MB 2 - Ceridust and Licoene PDF

Public
BU Additives
TM Waxes
10.02.2010
Clariant Waxes for

Pigment & Additive
Masterbatches
Masterbatch II
Ceridust & Licocene for color preparation
Table of Contents
Base information on Clariant waxes (focus on Ceridust & Licocene)
Information on selected monoazo-pigments in PP and LLDPE
Information on selected diazo-pigments in PP
Information on selected polycyclic pigments in PP and LLDPE
Information on Cu-phtalocyanine in PC, PET and PA (concrete example)
Summary
Back-up
Public: Masterbatch Presentation Part II

BU Additives, TM Waxes (Copyright Clariant. All rights reserved.)
10.02.2010
Slide 2
Base Information on
Clariant Waxes
focused on Ceridust & Licocene
Wax-Types Used in Masterbatch

Value Stories -ExtractCustomer
PP fiber
producer in
Latam
MB
manufacturer in
China
Dispersing aid
for PP MB
Product
Licocene PP 1502 FG,
Licocene PP 6102 FG

Ceridust 6050 M

Ceridust 6050 M
Public: Masterbatch Presentation Part II > Base Information on Clariant Waxes

Key benefit
optimized production process and formula with

economies of >15 %,
increased pigment load from 25 % to 50 %
better dispersion ability by lower content of

dispersing aid
the same filter value is achieved,
5 - 10 % higher tensile strength,
better compatibility
excellent price-performance ratio due to

superior dispersion ability,
oustanding technical performance in high

demanding fiber applications

10.02.2010
Slide 4
Wax-Types Used in Masterbatch

Value Stories
Customer
Product
MB producer in
Europe
Ceridust 6050 M
Dispersing aid
for PP MB in
China
Licocene PP 6102 FG
Key benefit
superior filter value and color strength at the

same
highly efficient dispersion agent for film and PP

fiber MB
source and full version available:
Teamroom Licocene grades for plastic application


10.02.2010
Slide 5
The Clariant Wax Range

Abstract
Polyolefin Waxes
non-polar
Polypropylene
Waxes
TP Ceridust 6050 M
Amide Waxes
Montan Waxes
oxidized
Polyethylene
Waxes
Licowax C
Licolub WE 4
Ceridust 3910
Licolub WE 40
Licolub H 4
Licolub CE 2 TP
Licolub WM 31
Licowax OP
Licowax PED 191
Licowax E
Licocene PP 1302
Liocwax PED 521
Licomont CaV 102
Licocene PP 1502
Licolub H 12
Licomont NaV 101
Licocene PP 1602
Ceridust 3715
Licocene PP 2602
Licomont ET 141
Licomont ET 132
Licocene PP 6502 TP
Polyethylene
Waxes
Licowax PE 130
highly modified
Polymer Wax
polar
Licocene PP 6102
Licocene PP 7502 TP
Hydrocarbon
Wax
modified
Polypropylene/
Polyethylene Waxes
Licowax PE 520
Licocene PP MA 6452 TP
Liocwax PE 190
Licocene PE 4201
Licocene PE MA 4221
Licocene PE 5301
Licocene PE MA 4351
Ceridust 5551
Ceridust 130
Ceridust 3620

10.02.2010
Slide 6
Clariant Wax used for Color Preparations

Recommended
Polyolefin Waxes
non-polar
Polypropylene
Waxes
TP Ceridust 6050 M
Amide Waxes
highly modified
Polymer Wax
Montan Waxes
polar
oxidized
Polyethylene
Waxes
Licowax C
Licolub WE 4
Ceridust 3910
Licolub WE 40
Licolub CE 2 TP
Licolub WM 31
Licowax OP
Licocene PP 1502
Licowax PED 191
Licowax E
Licocene PP 1602
Liocwax PED 521
Ceridust 5551
Licocene PP 2602
Licolub H 12
Licocene PP 6102
Ceridust 3715
Licocene PP 7502 TP
Polyethylene
Waxes
Licowax PE 130
modified
Polypropylene/
Polyethylene Waxes
Licowax PE 520
Liocwax PE 190
Licocene PE 4201
Licocene PE MA 4221
Legal status of waxes from Clariant

with respect to Food Legislation (FDA)
Ceridust 130
is listed in DA 8250 E_11/06
Ceridust 3620

