signicantly with subsequent pressings.
Although results of this study determined that reusing the material is
possible, the authors did notice some
qualitative differences in specimen
handling with increased reuse (up to 4
times). As such, conclusive support is
not possible for its reuse to this extent.
REFERENCES
1. Cattell MJ, Clarke RL, Lynch E. The transverse
strength, reliability and microstructural features of four dental ceramics: part 1. J Dent
1997;25:399-407.
2. Gorman CM, McDevitt WE, Hill RG. Comparison of two heat-pressed all-ceramic
dental materials. Dent Mater 2000;16:
389-95.
3. Cattell MJ, Knowles JC, Clarke RL, Lynch E.
The biaxial exural strength of two pressable
ceramic systems. J Dent 1999;27:183-96.
4. Dong JK, Luthy H, Wohlwend A, Scharer P.
Heat-pressed ceramics: technology and
strength. Int J Prosthodontics 1992;5:9-16.
5. Probster L, Geis-Gerstorfer J, Kirchner E,
Kanjantra P. In vitro evaluation of a glassceramic restorative material. J Oral Rehabil
1997;24:636-45.
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