10.02.2010
Slide 7
The Licocene Range

Abstract
Licocene
as processing/dispersing aid
Polyolefin Waxes
non-polar
Polypropylene
Waxes
Polyethylene
Waxes
polar
Licocene PP 6102*
Licocene PP 1602 *
Licocene PP 1302
Licocene PP 1502*
Licocene PP 2602*
Licocene PP 6502 TP
Licocene PP 7502 TP
Licocene PE 4201*
Licocene PE MA 4221*
Licocene PE 5301*
Licocene PE MA 4351
modified
Polypropylene
Waxes
modified
Polyethylene
Waxes
*Licocene used in masterbatch


10.02.2010
Slide 8
The Ceridust Range

Abstract
Ceridust
as
dispersing improver
Amide
Waxes
Polyolefin
Waxes
non-polar
polar
PE-wax
oxidized
PE-wax
Ceridust 130
Ceridust 3620
Ceridust 3715
Ceridust 3910
CompoundWaxes
PP-wax
Ceridust 6050 M
Montan
Waxes
Ceridust 5551
Legal status of waxes from Clariant

with respect to Food Legislation (FDA)
is listed in DA 8250 E_11/06
Ceridust 9615 A


10.02.2010
Slide 9
Influence of Particle Size and Amount of Wax

30 % Cu-Phthalocyanine in LLDPE
30 % Pigment Blue 15:1 + 50 % LLDPE (MFR 25) + 13,3 % Licowax PE 520 + 6,7 % Ceridust 3620
18
filter pressure value [bar/g]
16
14
decrease of filter pressure value (FPV) due to
12
finer particle size and higher amount of wax
10
8
6
4
2
0
without wax
10% Licowax
PE 520
filter value: DIN-EN 13900-5

filter:
40 m, 725 mesh

15% Licowax
PE 520
20% Licowax
PE 520
15% PE 520 + 20% PE 520 +

Ceridust 3620 Ceridust 3620
(2:1)
(2:1)
premix: cold mixing

10.02.2010
VN 86931 Slide
- 86941
10
In Medias Res from Practice for Practice

Monoazo-Pigments in PP and LLDPE
Licocene PP for Monoazo-Pigments

40 % Naphtol AS in PP
125
120
115
4
110
3
105
2
1
100
95
30 % PP-Wax A (800 mPas)

filter:
30 % Licocene PP 6102 FG
premix: cold mixing
rel. Color yield [%]
40 % Pigment Red 170 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102
Filter pressure value (FPV) in [bar/g]
FPV
rel. Color yield
color yield: DIN 55986
14 m, 724 mesh
Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Monoazo-Pigments in PP and LLDPE
10.02.2010
Slide 12
Licocene & Ceridust for Monoazo-Pigments

40 % Laked-Azo-Pigment in PP
40 % Pigment Red 48:2 + 30 % PP HG 245 (Borealis) + 20 % Licocene PP 6102 +
10 % Ceridust 6050 M
10
120
115
110
105
100
4
95
90
85
0
80
20 % PP-Wax B
(1700 mPas)

filter:
30 % PP-Wax B +
Ceridust 6071 (2:1)
30 % Licocene PP 6102 +
C 6050 M (2:1)
premix: hot mixing
FPV
rel. Color yield
25 m
10.02.2010
Slide 13
Ceridust for Monoazo-Pigments

40 % Laked-Azo-Pigment in PP
14
140
135
130
125
120
115
110
105
100
95
90
12
10
8
6
4
2
0
without wax

filter:
20% Licowax 30% Licowax 20% PE 520 + 30% PE 520 +

PE 520
PE 520
Ceridust 3620 Ceridust 3620
(2:1)
(2:1)
premix: cold mixing
40 % Pigment Red 57:1 + 30 % LLDPE (MFR 25) + 20 % Licowax PE 520 + 10 % Ceridust 3620
FPV
rel. Color yield
24 m, 615 mesh
VN 86196- 86203
10.02.2010
Slide 14

Diazo-Pigments in PP

40 % Pigment Yellow 155 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102 FG
20
125
120
15
115
10
110
105
5
100
0
95
20 % PP-Wax B

filter:
130
30 % Licocene PP 6102
premix: cold mixing
FPV
rel. Color yield
40 m
Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Diazo-Pigments in PP
10.02.2010
Slide 16
Licocene & Ceridust for Diazo-Pigments

40 % Diazo-Condensation in PP
10
1 (excellent)
20 % PP-Wax B

filter:
6050 M
20 % Licocene
PP 6102 FG
(bad)
Film note
40 % Pigment Yellow 155 + 40 % PP HG 245 (Borealis) + 13 % Licocene PP 6102 + 7 % Ceridust
13 % PP 6102 FG +
13 % PP 1302 +
7 % Ceridust 6050 M 7 % Ceridust 6050 M
premix: hot mixing
14 m, 725 mesh
FPV
Film note
film note: Clariant norm

VN 94186 94201 // 94295 298
10.02.2010
Slide 17

40 % Pigment Red 214 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102
20
125
120
15
115
10
110
105
5
100
0
95
30 % PP-Wax B

filter:
130
30 % PP-Wax A
30 % Licocene PP 6102
premix: cold mixing
FPV
rel. Color yield
25 m
10.02.2010
Slide 18

Polycylic Pigments:
Quinacridone in PP
Cu-Phtalocyanine in PP and LLDPE
Dioaxine in PP
Licocene & Ceridust for Polycyclic Pigments

30 % Quinacridone in PP
30 % Pigment Violett 19 + 40 % PP HG 245 (Borealis) + 20 % Licocene PP 6102 +
10 % Ceridust 6050 M
> 21 bar/g
20
130
15
120
10
5
110
100
no wax

filter:
140
25 m
30% PP-Wax B +
30% Licocene PP 6102 +
Ceridust 6050M, (2:1)
Ceridust 6050M (2:1)
premix: cold mixing
Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Polycylic Pigments:
Dioaxine in PP
Quinacridone in PP
FPV
rel. Color yield

10.02.2010
Slide 20

40 % Cu-Phtalocyanine in PP
40 % Pigment Green 7 + 45 % PP HG 245 (Borealis) + 10 % Licocene PP 6102 + 5 % Ceridust 6050 M
12
10
110
8
6
100
4
2
0
90
15% PP-Wax A

filter:
25 m
10% Licocene PP 6102 + 15% Licocene PP 6102 +

Ceridust 6050M, (2:1)
Ceridust 6050 M, (2:1)
premix: hot mixing
Dioaxine in PP
FPV
rel. Color yield
Quinacridone in PP

10.02.2010
Slide 21
Licocene PP for Polycyclic Pigments

40 % Cu-Phtalocyanine in LLDPE
1,2
300
250
0,8
200
0,6
150
0,4
100
0,2
50
0
30% Licowax PE 15% PP 1302 FG 15% PP 1502 FG 30% PP 1502 FG
520
+ PP 6102 FG (2:1)
+ PP 6102 FG (2:1)

filter:
Film surface irregularities (specs) in

[number]
40 % Pigment Green 7 + 30 % LLDPE (Borealis) + 20 % Licocene PP 1502 + 10 % Licocene PP 6102
14 m, 724 mesh
premix: Haake-Kneader (roller type rotor); 120 C; 40 rpm; 7 min.

application weight: 5 kg
Dioaxine in PP
Quinacridone in PP
FPV
Film specs
film note : Clariant norm

10.02.2010
Slide 22

40 % Pigment Green 7 + 30 % LLDPE (MFR 25) + 20 % Licowax PE 520 P + 10 % Ceridust 3620
15 kg/h
1,8
1500
1400
1,6
1300
1,4
1200
1,2
1100
1000
0,8
900
0,6
800
0,4
700
0,2
600
500
30 % Licowax
PE 520

filter:
18 kg/h
14 m, 724 mesh
30 % PE 520 +
C 3620 (2:1)
30 % Licowax
PE 520
30 % PE 520 +
C 3620 (2:1)
premix: cold mixing
Dioaxine in PP
Film surface irregularities (specs) in

[number]
FPV
Film specs
Quinacridone in PP

10.02.2010
Slide 23

40 % Heligonblue K-6907 + 40 % Escorene LL 6101 + 10 % Licowax PE 520 + 10 % Ceridust 3610
16
114
14
112
110
12
108
10
106
104
102
100
98
96
94
Withou Wax

filter:
14 m
20 % Licowax PE 520
30 % Licowax PE 520 +
Ceridust 3610 (2:1)
premix: cold mixing
Dioaxine in PP
Quinacridone in PP
FPV
rel. Color yield

10.02.2010
Slide 24

40 % Cu-phtalocyanine in LLDPE
16
120
14
115
12
110
10
8
105
100
4
95
2
0
90
Withou Wax

filter:
14 m
20 % Licowax PE 520
Ceridust 3610 (2:1)
premix: hot mixing
Dioaxine in PP
Quinacridone in PP
FPV
rel. Color yield

10.02.2010
Slide 25

16
14
5
12
10
8
3
6
4
2
0
1
Withou Wax

filter:
(bad)
film note
14 m
20 % Licowax PE 520
Ceridust 3610 (2:1)
premix: hot mixing
Dioaxine in PP
Quinacridone in PP
(excellent)
FPV
Film note

10.02.2010
Slide 26

40 % Dioazine in PP
40 % Pigment PV Fast Violet RL (violett 23) + 30 % PP powder (MFI 25 g/10 min) +
20 % (13) Licocene PP 6102 FG + 10 % (7) Ceridust 6050 M
10
9
8
7
6
5
4
3
2
1
0
hot mix
115
110
105
100
95
20 % PP 6102 13 % PP 6102 +
13 %
7 % C 6050 M PP 1302 +
7 % C 6050 M
13 %
20 % PP 6102 +
PP 1302 + 10 % C 6050 M
7 % C 6050 M

filter:
120
cold mix
14 m, 724 mesh
Dioaxine in PP
FPV
rel. Color yield
Quinacridone in PP

10.02.2010
Slide 27

Cu-Phtalocyanine in PC, PET and PA
Licowax & Ceridust used in PC-Masterbatch

17 % Cu-Phtalocyanine in PC
17 % Pigment Green 7 + 80 % PC powder + 2 % Licowax E + 1 % Ceridust 5551
highest color yield with mixture
of Licowax E & Cerdiust 5551
30
Correlated haze
25
130
lowest
correlated haze
with Ceridust 5551
20
140
120
15
110
10
100
90
80
without
3%
Licowax E
3 % Ceridust 2 % Licowax E
5551
+ 1 % Ceridust
5551
premix: cold mixing
Public: Masterbatch Presentation Part II > In Medias Res - from Practice for Practice Cu-Phtalocyanine in PC, PET and PA
3%
Licowax C
rel. Color yield in [%]
Corr. Haze
rel. color yield
10.02.2010
Slide 29
Licowax & Ceridust used in PC-Masterbatch

17 % Cu-Phtalocyanine in PC
Ultrafine sections
of granules, thickness 60-80 [nm]; cutter type Ultracut E

(sample preparation by German manufacturer) sample preparation
- TEM photographs of polycarbonate samples -
No wax
(colour yield = 100 %)
3 % Licowax E
(colour yield =117 %)
Magnification:
4000x
2 % Licowax E
1 % Ceridust 5551
(colour yield = 131 %)
10.02.2010
Slide 30
Licolub & Ceridust used in PET-Masterbatch

30 % Cu-Phtalocyanine in PET
30 % Pigment Green 7 + 69-65 % PET milled + 2 % Licolub WE 4 + 1 % Ceridust 5551
highest color yield with mixture
140
of Licolub WE 4 & Cerdiust 5551
30
25
130
20
120
15
110
lowest FPV
with 5% Licolub WE 4
10
5
0
90
80
1 % Licolub
WE 4
filter:
100
3 % Licolub
WE 4
5 % Licolub
WE 4
premix: cold mixing
2 % Licolub
WE 4 + 1 %
Ceridust 5551
FPV
rel. color yield
14 m, 724 mesh
10.02.2010
Slide 31
Licolub & Ceridust used in PA-Masterbatch

30 % Cu-Phtalocyanine in PA
30 % Pigment Blue 15.3 + 67 % (PA) Aquamid AQ 500 milled + 3 % Ceridust 5551
8
114
7
6
109
5
4
104
3
2
99
1
0
94
without
wax
3%
Licolub
WE 4

filter:
3%
3%
3%
3%
3%
3%
Licolub Licocene Licowax E Ceridust Ceridust Ceridust
CE 2
PE MA
9615
8020
5551
4221
premix: cold mixing
FPV
rel. color yield
14 m, 724 mesh
10.02.2010
Slide 32
Summary
Summary
Ceridust and Licocene
products, which meet your demands and bring your ideas in form
Increased demands like

Economical processing and cost compensation
Stable production process and constant quality
always a
Fully compatible products for selected plastics
step ahead
Reduction of the agglomerates
with:
Reduction in screen filter blockage
Ceridust
Reduction of specks, spots and surface irregularities
Licocene
Reduction in number of extrusions
Public: Masterbatch Presentation Part II > Summary

10.02.2010
Slide 34
Summary
High quality masterbatches are achievable by the use of

Well defined waxes:
Licowax, Licolub, Licomont
Micronized waxes (particle: < 0,025 mm) :
Ceridust
Metallocene waxes:
Finis
Thank you
Questions?
Licocene
Hermann Diem, Feb. 2009
Public: Masterbatch Presentation Part II > Summary

10.02.2010
Slide 35
Back-up
The Licocene PP-Range

Technical Data
Public: Masterbatch Presentation Part II > Back-up

10.02.2010
Slide 37
The Licocene PE-Range

Technical Data

10.02.2010
Slide 38
The Licocene Modified Range

Technical Data

10.02.2010
Slide 39
The Licocene PP Range

Viscosity vs. Temperature
Licocene PP 1502 and 2602

40.00 0
visc. [mPas]
m P a s
36.00 0
34.00 0
32.00 0
30.00 0
28.00 0
26.00 0
24.00 0
PP 2602
22.00 0
20.00 0
PP 3502
PP 1502
18.00 0
16.00 0
14.00 0
12.00 0
10.00 0
8 .00 0
6 .00 0
4 .00 0
2 .00 0
80
90
100
110
120
130
140
150
16 0
170
180
Temp. [C]
10.02.2010
Slide 40
The Ceridust Range

Physical Data
product
description
acid value
density
drop point
paticle size
[mg/KOH/g]
[g/cm]
[C]
d50 [m]
Ceridust 130
PE-wax
~0,97
~125
~13
Ceridust 3615
PE-wax
~0,97
~125
~7
Ceridust 3620
PE-wax
~0,97
~125
~8
Ceridust 3715
polar modified PE-wax
2-5
~0,97
~125
~8
Ceridust 3910
amide wax
5-8
~1,0
~142
~6
Ceridust 5551
partly saponified ester of

montanic acids
13 - 18
~1,1
~96
~8
PP-wax
<1
~0,9
~145
< 20 (d100)
TP Ceridust 6050 M

10.02.2010
Slide 41

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Public

Clariant Waxes for

Ceridust & Licocene for color preparation

Public: Masterbatch Presentation Part II

Wax-Types Used in Masterbatch

Licocene PP 6102 FG,

Licocene PP 6102 FG,

Public: Masterbatch Presentation Part II > Base Information on Clariant Waxes

optimized production process and formula with

increased pigment load from 25 % to 50 %

better dispersion ability by lower content of

the same filter value is achieved,

5 - 10 % higher tensile strength,

excellent price-performance ratio due to

oustanding technical performance in high

focused on Ceridust & Licocene

Wax-Types Used in Masterbatch

superior filter value and color strength at the

highly efficient dispersion agent for film and PP

source and full version available:

Teamroom Licocene grades for plastic application

focused on Ceridust & Licocene

The Clariant Wax Range

Licowax PED 191

Liocwax PED 521

Licomont CaV 102

Licomont NaV 101

focused on Ceridust & Licocene

Clariant Wax used for Color Preparations

Licowax PED 191

Liocwax PED 521

Legal status of waxes from Clariant

is listed in DA 8250 E_11/06

focused on Ceridust & Licocene

The Licocene Range

*Licocene used in masterbatch

focused on Ceridust & Licocene

The Ceridust Range

Legal status of waxes from Clariant

Public: Masterbatch Presentation Part II > Base Information on Clariant Waxes

focused on Ceridust & Licocene

Influence of Particle Size and Amount of Wax

decrease of filter pressure value (FPV) due to

finer particle size and higher amount of wax

filter value: DIN-EN 13900-5

Public: Masterbatch Presentation Part II > Base Information on Clariant Waxes

15% PE 520 + 20% PE 520 +

premix: cold mixing

In Medias Res from Practice for Practice

Licocene PP for Monoazo-Pigments

filter value: DIN-EN 13900-5

rel. Color yield [%]

40 % Pigment Red 170 + 30 % PP HG 245 (Borealis) + 30 % Licocene PP 6102

Filter pressure value (FPV) in [bar/g]

Licocene & Ceridust for Monoazo-Pigments

Filter pressure value (FPV) in [bar/g]

filter value: DIN-EN 13900-5

rel. Color yield [%]

premix: hot mixing

Ceridust for Monoazo-Pigments

filter value: DIN-EN 13900-5

20% Licowax 30% Licowax 20% PE 520 + 30% PE 520 +

rel. Color yield [%]